High-speed Observations Research Articles

Methodology for Surface Reconstruction and Prediction Based on the Electrical Discharge Machining Removal Mechanism of Cf-UHTC Materials.

Cf-UHTC is an ideal aerospace material because of its exceptional properties, but its machinability is facing great challenges. Electrical discharge machining (EDM) offers a potential solution, but its removal mechanism remains unclear, lacking reliable prediction tools to guide the actual production. This paper deeply explores the EDM removal mechanism of Cf-ZrB2-SiC through single-pulse experiments, high-speed camera observations, and thermal-fluid coupling simulations, revealing key processes like heat transfer, phase transformation, molten pool dynamics, crater formation, and reinforcing phase effects. And the prediction of single-pulse removal with different parameters is also realized. Based on experimental and simulation results, a random continuous discharge model is developed, which deeply studies the dynamic erosion process, reconstructs EDM surfaces, and accurately predicts surface roughness. Furthermore, the thickness of the recast layer can be predicted based on the equivalent temperature method. Undoubtedly, this model provides an ideal approach for efficient production.

A novel late-stage oscillating discharge current for plasma regulation and its effect in material removal in electrical discharge machining

Abstract Improving the material removal rate (MRR) has recently become one of the most important issues in electrical discharge machining. During the discharge process, a large portion of molten material cannot be sufficiently expelled from the molten pool but re-solidifies, ultimately resulting in low energy utilization and machining efficiency. Unlike existing methods that primarily focus on optimizing general discharge parameters, this study aims to enhance molten material expulsion and MRR through discharge plasma regulation by employing a redesigned late-stage oscillating discharge current. During a single-pulse discharge process, this kind of discharge current firstly remains constant to ensure stable heat transfer from the plasma to the workpiece, then transitions to periodic oscillations to enhance plasma movement and facilitate molten material expulsion. High-speed plasma observations and heat-flow coupling simulations are conducted to analyze the effects of the discharge currents on material removal, and the optimal oscillation start time is obtained. Experimental results in machining stainless steel demonstrate that the use of the late-stage oscillating discharge current, in comparison to the conventional rectangular discharge current, results in a 74% increase in material removal volume per unit of energy and a 56% in average recast layer thickness.

Combustion characteristics of Ammonia/Air mixture ignited by flame jet with and without hydrogen injection in Pre-Chamber

Ammonia is one of the important fuels that can promote the achievement of carbon neutrality, but its combustion characteristics are not conducive to its application in engines. Injecting hydrogen in the pre-chamber to form a flame jet to ignite the ammonia/air mixture is a method to improve the combustion of ammonia. This ignition method was investigated with the constant volume combustion chamber, high-speed video camera observation and the main-chamber pressure analysis. The flame behavior and combustion characteristics were compared with those ignited by the ammonia flame jet. Hydrogen flame jet significantly enhanced the combustion of the mixture and extended the lean flammability limit. Under conditions of hydrogen injection, the pressure rise delay and combustion duration became shorter, the average heat release rate became higher, and the combustion process was more stable. The hydrogen flame jet rapidly penetrated the main-chamber and impinged on the lower surface, generating intense turbulence. As a result, the combustion pressure took less time to rise from 10% to 50% than it did to go from 50% to 90%. This was different from the situation without hydrogen injection, where time required for both was similar. The hydrogen flame jet was shuttle-shaped when touching the lower surface owing to the rapid combustion speed of hydrogen, while the ammonia flame jet was spindle-shaped with the flame kernel in the center. The combustion process of the flame jet igniting the mixture exhibited two peaks in the heat release rate, reflecting two combustion stages dominated by the flame jet and flame propagation.

Spatter detection and tracking in high-speed video observations of laser powder bed fusion

PurposeIn laser powder bed fusion (L-PBF) additive manufacturing, spatter particles are ejected from the melt pool and can be detrimental to material performance and powder recycling. Quantifying spatter generation with respect to processing conditions is a step toward mitigating spatter and better understanding the phenomenon. This paper reveals process insights of spatter phenomena by automatically annotating spatter particles in high-speed video observations using machine learning.Design/methodology/approachA high-speed camera was used to observe the L-PBF process while varying laser power, laser scan speed and scan strategy on a constant geometry on an EOSM290 using Ti-6Al-4V powder. Two separate convolutional neural networks were trained to segment and track spatter particles in captured high-speed videos for spatter characterization.FindingsSpatter generation and ejection angle significantly differ between keyhole and conduction mode melting. High laser powers lead to large ejections at the beginning of scan lines. Slow and fast build rates produce more spatter than moderate build rates at constant energy density. Scan strategies with more scan vectors lead to more spatter. The presence of powder significantly increases the amount of spatter generated during the process.Originality/valueWith the ability to automatically annotate a large volume of high-speed video data sets with high accuracy, an experimental design of observed parameter changes reveals quantitively stark changes in spatter morphology that can aid process development to mitigate spatter occurrence and impacts on material performance.

Fundamental study on dielectric oil viscosity for high-performance wire EDM

Dielectric oil has been recently used in wire electrical discharge machining (wire EDM) for achieving high-precision machining. However, the influence of dielectric oil properties on wire EDM characteristics has not been clarified sufficiently. This study fundamentally investigated the influence of dielectric oil viscosity on wire EDM characteristics. In this study, three types of dielectric oil differing only in viscosity were prepared and examined. Linear cutting experiment results showed that the removal rate and the machined surface roughness increase with dielectric oil viscosity. Then, the influence of viscosity on crater removal volume was investigated to discuss the cause of the change in removal rate, and it was found that crater removal volume increases with the viscosity. Furthermore, CFD (computational fluid dynamics) analysis results and discharge observation results showed that the debris exclusion becomes worse in higher viscosity oil, and the discharge concentration occurs frequently, resulting in the deterioration in machined surface roughness. Next, the difference in machining accuracy with dielectric oil viscosity was investigated. It was found that the corner shape accuracy deteriorates with the increase of viscosity while the machined surface waviness and straightness improve slightly. Structural analysis results showed that wire deflection increases with viscosity, resulting in the deterioration in corner shape accuracy. On the other hand, high-speed observation of wire vibration was carried out, and it was found that the wire vibration decreases in the case of higher viscosity, which leads to the improvement in machined surface waviness and straightness.

Fractal dimension analysis of lightning discharges of various types based on a comprehensive literature review

In this study, photographic records of natural lightning flashes obtained from high-speed video camera observations are analyzed based on an extensive literature review. The purpose of this work is to estimate the fractal dimension of lightning discharges and to analyze and evaluate the effect of lightning type (downward and upward flashes during their propagation as well as return strokes) and lightning polarity (negative and positive). Three methods of fractal dimension estimation are employed namely the: (i) box-counting, (ii) sandbox, and (iii) correlation method, utilizing algorithms developed in MATLAB software. Appropriate image processing techniques are employed to guarantee precision in fractal dimension estimation. A thorough discussion is conducted by comparing the estimated fractal dimension values with those previously documented in the relevant literature based on field observations. The mean fractal dimension of downward negative leaders for the three methods (1.18, 1.31, 1.38) aligns well with previous studies, while positive downward leaders exhibit lower values (1.08, 1.15, 1.26), denoting a reduced branching behavior; upward leaders demonstrate slightly higher fractal dimensions than downward ones. Additionally, an attempt to correlate the lightning return stroke peak current with the fractal dimension is made. The outcomes of this research may assist in facilitating precise modeling of the lightning attachment phenomenon, thereby contributing to the development of safer lightning protection systems.

The Influence of the Gap Phenomenon on the Occurrence of Consecutive Discharges in WEDM Through High-Speed Video Camera Observation

The Wire Electrical Discharge Machining (WEDM) process is an accurate method for manufacturing high-added-value components for industry. Continuous developments in the process have resulted in specialized machines used in sectors such as aerospace and biomedical engineering. However, some fundamental aspects of the discharge process remain unresolved. This work aims to study the influence of discharge location and bubble expansion on the occurrence of subsequent discharges. A high-speed video camera observation system was constructed to capture images of each discharge. From the acquired images, an algorithm was devised to determine the discharge location based on grayscale analysis. Moreover, the voltage and current waveforms of the discharges and the framing signals of the high-speed video camera were then obtained using an oscilloscope. Synchronizing the observation images and signals allowed for calculating the delay time for each single discharge. The results indicate that most of the discharges occurred near the boundary of the bubble and during bubble expansion. This finding has been observed for a variety of machining conditions and can be explained by the effect of the debris particles concentrated at the bubble boundary. This study provides useful information for better understanding the discharge process in WEDM.

Ultrasonic vibration-assisted femtosecond laser submerged ablation process for the preparation of titanium-based crack-free hydroxyapatite

Titanium alloy-based hydroxyapatite (HAp) coating materials are beneficial for reducing stress shielding and improving the biocompatibility of implants. However, the significant disparity in thermal conductivity between titanium alloy and hydroxyapatite results in the material being highly susceptible to cracking during preparation, which diminishes the mechanical properties of the material and predisposes the implant to aseptic loosening. To obtain coatings of HAp that are free of cracks, this study proposes a process method of ultrasonic-assisted femtosecond laser under-liquid ablation of a Ca/P solution to synthesize HAp by a one-step process and apply coatings on the surface of TC4 titanium alloy. The relationship between the laser process parameters and the resulting surface morphology, coating spatial distribution, elemental composition, chemical state of the elements, phase, coating thickness, coating bonding, friction coefficient, corrosion resistance and the number of cells was investigated through a series of analytical techniques, including high-speed photographic observation, scanning electron microscopy (SEM), X-ray Photoelectron Spectroscopy (XPS), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), scratch testing, Tafel plot and cell adhesion assays. The findings demonstrate that titanium-based HAp coatings with a thickness of 42.5 μm, a bonding force of 55 N, a polarization resistance of 10 Ω.cm2, the absence of cracks defects, and notable bioactivity can be produced with ultrasonic-assisted submerged laser ablation in a highly concentrated Ca/P solution. The proposed method represents a novel approach to the preparation of multifunctionalized implants.

Investigation of high internal phase water-in-oil emulsion on coal gasification fine slag flotation decarburization and its oil saving mechanism

Froth flotation stands as the preferred technique for the separation of charcoal and ash from coal gasification fine slag (CGFS). However, the presence of a well-developed pore structure and an abundance of oxygen-containing functional groups on the surface of residual charcoal necessitates the use of substantial dosage of collectors during the flotation of CGFS. To address this, a high internal phase water-in-oil (HIP W/O) emulsion, with an internal phase water volume fraction of 85 %, was formulated for the flotation decarburization of CGFS, with the objective of reducing the collector dosage. The outcomes of flotation tests demonstrated that at dosages of 50 kg/t for kerosene and 15.04 kg/t for the organic liquid of the HIP W/O emulsion, both were capable of yielding tailings with an ash content exceeding 95 %. The results from Cryo-SEM and viscosity tests suggest that the high viscosity characteristics of the HIP W/O emulsion are primarily attributed to the compact arrangement of emulsion droplets and the active influence of emulsifiers at the oil–water interface. High-speed camera observations revealed that the HIP W/O emulsion droplets exhibited a tendency to disperse into bar-shaped flocs with larger particle sizes in water. This particular dispersion morphology is advantageous for enhancing the oil agglomeration flotation mechanism within the flotation decarburization process of CGFS. LF-NMR tests have further substantiated that the emulsion droplets are not readily absorbed by the microporous structure of the residual charcoal within the CGFS. Wettability tests and FTIR analyses have demonstrated that the hydrophobic modification of the residual charcoal surface, achieved through the HIP W/O emulsion, markedly surpasses that of conventional kerosene. The combination of these results indicates that the use of HIP W/O emulsion in the flotation decarbonization process of CGFS offers multiple benefits. It not only significantly reduces the dosage of organic collectors required, but also enhances the economic efficiency and effectiveness of the flotation process, presenting a novel reagent option for the decarbonization of CGFS.

Interdependence of metal vapor plume and melt pool dynamics during laser beam welding under vacuum

Deep penetration laser beam welding involves the emission of hot metal vapor and particles from the keyhole, which interact with the laser beam by means of scattering, absorption, and phase front deformation. The combination of scattering and absorption leads to an extinction of the laser beam, while the phase front deformation adversely affects the beam quality. The capillary formation depends on the local distribution of the absorbed irradiance of the laser beam, which in turn is related to the material process emissions. Additionally, the process atmosphere, in particular the oxygen content, and the working pressure influence the capillary fluctuations and cause variations in welding penetration. This study introduces a measurement setup using simultaneous high-speed observation of the melt pool and the keyhole while measuring the interaction mechanisms between the laser beam and the metal vapor plume during laser beam welding under vacuum of stainless steel. The obtained measurement provides a quantification of the various interaction mechanisms between the laser beam, vapor plume, keyhole, and interdepended melt pool dynamics. These quantitative high-frequency measurements at various working pressures and laser parameters provide useful insights that are crucial for understanding the formation of weld defects, resulting in process monitoring and validation of process-oriented welding simulations.

Dynamic behavior regulation of droplet transfer based on arc-bubble control by ultrasound-induced during underwater wet welding

In comparison to welding in air, the periodic formation of unstable arc bubbles is a significant factor contributing to the unstable mass transfer process during underwater wet welding (UWW). Up to now, there is no ideal method to control droplet transfer and improve arc stability. In this study, the ultrasound-induced method (UIM) was used to regulate the droplet transition behavior and improve the process stability. The behavior features and key mechanisms of arc-bubble and droplet transfer induced by ultrasound were revealed with the employment of highspeed camera and X-ray observation, respectively. The incident angle of ultrasound was taken as a variable to reveal its effects and mechanism of action on the behaviors of arc bubble and droplet transfer, weld formation quality, microstructure, and property of weld joint. The results show that ultrasound-induced a new rising mode of arc bubble, which can significantly reduce the repulsive resistance that come from the bubble rising on the droplet transfer process. Compared with underwater wet welding without ultrasound, the average diameter of molten droplets reduces from 3.2 mm to 1.7 mm, and the droplet transfer frequency increases from 7.8 Hz to 13 Hz as the incident angle of ultrasound increases to 60°. In addition, the weld seam without obvious defects could be produced by UWW with UIM, of which the Variation coefficient of weld reinforcement is reduced from 21.3 to 11.6 and 17.4 at an ultrasonic incident angle of 30° and 45°. With increasing of ultrasound incident angle, it showed that the microhardness of the weld joint has a slight increase. In the heat-affected zone, the microhardness for the joint increased from 290 HV to 320 HV while the incident angle increased to 60°. This research shows that an appropriate incident angle of ultrasound can obtain good-quality joints which has a stable metal transfer process in underwater wet welding.

Real-time mapping of photo-sono therapy induced cavitation using Doppler optical coherence tomography.

Photo-sono therapy (PST) is an innovative anti-vascular approach based on cavitation-induced spallation. Currently, passive cavitation detection (PCD) is the prevalent technique for cavitation monitoring during treatment. However, the limitations of PCD are the lack of spatial information of bubbles and the difficulty of integration with the PST system. To address this, we proposed a new, to the best of our knowledge, cavitation mapping method that integrates Doppler optical coherence tomography (OCT) with PST to visualize bubble dynamics in real time. The feasibility of the proposed system has been confirmed through experiments on vascular-mimicking phantoms and in vivo rabbit ear vessels, and the results are compared to high-speed camera observations and PCD data. The findings demonstrate that Doppler OCT effectively maps cavitation in real time and holds promise for guiding PST treatments and other cavitation-related clinical applications.

Insights into ground strike point properties in Europe through the EUCLID lightning location system

Abstract. Evaluating the risk of lightning strikes to a particular structure typically involves adhering to the guidance outlined in IEC 62305-2. Among the multitude of factors influencing the overall risk, flash density emerges as a crucial parameter. According to its definition, each flash is assigned only one contact point to ground. Nevertheless, it is well known that, on average, flashes exhibit multiple ground termination points as shown by high-speed camera observations. In this research, lightning data collected by the European Cooperation for Lightning Detection (EUCLID) network are utilized in combination with a ground strike point (GSP) algorithm that aggregates individual strokes within a flash into ground strike points. This approach enables the examination of spatio-temporal patterns of GSPs across Europe throughout a decade, spanning from 2013 to 2022. Average GSP densities exhibit variations across the European continent, mirroring the observed patterns in flash densities. The highest densities are concentrated along the Adriatic Sea and the western Balkan region, reaching peak values of up to 8.5 GSPs km−2 yr−1. The spatial distribution of the mean number of ground strike points per flash reveals a noticeable increase in the Mediterranean, Adriatic, and Baltic Sea regions compared to inland areas. Moreover, it has been determined that the average number of GSPs per flash reaches its peak between September and November. Additionally, a daily pattern is discernible, with the lowest number of GSPs per flash occurring between 12:00 and 18:00 UTC (universal time coordinated). It is found that 95 % of the separation distances between distinct GSPs are less than 6.7 km. Lastly, it is worth noting that the presence of the Alps has an impact on GSP behaviour, resulting in lower GSP counts in comparison to the surrounding areas, along with the shortest average distances between different GSPs.

Shedding of Cavitation Clouds in an Orifice Nozzle

Focused on the unsteady property of a cavitating water jet issuing from an orifice nozzle in a submerged condition, this paper presents a fundamental investigation of the periodicity of cloud shedding and the mechanism of cavitation cloud formation and release by combining the use of high-speed camera observation and flow simulation methods. The pattern of cavitation cloud shedding is evaluated by analyzing sequence images from a high-speed camera, and the mechanism of cloud formation and release is further examined by comparing the results of flow visualization and numerical simulation. It is revealed that one pair of ring-like clouds consisting of a leading cloud and a subsequent cloud is successively shed downstream, and this process is periodically repeated. The leading cloud is principally split by a shear vortex flow along the nozzle exit wall, and the subsequent cloud is detached by a re-entrant jet generated while a fully extended cavity breaks off. The subsequent cavitation cloud catches the leading one, and they coalesce over the range of x/d≈1.8~2.5. Cavitation clouds shed downstream from the nozzle at two dominant frequencies. The Strouhal number of the leading cavitation cloud shedding varies from 0.21 to 0.29, corresponding to the injection pressure. The mass flow rate coefficient fluctuates within the range of 0.59~0.66 at the same frequency as the leading cloud shedding under the effect of cavitation.

Extremely high spatiotemporal resolution microscopy for live cell imaging by single photon counting, noise elimination, and a novel restoration algorithm based on probability calculation.

Optical microscopy is essential for direct observation of dynamic phenomena in living cells. According to the classic optical theories, the images obtained through light microscopes are blurred for about half the wavelength of light, and therefore small structures below this "diffraction limit" were thought unresolvable by conventional optical microscopy. In reality, accurately obtained optical images contain complete information about the observed objects. Temporal resolution is also important for the observation of dynamic phenomena. A challenge exists here to overcome the trade-off between the time required for measurement and the accuracy of the measurement. The present paper describes a concrete methodology for reconstructing the structure of an observed object, based on the information contained in the image obtained by optical microscopy. It is realized by accurate single photon counting, complete noise elimination, and a novel restoration algorithm based on probability calculation. This method has been implemented in the Super-resolution Confocal Live Imaging Microscopy (SCLIM) we developed. The new system named SCLIM2M achieves unprecedented high spatiotemporal resolution. We have succeeded in capturing sub-diffraction-limit structures with millisecond-level dynamics of organelles and vesicles in living cells, which were never observed by conventional optical microscopy. Actual examples of the high-speed and high-resolution 4D observation of living cells are presented.

Experimental Study on Energy Evolution and Acoustic Emission Characteristics of Fractured Sandstone under Cyclic Loading and Unloading

To investigate the dynamic response of fractured rock under cyclic loading and unloading, a WHY-300/10 microcomputer-controlled electro-hydraulic servo universal testing machine was used to conduct uniaxial cyclic loading and unloading tests. Simultaneously, acoustic emission (AE) and a CCD high-speed camera were employed to monitor the fracturing characteristics of sandstone. The mechanical properties, energy evolution, AE characteristics, and deformation of 45° sandstone were analyzed. The results indicate that as the load cycle level increases, both the elastic modulus and deformation modulus exhibit a “parabolic” increase, with a rapid rise initially and a slower rate of increase later. The damping ratio generally shows a decreasing trend but tends to rise near the peak load. The total energy, elastic energy, dissipated energy, damping energy, and damage energy all follow exponential function increases with the load level. The b-value fluctuates significantly during the stable crack propagation phase, unstable crack propagation phase, and peak phase. When the FR (Felicity ratio > 1), the rock is relatively stable; when the FR (Felicity ratio < 1), the rock gradually extends towards an unstable state. The Felicity ratio can be used as a predictive tool for the precursors of rock failure. Shear fractures dominate during the compaction and peak phases, while tensile fractures dominate during the crack propagation phase, ultimately leading to a failure characterized by tensile fracture. High-speed camera observations revealed that deformation first occurs at the tips of the prefabricated cracks and gradually spreads and deflects toward the ends of the sandstone. This study provides theoretical support for exploring the mechanical behavior and mechanisms of fractured rock under cyclic loading and unloading, and it has significant practical implications.

Damage-tolerant behavior of structural epoxies with thin PEI and PVDF interlayers

This work examines the crack-arresting capability of PEI and PVDF thermoplastic interlayers in short-glass fiber modified and core–shell rubber toughened epoxy materials under mode-I fracture loading. Experimental results show that the initial crack can be effectively arrested by the thermoplastic-epoxy interface and reinitiation of this crack at the thermoplastic layer requires up to 2.5 times higher load than the crack initiation load of the pristine epoxies. The interlayered designs also exhibit a significant increase in energy absorption by up to 43 times more than their pristine counterparts. Competing damage mechanisms and failure events are captured by microscopy images, digital image correlation and high-speed photography observations. Additionally, elasto-plastic fracture mechanics models based on configurational material forces theory are developed for a preliminary crack-arresting material selection and to elucidate the material inhomogeneity effects.

Ionic Liquid Interface as a Cell Scaffold.

In sharp contrast to conventional solid/hydrogel platforms, water-immiscible liquids, such as perfluorocarbons and silicones, allow the adhesion of mammalian cells via protein nanolayers (PNLs) formed at the interface. However, fluorocarbons and silicones, which are typically used for liquid cell culture, possess only narrow ranges of physicochemical parameters and have not allowed for a wide variety of cell culturing environments. In this paper, it is proposed that water-immiscible ionic liquids (ILs) are a new family of liquid substrates with tunable physicochemical properties and high solvation capabilities. Tetraalkylphosphonium-based ILs are identified as non-cytotoxic ILs, whereon human mesenchymal stem cells are successfully cultured. By reducing the cation charge distribution, or ionicity, via alkyl chain elongation, the interface allows cell spreading with matured focal contacts. High-speed atomic force microscopy observations of the PNL formation process suggest that the cation charge distribution significantly altered the protein adsorption dynamics, which are associated with the degree of protein denaturation and the PNL mechanics. Moreover, by exploiting dissolution capability of ILs, an ion-gel cell scaffold is fabricated. This enables to further identify the significant contribution of bulk subphase mechanics to cellular mechanosensing in liquid-based culture scaffolds.

Plasma pretreatment to enhance the sedimentation of ultrafine kaolinite particles: Experiments and mechanisms

Coal-slime water treatment not only has a direct impact on the reuse of water as well as the recovery of coal-slime, but also has an essential significance for the sustainable development of a green ecology and carbon neutrality. In this study, the sedimentation behavior of ultrafine kaolinite particles (the main component of high-ash fine slime) using plasma pretreatment was investigated via sedimentation tests, turbidity detections and high-speed camera observations. The results showed that with plasma pretreatment, the arrival time of the maximum (final) thickness of the thickening layer considerably shortens, the final thickness of the thickening layer slightly decreases, and the turbidity of the supernatant significantly reduces. The mechanism of the plasma pretreatment method for the enhanced sedimentation of ultrafine kaolinite particles was elaborated via laser particle size analysis, microscopic observations, zeta potential determinations, and particle interaction energy calculations. The results showed that with plasma pretreatment, the zeta potential of kaolinite particles lowers, and the decrease in repulsive electrostatic force strengthens the coagulation of kaolinite particles, therefore making kaolinite flocs more compact and enhancing the sedimentation process of ultrafine kaolinite particles. And the enhanced sedimentation mechanism of ultrafine kaolinite particles via plasma pretreatment was drawn.

Ignition Delay and Reaction Time Measurements of Hydrogen–Air Mixtures at High Temperatures

Induction and reaction times of hydrogen–air mixtures (ϕ = 0.5–2) have been measured behind reflected shock waves at temperatures of 1000–1600 K, pressures of 0.1, 0.3, 0.6 MPa in the domain of the extended second explosion limit. The measurements were performed in the shock tube with a completely transparent test section of 0.5 m long, which provides pressure, ion current, OH and high-speed chemiluminescence observations. The experimental induction time plots demonstrate a clear increasing of the global activation energy from high- to low temperature post-shock conditions. This trend is strongly pronounced at higher post-shock pressures. For a high-temperature range of T > 1200 K, induction time measurements show an activation energy for the global reaction rate of hydrogen oxidation of 64–83 kJ/mole. Detected reaction times exhibit a big scatter and a weak temperature dependence. The minimum reaction time value was nearly 2 µs. Obtained induction time data were compared with calculations carried out in accordance with the known kinetic mechanisms. For current and former shock-tube experiments within a pressure range of 0.1–2 MPa, critical temperatures required for strong (1000–1100 K), transient and weak auto-ignition modes behind reflected shock waves were identified by means of the pressure and ion-probe measurements in stoichiometric hydrogen-air mixture. The transfer from the strong volumetric self-ignition near the reflecting wall to the hot spot ignition (transient) was established and visualized below <1200 K with a post-shock temperature decreasing.