AbstractIn the practical use of rewritable holographic stereograms, azobenzene‐functionalized polymers with high diffraction efficiency, fast response time, preservation stability, rewritability, and optical transparency capabilities are of extreme importance. Two novel azobenzene‐functionalized copolymers consisting of a 3‐[(4‐cyanophenyl)azo]‐9H‐carbazole‐9‐ethyl acrylate (acrylate monomer with CACzE) with methyl methacrylate (MMA) (poly(CACzE‐MMA)) and an ethyl methacrylate, EMA (poly(CACzE‐EMA)) are synthesized. Their holographic properties are evaluated through Raman–Nath diffraction characteristics, angular dependence of absorbance, and polarized Raman spectra. Between them, a material with the most excellent characteristics is a poly(CACzE‐MMA)/CACzE (50/15 wt%) composite. As a result, a first‐order diffraction efficiency (η1 ), grating formation speed (response time) (τ ), and retention ratios (R300s% and R50day%) in the poly(CACzE‐MMA)/CACzE (50/15 wt%) composite show 31.2%, 2.0 s, 100%, and 80%, respectively, in which a dichroism degree of 64.2° and refractive index modulation Δn of 0.00801 are achieved. Additionally, the holographic stereogram obtained with the poly(CACzE‐MMA)/CACzE (50/15 wt%) composite can be refreshed to its original state by heat treatment. The holographic properties of the poly(CACzE‐MMA)/CACzE (50/15 wt%) composite will be a contribution to the application of updatable holographic stereograms.
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