Neutrons have many extraordinary properties, including no overall charge, highly sensitive to light elements like hydrogen and carbon, magnetic moment, and power of polarization, etc. All these characteristics make them excellent probes of materials, providing details about the structure and motion of atoms that cannot be easily obtained with other research techniques. Neutron reflectometry (NR), a neutron scattering technique, is a powerful tool to examine surface and interfacial structures of thin films in a non-destructive and non-invasive fashion. The Liquids Reflectometer (LR) at the Spallation Neutron Source at Oak Ridge National Laboratory measures specular neutron reflectivity in a horizontal sample geometry, and tracks changes of layer thickness, scattering length density, and roughness as a function of depth. LR provides valuable information over a wide variety of scientific and technological applications, such as, interfacial reactions in energy storage materials, phase separation in polymer films, surfactants at interfaces, biological membranes in intermolecular interaction, protein adsorption, and so on. The exceptional sample environment at LR offers the capability to conduct in situ electrochemistry to probe the morphological and structural changes of solid/liquid interfaces during operation as a function of chemical and electrochemical gradients over time. Furthermore, event mode data collection at LR can be carried out continuously over a reduced Q range and binned into 60-second intervals. The improved time resolution of the NR measurement can help elucidate the kinetic behavior of surface/interfaces under dynamic conditions and bring a unique perspective to equilibrium studies. A specific example of applications in electrochemically modulated separation for water remediation by using in situ/operando neutron reflectometry will be presented. The example study sheds light on fundamental understanding of selectivity mechanisms at electroactive interfaces, with direct benefits to the water separations research field. In addition to neutron techniques, some complementary capabilities for surface chemistry and electrochemistry available at both user facilities (Center for Nanophase Materials Sciences and Neutron Scattering Division) will also be outlined. Together, they will play a key role in creating new, and more efficient systems through rationally design of the structure and operating conditions.
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