An experimental setup was established to analyze the performance of a spiral wound heat exchanger applied to natural gas liquefaction. The boiling behavior of subcooled flow over a small diameter, non-round, horizontal tube was investigated using n-pentane as the working fluid. The effects of flow rate, heat flux, fluid inlet temperature and tube spacing on heat transfer performance were investigated. Based on the experimental conditions of this study, the results indicate that: (1) raising the Reynolds number can effectively enhance the heat transfer coefficient; (2) the increasing in heat flux also has a positive impact on heat transfer performance, but the extent of which is related to the Reynolds number; (3) increasing the tube spacing resulted in higher heat transfer coefficients; (4) under the same working conditions, the heat transfer performance of non-round tubes is higher than that of round tubes; (5) correlation equations were developed to calculate the Nu for smooth, round, elliptical, and egg-shaped tubes. The predictions made by these correlation equations deviated by less than 10 % from the experimental results for the entirety of the experimental conditions.