In order to investigate the microstructural evolution in a nitrogen-bearing 2205 duplex stainless steels (DSS) during welding, a simulated weld thermal cycle with 5 kJ cm −1 heat input followed by exposure at 700 °C for different time intervals was performed. The microstructure of high-temperature heat affected zone (HTHAZ) developed with the thermal experience was characterized via optical metallography and transmission electron microscopy (TEM). The duplex structure with equivalent phase components was drastically destroyed by the rapid thermal cycle. In the simulated HTHAZ structure, three different morphologies of newly formed austenite were observed in the coarse-grained δ-ferrite matrix; i.e. allotriomorphic austenite, Widmanstäten autenite and intragranularly nucleated autenite. During the exposure at 700 °C, the intragranularly nucleated austenite got coarse and the Widmanstäten austenite grew progressively. TEM revealed that several variants of rod-like Cr 2N were precipitated selectively at intragranular and intergranular sites. From the analyses of diffraction patterns of TEM, Kurdjumov–Sachs orientation relationship was found to describe the interface between intragranularly nucleated autenite and δ-ferrite, while Pitch–Schrader orientation relationship to describe the disposition between hexagonal Cr 2N precipitates and δ-ferrite matrix.
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