Among the accessories of the dc high-temperature superconducting (HTS) power cable, a stop joint box (SJB) is an essential component for the long-distance transmission cable connections and the separation of the cooling section. The main insulating material of the SJB is a polypropylene laminated paper (PPLP), which is already generally used for dc HTS power cable. In order to separate the cooling section, an epoxy spacer is located at the center of the SJB. Due to the weakness of surface breakdown characteristics compared with that of punctual breakdown and different nature of dc electric field distribution determined by the ratio of conductivities of dielectric materials, the epoxy spacer configuration of the SJB should be carefully designed based on dc electric field analysis. In this paper, the optimum configuration of the epoxy spacer of the SJB was investigated based on dc electric field analysis. On the basis of the initial SJB model, which is already designed for the joint box of the conventional ac oil-filled power cable, a variety of improved SJB models with different epoxy spacer configurations were considered. In dc electric field simulations, the main objective was to reduce the tangential dc electric field intensity at the interface between PPLP and epoxy spacer. To find the optimum epoxy spacer configuration, a parametric sweep technique was applied, and an appropriate SJB model could be identified. However, its tangential dc electric field intensity remained still higher than that of the design criteria for the dc electric field from the experimental results. Therefore, as a novel method, a thin Kraft layer between the PPLP and the epoxy spacer was added to reduce electric field intensification. The simulation result of the newly designed insulation structure revealed the possibility of lowering the tangential electric field. Furthermore, different electrical conductivity values were applied to the additional layer instead of the original Kraft value in order to meet the critical electric field intensity. Finally, 1E-11 S/m, among those values, showed the best simulation result, which was lower than the design criteria for the dc electric field. To verify the effect of the additional layer for dc electric field mitigation, miniature SJB specimens were fabricated, and dc breakdown tests were performed using a step-by-step test method. Based on the experimental results, SJB specimens with an additional layer showed the highest breakdown strength compared with that of SJB specimens without an additional layer. Thus, the optimum configuration of SJB determined by dc electric field analysis was approved by experimental works. Consequently, these insulation design skills based on dc electric field analysis could be usefully adopted in developing the SJB of 80-kV dc HTS power cables.