High Melting Temperature Research Articles

Recent Progress of Functional Solvent-free Nanofluids: A Review.

Nanoparticles have aroused widespread interest because of their unique surface structure and nano effect, which presents novel characteristics like as sound, light, electricity, magnetism, and thermal properties. However, two critical defects have hindered their applications: (1) poor processability resulting from the high melting temperature (e.g., >1000 °C) for some inorganic nanoparticles; (2) the restriction of the nano effect caused by the easy aggregation of the nanoparticles. To solve those issues, solvent-free nanofluids (SNFs) with hard cores and flexible organic chains were successfully designed and fabricated at the beginning of the twenty-first century. The promising technology of SNFs not only solved the dispersion problem of nanomaterials but also imparted novel functionalization to nanoparticles. Up to now, many researchers have been devoted to developing diverse cores and flexible organic polymer chains to endow SNFs with particular functions, such as conductivity, fluorescence, lubricity, and so on. However, there are few review reports on the research progress in the fabrication and applications of functional SNFs. To gain a better understanding of SNFs, this paper presents an overall investigation into the development, fabrication, as well as the applications of functional SNFs.

Experimental Study on Preparation of Inorganic Fibers from Circulating Fluidized Bed Boilers Ash.

The ash generated by Circulating Fluidized Bed (CFB) boilers is featured by its looseness and porosity, low content of glassy substances, and high contents of calcium (Ca) and sulfur (S), thus resulting in a low comprehensive utilization rate. Currently, the predominant treatment approach for CFB ash and slag is stacking, which may give rise to issues like environmental pollution. In this paper, CFB ash (with a CaO content of 7.64% and an SO3 content of 1.77%) was used as the main raw material. The high-temperature melting characteristics, viscosity-temperature characteristics, and initial crystallization temperature of samples with different acidity coefficients were investigated. The final drawing temperature range of the samples was determined, and mechanical property tests were conducted on the prepared inorganic fibers. The results show that the addition of dolomite powder has a significant reducing effect on the complete liquid phase temperature. The final drawing temperatures of the samples with different acidity coefficients range as follows: 1270-1318 °C; 1272-1351 °C; 1250-1372 °C; 1280-1380 °C; 1300-1382 °C; and 1310-1384 °C. The drawing temperature of this system is slightly lower than that of basalt fibers. Based on the test results of the mechanical properties of inorganic fibers, the Young's modulus of the inorganic fibers prepared through the experiment lies between 55 GPa and 74 GPa, which basically meets the performance requirements of inorganic fibers. Consequently, the method of preparing inorganic fibers by using CFB ash and dolomite powder is entirely feasible.

A novel plasma-facing NdB6 particulate reinforced W1Ni matrix composite: Powder metallurgical fabrication, microstructural and mechanical characterization

Tungsten (W) is one of best candidate metal for plasma-facing materials (PFM), especially due to its high melting temperature and neutron absorption capability. However, converting W into bulk PFM is hard because of its high melting point. This problem can be solved by adding metallic sintering aids with low melting points. In this study, W matrix with 1 wt% Ni aid was reinforced by adding NdB6 particles (1, 5, and 10 wt%). It can be introduced as a novel potential PFM, thanks to its low volatility and high neutron absorbability. The ceramic and composite powders produced via mechanochemical synthesis and mechanical alloying were examined in terms of composition, particle size, crystallite size, and lattice strain. Samples sintered via pressureless sintering (PS) and spark plasma sintering (SPS) were microstructurally analyzed by using an X-ray diffractometer (XRD), a scanning electron microscope (SEM) attached with an energy dispersive spectroscope (EDS), and mechanically analyzed in terms of microhardness and wear behavior. Based on the results, W2B and WB phases emerged in the SPS'ed W1Ni-5NdB6 and PS'ed./SPS'ed W1Ni-10NdB6 composites. SPS'ed W1Ni-10NdB6 composite had the highest hardness value and the lowest specific wear rate. The SPS'ed W1Ni-5NdB6 composite showed fewer surface damages and higher irradiation resistance as compared with other samples after exposure of He+ irradiation.

Unleashing the Power of Evolution in Xylanase Engineering: Investigating the Role of Distal Mutation Regulation.

The drive to enhance enzyme performance in industrial applications frequently clashes with the practical limitations of exhaustive experimental screening, underscoring the urgency for more refined and strategic methodologies in enzyme engineering. In this study, xylanase Xyl-1 was used as the model, coupling evolutionary insights with energy functions to obtain theoretical potential mutants, which were subsequently validated experimentally. We observed that mutations in the nonloop region primarily aimed at enhancing stability and also encountered selective pressure for activity. Notably, mutations in this region simultaneously boosted the Xyl-1 stability and activity, achieving a 65% success rate. Using a greedy strategy, mutant M4 was developed, achieving a 12 °C higher melting temperature and doubled activity. By integration of spectroscopy, crystallography, and quantum mechanics/molecular mechanics molecular dynamics, the mechanism behind the enhanced thermal stability of M4 was elucidated. It was determined that the activity differences between M4 and the wild type were primarily driven by dynamic factors influenced by distal mutations. In conclusion, the study emphasizes the pivotal role of evolution-based approaches in augmenting the stability and activity of the enzymes. It sheds light on the unique adaptive mechanisms employed by various structural regions of proteins and expands our understanding of the intricate relationship between distant mutations and enzyme dynamics.

Five-Surface Phosphor-in-Glass for Enhanced Illumination and Superior Color Uniformity in Large-View Scale LEDs.

A novel five-surface phosphor-in-glass (FS-PiG) structure for high illumination and excellent color uniformity in large-view scale LEDs for sensor light source application is demonstrated. YAG phosphor (Y3Al5O12:Ce3+) was uniformly mixed with ceramic and sintered at 680 °C to form a phosphor wafer. Sophisticated laser engraving was employed on the phosphor wafer to form saddle-shaped large-view scale FS-PiG LEDs. The performance of the FS-PiG LEDs exhibited an illumination of 401 lm, average color temperature (CCT) of 5488 K ± 110 K, and color coordinates (CIE) of (0.3179 ± 0.003, 0.3352 ± 0.003). In contrast to convention single-surface phosphor-in-glass (SS-PiG) LEDs, the performance exhibited an illumination of 380 lm, average CCT of 5830 K ± 758 K, and CIE of (0.3083 ± 0.07, 0.3172 ± 0.07). These indicated that the performance of the FS-PiG LEDs was higher than the SS-PiG LEDs for illumination, CCT, and CIE by 1.7, 7, and 23 times, respectively. Furthermore, the FS-PiG LEDs demonstrate a lower lumen loss of 2% and a reduced chromaticity shift of 5.4 × 10-3 under accelerated aging at 350 °C for 1008 h, owing to the high ceramic melting temperature of up to 510 °C. In this study, the proposed FS-PiG large-view scale LEDs with excellent optical performance and high reliability may be promising candidates to replace the conventional phosphor-in-organic silicone material used in high-power LEDs for the next generation of sensor light sources, display, and headlight applications.

Formation of oceanic crust within the Andrew Bain fault zone of the Southwest Indian ridge (Petrological and geochemical data)

A petrogeochemical study of basalts (lithophile elements and Sr-Nd-Pb isotopes, compositions of liquidus olivine and spinel) from the transition zone of the Southwest Indian Ridge in the area of the Du Toit and Andrew Bain faults revealed significant differences in their composition. Within the rift valley adjacent to the faults, tholeiites enriched in Na and depleted in Fe (Na-TOR genetic type) are typical. Deep-type basalts (TOR-1) are present in the western side of the Andrew Bain Fault. The outpouring of these types of magmas reflects a possible change in geodynamic regime during this zone formation: from deeper and higher temperature melting to shallower ones (Sushchevskaya et al., 2022). Differences in the primary melts of tholeiites from the rift valley and the Andrew Bain Transform Fault are also traced in the liquidus olivine compositions. The rift valley olivines are similar to typical Na-TOR olivines with a Mg content of Fo88–87, low Ni and elevated Mn. On the contrary, tholeiite olivines of the Andrew Bain Fault are enriched in Ni and depleted in Mn, which may indicate pyroxenite included in the primary melt formation. This component is either oceanic lithosphere recycled through the deep mantle or fragments of previously formed oceanic crust, which are subsequently involved in melting during the spreading axes jumping. A similar process is typical for the region of the Bouvet Triple Junction, where a significant heterogeneity of the olivine composition in terms of trace-element contents was revealed. The isotope characteristics of the Andrew Bain Fault tholeiites differ in Pb and Sr radiogenic composition and are similar to those of enriched magmas from such Indian Ocean rises as Crozet, Marion and Bouvet, but not from the Konrad and Af. Nikitin Rises. The source of such tholeiite melts is close in composition to the model HIMU type (with high U/Pb), possibly with an admixture of mantle material with EMII characteristics (with elevated Rb/Sr).

Effect of substrate temperature on the structural properties of Tungsten Carbide and Tungsten-rich Tungsten Carbide films

ABSTRACT The unique mechanical properties of Tungsten Carbide (WC), such as fracture toughness, exceptional hardness, high melting temperature, outstanding thermal stability, anti-oxidation qualities fatigue and creep resistance, have made it a suitable industrial material for different applications. It is also considered to be a promising material for coating on plasma-facing walls in a Tokamak reactor. The aim of the present work is to study the effect of varying substrate temperature, concentration of tungsten (W) and annealing in the structural properties of WC films. The WC films are deposited on a silicon substrate at different substrate temperatures viz. RT (300 K), 400, 500, 600 and 700 K using DC magnetron sputtering. W-rich WC films were deposited keeping the power of WC constant (100 Watt) and varying W powers (10 Watt, 20 Watt, 30 Watt, 40 Watt) at room temperature. Later, these W-rich WC films were annealed at 800°C in a reducing atmosphere. Glancing incidence X-ray diffraction (GIXRD) and Raman spectroscopy of the films are performed for structural analysis. GIXRD of the WC films reveals that as-deposited RT films are amorphous. However, films which are either deposited at elevated substrate temperature or are annealed are crystalline. This is confirmed by Raman’s measurements. It also indicates the presence of disorder and nanocrystalline phases due to temperature variations.

Geochemical Evidence of Water-Fluxed Crustal Melting in the Northern Colombian Andes

Abstract The compositions of crustal magmas are powerful tools for understanding the formation and differentiation of continents. However, the geochemical fingerprints that distinguish the two dominant mechanisms of crustal melting, namely dehydration and water-fluxed melting, are still controversial. To provide new insights into this problem, we discuss the petrogenesis of the Paipa Volcanic Complex (PVC), an isolated Quaternary volcanic field in the Colombian Eastern Cordillera. The PVC is characterized by peraluminous trondhjemite-like rhyolites with exceptionally high Na2O contents (~6 wt %), super-chondritic Nb/Ta (~27), elevated Sr/Y ratios (~120), spoon-shaped REE patterns, and enriched isotopic compositions that overlap with those of the local basement. They also exhibit high pre-eruptive H2O contents (~up to 9.5 wt %) and abundant Paleozoic zircon inheritances. We demonstrate that these characteristics are inconsistent with a process of intra-crustal differentiation from a mafic or intermediate mantle-derived precursor. Instead, we propose that the origin of the PVC is best explained by melting the local (meta)sedimentary basement under H2O-saturated conditions, at middle-crustal pressures (~1.3 GPa) and relatively low temperatures (~690–740°C), following the complete breakdown of plagioclase and biotite, and the formation of reactive peritectic amphibole. This scenario differs from the high-temperature dehydration melting conditions that have been widely proposed for the Andes and globally, which result in the production of water undersaturated magmas in equilibrium with anhydrous lithologies rich in plagioclase and/or garnet. Accordingly, we speculate that an external H2O flux was ultimately sourced from a buoyant, cold, and hydrated mantle wedge that was extensively metasomatized by fluids derived from the Nazca and Caribbean flat-slab fronts. These conditions depressed the asthenospheric mantle potential temperature, likely inhibiting mantle melting. In turn, they facilitated the infiltration and ascent of mantle-derived H2O through pre-existing crustal faults and shear zones. Our results indicate that water-fluxed melting could be a plausible mechanism for generating crustal magmas in orogenic regions where the availability of free H2O has been difficult to confirm.

Research on structure and optical properties of Tm3+-Tb3+ doped borate glass

In this paper, a series of B2O3–Al2O3–ZnO–BaO–Tm2O3–Tb2O3 glasses were synthesized by high temperature melting method. Under appropriate ultraviolet excitation, Tm3+ ions produce 1D2→3F4 energy level transition and emit blue light. The concentration quenching point is 0.75 % mol, and the color saturation is high. Tb3+ ions produce 5D4→7F5 energy level transition and emit green light, and the concentration quenching point of Tb3+ ions is 0.75 % mol. By characterizing the fluorescence lifetime and luminescence intensity of B2O3–Al2O3–ZnO–BaO–Tm2O3–Tb2O3 glass, the existence of Tm3+→Tb3+ energy transfer in the glass was verified, and the energy transfer efficiency and energy transfer mechanism were studied in detail. It is found that B2O3–Al2O3–ZnO–BaO–Tm2O3–Tb2O3 glass is an ideal material for light-emitting diodes, light-emitting materials and fluorescent display devices.

A counter-gravity casting system for in situ high-speed synchrotron x-ray imaging characterization.

Counter-gravity casting (CGC) aims to eliminate turbulent melt flow and defect formation during filling and subsequent solidification by pushing high-temperature melt into the mold cavity against gravity with regulated pressure. However, limited by the opaqueness of molten metals and the complexity of the CGC apparatus, it is extremely difficult to directly quantify the high-velocity mold filling and pressurized solidification in real-time. Here, we report the design and characterization of a CGC system capable of in situ monitoring of mold filling and subsequent solidification processes in the synchrotron beamlines by deploying a high-energy, high-speed synchrotron x-ray imaging technique. The high-velocity melt flow and dendrite growth during pressurized solidification have been quantified for systematical process parameter analysis by investigating time-resolved x-ray images of an exemplary Al-Cu alloy. The high-speed imaging results demonstrate that the in situ CGC system provides a useful way to better understand the fundamentals of mold filling, pressurized solidification, and experimental inputs for high-fidelity modeling in scientific and industrial applications.

Жароміцні інтерметалідні сплави та особливості їх легування

The work considers the prerequisites for the development of creep-resistant and heat-resistant alloys, based on intermetallics, taking into account the optimal combination of their physical and mechanical properties, as well as structural characteristics. It is shown that there is a sufficient number of intermetallics, which have a density lower than iron-based alloys, which, in combination with high melting temperatures and heat resistance, makes them promising materials for aerospace application, in particular, for gas turbine engine parts manufacturing. The most suitable creep-resistant and heat-resistant intermetallics can be called aluminides and silicides of titanium, nickel and molybdenum. For these compounds, it is possible to combine high values of specific strength with alloying-favorable types of crystal lattice. One of the most important and common creep-resistant alloys based on intermetallics is Ni3Al with FCC lattice. For this material, complex optimized alloying is the main way to increase creep resistance. The heat resistance of such alloys is significantly increased by applying ceramic coatings. Titanium aluminides Ti3Al and TiAl mainly have only a low density among the advantages. Their fragility at room temperatures and tendency to superplasticity at high temperatures significantly limits their application. The impact of disadvantages may be reduced by applying thermomechanical processing of such materials, which aims to change their structure. Alloying titanium aluminides with a large amount of niobium was chosen as a solution that significantly reduced marked week sides of Ti-Al intermetallic alloys. As a result, this led to the creation of a new alloy based on intermetallic Ti2AlNb with a high set of operational characteristics. Mo-Si and Mo-Si-B can be considered as one of the most perfect systems for creating heat-resistant intermetallic alloys. They combine an acceptable density, high creep and heat resistance, which can be additionally increased by reinforcing with ceramic particles. Keywords: intermetallic-based alloys, creep resistance, alloying, Ni-Al, Ti-Al, Mo-Si, Mo-Si-B.

Investigation of molecular polarity and thermal stability of monoethanolamine based deep eutectic solvents

In this work, sigma profile and sigma potential were generated using COSMOtherm software to examine the molecular polarity of choline chloride with monoethanolamine based deep eutectic solvents at various mole ratios (i.e., 1:2, 1:3, 1:4, 1:5, 1:6 and 1:7). It is used to analyses the interaction between the molecules during extraction process. The result revealed that the selected DES are feasible for use as extracting solvents for polyphenol extraction process. Also, it shows that the prepared DES was hydrophilic in nature and it denotes ability of the amine to act as a base. Then, using thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC), the similar molar ratio of amine-based DES was synthesized and their thermal stability was described in terms of decomposition temperatures, mass loss and melting temperature. When heating rate increased, the TGA curves of 1:6 and 1:7 DES, temperature shifted to higher direction when compared to other mole ratios of DES. When HBD is increases thermal stability also increases in this case. HBD plays an important role in thermal stability of DES which mainly depends on intermolecular interactions. Similarly, in DSC 1:6 and 1:7 high melting temperature and high enthalpy was observed when compare to other mole ratios. It denotes by increasing the HBD ratio melting temperature also increased due to stronger intermolecular force and stronger interaction between HBA and HBD. In end the synthesized DES was suggested to be used as intermediate for the extraction of polyphenols from agricultural wastes.

The effect of trace Fe3+ on the magneto-optical properties of Tb3+ doped B2O3-GeO2-Al2O3-ZnO-BaO glass

Magnetic particles of BaFe12O19 were synthesized using a high-temperature solid-phase method. Magneto-optical glass samples were prepared by incorporating different concentrations of Fe3+ ions (ranging from 0 to 0.25 mol%) into the glass matrix with a constant doping of Tb2O3 (30 mol%) using a high-temperature melting method. The glasses are composed of B2O3-GeO2-Al2O3-ZnO-BaO-Tb2O3 (BGAZBa-T30-xFe). The effects of varying Fe3+ ion concentrations on the structure, physical properties, and magneto-optical performance of BGAZBa-T30 glass were investigated. The study reveals that the density and magneto-optical properties of the glass are enhanced with the increase of Fe3+ ion concentration. When the Fe3+ ion concentration reaches 0.20 mol%, the Verdet constant of BGAZBa-T30 glass increases from −82.51 rad/(T·m) to −91.90 rad/(T·m) at an incident light wavelength of 633 nm. Meanwhile, the density rises from 4.93 g/cm3 to 4.98 g/cm3. Notably, the BGAZBa-T30-0.20Fe glass sample exhibits excellent magneto-optical performance, with a Verdet constant value of −142.50 rad/(T⋅m) at an incident light wavelength of 515 nm, which is 1.2 times that of the glass matrix main body (−118.28 rad/(T·m)). This presents potential research value in the field of optoelectronic functionality.

Zero-dimensional model of a pumped heat energy storage system with reciprocating machines

The technology of Pumped Heat Energy Storage allows for the storage of large amounts of electrical energy, which is currently crucial due to the worldwide use of renewable energy sources (intrinsic and highly variable). In these systems, electrical energy is used to feed a heat pump cycle (charging phase) that exchanges heat with two thermal reservoirs, storing part of the input energy in the form of thermal energy. This energy is then supplied to the grid through a power cycle (discharging phase) when needed. This article presents a zero-dimensional model of a Pumped Heat Energy Storage system that uses a numerical zero-dimensional model for the reciprocating machines and an analytical model for the heat exchangers. By feeding the model with the operating point data (rotational speed of the reciprocating machines, pressure at a point in the system, fluid temperatures in the reservoirs, and mass flows of the thermal fluids circulating through the heat exchangers) and the geometric dimensions of all the machines, the steady-state evolution of the system can be obtained as result and also the powers of the reciprocating machines and heat exchanged with the thermal reservoirs, circulating mass flow of the working fluid, inlet and outlet temperatures and pressures of each machine, and the round-trip efficiency of a certain configuration, among others. Evaluating the coupling of the machines in a particular setup an overall efficiency of around 36% was calculated for the condition with the maximum local performance coefficient. Analysing the dependency between the stages of charge and discharge an operating condition that improved this value up to an efficiency of approximately 40% was obtained. Both values are conditioned for the use of molten salt, particularly its high melting temperature, which imposes higher temperatures at the expander inlet thus decreasing the overall efficiency of the system.

Ab-initio insights into the mechanical, phonon, bonding, electronic, optical and thermal properties of hexagonal W2N3 for prospective applications

We thoroughly investigated the structural, mechanical, electronic, vibrational, optical, thermodynamic, and a number of thermophysical properties of W2N3 compound through first-principles calculations using the DFT based formalism. The calculated structural parameters show very good agreement with the available theoretical and experimental results. The mechanical and dynamical stabilities of this compound have been investigated theoretically from the elastic constants and phonon dispersion curves. The Pugh's and Poisson's ratios of W2N3 are located quite close to the brittle/ductile borderline. W2N3 is elastically anisotropic. The calculated electronic band structure and density of states reveal that W2N3 is conducting in nature. The Fermi surface topology has also been explored. The analysis of charge density distribution map shows that W atoms have comparatively high electron density around compared to the N atoms. Presence of covalent bondings between W–N, W–W, and N–N atoms are anticipated. High melting temperature and high phonon thermal conductivity of W2N3 imply that the compound has potential to be used as a heat sink system. The optical characteristics show anisotropy. The compound can be used in optoelectronic devices due to its high absorption coefficient and low reflectivity in the visible to ultraviolet spectrum. Furthermore, the quasi-harmonic Debye model is used to examine temperature and pressure dependent thermal characteristics of W2N3 for the first time.

Experimental and numerical investigations on formation mechanisms of hollow structures in overflow water‐assisted injection‐molded parts of short‐glass‐fiber‐reinforced polypropylene

AbstractIn water‐assisted injection molding processes, it is crucial to understand the mechanisms governing the formation of hollow structures and identify the key factors influencing their morphology and dimensional accuracy. This work combined experimental analysis and numerical simulation to investigate the influence of different mold cavities and main processing parameters on hollow structures in overflow water‐assisted injection molded parts of short‐glass‐fiber‐reinforced polypropylene, that is, hollow shape and hollow ratio. The results show that the hollow shape and hollow ratio depended not only on the cross‐sectional location but also on the cross‐sectional shape of the mold cavity. For the circular parts, the hollow shape resembled the cross‐sectional shape of the mold cavity, with a relatively small and uniform hollow ratio across cross‐sectional locations. For the noncircular parts, the hollow shape varied considerably with increasing distance from the water inlet. Moreover, the results also show that except for the influence of water‐injection delay time on the uniformity of the hollow ratio, higher melt temperature (250°C), shorter water‐injection delay time (0 s), and higher water pressure (10 MPa) contributed to the hollow shape being closer to the cross‐sectional shape of mold cavities and made hollow ratios relatively larger and more uniform.

Mild extraction of faba bean (Vicia faba L.) proteins against conventional methods: Impact on physicochemical and thermal characteristics

Faba bean (high- and low-tannin) protein isolates were water extracted followed by dialysis or micellization in comparison to concentrates from conventional alkali extraction + acid precipitation, and salt-based extraction (1% NaCl) + dialysis. Protein fractions were characterised for secondary structure conformational changes, crystalline structure, particle size distribution in aqueous suspension and thermal properties. Mild water or salt extraction did not influence particle size distribution. Based on XRD, FTIR and CD, β-sheet structures were the most abundant secondary structures and water extraction + dialysis had minimal impact on their native conformation. DSC results showed an association between protein purity, glass transition temperature and endothermic enthalpy. High melting temperature above glass transition confirms the suitability of faba bean proteins for thermal/extrusion processing. Fractionation method was a more significant determinant of physicochemical characteristics compared to the cultivar. Further exploration of the techno-functional characteristics of faba bean proteins is essential for value-added food applications.

First-principles prediction of the Co–Al phase diagram including configurational, vibrational and magnetic contributions

Co-based superalloys have attracted attention to replace Ni-based superalloys in high temperature structural applications because of their higher melting temperature and corrosion resistance. Strengthening is provided by Co3(Al, X) (X = W, Cr, Mo, Ni) phases and optimization of their properties requires detailed information about the free energies of the different phases and of the phase diagram of the Co–Al system. This is achieved in this paper through first principles calculations in combination with statistical mechanics. Configurational entropic contributions to the free energy were included through Monte Carlo simulations using the cluster expansion formalism. The vibrational entropy of each phase was determined through the length-stiffness relationship while the magnetic entropy was also included through the Heisenberg Hamiltonian. The computed phase diagram is compared with the currently accepted experimental phase diagram and the different contributions to the stability of each phase are analyzed independently. The potential of this strategy to predict phase diagrams of magnetic systems is clearly established.

CLIMATE AND ENVIRONMENTAL BACKGROUNDS OF FUEL UTILIZATION, INFLUENCING UPON ALTERATION THE EUROPEAN AND UKRAINIAN TRENDS OF GAS SUPPLY. PART 2. PROVIDING THE EFFICIENCY OF FUEL USE IN CONDITIONS OF DECARBONIZATION OF ENVIRONMENT

The paper is dedicated to power and environmental aspects of option the most appropriate types of fuel for supplying the economics of European countries and Ukraine. Accordingly notions about influence of C-containing fuels on greenhouse effect and on warming of environment, the existing tendency of substitution the fossil fuels — generally — and the natural gas — particularly — for methane-hydrogen mixtures is discussed as a controversial point. The problem of advancement the national fuel complexes is under consideration and has been studied with approach based upon the example of Ukrainian pre-war state of economics. An attention has been paid up on reduction of production and consumption of all types of the fossil fuels in the last decades, mainly due lowering the industrial using constituent. An enhancement of fuel using efficiency due improvement of furnace equipment basis provides an successive solution the fuel problems. The thermodynamic background for evaluation the efficiency of fuel using with account of the furnace’s non-ideality has been developed. The problem of “wet combustion” takes of special significance by the reason of weather and climate conditions’ account, on the one hand, and an opportunity to control the efficiency of fuel using, on the other hand, with new combined technique. The contemporary approach consists in combination the direct method of decrease the CO2 emission due exclusion of using the C-containing fuels (firstly — the fossil fuels) and with enhancement the efficiency of using the fossil fuels, for example due erection the recuperative heat recovery facilities with preliminary preheating of combustion air, in some advanced cases by combination with an air, humidification. The perspective ways of provision the decarbonization of environment consists in substitution the fossil fuels (mainly the natural gas NG) for hydrogen or H2-containing gas mixtures. The thermodynamic analysis of relevant technique has been carried out to estimate the opportunities of control the efficiency of hydrogen admixture to NG. Taking into account the variety of technologies of hydrogen production, the engineering method with giving of conditional coloration of hydrogen as a fuel has been considered. The “green” H2 makes the most valuable type of fuel (compared with “blue”, “turquoise”, “yellow”, “rose” colored and especially to the “grey” H2) as a substituting fuel from the standpoint of H2 fitness to process and plant. Particularly for high-temperature melting furnaces a provision of maximum emissivity of flame requires an using of carbon containing fuels to organize thermal pyrolysis of gas and soot formation within the combustion zone. Ref. 44, Fig. 5, Tab. 3.

The Effect of Scanning Strategy on the Thermal Behavior and Residual Stress Distribution of Damping Alloys during Selective Laser Melting.

The manufacture of damping alloy parts with stable damping properties and high mechanical performances in the selective laser melting (SLM) process is influenced by temperature evolution and residual stress distribution. Choosing an appropriate scanning strategy, namely the specific trajectory along which the laser head scans powders within given area, is crucial, but clearly defined criteria for scanning strategy design are lacking. In this study, a three-dimensional finite element model (FEM) of the SLM process for manufacturing a WE43 alloy component was established and validated against the published experimental data. Eleven different scanning strategies were designed and simulated, considering variables such as scanning track length, direction, Out-In or In-Out strategy, start point, and interlayer variation. The results showed that scanning strategy, geometry, and layer number collectively affect temperature, melt pool, and stress outputs. For instance, starting scanning at a colder part of the powder layer could lead to a high peak temperature and low melt pool depth. A higher layer number generally results in lower cooling rate, a lower temperature gradient, a longer melt pool life, and larger melt pool dimensions. Changing the start point between scanning circulations helps mitigate detrimental residual stress. This work highlights the potential of analyzing various scanning strategy-related variables, which contributes to reducing trial-and-error tests and selecting optimal scanning strategies under different product quality requirements. This article can assist in the design of appropriate scanning strategies to prevent defects such as element loss due to evaporation, poor bonding, and deformation or cracking from high residual stress. Additionally, identifying stress concentration locations and understanding the effects of geometry and layer number on thermal and mechanical behaviors can assist in geometry design.