High-temperature Characteristics Research Articles

The influence of rice bran oil and nano-calcium oxide into bitumen as sustainable modifiers

Bio-oils are increasingly used to enhance petroleum bitumen’s intermediate and low-temperature characteristics regarding their economic and environmental benefits. Research has shown a beneficial impact of nanomaterials on altering bitumen’s high-temperature characteristics. The present study uses a mixture of rice bran oil and nano-calcium oxide to improve the performance of bitumen in all three temperature conditions. Rice bran oil was added to pure bitumen at doses of 3, 5, and 7 % relative to the weight of bitumen. The rheological tests (dynamic shear rheometer, multiple stress creep recovery, linear amplitude sweep, and bending beam rheometer) demonstrated that using rice bran oil in bitumen enhanced its performance at intermediate and low-temperatures but declined its performance at high-temperatures. Therefore, to improve the performance at high-temperatures, the bituminous sample containing 5 % rice bran oil was combined with 1, 3, and 5 % nano-calcium oxide, followed by repeating the rheological tests on them. The samples modified with nano-calcium oxide showed increased friction and shear stress, viscosity, and rutting parameters. Besides, the samples exhibited reduced sensitivity to aging compared to the bio-oil samples. However, the non-recoverable creep compliance and percentage of recovery showed improvements. The fatigue life of bio-oil samples decreased after adding nano-calcium oxide. However, the fatigue life remained higher than the base bitumen sample when adding 1 % nano-calcium oxide. Fourier-transform infrared spectroscopy analysis showed that a new chemical reaction occurred due to adding nano-calcium oxide to bitumen containing rice bran oil. Besides, the scanning electron microscope image revealed that the nano-calcium oxide particles are uniformly and homogeneously distributed within the bitumen sample containing 5 % rice bran oil. Consequently, the mix containing 5 % rice bran oil and 3 % nano-calcium oxide increases the resistance against high-temperature failures and improves the low-temperature performance compared to the base bitumen sample.

Supersonic plasma-sprayed TiO2 coating: Performance optimization based on response surface methodology and tribological properties

This study investigated the microstructure and tribological performance of TiO2 coating prepared through the plasma-spraying of TiO2 on an aluminum alloy (ZL109) surface. Box–Behnken design was employed to calculate the optimal spraying parameters (spraying current: 439 A, spraying voltage: 129 V, and Ar flow rate: 117 m3/h). High-temperature tribological characteristics (T = 120 °C) were examined under varying loads (F = 100 N, 120 N, and 140 N). The scanning electron microscopy and energy-dispersive X-ray spectroscopy analysis results revealed that the coating porosity decreased from 3.31 % to 0.31 % with the increase in the spraying voltage from 120 V to 130 V. Both powder and coating exhibited consistent elemental composition (Ti, O) and phase composition (TiO2, TiO, Ti2O3). During the spraying process, part of the powder was oxidized. The average coefficient of friction of the coatings varied from 0.05 to 0.08, and as the load increased, the wear mechanism of the coating changed from abrasion to adhesive wear and oxidation.

Study on the Law of Rock Drillability under High-Temperature and High-Pressure Conditions in the Western Margin of the Ordos Basin

The deep strata in the Ordos Basin exhibit characteristics of high temperature and high stress. Conventional methods for assessing drillability (normal temperature and pressure) fail to accurately understand the drilling resistance characteristics of deep rocks in this region, leading to improper guidance for selecting formation drilling tools and prolonging drilling cycles. This study employs physical experiments and numerical simulations to conduct drillability tests on core samples taken from the region under high-temperature and high-pressure conditions, simultaneously simulating the rock breaking process under different temperature and pressure conditions. The study investigates the variation patterns of rock drillability grade values and von Mises stress values during rock breaking under single-factor and multi-factor analyses of temperature and pressure conditions. Combining these variation patterns, an optimization analysis of the back rake angle of PDC drill bits used in drillability experiments is conducted to guide the selection of drill bits on site. The results indicate that the variation patterns of von Mises values from finite element simulations are consistent with the drillability grade values under high-temperature and high-pressure conditions. Under single-factor conditions, von Mises stress and drillability grade values generally increase with rising temperature before decreasing, while they increase with increasing confining pressure. Under multi-factor conditions, confining pressure is the primary influencing factor within the range of 0 to 50 MPa, while the influence of temperature becomes prominent between 180 °C to 200 °C, with a weakening effect of confining pressure. Model application: Selecting a back rake angle of 30° for PDC drill bits yields optimal rock-breaking results. The research findings hold significant implications for understanding the low rock-breaking efficiency of deep strata, optimizing drill bit parameters, and enhancing drilling efficiency.

Mechanical failure analysis of drill string aggravated by stuck pipe after high-temperature melting-cutting operations

High-temperature melt cutting is an important technology for fast cutting and unjamming of downhole jammed tubular rods, but due to the well depth and mud environment, it cannot completely cut through the large wall thickness tubular rods such as weighted drill pipe, and it needs to be damaged by external load applied by drilling rig. The shape of the drill pipe kerf after the melt cutting operation is not the same, so the size of the applied external load needs to be further investigated. To address this problem, firstly, this paper establishes the Johnson-Cook ontology and failure model of S135 steel grade drilling tools based on the high temperature tensile test; secondly, according to the characteristics of the weighted drill pipe melt-cutting notch, a finite element model for mechanical damage failure analysis of weighted drill pipe with melt-cutting notch is established, and the reliability of the model is verified; lastly, the influence of high temperature and different notch characteristics (melt-cutting depth, circumferential cutting angle, Finally, the effects of high temperature and different notch characteristics (depth of cut, circumferential cutting angle, number of perforations) on the mechanical failure capacity of weighted drill pipe with fusion notch are analysed. The results show that the errors of the maximum stresses and strains of the samples obtained from the tensile fracture simulations at 20 °C and 400 °C and the maximum stresses and fracture strains obtained from the experiments are within 9 %, which verifies the accuracy of the model. Tensile loading was more effective than compressive loading in destroying the drill pipe; the change in loading speed had a small effect of 4.1 % on the tensile force required to destroy the drill pipe. The damage load of the drill pipe and the pressure acting on the cross-section of the fusion cut decreases with the increase of the fusion cutting depth; the damage load required decreases with the increase of the circumferential cutting angle and the number of openings, but the pressure acting on the cross-section of the fusion cut does not decrease. The softening effect of high temperature on the drill pipe is very obvious, and the tensile capacity of the drill pipe is attenuated by 80.6 % at a temperature of 800 °C. The research work can improve the operation process of cutting and unjamming thick-walled drilling tools in deep wells and guide the field operation to achieve the purpose of rapid unjamming.

Experimental research on high-temperature radiation characteristics of film-cooled plate of gas turbines

With the rise in pre-turbine temperature and advancements in cooling technology, the temperature gap between the hot-gas and the blades increases. This phenomenon accentuates the significance of high-temperature radiation. However, the relevant experiments available to provide quantitative assessments of radiation are limited because of the challenging task of designing, constructing, and operating a high-temperature radiation facility. In this study, a high-temperature radiation facility is constructed to study the measurement method of evaluating radiation. The radiative heat flux of film-cooled plate of gas turbines are quantified successfully through the presented infrared-thermocouple dual reference body measurement and regression technique based on thermocouple data. The two proposed methodologies can pave the way for novel research avenues in evaluating radiation of the guide vanes. It is found that the proportion of radiation to total heat flux decreases gradually as the wall temperature increases. When the mainstream temperature is 912 K and the coolant temperature is 303 K, the radiation constitutes 50 % of the total heat flux.

High-Temperature Characteristics of Polyphosphoric Acid-Modified Asphalt and High-Temperature Performance Prediction Analysis of Its Mixtures

To promote the application of economical and sustainable polyphosphoric acid (PPA)-modified asphalt in road engineering, styrene-butadiene block copolymer (SBS), styrene-butadiene rubber (SBR), and PPA were used to prepare PPA/SBS and PPA/SBR composite-modified asphalts, which were tested and the data analyzed. Fourier transform infrared spectroscopy (FTIR) tests and thermogravimetric analysis (TG) tests were carried out to study the modification mechanisms of the composite-modified asphalts, and the high-temperature performance of the PPA-modified asphalt and asphalt mixtures was analyzed by dynamic shear rheology (DSR) tests and wheel tracking tests. A gray correlation analysis and a back-propagation (BP) neural network were utilized to construct a prediction model of the high-temperature performance of the asphalt and asphalt mixtures. The test results indicate that PPA chemically interacts with the base asphalt and physically integrates with SBS and SBR. The PPA-modified asphalt has a higher decomposition temperature than the base asphalt, indicating superior thermal stability. As the PPA dosage increases, the G*/sinδ value of the PPA-modified asphalt also increases. In particular, when 0.6% PPA is combined with 2% SBS/SBR, it surpasses the high-temperature performance achieved with 4% SBS/SBR, suggesting that PPA may be a good alternative for polymer modifiers. In addition, the creep recovery of PPA-modified asphalt is influenced by the stress level, and as the stress increases, the R-value decreases, resulting in reduced elastic deformation. Furthermore, the BP neural network model achieved a fit of 0.991 in predicting dynamic stability, with a mean percentage of relative error (MAPE) of 6.15% between measured and predicted values. This underscores the feasibility of using BP neural networks in predictive dynamic stability models.

Long-term aging simulation of asphalt mixture: A comparative experimental study

In this study, the efficacy of the extended oven aging procedure outlined in NCHRP 973 for generating laboratory-produced reclaimed asphalt pavement (RAP) was explored. The study also sought to establish a correlation between the results obtained from the aged bitumen extracted from oven-aged asphalt mixture and PAV-aged bitumen. Both aging techniques, with varying durations, were applied, and a series of tests, encompassing penetration, softening point, rotational viscosity, bending beam rheometer, temperature sweep using dynamic shear rheometer, and FTIR, were conducted for comprehensive comparison. The outcomes revealed that the oven aging procedure has limited applicability for simulating the long-term aging of asphalt mixtures. At the temperature of 95°C, an increase in the oven aging duration had minimal impact on the degree of aging, especially beyond five days, as evidenced by various parameters such as penetration, softening point, viscosity, master curves of viscoelastic properties, aging index, and low-, intermediate-, and high-temperature characteristics of the different aged bitumens. Furthermore, a comparative analysis between PAV and bitumen extracted from oven-aged asphalt mixture indicated that bitumen aged for five days in the oven exhibited analogous properties to bitumen subjected to 1 cycle of PAV aging, encompassing chemical, rheological, and physical test results. In conclusion, while some researchers have suggested that performing 2 or 3 cycles of PAV aging may be necessary to simulate long-term aging, the findings indicate that oven aging of asphalt mixture cannot effectively simulate aging characteristics beyond 1 cycle of PAV aging.

High-Temperature Tensile Characteristics of an Al-Zn-Mg-Cu Alloy: Fracture Characteristics and a Physical Mechanism Constitutive Model.

High-temperature tensile tests were developed to explore the flow features of an Al-Zn-Mg-Cu alloy. The fracture characteristics and microstructural evolution mechanisms were thoroughly revealed. The results demonstrated that both intergranular fractures and ductile fractures occurred, which affected the hot tensile fracture mechanism. During high-temperature tensile, the second phase (Al2CuMg) at the grain boundaries (GBs) promoted the formation and accumulation of dimples. With the continual progression of high-temperature tensile, the aggregation/coarsening of dimples along GBs appear, aggravating the intergranular fracture. The coalescence and coarsen of dimples are reinforced at higher tensile temperatures or lower strain rates. Considering the impact of microstructural evolution and dimple formation/coarsening on tensile stresses, a physical mechanism constitutive (PMC) equation is herein proposed. According to the validation and analysis, the predictive results were in preferable accordance with the testing data, showing the outstanding reconfiguration capability of the PMC model for high-temperature tensile features in Al-Zn-Mg-Cu alloys.

Evaluation of High-Temperature Rheological and Aging Characteristics in Asphalt Binders Modified with Recycled High-Density Polyethylene and Recycled Polypropylene

Evaluation of High-Temperature Rheological and Aging Characteristics in Asphalt Binders Modified with Recycled High-Density Polyethylene and Recycled Polypropylene

Non-flammable long chain phosphate ester based electrolyte via competitive solventized structures for high-performance lithium metal batteries

Safety remains a persistent challenge for high-energy–density lithium metal batteries (LMBs). The development of safe and non-flammable electrolytes is especially important in harsh conditions such as high temperatures. Herein, a flame-retardant, low-cost and thermally stable long chain phosphate ester based (tributyl phosphate, TBP) electrolyte is reported, which can effectively enhance the cycling stability of highly loaded high-nickel LMBs with high safety through co-solvation strategy. The interfacial compatibility between TBP and electrode is effectively improved using a short-chain ether (glycol dimethyl ether, DME), and a specially competitive solvation structure is further constructed using lithium borate difluorooxalate (LiDFOB) to form the stable and inorganic-rich electrode interphases. Benefiting from the presence of the cathode electrolyte interphase (CEI) and solid electrolyte interphase (SEI) enriched with LiF and LixPOyFz, the electrolyte demonstrates excellent cycling stability assembled using a 50 μm lithium foil anode in combination with a high loading NMC811 (15.4 mg cm−2) cathode, with 88% capacity retention after 120 cycles. Furthermore, the electrolyte exhibits excellent high-temperature characteristics when used in a 1-Ah pouch cell (N/P = 0.26), and higher thermal runaway temperature (238 °C) in the ARC (accelerating rate calorimeter) demonstrating high safety. This novel electrolyte adopts long-chain phosphate as the main solvent for the first time, and would provide a new idea for the development of extremely high safety and high-temperature electrolytes.

The excellent adaptability to large temperature differences of alkali-activated slag using Na2SO4+ Ca(OH)2 as the activator

The thickening time of NaOH-activated slag system is difficult to control by retarders, which limits its application in oil and gas well cementing. To facilitate the application of alkali-activated slag, the high-temperature thickening and strength characteristics of Na2SO4+Ca(OH)2 activated slag, Na2CO3+Ca(OH)2 activated slag and NaOH activated slag were studied in this paper. It is found that the strength properties of the three are similar, with a strength of about 18 MPa for 72 h. The Na2SO4+Ca(OH)2 activated slag system has superior high-temperature thickening performance (up to 180℃) and extensive temperature difference adaptability (25–180℃). With similar thickening time at 120℃, the Na2SO4+Ca(OH)2 activated slag system has a strength of up to 15 MPa at 48 h at a low temperature of 25℃, and the Portland cement don’t set at 48 h. The Na2SO4+Ca(OH)2 activated slag system shows good thickening properities at 180℃ while still maintaining rapid strength development at 25℃. The large temperature difference adaptability of Na2SO4+Ca(OH)2 activated slag is apparently better than that of Portland cement. The mechanism analysis shows that the effective control of the retarder on the reaction of Na2SO4 and Ca(OH)2 to generate NaOH, and the low-temperature sensitivity of the reaction of Na2SO4 and Ca(OH)2 under the action of the retarder are the main reasons why the ease of adjusting the high-temperature thickening time of the Na2SO4 and Ca(OH)2 activated slag, and the good performance of large temperature difference adaptability. This provides a new way to solve the problem of over-retarding at the top of cement slurry column for long sealing section in deep wells.

Melting and Flow Behavior of Coal Ash at High Temperatures Based on SiO2-Al2O3-CaO/Na2O Pseudoternary Phase Diagram.

The entrained-flow gasifier has a better adaptability to various coals. The composition of coal ash is an important factor affecting the high-temperature flow characteristics of molten slag. Based on the SiO2-Al2O3-CaO/Na2O ternary phase diagram, the high-temperature molten flow characteristics of slag located in the main phase regions of feldspar, melilite, diopside, and mullite were investigated by experiments and thermodynamic software calculations. The results indicate that the melting process of ash in the three phase zones is influenced by different factors. It was discovered by infrared spectroscopy analysis that the slag was dominated by Si2O52- ion clusters in the feldspar region. The slag in the diopside region had a slightly higher proportion of simple silicate ion clusters than the slag in the feldspar region, resulting in better fluidity. This is significant for revealing the mechanism of coal ash melting and flowing and guiding industrial coal blending.

Metal intrusion enhanced deep learning-based high temperature deterioration analysis of rock materials

The deep learning-based method demonstrates superior capability in high-temperature deterioration analysis of rock materials through scanning electron microscopy (SEM) characterization. However, the blurred boundaries between rock particles and pore structure presented in SEM images always affect the training efficiency. Hence, in this study, the metal intrusion technology and backscattered electron (BSE) observations are applied to assist a deep learning-based model to analyze the deterioration of the rock materials exposed to different levels of high temperatures. >2000 micro images for each level were inputted and trained to distinguish the features of rock after 5 temperature levels deterioration. The results reveal that the classification accuracy on the heat deterioration of the rock materials achieved 94.3%. The classification accuracy under the optimized observation area (from 240 pixels × 240 pixels to 280 pixels × 280 pixels) is stable over 90%, balancing the high precision and training efficiency. Moreover, the interpretable high-temperature degradation characteristics of the micro-damage on rock particles and pore regions can be extracted, enabling further analysis of the degradation process of high-temperature treated rocks. We expect this work will inspire a high-precision, wide-application and cost-efficient method for the deterioration analysis of rock materials in underground projects.

High-temperature oxidation characteristics of 20CrMnTi electroplated with copper

During high-temperature forming and phase change heat treatment, the steel surface is susceptible to oxidation. This can negatively affect the surface quality of steel parts. The production of antioxidant coatings on the surface of steel parts is important for high-temperature precision forming and heat treatment. In this paper, the high-temperature oxidation tests of 20CrMnTi steel, copper, and 20CrMnTi electroplated with copper are conducted. The 20CrMnTi samples showed varying degrees of mass gain above 900 °C; the copper samples showed varying degrees of mass gain above 700 °C; and the process of mass gain for copper-plated 20CrMnTi followed the same trend as for copper during heating and holding. For heated samples of 20CrMnTi plated with copper, the copper coating was oxidized and residual copper was observed in the oxide layer. The distance between the residual copper and the surface of the sample is greater than between the residual copper and the junction of the plating layer and the substrate. Oxygen diffuses through internal defects in the material at a higher rate than copper oxidation. In this study, an oxygen diffusion model and an antioxidant protective layer model at high temperatures were suggested. The protective layer against oxidation recommended in this research is a dense coating consisting of single crystals or fine grains free of porosities and cracks.

Experimental investigation on hydrogen jet flame behavior and temperature distribution with different shapes of outlet

Hydrogen's wide flammability range causes its high-pressure jet flames to exhibit large-scale, high-temperature characteristics, posing risks of casualties and property damage. This study investigates the impact of different nozzle shapes and release pressures on flame behavior and temperature distribution through high-pressure hydrogen jet flame experiments. Circular outlets (0.5–4 mm diameter) and rectangular outlets (aspect ratios 1 to 8) are used, covering release pressures from 20 to 220 bar. High-pressure hydrogen is released through a nozzle into ambient air, igniting to form a flame. Flame length, width, and axial temperature are measured. Findings indicate that visible flame size increases with release pressure. The models for dimensionless visible flame length and width, considering the dimensionless heat release rate, are proposed for different nozzle shapes. Additionally, the dimensionless temperature rise along the flame axis is observed to be a function of the dimensionless distance and dimensionless heat release rate.

High-entropy chromate (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)CrO3 for high-temperature NTC thermistors

This paper presents a novel rare earth-based chromate (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)CrO3 for high-temperature thermistor applications. X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, and X-ray photoelectron spectroscopy tests reveal that the material is a high-entropy ceramic with a perovskite structure, exhibiting a dense microstructure with a relative density of 97.6 %. Electrical analysis shows that (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)CrO3 exhibits high resistivity at high temperatures but with a material constant of 1,968 K, making it capable of meeting the resistance requirements for commercial thermistors over an ultrawide temperature range of 25 – 1,300 °C. AIMD simulations indicate the excellent structural stability of (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)CrO3 even at 1,300 °C, suggesting promising high-temperature aging characteristics. Further aging tests demonstrate that its resistance only drifted by 4.57 % after being subjected to 1,300 °C for 1,000 h. The above findings represent breakthroughs in terms of maximum operating temperature, applicable temperature range, aging performance and sintering densification for chromate-based high-temperature thermistor ceramics.

Performance evaluation of asphalt binders incorporating surface-modified diatomite and bio-oil: A value-added utilization of natural resource

To study the effect of surface-modified diatomite (SMD) on bio-asphalt performance, the asphalt binders incorporating SMD and bio-oil (SMDB) was prepared with different dosages. The high-temperature characteristics of SMDB were assessed by consistency test, viscosity test, and dynamic shear rheometer (DSR). Meanwhile, the low-temperature characteristics of SMDB were evaluated by bending beam rheometer (BBR) and ductility test. The compatibility of SMDB was assessed by a storage stability test and a Fluorescence microscope (FM). The adhesion and chemical composition of SMDB were analyzed using the sessile drop method and Fourier transform infrared (FTIR) spectroscopy, respectively. Finally, the moisture stability and high-temperature properties of the SMDB mixture were studied using the tensile strength ratio (TSR) test and wheel track test, respectively. The preliminary results of this work show that the addition of SMD increases the viscosity, softening point, fatigue index, and rutting factor of asphalt and reduces the penetration. It is found that SMD improves the anti-aging performance, adhesion performance, and high-temperature stability of SMDB. Although SMD has a negative effect on the low-temperature properties and fatigue resistance of asphalt, the characteristics of SMDB at low temperatures are still superior to those of virgin asphalt. SMD at low content had little effect on the fatigue resistance of the bio-asphalt. Moreover, it is found that SMD is better than the original diatomite in enhancing bio-asphalt properties more significantly. In addition, the blending among SMD, asphalt matrix, and bio-oil is the physical modification, and the mixture has excellent storage stability. Finally, the mixture property testing results indicate that SMD improves the rutting and moisture resistance of the SMDB mixture.

Revealing the effect of Gd alloying on oxidation resistance and oxide film protection performance of AZ80 alloy

The high-temperature oxidation behaviors and oxide film characteristics as well as corrosion protection of AZ80 and AZ80–0.75Gd (wt%) alloys were investigated to research the effect of Gd addition on oxidation resistance and oxide film corrosion protection performance of AZ80 alloy. The results showed that with 0.75 wt% Gd alloying, Gd2O3 appeared in oxide film, which promoted densification of oxide film and translation of the superlinear rate law oxidation kinetics to approximate parabolic rate law oxidation kinetics of alloy. And after erosion of oxide film containing Gd2O3, the corrosion products were extensively nodulated, resulting in corrosion passivation and showing protection effect.

Investigation of Two High-Temperature Bipolar Phenomena and Characteristics of 1.2-kV SiC Power Diodes for High-Temperature Applications

Investigation of Two High-Temperature Bipolar Phenomena and Characteristics of 1.2-kV SiC Power Diodes for High-Temperature Applications

A Comparison Study on the Microstructure, Mechanical Features, and Tribological Characteristics of TiN Coatings on Ti6Al4V Using Different Deposition Techniques

Titanium alloys are considered lightweight alloys and are widely applied across various industries. However, their low hardness, poor wear resistance, and limited oxidation resistance restrict their prospects for wider application. In this paper, nitride coatings were prepared using three preparation processes, namely laser surface nitriding (LSN), physical vapor deposition (PVD), and plasma ion implantation (PII). Their microstructure, microhardness, tribological behavior, and high-temperature oxidation characteristics were compared. The experimental results revealed that nitrided coatings were successfully prepared using the three methods. However, a comparison of these data shows that the LSN coating exhibited superior comprehensive performance. It achieved the maximum thickness within the shortest preparation time: the thickness was about 280 μm and the deposition rate of the LSN method was 2250 and 90,000 times higher than those of the PVD and PII methods. Nitrides have high hardness, but the carrying capacity could be attributed to the thickness of the coatings: the PVD coating could withstand a force of 500 g, while the PII coating only withstood a force of less than 25 g. In addition, as hardness is the most important factor for excellent wear resistance, the average volumetric wear rate of the LSN and PVD coatings was about 9 × 10−6 mm3/m·N, and their relative wear resistance was 49.2 times that of Ti6Al4V. Meanwhile, the excellent bond between the LSN coating and the substrate was evidenced by a high-temperature oxidation test during a rapid heating–cooling cycle.