Water scarcity is a current concern and a future problem. Air-water harvesting (AWH) is a novel proposed solution to provide enough water for human-being's needs especially in remote areas. However, the sorbent material is one of the challenging components of these systems. Generally, a proper sorbent must have a high water uptake capacity, a low regeneration temperature and an easy replacement structure, suitable to deploy in the bed. Here we synthesized three active carbon felt composites with a layer structure and analyzed their potential for being used in AWH systems. The performance of these ACFs composites concerning three different salts was investigated. Experimental results showed that the highest capacity is 2.9 g water per g sorbent at 70% of RH without any leakage. Also, pore parameters, non-equilibrium and equilibrium adsorption, regeneration temperature, recyclability and thermal diffusivity of samples were tested. The thermodynamic cycle of the system is studied, and a three-phase sorption cycle is proposed in this study. The detailed analysis reveals that the presence of the combined use of adsorption-absorption process can improve the sorption capacity extensively. The experimental and theoretical studies proved that these composites are very promising materials for water harvesting applications. To demonstrate these materials capability, a prototype is proposed which adopts these materials as its desiccant. This small prototype automatically could harvest 1.51 g of fresh water per cycle per g of sorbent at RH of 70%, without any human involvement.