Higher Energy Research Articles

Galvanic Corrosion Behavior of the X80 Steel Welded Joint

Wire beam electrode techniques and classical electrochemical techniques were used to investigate the effect of the area ratio of each part of the welded joint on the galvanic corrosion behavior. The results showed that the order of the corrosion current density of the different regions in the simulated X80 steel welded joint was as follows: coarse-grained heat-affected zone > fine-grained heat-affected zone > intercritical heat-affected zone > base metal > weld metal. As the area ratio of weld metal increased, the galvanic potential shifted positively, the maximum anode galvanic current density increased and the main anode galvanic effect increased. On the other hand, as the area ratio of the base metal and the heat-affected zone decreased, the coupled potential shifted negatively and the maximum anode galvanic current density decreased. The galvanic corrosion intensity of the simulated X80 steel welded joint increased as the area ratio of the weld metal decreased and increased as the area ratio of the heat-affected zone and base metal increased. To enhance corrosion resistance, it is advisable to choose a shape with a larger groove to increase the WM area in the welded joint. Additionally, selecting a welding method with lower heat input and a higher energy density can help reduce the HAZ area in the welded joint.

The variable water temperature control strategy of the air-source heat pump compatible with floor heating system for an apartment

The adjustment of operating parameters and control strategies of an air-source heat pump (ASHP) heating system is of great significance for achieving system energy-saving. Ordinary constant supply water temperature setting could lead to higher energy consumption without concerning the changing of outdoor ambient temperature. In order to save the operational cost, we proposed a variable water temperature control strategy based on the hourly outdoor temperatures. In combination of TRNSYS simulation and experimental study, the system performance under variable supply water temperature control strategy were investigated and compared with four-period-adjusted supply water strategy and constant supply water strategy. The results showed that compared to operating at a constant supply water temperature of 35 °C, the daily power consumption of the system decreased by 56.7 % and 29.5 %, respectively under the typical high and low ambient temperature circumstances. Relative to operation with four-period-adjusted supply water temperature, the power consumption of the system decreased by 53.6 % and 24.6 %, respectively. Moreover, the variable water temperature control strategy could improve the coefficient of performance (COP) of the heating system. The control method proposed in this study would provide design reference for equipment manufacturers and help users to efficiently operate the ASHP unit.

Nitrergic inhibition of sympathetic arteriolar constrictions in the female rodent urethra.

During the urine storage phase, tonically contracting urethral musculature would have a higher energy consumption than bladder muscle that develops phasic contractions. However, ischaemic dysfunction is less prevalent in the urethra than in the bladder, suggesting that urethral vasculature has intrinsic properties ensuring an adequate blood supply. Diameter changes in rat or mouse urethral arterioles were measured using a video-tracking system. Intercellular Ca2+ dynamics in arteriolar smooth muscle (SMCs) and endothelial cells were visualised using NG2- and parvalbumin-GCaMP6 mice, respectively. Fluorescence immunohistochemistry was used to visualise the perivascular innervation. In rat urethral arterioles, sympathetic vasoconstrictions were predominantly suppressed by α,β-methylene ATP (10μM) but not prazosin (1μM). Tadalafil (100nM), a PDE5 inhibitor, diminished the vasoconstrictions in a manner reversed by N-ω-propyl-l-arginine hydrochloride (l-NPA, 1μM), a neuronal NO synthesis (nNOS) inhibitor. Vesicular acetylcholine transporter immunoreactive perivascular nerve fibres co-expressing nNOS were intertwined with tyrosine hydroxylase immunoreactive sympathetic nerve fibres. In phenylephrine (1μM) pre-constricted rat or mouse urethral arterioles, nerve-evoked vasodilatations or transient SMC Ca2+ reductions were largely diminished by l-nitroarginine (l-NA, 10μM), a broad-spectrum NOS inhibitor, but not by l-NPA. The CGRP receptor antagonist BIBN-4096 (1μM) shortened the vasodilatory responses, while atropine (1μM) abolished the l-NA-resistant transient vasodilatory responses. Nerve-evoked endothelial Ca2+ transients were abolished by atropine plus guanethidine (10μM), indicating its neurotransmitter origin and absence of non-adrenergic non-cholinergic endothelial NO release. In urethral arterioles, NO released from parasympathetic nerves counteracts sympathetic vasoconstrictions pre- and post-synaptically to restrict arteriolar contractility. KEY POINTS: Despite a higher energy consumption of the urethral musculature than the bladder detrusor muscle, ischaemic dysfunction of the urethra is less prevalent than that of the bladder. In the urethral arterioles, sympathetic vasoconstrictions are predominately mediated by ATP, not noradrenaline. NO released from parasympathetic nerves counteracts sympathetic vasoconstrictions by its pre-synaptic inhibition of sympathetic transmission as well as post-synaptic arteriolar smooth muscle relaxation. Acetylcholine released from parasympathetic nerves contributes to endothelium-dependent, transient vasodilatations, while CGRP released from sensory nerves prolongs NO-mediated vasodilatations. PDE5 inhibitors could be beneficial to maintain and/or improve urethral blood supply and in turn the volume and contractility of urethral musculature.

Design Thinking in Lighting Design to Meet User Needs

In the age of noticing the adverse effects of our activities on the climate, we pay more and more attention to designing sustainable solutions. Assumptions made during such sustainable designs often do not fulfil user needs. Therefore, we frequently encounter discrepancies, such as higher energy consumption and user modifications in the building systems compared to the design and use stages. To mitigate these problems in the lighting design context, the author describes the proposed lighting design method based on the Design Thinking methodology and concerns the commonly applied basic lighting design process. As an example design, an office room interior and lighting design are presented using the Design Thinking method described by the author. The utilised method allowed us to learn about problems that are only sometimes typical for offices and enter them into the design scope. The article contains a detailed analysis and comparison of normative requirements with users’ needs, collected from four room users and six guests. The discrepancies between the sustainable design and use stages presented in the article can be considered reduced, and users’ interference in the operation of devices will be eliminated due to meeting users’ needs and thus achieving sustainable goals.

Additive Manufacturing of Zn‐Doped ZrO2 Architectures

Tailoring the properties of microfabricated ceramics through doping can unlock new avenues for the additive manufacturing (AM) of advanced 3D architectures. The first step to achieving optical functionality is to control material morphology, crystallinity, and defects associated with the composition of the produced AM architecture and dopants. For this purpose, AM of zinc‐doped zirconia (ZrO2:Zn) 3D microarchitectures is proposed using two‐photon lithography and tailor‐made resin. It is found that Zn doping modulates ZrO2:Zn architecture crystallinity and optical properties. The modification of optical properties through Zn doping is confirmed by micro‐photoluminescence, where higher energy photon emission is observed due to the promotion of oxygen vacancies and surface defects. It is also shown that Zn 2.5% and 5 wt% stabilizes the monoclinic ZrO2 at a lower temperature than in the case of undoped ZrO2. Furthermore, there is evidence that Zn tends to form ZnO wurtzite, which is later sublimated. The findings provide a promising route to understand the role of defects ZrO2:Zn optically upon annealing.

Gaining More Insights from Synchrotron-Based X-ray Spectroscopy for Alkali Ion Rechargeable Batteries.

Alkali ion rechargeable batteries play a significant part in portable electronic devices and electronic vehicles. The rapid development of renewable energy technology nowadays demands batteries with even higher energy density for grid storage. To fulfill such demand, extensive research efforts have been devoted to optimizing electrochemical properties as well as developing novel energy storage schemes and designing new systems. In the investigation process, synchrotron-based X-ray spectroscopy plays a vital role in investigating the detailed degradation mechanism and developing novel energy storage schemes. Herein, we critically review the applications of synchrotron-based X-ray spectroscopy in battery research in recent years. This review begins with a discussion of the different scientific issues in alkali ion rechargeable batteries within various time and space scales. Subsequently, the principle of synchrotron-based X-ray spectroscopy is introduced, and the characteristics of various characterization techniques are summarized and compared. Typical application cases of synchrotron-based X-ray spectroscopy are then introduced into battery investigations. The final part presents perspectives in the development direction of both alkali ion rechargeable battery systems and synchrotron-based X-ray spectroscopy in the future.

Second harmonic generation in Harmonic-Gaussian asymmetric double quantum well: effect of magnetic and intense laser fields

We have theoretically analyzed the effects of externally applied fields (magnetic and intense laser) as well as various structural parameters such as well width, barrier width, barrier height, and structural asymmetry on the second harmonic generation (SHG) coefficients of GaAs/Al0.3Ga0.7As Harmonic-Gaussian asymmetric double quantum wells (QW). The time-independent Schrödinger equation was solved using the diagonalization method and effective mass approximation to obtain the energy eigenvalues and eigenfunctions of the structure. An expression derived within the compact density matrix approach has been used to evaluate the second harmonic generation (SHG) coefficient. Our numerical results indicate that increasing the magnitude of the magnetic (intense laser) field causes the peak positions of SHG to shift towards higher energy regions/blue (lower energy regions/red). On the other hand, as the structural parameters A1 and A2 ( k and z0 ) increase, the peak positions of the SHG coefficients exhibit a shift towards higher energy regions/blue (lower energy regions/red). We expect that the results of our study will contribute to the development of new optoelectronic devices based on the Harmonic-Gaussian asymmetric double quantum well structure.

Magnetic impurity states of a Fermi system in a local magnetic field

The ultracold atomic Fermi gas provides a flexible and controllable experimental platform for exploring magnetic impurity states. In this study, we theoretically examine the magnetic impurity states in a Fermi system with spin-1/2 and spin-3/2 under a local magnetic field. Firstly, the spin-1/2 impurity system contains three types of magnetic solutions. One type magnetic solution with higher energy can be regarded as the result of induced magnetization of a trivial solution, while the other two types magnetic solutions with lower energy can be understood as the results of Zeeman splitting of nontrivial solutions with double degeneracy. Notably, the magnetic solution corresponding to the spin state parallel to the Zeeman magnetic field is always the most stable in terms of the energy. Secondly, we extend the idea of studying spin-1/2 impurity to spin-3/2 impurity, where the half-filled state of impurity atoms is calculated. We found that four types of magnetic solutions at zero magnetic field were split into four, six, four, and twelve new magnetic solutions in the presence of a Zeeman magnetic field, respectively. We obtained that the magnetic solution corresponding to the spin state parallel to the magnetic field is the most stable, and its energy is lower than that of the corresponding magnetic solution at zero magnetic field. Therefore, the introduction of a local magnetic field is beneficial for the formation of magnetic impurity states. Finally, the calculated data illustrate that the Anderson impurity model we adopt exhibits invariance under the combined transformations of spin-flip and particle–hole.

Comparative Study on Energy Yield of Tunnel Oxide Passivated Contact (TOPCon) and Passivated Emitter and Rear Contact (PERC) Solar Cells and Analysis of Optimal Installation Method for Vertical Photovoltaics

AbstractPhotovoltaic (PV) installations have traditionally relied on a conventional south-facing orientation, which maximizes energy production at noon but has lower energy generation in the morning and afternoon. Vertical photovoltaic (VPV) systems have emerged as promising alternatives to address this inconsistency. Vertical photovoltaic systems can enhance energy generation by facing east in the morning and west in the afternoon. We compared the performance of n-tunnel oxide passivated contact (n-TOPCon) and p-passivated emitter and rear contact (p-PERC) cells in vertical photovoltaic systems to determine whether the optimal installation direction of bifacial vertical photovoltaics is east or west. Our findings indicated that n-TOPCon cells exhibited higher energy yields than p-PERC cells, with a difference of approximately 8%, attributed to the superior bifaciality and lower temperature coefficient of power of n-TOPCon. Additionally, the energy yield was higher for n-TOPCon modules when the front faced east, whereas the PERC modules performed better with a west-facing front. This contributes to the knowledge of the factors for energy production in vertical photovoltaic systems and the optimization of installation configurations.

Preparation of core-shell NiMnB/rGO composite electrodes and their application in hybrid supercapacitors

The rapid advancement of science and technology has led to the development of electronic devices that require higher energy storage capacities. Because of their greater energy as well as power density capabilities, hybrid supercapacitors offer an answer to the problems that result from the limitations of both supercapacitors and batteries when it comes to power densities and energy density. Borate ion-functionalized nickel manganese hydroxide nanoparticles (denoted as NiMnB) were prepared by a simple chemical reduction method, and novel complexes were obtained by growing NiMnB with a core-shell structure on reduced graphene oxide (rGO). The NiMnB inner core facilitates electron transport, while the borate/metal borate shell layer on the outer layer aids in OH- absorption. Additionally, rGO integrates the dispersed nanoparticles, resulting in a comprehensive conductive system. This design optimizes the electrochemical performance of NiMn-based electrodes. The specific capacitance of the NiMnB/rGO-16 electrode was 916 F g−1 when tested at a current density of 1 A g−1. NiMnB/rGO-16 was used as the positive electrode and activated carbon (AC) as the negative electrode assembled the hybrid supercapacitor. It showed strong cycling stability and an energy density of 50.2 Wh kg−1.

Bioinspired binary-site catalysts for novel urea-assisted Zn-air battery: A transfer station between renewable energy and hydrogen

The slow reaction kinetics of oxygen electrode is the bottleneck restricting the development of rechargeable Zn-air batteries (ZABs). In order to further improve the energy conversion efficiency of ZABs, a novel urea-assisted ZAB system was proposed by replacing oxygen evolution reaction (OER) with urea oxidation reaction (UOR) with lower theoretical thermodynamic potential. Inspired by nature’s ingenious structure-function, a “leaf-branch” CoNi@NCNTs-LDH/CC binary-site electrocatalyst was designed for the above system, where spatially separated branches and leaves serve as the main active sites for ORR and UOR, respectively. A build-in electric field from CoNi-LDH to CoNi@NCNTs is formed at the interface of the composite, which plays a command effect, effectively triggering the accumulation of O2 and urea reactants around the CoNi and LDH sites, respectively, and thus improving the efficiency of both ORR and UOR reactions. Based on that, a conceptual urea-assisted rechargeable ZAB is demonstrated to have significantly decreased charging voltage, higher energy conversion efficiency (74.6 %) compared with the conventional ZAB, as well as high urea elimination rates. Considering the urea-assisted ZAB with high energy conversion efficiency and wastewater treatment versatility as an energy transfer station applied in a high value-added agricultural system, uninterrupted hydrogen production and wastewater treatment of agricultural wastewater can be simultaneously achieved using sustainable energy sources.

Early Cretaceous bivalves of the Romualdo Formation, Araripe Basin, northeastern Brazil

The fossil-rich Romualdo Formation (late Aptian/early Albian), Araripe Basin, northeastern Brazil, contains world-renowned Fossillagerstätten characterized by exceptionally preserved fossils. Macroinvertebrates in this formation are primarily represented by mollusks, echinoids, and decapod crustaceans. Mollusk shells are abundant in certain stratigraphic intervals, forming coquinas or shell pavements. Despite recent advances in our understanding of the taxonomy of certain groups, comprehensive taxonomic studies are lacking for almost the entire bivalve fauna. Therefore, a detailed taxonomic analysis is presented here. The described bivalves include four new genera (Araripenomia, Ciceromya, Inversatella, Australoeocallista), and six new species (Araripenomia infirma, Inversatella cearensis, Ciceromya edentulosa, Australoeocallista juazeiroi, Legumen kaririense, and Corbulomima delicata), in addition to Musculus maroimensis, Crassatella maroimensis, “Myrtea” sp. and “Tellina” sp. This bivalve fauna mainly consists of cosmopolitan and endemic brackish/marine genera, with Tethyan affinities. The fauna is not homogeneously distributed in the sedimentary succession of the Romualdo Formation, but is constrained to the third order highstand systems tract. Bivalves recorded from muddy facies are strongly dominated by infaunal and semi-infaunal suspension feeders. Assemblages of the sand-dominated facies, with dense shell accumulations of semi-infaunal to epifaunal byssate and infaunal suspension feeders, were formed under shallow, higher energy conditions. Despite the degree of generic endemicity, the mytilids, anomiids, crassateliids, astartids, tellinids, and corbulids are related to the bivalve fauna of the Early Cretaceous Riachuelo Formation of the Sergipe-Alagoas Basin, as previously demonstrated for the bakevelliids and echinoids. Indeed, the Romualdo bivalve fauna is, in part, a modified and impoverished brackish/marine fauna of the Riachuelo Formation.

Bio-thermal response during laser haemorrhoidoplasty: an exclusive analytical and numerical approach for theoretical investigation.

Haemorrhoidal disease is identified by declension of the inflamed and bleeding of vascular tissues of the anal canal. Traditionally, haemorrhoids are associated with chronicconstipation and the most common symptoms are irritation in anus region, pain and discomfort, swelling around anus, tender lumps around the anus and rectal bleeding (depending upon the grade of haemorrhoid). Among the several conventional treatment procedures (commonly mentioned as, rubber band litigation, sclerotherapy and electrotherapy), laser haemorrhoidoplasty is an out-patient and less-invasive laparoscopic procedure. From literature survey it has been observed that an exclusive theoretical model depicting the impact of 1064nm wavelength laser wave on living tissues subjected to haemorrhoid therapy is not available. This research work is a pioneering attempt to develop a theoretical study attributing specifically on laser therapy of haemorrhoid treatment based on Pennes' biological heat transfer model. The corresponding mathematical model has been solved by analytical method to establish thermal response of tissue during the treatment and also the same has been solved a numerical approach based on finite difference method to validate the feasibility of former method due to unavailability of any theoretical model. Impact of variation of blood perfusion term, laser pulse time and optical penetration depth on temperature response of skin tissue is captured. The tissue temperature decreases along with time of laser exposure with increasing the blood perfusion rate as it carries away large amount of heat. With the increase in laser pulse time, tissue temperature declines due to shorter pulse time resulting in higher energy consumed by electrons. The research outcome is successfully validated with less than 1% of error observed between the appointed analytical and numerical scheme.

In-band dual-polarization RCS reduction of waveguide slot array antenna integrated with AMC and PEC chessboard structure

An in-band low radar cross section (RCS) waveguide slot array antenna (WSAA) is proposed by using a chessboard structure composed of artificial magnetic conductor (AMC) and perfect electric conductor (PEC), which serves as the antenna radiator. The method for RCS reduction is the reflection energy cancellation. Standing wave array is used to achieve higher energy efficiency and more compact antenna structure. Experimental results show that the in-band monostatic RCS is sufficiently reduced with the chessboard structure application for both co- and cross-polarized incident waves, where 10-dB RCS compression is realized among the frequency range of 9.7–9.91 GHz for co-polarization and 9.5–9.85 GHz for cross-polarization with maximum RCS reductions of −13.3 dB and −11.9 dB, respectively. Meanwhile, the designed WSAA maintains the high gain characteristics of the original WSAA. The paper provides a simple, practical and effective strategy for stable RCS compression in the operation band of waveguide antenna array, which has potential applications in stealth platforms.

Performance investigation of n-type PERT bifacial solar photovoltaic module installed at different elevations

In recent years, bifacial solar photovoltaic (bPV) cells have gained much interest in the solar PV market as they produce additional electrical energy at a marginally higher cost. Their ability to generate additional energy mainly depends on their rear side response. Module elevation, albedo, row spacing, and frame structure are the few factors that affect its rear side response and thus the overall efficiency. In this research work, the performance of a bPV module installed at the geographical location of latitude 9.673° N, and longitude 77.964° E is analyzed with different module elevations. Module elevation is one of the key installation parameters that causes the non-uniformity in the rear side irradiance. At low elevations, the non-uniformity is higher and starts reducing with the increase in elevation, reaching a negligible value at greater elevations. The experimental results showed that for the module elevation of above 1m, the non-uniformity is reduced to 5 % from 12 % at 0.25m. The peak power output for the elevation of above 1m is around 375W at which the bifaciality factor is about 25 %. Overall, it is observed that the bifacial solar PV module at a higher optimum elevation produces lesser non-uniformity and a higher energy yield.

Hidden Negative Issues and Possible Solutions for Advancing the Development of High-Energy-Density in Lithium Batteries: A Review.

This review article discusses the hidden or often overlooked negative issues of large-capacity cathodes, high-voltage systems, concentrated electrolytes, and reversible lithium metal electrodes in high-energy-density lithium batteries and provides some feasible solutions that can realize the construction of realistic rechargeable batteries with higher energy densities. Similar objective discussion of the negative aspects of lithium-air batteries, multi-valent shuttles, anion shuttles, sulfur cathode systems, and all-solid ceramic batteries can help fabricate more realistic batteries.

Effect of mutual interaction of two cosh-Gaussian laser beams on upper hybrid wave excitation and subsequent electron acceleration

This paper presents the excitation of an upper hybrid wave by resonant excitation of two intense cosh-Gaussian laser beams of frequencies ω 1 and ω 2 in a collisionless plasma. The excited upper hybrid wave is used for electron acceleration which accelerates the electrons towards higher energy. The acceleration of electrons through an excited upper hybrid wave has also been studied. This study has been analysed using the Wentzel Kramers Brillouin (WKB) and paraxial-ray approximation, where relativistic and ponderomotive nonlinearities are employed together. Analytical expressions for the beam width/intensity of the cosh-Gaussian laser beams, the electric field/power of the excited upper hybrid wave and the electron acceleration have been derived, which have been solved numerically for an established set of laser and plasma parameters. The results are also compared to relativistic nonlinearity. It has been observed that the mutual interaction of two cosh-Gaussian laser beams at a difference frequency significantly affects the self-focusing of each beam, leading to an increase in the amplitude/power of the upper hybrid wave as well as energy gain by the electrons. The effect of the magnetic field (ωc) and decentered parameter (b) on the power of the excited upper hybrid wave and the energy gain by the electrons are also explored. The results show that the power of upper hybrid wave and the energy gain by the electrons increase at higher values ​​of b and ω c.

Comparing Pr3+ and Nd3+ for deactivating the Er3+: 4I13/2 level in lanthanum titanate glass

Erbium lanthanum titanate glasses were prepared by levitation melting for the spectroscopic study of ways to promote the mid-infrared fluorescence. Two series of heavily erbium doped glasses (15 wt%) were prepared with the addition of either Pr3+ or Nd3+ in amounts relative to Er3+ of 0.05, 0.1, and 0.2. Both ions quench the lower Er3+ laser level with the Pr3+ doing so more rapidly. Although high co-dopant concentrations result in higher energy transfer, as clearly evidenced in upconversion and downconversion fluorescence measurements, the mid-infrared lifetime also suffers a reduction and, therefore, a balance must be struck in the co-dopant concentration. Lifetime and spectral measurements indicate that, at a fixed relative co-dopant amount, Pr3+ is more effective than Nd3+ at removing the bottleneck of the Er3+ 4I13/2 level. Moreover, consideration of the lifetimes alongside the absorption data of the individual ions indicates that despite the large absorption cross-section of Nd3+ at 808 nm, the concentration needed to yield more absorbed power than utilizing direct 976 nm excitation of Er3+ results in unfavorable lifetimes of the mid-infrared transition. In the end, Pr3+ prevails as the superior co-dopant in terms of the effects on fluorescence lifetimes as well as potential laser system design considerations. In a unique self-doping approach, a reducing melt atmosphere of Ar instead of O2 creates a small fraction of Ti3+. In 5Er2O3-12La2O3-83TiO2 glass, the presence of Ti3+ quenches the 4I13/2 emission about 2.6 times more than the 4I11/2 when lifetimes are compared to an O2 melt environment. As an additional means of increasing the mid-infrared emission, the effect of temperature on the mid- and near- infrared lifetimes of a lightly doped lanthanum titanate composition is investigated between 77-300 K. The mid-infrared lifetime increases by ∼30% while the near-infrared lifetime increases by ∼10%, which suggests in addition to co-doping, active cooling of the gain media will further enhance performance.

Investigation of a Building with Male and Female Residents to Achieve Equality of Thermal Sensation Associated with Rational Use of Exergy and Energy

The intensive use of air conditioning systems, primarily refrigerating, to promote thermal comfort in countries such as Brazil (a hot climate country) is changing the electrical energy consumption patterns and peak demand. Even with the increased number of appliances, we must learn to consume less energy to achieve similar outcomes with higher energy efficiency. Consequently, exergy analysis is used to evaluate the quality of these energy conversion systems. Four computational human thermal models were used to assess thermal comfort conditions: one man wearing lighter clothing, one man wearing traditional office clothing, and two women in the two types of clothing. We chose these four models since the body composition and basal metabolism rates for males and females differ. In addition, the insulation of clothes influences the temperature of the thermal environment, leading to a significantly lower percentage of people being unsatisfied, from 12.8% to values close to 5%. The outputs of these occupants are used as inputs for a computational model of the room to calculate its associated thermal loads and evaluate different temperature setpoints and their effects on thermal comfort and energy consumption. Results indicate that environmental temperatures above 24 °C and below 26 °C may lead to thermal comfort conditions, depending on the occupants’ clothing. Clothing would represent a thermal resistance of 0.7 CLO for men and women (when in the luteal phase of the menstrual cycle) and 0.8 CLO for women in the follicular phase when the environment is at 25 °C. Therefore, there is a significant reduction in the compression power of the central cooling system by about 2.2% compared to 24 °C and around 8% compared to ambient temperatures around 21 °C.

Fluoroethylene Carbonate: Bis(2,2,2,) Trifluoroethyl Carbonate as High Performance Electrolyte Solvent Blend for High Voltage Application in NMC811|| Silicon Oxide‐Graphite Lithium Ion Cells

LiNixMnyCozO2 cathode materials combined with Si‐based anode materials are current state‐of‐the‐art high energy density chemistries for lithium ion batteries. Increasing the upper cut‐off voltage is an intriguing approach to achieve even higher energy density in lithium ion batteries. However, poor oxidation stability of the state‐of‐the‐art electrolytes leads to transition metal dissolution (TMD), migration, and deposition (TMDMD) on the negative electrode, followed by sudden and rapid capacity fade. Furthermore, the chemical instability of the lithium hexafluorophosphate causes hydro‐fluoric acid to develop, which targets the native SiOx layers on silicon anodes and breaks the chemical bond to the carboxymethylcellulose sodium salt binder. Herein, a fluorine‐rich electrolyte formulation consisting of lithium‐bis(fluorsulfonyl)imide with fluoroethylene carbonate (FEC): bis(2,2,2,) trifluoroethyl carbonate (BFEC) was applied in NMC811||10%SiOx‐90%graphite cells to achieve high oxidation stability and prevent TMD and deposition. Up‐to‐date, this is the premier electrochemical performance reported in literature with a capacity retention of 94.5% and 92.2% with 0.5 °C and 4.5 V upper cut‐off voltage cycling at 20 and 40 °C after 100 cycles, respectively. The post mortem analysis showed that stabilization is achieved by forming inorganic‐ and salt‐rich interphases that protect the electrolyte versus decomposition at the electrode.