High-temperature Experiments Research Articles

Genetic dissection of crayfish (Procambarus clarkii) high temperature tolerance and assessment of the potential application in breeding of the HSP genes

Red swamp crayfish (Procambarus clarkii) is an important freshwater aquaculture species in China. In the process of crayfish aquaculture, high temperature stress is common, which seriously affects its yield and quality. It is urgently recommended to improve these traits in the breed. However, the application of high-temperature tolerance genes in molecular breeding of crayfish has not been reported. In this study, transcriptome analysis was used to explore the high-temperature tolerance genes of crayfish. The results showed that genes related to energy metabolism, antioxidant, immunity and body restoration were involved in high temperature adaptation of crayfish. Based on the selected high temperature tolerance genes Heat Stress Protein 70 and Heat Stress Protein 90 (HSP70 and HSP90), the genetic variation of their open reading frames was investigated. Totally, three and four SNPs of HSP70 and HSP90, were obtained respectively. In addition, three high-temperature stress experiments were conducted on crayfish to identify favoured haplotypes. HSP70–1 and HSP90–1 are the favoured haplotypes of HSP70 and HSP90, respectively. Furthermore, a series of molecular markers were developed to identify the favoured haplotype combinations of HSP70 and HSP90. Finally, we propose a molecular breeding strategy to improve crayfish tolerance to high temperature, thereby providing a potential to increase crayfish yield. Together, this study provides a theoretical basis and molecular markers for the breeding of high-temperature tolerant crayfish.

Experimental study on eutectic reaction between lower head of reactor pressure vessel and molten pool using simulant materials

The eutectic reaction between core materials is an important behavior during reactor severe accidents because it will affect the accident progression. To comprehend the eutectic reaction between molten corium and the lower head of the reactor pressure vessel, this study conducted a series of simulated experiments. Liquid bismuth (Bi) and lead (Pb) rods, chosen for their relatively low eutectic point of 398.5 K, were utilized in a self-designed apparatus. For a more comprehensive understanding, various experimental parameters, including the temperature of Bi pool (548–578 K), temperature of Pb rod (548–578 K), charged gas pressure (0.002–0.006 MPa), weight of load block (3.3–7.3 kg) and style of baffles (type A, type B) were varied. Upon analyzing the experimental observations and quantitative data gathered, we investigated the influence of experimental conditions on the reaction rate. It is found that the temperature of the Bi pool exerts a notably positive influence on the eutectic reaction rate constant, regardless of the baffle pattern and the initial Pb rod temperature, while the role of Pb rod temperature seems to be insignificant. In experiments employing baffle A, both the weight of the load block and gas pressure significantly impact the reaction rate constant. Conversely, in the case of baffle B, their impact is insignificant. Knowledge and evidence gained from this study will be applied to future preparation of high-temperature experiments that involve actual reactor materials. Furthermore, this study furnishes experimental data aimed at enhancing and validating the eutectic reaction related model within the severe accident analysis code for water-cooled reactors.

Constitutive model of high-temperature rapid fracture of Si3N4 ceramics for engine turbine discs and their pore insensitivity parameters

ABSTRACT The metallic materials used to manufacture turbine components can potentially be replaced with ceramics such as Si3N4, but the stress on turbine discs is difficult to determine experimentally, which hinders the development and optimization of ceramics. The finite element method solves this problem, but it requires an accurate constitutive model and parameters. Existing methods for determining model parameters lack versatility and do not consider the internal pores of ceramics. This work proposes a method for determining the parameters of the high-temperature rapid fracture constitutive model of ceramics with internal pores based on the results of industrial computed tomography (CT) and high-temperature fracture toughness experiments. The constitutive model for a ceramic with internal pores was selected based on the typical service conditions of turbine discs. Industrial CT was used to measure pore information. A finite element preprocessor was developed to create simulated specimens with pores. The high-temperature fracture toughness of the ceramics was measured. Pore insensitivity was the parameter obtained from the high-temperature constitutive model of ceramics with pores using this method. The maximum relative error between the predicted and experimental flexural strengths was 6.8%. It provides a new idea for determining the parameters of constitutive models for materials with pores.

Study on the preparation and mechanism of oil-soluble amphiphilic polymer asphaltene inhibitor

In order to solve the problem that the asphaltene in YM35-6 crude oil is easy to precipitate and accumulate, resulting in wellbore blockage. In this paper, an oil-soluble amphiphilic polymer asphaltene inhibitor (SYRJ) was developed. The wellbore environment was simulated by static experiments and high temperature and high-pressure dynamic experiments. The inhibition effect on asphaltene was evaluated respectively. The inhibition rate reached 84.65% and 82.03% respectively at 400 ppm dosage. Furthermore, the inhibitor showed good inhibition effect on different high asphaltene crude oils. Even at 120 °C, the inhibition rate was more than 85%. Finally, the microstructure and particle size of asphaltene after adding SYRJ were studied by scanning electron microscopy and laser scattering system. The results show that SYRJ adsorbs on the surface of asphaltene and penetrates into its crevices by virtue of its ultra-long carbon chain and hyperbranched structure. The interlayer spacing between asphaltenes is increased. Thus, the interaction between asphaltene molecules is hindered, and the growth and aggregation of asphaltene particles are inhibited. The average particle size of asphaltene molecules was reduced from 409.5 nm to 189.3 nm.

Experimental study on thermal–hydraulic performance of a nature-inspired mini-channel heat exchanger manufactured by 3D printing

Zigzag-channel printed circuit heat exchangers (PCHEs) are widely used in nuclear energy, solar energy, and aerospace due to their good heat transfer performance. However, the high flow resistance of zigzag channels leads to large pumping power consumption and thus limits the overall performance. Although previous modified channels could reduce the flow resistance of PCHEs, they also bring a decrease in the heat transfer efficiency. Inspired by river islands, this study proposes a novel nature-inspired channel. The nature-inspired channel heat exchanger, along with a traditional zigzag-channel heat exchanger, were manufactured by 3D printing. The high-temperature air-air flow and heat transfer experiments show that the nature-inspired channel heat exchanger increases the average heat transfer rate by 1.5% and significantly reduces the pressure drop by 34.85%. The addition of airfoil fins at the corners effectively alleviates the flow resistance caused by flow separation, reattachment, and collision, leading to a higher Nusselt number and a lower Fanning friction factor. The Nusselt number of nature-inspired channel is 59% higher than that of the zigzag channel with a 15° inclined angle. This work demonstrates that the nature-inspired channel could significantly reduce the flow resistance while maintaining high heat transfer efficiency compared with the traditional zigzag channel.

Recension of boron nitride phase diagram based on high-pressure and high-temperature experiments

Abstract Cubic boron nitride and hexagonal boron nitride are the two predominant crystalline structures of boron nitride. They can interconvert under varying pressure and temperature conditions. However, this transformation requires overcoming significant potential barriers in dynamics, which poses great difficulty in determining the c-BN/h-BN phase boundary. This study used high-pressure in situ differential thermal measurements to ascertain the temperature of h-BN/c-BN conversion within the commonly used pressure range (3–6 GPa) for the industrial synthesis of c-BN to constrain the P–T phase boundary of h-BN/c-BN in the pressure–temperature range as much as possible. Based on the analysis of the experimental data, it is determined that the relationship between pressure and temperature conforms to the following equation: P = a + 1 b T . Here, P denotes the pressure (GPa) and T is the temperature (K). The coefficients are a = −3.8±0.8 GPa and b = 229.8±17.1 GPa/K. These findings call into question existing high-pressure and high-temperature phase diagrams of boron nitride, which seem to overstate the phase boundary temperature between c-BN and h-BN. The BN phase diagram obtained from this study can provide critical temperature and pressure condition guidance for the industrial synthesis of c-BN, thus optimizing synthesis efficiency and product performance.

Interphase migration and enrichment of lead and zinc during copper slag depletion

An interphase migration and enrichment model of lead and zinc during molten copper slag depletion was established. The occurrence of various components in copper slag was predicted using sulfur−oxygen potential calculations and confirmed through high-temperature experiments. The recovery rate of copper can reach 90.13% under the optimal conditions of 1200 °C, an iron to silicon mass ratio of 1.0, 3 wt.% ferrous sulfide, and a duration of 45 min. Lead (54.07 wt.%) and zinc (17.42 wt.%) are found in the flue dust as lead sulfate, lead sulfide, and zinc oxide, while copper matte contains lead (14.44 wt.%) and zinc sulfide (1.29 wt.%). The remaining lead and zinc are encapsulated as oxides within the fayalite phase.

Thermally induced release and generation of CO2 and C1–C4 hydrocarbons in Opalinus Clay from Mont Terri (Switzerland)

Claystone formations are candidate host rocks for high-level heat-emitting nuclear waste (HLW). Temperatures from 90 to 150 °C at the canister surface are discussed internationally as potential emplacement and storage conditions. The thermal energy emitted from waste containers will be transported into the host rock formation, accelerating chemical reactions including the release of sorbed and dissolved gases and the generation of new gases. This study investigated gas release and generation in Opalinus Clay from Mont Terri (Switzerland) at elevated temperature and pressure conditions relevant for HLW storage and beyond. Hydrous pyrolysis experiments were conducted in Dickson-type flexible gold-titanium reaction cells and gold capsules in the temperature range of 80–345 °C and at 20 MPa. CO2(g) was the predominant product, followed by C1–C4 hydrocarbons, which decrease in abundance with increasing carbon atom number. Neither CO nor H2S was detected. H2 was generated only in high temperature experiments at 315 °C and 345 °C, respectively. A combination of CO2(g) quantification, stable carbon isotopic composition data, thermodynamic calculations and aqueous fluid composition (dissolved ions, pH) demonstrated that ≥80 % of the measured CO2(g) originated from carbonate mineral dissolution. The model calculations also suggest that the fraction of CO2(aq) in DIC increases from ∼50 % at 80 °C to nearly 100 % at higher temperatures. Thermal transformation of organic matter represented an additional source for CO2(g) and was the predominant process yielding the C1–C4 hydrocarbons. Our findings stress the importance of quantitative geochemical data for the safety assessment of potential host rocks for HLW storage. We demonstrated that two sources are involved in gas release and generation at temperatures relevant for HLW storage, e.g., in the Opalinus Clay – organic matter and carbonate minerals. Our data will contribute to numerical modelling studies and the refinement of feature, events, and processes (FEP) catalogues.

High Entropy Protected Sharp Magnetic Transitions in Highly Disordered Spinel Ferrites.

How disorder affects magnetic ordering is always an intriguing question, and it becomes even more interesting in the recently rising high entropy oxides due to the extremely high disorder density. However, due to the lack of high-quality single crystal samples, the strong compositional disorder effect on magnetic transition has not been deeply investigated. In this work, we have successfully synthesized high-quality single crystalline high entropy spinel ferrites (Mg0.2Mn0.2Fe0.2Co0.2Ni0.2)xFe3-xO4. Our findings from high-temperature magnetization and neutron diffraction experiments showed ferrimagnetic transitions at 748, 694, and 674 K for x values of 1, 1.5, and 1.8, respectively. Notably, the magnetic transition almost showed no broadening for x values of 1 and 1.5, compared to Fe3O4. Extended X-ray absorption fine structure measurements provided insights into the elemental distribution among the octahedral and tetrahedral sites. The random distribution of elements across these sites reduced the formation of local clusters and short-range orders, enhancing sample homogeneity and preserving the sharpness of the magnetic transition, despite bond length variation. Our study not only marks the first successful synthesis of an HEO bulk single crystal exhibiting long-range magnetic order but also sheds light on the interaction between high configurational entropy and magnetic orderings. This opens new avenues for future research and applications of magnetic high entropy oxides.

Preparation and Performance Evaluation of a Supramolecular Polymer Gel-Based Temporary Plugging Agent for Heavy Oil Reservoir.

When encountering heavy oil reservoirs during drilling, due to the change in pressure difference inside the well, heavy oil will invade the drilling fluid, and drilling fluid will spill into the reservoir along the formation fractures, affecting the drilling process. A supramolecular polymer gel-based temporary plugging agent was prepared using acrylamide (AM), butyl acrylate (BA), and styrene (ST) as reacting monomers, N, N-methylenebisacrylamide (MBA) as a crosslinking agent, ammonium persulfate (APS) as an initiator, and poly(vinyl alcohol) (PVA) as a non-covalent component. A supermolecular polymer gel with a temperature tolerance of 120 °C and acid solubility of 90% was developed. The experimental results demonstrated that a mechanically robust, thermally stable supramolecular polymer gel was successfully synthesized through the copolymerization of AM, BA, and ST, as well as the in situ formation hydrogen bonding between poly (AM-co-BA-co-ST) and PVA, leading to a three-dimensional entangled structure. The gel-forming solution possessed excellent gelling performance even in the presence of a high content of salt and heavy oil, demonstrating superior resistance to salt and heavy oil under harsh reservoir conditions. High-temperature and high-pressure plugging displacement experiments proved that the supramolecular polymer gel exhibited high pressure-bearing capacity, and the blocking strength reached 5.96 MPa in a wedge-shaped fracture with a length of 30 cm. Furthermore, the dissolution rate of the supramolecular polymer gel was as high as 96.2% at 120 °C for 48 h under a 15% HCl solution condition.

First principles modeling of WO3 transport in molten Na2WO4 via a grotthuss-like mechanism and the kinetic characterization involved

Between the inherent difficulties associated with high temperature experiments and the inherent complexity of multi-component liquid phase systems, a Grotthuss-like transport mechanism for WO3 in molten Na2WO4 has been discovered and investigated in order to deepen the understanding of the properties of the Na2WO4-WO3 molten salt and to broaden its applications in areas such as electroplating, catalysis and energy. The research on the Grotthuss-like transport mechanism of WO3 in molten Na2WO4 shows that the mass transfer rate of this mechanism is about 1.5 times faster than the self-diffusion of tungsten ions. The bridging oxygen bond of W2O72- is longer, the Mayer bond level is lower and has a smaller ELF than that of the non-bridging oxygen bond, which makes the bridging oxygen bond more susceptible to breakage. The total energy, Pauli mutual repulsion energy and orbital interaction energy of the non-bridging oxygen bond are larger than those of the bridging oxygen bond. The transition state of the W2O72- dissociation process is the torsion of the bridging oxygen bond with a potential barrier of 42.903 kJ/mol.

Derivatives of (5-Oxooxazolidin-4-yl)acetic acids in aspartic acid α-carboxyl protection: a word of caution

Isomeric products could be isolated in a reaction of pentafluorophenyl ester of (S)-2-(3-((benzyloxy)-carbonyl)-5-oxooxazolidin-4-yl)acetic acid with aminoacid esters. One product is an expected dipeptide, the isomeric one is an N-hydroxymethylamino succinimide – a product of methylene bridge cleavavge. Steric bulkness of aminoacid esters favors the formation of a peptide, however the reaction selectivity is quite unpredicatable. Moreover, the precise structure assignement requires high-temperature NMR experiments.

Microelectrode-Based Diffusivity Measurements of Hydrogen in Molten 2LiF-BeF2

Detailed knowledge of the mass transport behavior of hydrogen isotopes in molten 2LiF-BeF2 salt (FLiBe) is essential to the design of new nuclear fusion technologies that make use of this molten salt to breed tritium to fuel the fusion reaction. However, typical studies of hydrogen transport using macroelectrodes are limited to solely measuring the permeability of an analyte—a property defined as the product of concentration squared and diffusivity. This challenge necessitates the development of microelectrodes capable of dynamically measuring diffusion coefficients when concentrations are variable. Unlike macroelectrodes, microelectrodes can measure diffusivity and concentration independently due to a steady-state current proportional to the product of diffusivity and concentration captured in addition to the Cottrellian current response.This steady-state current is established due to a continuously expanding diffusion layer from the electrode that cannot expand indefinitely within finite experimental setups. Therefore, COMSOL Multiphysics simulations mirroring experimental conditions were performed to validate the analytical mass transport model based on the solution of Fick’s Second Law in radial coordinates. These simulations employed a 2D axisymmetric model to examine the conditions under which the infinite bulk solution approximation is valid, confirming that our electrode design would yield true steady-state current responses indicative of radial diffusion.Platinum microelectrodes developed in this study served a dual purpose: they not only addressed previous limitations in high-temperature molten salt experimentation but also enabled dynamic measurements of both the diffusion coefficient and concentration of hydrogen in molten FLiBe introduced by lithium hydride. Square wave voltammetry and chronoamperometry were performed on a three-electrode cell using a platinum working microelectrode, a tungsten counter electrode, and a Ni/Ni2+ thermodynamic reference electrode. The successful measurement of hydrogen diffusivity in these experiments not only offers essential insights into molten FLiBe behavior but also sets the stage for future investigations into the effects of redox conditions, impurities, and equilibration time on tritium within nuclear fusion reactors.

Microstructure characterization and high-temperature wear behavior of plasma nitriding mold steel

Considering the cyclic variation of temperature and load in the glass molding, the mechanical properties and wear behavior of the nitriding mold steel at high temperatures are necessary to investigate. In this research, the microhardness variation of mold steel after plasma nitriding is elucidated and associated with the microstructure. The high-temperature nanoindentation experiments are conducted to clarify the impact of temperature on mechanical behavior of the nitriding steel. The hardness and elastic modulus of the nitriding steel are decreased by 40.9 % and 19.5 % when the temperature increased from room temperature to 400 °C. Correspondingly, due to the hardness dropping, the wear resistance of the nitriding mold steel decreases gradually with the temperature. However, the wear resistance of the nitriding mold steel under high temperatures is still superior to that of conventional mold steel. A wear schematic model is developed to elucidate the wear behavior evolution mechanism of the nitriding steel with temperatures. This work provides a comprehensive investigation of the mechanical and wear behavior of the nitriding mold steel under high temperatures which avoids mold wear failure in glass compressing molding.

Co-wetting behavior of molten slag and iron on carbon materials in blast furnace

The interaction between molten slag, liquid iron, and carbon is one of the most typical and complex multiphase flow behaviors in the high-temperature zone of blast furnace. The wetting behavior among these phases is the most fundamental characteristic that determines their interactions. This research focuses on the co-wetting behavior of molten slag and iron on graphite, using high-temperature experiments and atomistic simulations. The results revealed that the multiphase cooperative reaction wetting process is influenced by multiple factors. The wettability of molten iron is mainly affected by its initial carbon content, while the wettability of slag is influenced by both the initial carbon content of the molten iron and its own compositional changes. The initial carbon content in molten iron affects the carburizing reaction, which in turn influences the wetting mechanism between molten iron and graphite. Additionally, it alters the reaction of FeO in the slag, thereby modifying the properties of the slag-carbon interface and affecting the overall co-wetting process. Meta-dynamic calculations showed that the reduction of molten iron oxide by dissolved carbon is significantly more effective than that by solid graphite carbon, demonstrating that the behavior of carbon between iron and slag is a key factor in the multiphase cooperative reaction process.

Degradation of the protective layer on stainless steel by chlorine variation under high-temperature conditions

This study investigates the impact of various chlorine (Cl) content ratios on the degradation of 304 stainless steel during co-combustion of coal with solid recovered fuel (SRF) at a combustion temperature of 1250 °C. The research specifically focuses on the corrosion potential at 550 °C, which represents the temperature in the superheater area of a power plant. High-temperature corrosion experiments are conducted in a laboratory-scale drop tube furnace to observe initial corrosion during combustion. Analyses include visual examination, mineral analysis, microstructure-based metal analysis, and corrosion rate determination. The results show significant degradation at Cl contents higher than 0.09 wt%. The usual carbide formation at the grain boundaries in 304 stainless-steel does not occur in the short-term tests, as indicated by Cr content remaining above 12 % and Cl content less than 0.06 wt%. In addition, material degradation is due to the Cl reacting with alkali content, damaging the oxide layer and causing pits in the cross-section area of the probe material. This research provides insights into the critical role of Cl in metal degradation and identifies the optimum Cl amount suitable for coal blending in power plants.

Design solutions and characterization of a small scale and very high concentration solar furnace using a Fresnel lens

The use of Fresnel lenses for solar energy concentration technology dates back to the 1950 s. These lenses feature a plano-convex optical design with a series of discontinuous convex grooves. Typically made from materials like polymethyl methacrylate, Fresnel lenses are lightweight, resistant to sunlight, thermally stable, and cost-effective.This study presents a novel Fresnel lens-based solar furnace configuration installed at the Eduardo Torroja Institute for Construction Science in Madrid, Spain. The novelty of this work lies in the exceptional performance and operability of the facility. Experimental characterization revealed a record peak irradiance over 7 MW m−2 for an incident target power exceeding 800 W. Comparison with ray tracing simulations shows good agreement with experimental results. This setup enables high temperature experiments up to 2000 °C with rapid execution times. A fixed receiver, a shutter system and a closed-loop heliostat tracking control system allow for flexible operation up to 5000 suns and straightforward maintenance. The concentrator element costs less than 300 USD (2022) m−2, offering an economical solution to solar-powered high concentration and temperature applications. This innovative design overcomes previous operational challenges, providing a robust and economical method for high-temperature material processing and other industrial applications.

Advances in rock physics for pore pressure prediction: A comprehensive review and future directions

Advances in rock physics have significantly enhanced pore pressure prediction, a critical aspect of subsurface exploration and drilling operations. This comprehensive review delves into the latest developments in rock physics methodologies, integrating empirical, theoretical, and computational approaches to predict pore pressure more accurately. Traditional pore pressure prediction methods often rely on well log data and seismic attributes, but recent advancements have introduced innovative techniques that leverage the physical properties of rocks to provide more reliable predictions. Key advances include the development of improved rock physics models that better account for the complexities of subsurface environments, such as heterogeneity and anisotropy. These models integrate data from various sources, including well logs, core samples, and seismic surveys, to create a more comprehensive understanding of the subsurface. Additionally, the application of machine learning and artificial intelligence to rock physics has opened new avenues for analyzing large datasets, identifying patterns, and refining predictive models. This review also examines the role of laboratory experiments and field studies in validating and calibrating rock physics models. High-pressure and high-temperature experiments have provided valuable insights into the behavior of rocks under different conditions, which are essential for accurate pore pressure prediction. Field studies, on the other hand, offer real-world data that help in fine-tuning models and methodologies. Future directions in rock physics for pore pressure prediction include the integration of advanced geophysical techniques, such as full-waveform inversion and distributed acoustic sensing, which offer higher resolution data and more detailed subsurface imaging. The use of cloud computing and high-performance computing platforms is also expected to enhance the processing and analysis of large datasets, making predictive models more efficient and scalable. The comprehensive review concludes by highlighting the importance of interdisciplinary collaboration in advancing rock physics methodologies. By combining expertise from geophysics, petrophysics, geomechanics, and data science, the field can continue to innovate and improve the accuracy and reliability of pore pressure predictions, ultimately enhancing exploration and production efficiency in the oil and gas industry. Keywords: Advances, Rock Physics, Pore Pressure, Prediction, Future Directions.

Fulvenallenyl Radical (C7H5·)-Mediated Gas-Phase Synthesis of Bicyclic Aromatic C10H8 Isomers: Can Fulvenallenyl Efficiently React with Closed-Shell Hydrocarbons?

To understand the reactivity of resonantly stabilized radicals, often found in relevant concentrations in gaseous environments, it is important to determine their main reaction pathways. Here, it is investigated whether the fulvenallenyl radical (C7H5·) reacts preferentially with closed-shell molecules or radicals. Electronic structure calculations on the C10H9 potential energy surface accessed by the reactions of C7H5· with methylacetylene (CH3CCH) and allene (H2CCCH2) were combined with RRKM-ME calculations of temperature- and pressure-dependent rate constants using the automated EStokTP software suite and kinetic modeling to assess the reactivity of C7H5· with closed-shell unsaturated hydrocarbons. Experimentally, the reactions were attempted in a chemical microreactor heated to 998 ± 10 K by preparing fulvenallenyl radicals via pyrolysis of trichloromethylbenzene (C7H5Cl3) and seeding the radicals in methylacetylene or allene carrier gas, with product identification by means of photoionization mass spectrometry. The measured photoionization efficiency curve of m/z = 128 was assigned to a linear combination of the reference curves of two C10H8 isomers, azulene (minor) and naphthalene (major), presumably resulting from the C7H5· plus C3H4 reactions. However, the calculations demonstrated that these reactions are too slow, and kinetic modeling of processes in the reactor allowed us to conclude that the observation of naphthalene and azulene is due to the C7H5· plus C3H3· reaction, where propargyl is produced by direct hydrogen atom abstraction by chlorine (Cl) atoms from allene or methylacetylene and Cl stem from the pyrolysis of C7H5Cl3. Modeling results under the copyrolysis conditions of toluene and methylacetylene in high-temperature shock tube experiments confirmed the prevalence of the fulvenallenyl reaction with propargyl over its reactions with C3H4 even when the concentrations of allene and methylacetylene largely exceed that of propargyl. Overall, the reactions of fulvenallenyl with both allene and methylacetylene were found to be noncompetitive in the formation of naphthalene and azulene thus attesting the inefficiency of the fulvenallenyl radical reactions with the prototype closed-shell hydrocarbon species. In the meantime, the new reaction pathways revealed, including H-assisted isomerizations between C10H8 isomers and decomposition reactions of various C10H9 isomers, emerge as relevant and are recommended for inclusion in combustion kinetic models for naphthalene formation.

Study on fire resistance of high performance concrete nonplanar beam-wall joints

The utilization of high performance concrete (HPC) in the core region of beam-wall joints can enhance the structural integrity and load-bearing capacity of prefabricated buildings. However, due to the high-temperature bursting characteristics of HPC, the mechanical properties of the joints degrade prematurely under fire. In this paper, the fire resistance of HPC nonplanar beam-wall joints was investigated using high-temperature experiments and numerical simulations. First, the prefabricated beam-wall joint and the cast-in-place beam-wall joint proposed in this study were subjected to high-temperature and post-fire static loading tests, enabling a comparative analysis of their fire resistance and load-bearing capacity. The results demonstrated that the utilization of HPC in the core region of the prefabricated beam-wall joints can enhance its load-bearing capacity and fulfill the fire resistance requirements. Subsequently, a finite element model of the nonplanar beam-wall joint was established based on test results to investigate the influence of different structural parameters on its post-fire mechanical properties. The results demonstrate that the diameter of vertical reinforcement in the wall can significantly influence the post-fire load-bearing capacity of the joints, while the concrete strength in the core area of the joints has little impact on the post-fire bearing performance of the joints. Compared to the conventional cast-in-place beam-wall joints with normal strength concrete, the prefabricated beam-wall joints have superior fire resistance and post-fire load-bearing performance.