The scattering spectrum of orthorhombic TlI has been measured at 2 K under the resonant excitation around the first exciton energy of 2.87 eV. The spectrum is composed of multiple LO phonon lines showing a characteristic intensity alternation as was found in indium halides. The dependence of intensities of the LO lines on the incident photon energy has been investigated. The LO lines show a resonant enhancement in intensity with 2 s and higher exciton states as well as with the 1 s exciton state. It is also found that some of the excitons relaxed to the band bottom are transformed into photons with the emission of 2LO phonons rather than 1LO phonon.
Read full abstract