Hollow Cathode Assembly Research Articles

Reactive magnetron sputtering of N-doped carbon thin films on quartz glass for transmission photocathode applications

N-doped carbon thin films were deposited on a silicon substrate and quartz glass by RF reactive magnetron sputtering using a carbon target and an Ar+N2 gas mixture. During the magnetron sputtering, the substrate holder temperatures was kept at 800 °C. The carbon film thickness on the silicon substrate was about 70 nm, while on the quartz glass it was in the range 15 nm – 60 nm. The elemental concentration in the films was determined by RBS and ERD. Raman spectroscopy was used to evaluate the intensity ratios ID/IG of the D and G peaks of the carbon films. The transmission photocathodes prepared were placed in the hollow-cathode assembly of a Pierce-structure DC gun to produce photoelectrons. The quantum efficiency (QE) was calculated from the laser energy and cathode charge measured. The properties of the transmission photocathodes based on semitransparent N-doped carbon thin films on quartz glass and their potential for application in DC gun technology are discussed.

Compact lanthanum hexaboride hollow cathode

A compact lanthanum hexaboride hollow cathode has been developed for space applications where size and mass are important and research and industrial applications where access for implementation might be limited. The cathode design features a refractory metal cathode tube that is easily manufactured, mechanically captured orifice and end plates to eliminate expensive e-beam welding, graphite sleeves to provide a diffusion boundary to protect the LaB6 insert from chemical reactions with the refractory metal tube, and several heater designs to provide long life. The compact LaB(6) hollow cathode assembly including emitter, support tube, heater, and keeper electrode is less than 2 cm in diameter and has been fabricated in lengths of 6-15 cm for different applications. The cathode has been operated continuously at discharge currents of 5-60 A in xenon. Slightly larger diameter versions of this design have operated at up to 100 A of discharge current.

Exploitation of the hollow cathode effect for sensitivity enhancement of Grimm-type DC glow discharge optical emission spectroscopy

The hollow cathode (HC) effect was investigated in non-cooled 15 mm deep drilled flat metallic analytical samples that were easy to prepare. The deep cavity used (“complete HC” in contrast to “recessed HC” with 2–3 mm deep cavity) intensified the HC effect notably and therefore distinctly improved the detection power of the common GD-OES with planar cathodes. A signal enhancement of up to a factor of 150, not reported earlier, in comparison with flat conventional samples was achieved. A better separation of the analytical lines from spectral interferences was observed when the HC assembly was applied. Additionally, an effect of strongly enhanced intensities of atomic lines and somewhat decreased intensities of ionic lines was detected in the case of HC in comparison to usual planar cathodes. The investigations were carried out with samples of copper, steel and zinc matrices using both the same and individually optimised glow discharge (GD) electrical parameters.

Laser-induced fluorescence characterization of ions emitted from hollow cathodes

Laser-induced fluorescence (LIF) was used to measure the mean and variance of the velocity distribution of xenon ions emitted from two hollow cathode assemblies operating at low power. High-energy ions detected in plume-mode and spot-mode operation are consistent with the potential-hill model of high-energy ion production. The distributions of velocities were modeled, yielding temperatures on the order of a few electronvolts in plume mode and 1 eV in spot mode. The LIF of neutral xenon atoms in the plumes indicated thermal temperatures significantly less than the temperatures associated with the ion velocity distributions.

A simple demountable hollow-cathode tube for the analysis of solutions: Application to lead in biological materials

A simple, demountable hollow-cathode excitation source for the analysis of solutions is described which allows water cooling, high emission intensity, discharge shielding, and extreme ease of operation. A graphite hollow-cathode assembly is shown which is particularly suitable for the analysis of acidic digestion residues. A high salt concentration can be used with the tube, allowing a lithium and potassium carrier salt-spectroscopic buffer which controls effects caused by matrix variation. Analyses of lead in biological materials are used to demonstrate the capabilities of the tube.