High Recovery Research Articles

"Hedgehog Ball"-Shaped Nanoprobes for Multimodal Detection and Imaging of Inflammatory Markers in Osteosarcoma Using Fluorescence and Electrochemiluminescence.

Inflammation can affect the progression of cancer at tumor sites, such as in osteosarcoma, by intensifying metastasis and complicating outcomes. The current diagnostic methods lack the specificity and sensitivity required for early and accurate detection, particularly in differentiating between inflammation-induced changes and tumor activities. To address this, a novel "hedgehog ball"-shaped nanoprobe, Fe3O4@Au-pep-CQDs, was developed and designed to enhance the detection of caspase-1, a key marker of inflammation. This magnetic nanoprobe facilitates simultaneous fluorescence (FL) and electrochemiluminescence (ECL) detection. Magnetic separation minimizes the quenching of nanoparticles in solution and eliminates the need for frequent electrode replacement in ECL tests, thereby simplifying diagnostic procedures. The experimental results showed that in the detection of caspase-1, the nanoprobe had a detection limit of 0.029 U/mL (FL) and 0.033 U/mL (ECL) and had a dynamic range of 0.05 to 1.0 U/mL. Additionally, the nanoprobe achieved high recovery rates of 94.36 to 102.44% (FL) and 94.36-100.12% (ECL) in spiked biological samples. Furthermore, the nanoprobe's capabilities were extended to in vivo bioimaging to provide direct, intuitive visualization of biological processes. These novel nanoprobes were able to significantly enhance the accurate detection of inflammation at tumor sites, thereby optimizing both diagnostic and therapeutic strategies.

Correlation of in vitro digestibility with chemical composition and bioaccessibility of phenolic compounds in date pomace and antioxidant potential

ABSTRACT This study aimed to evaluate the chemical composition and impact of in vitro gastrointestinal digestion on the recovery, bioaccessibility, indices, and changes in the bioactive compounds of date pomace. Bioactive compounds were extracted using various solvents. The results revealed that pomace is a rich source of fiber. Methanol was found to be the most effective solvent for extraction of the bioactive compounds. A high recovery index for phenolic and flavonoid compounds and high antioxidant activity were obtained for the sample subjected to mouth-digestion. The bioaccessibility index revealed that a low percentage of phenols and flavonoids was available for absorption in the intestine. The TPC, TFC, and antioxidant activities (DPPH and ABTS) were positively correlated (r = 0.855-0.995) with oral, gastric, and intestinal digestion. Date pomace is an excellent source of bioactive compounds that can be utilized in the formulation of functional foods with health benefits.

Chemical Characterization and Temporal Variability of Pasta Condiment By-Products for Sustainable Waste Management.

Sustainable waste management is an extremely important issue due to its environmental, economic, and social impacts. Knowledge of the chemical composition of the waste produced is a starting point for its valorization. This research focuses, for the first time, on the by-products of pasta condiment production, starting with their characterization. In particular, the presence of potential bioactive compounds and their variability over time have been studied. The latter aspect is crucial for the subsequent valorization of these by-products. In addition to acidity and total phenolic content, an untargeted strategy was adopted, using spectroscopic and chromatographic techniques coupled with chemometrics, to study waste samples coming from four single condiment production lines, i.e., Genoese pesto, tomato, ricotta, and ragù sauces. The presence of lycopene, polyphenols, and several valuable volatile compounds was highlighted. Their presence and relative amounts vary mainly according to the presence of tomatoes in the sauce. The results obtained at different storage times (after 0, 7, 10, and 15 days) showed that the samples studied, despite having similar chemical characteristics, underwent changes after one week of storage and then presented a relatively stable chemical profile. A general decrease is observed after 7 days for almost all the chemical variables monitored, so careful planning within the first days is required to obtain a high recovery.

Experimental study on microscopic production characteristics and influencing factors during dynamic imbibition of shale reservoir with online NMR and fractal theory

Dynamic imbibition and displacement between the matrix and fractures in shale reservoirs can significantly enhance oil recovery (EOR) following initial depletion. However, the microscopic production characteristics and seepage mechanisms at different pore scales during the dynamic imbibition process remain incompletely understood. In this study, we established an online physical simulation experiment method that combines dynamic displacement and imbibition based on nuclear magnetic resonance (NMR) and fractal theory, and a series of online NMR water flooding dynamic imbibition experiments were conducted. Through real-time dynamic monitoring of multiphase flow and migration behavior of crude oil in each stage of dynamic imbibition, the microscopic production characteristics and influencing factors were quantitatively studied from the recovery and residual oil saturation field distribution of different scale pores. Additionally, we developed a novel two-dimensional (2-D) NMR interpretation model to investigate the dynamic development characteristics of shale oil injection-imbibition-soaking-production integration, and the multiphase and multi-scale dynamic imbibition crude oil migration models were discussed. The results show that shale oil occurrence pores can be categorized into two types based on the corresponding production mode (imbibition + displacement). The water flooding dynamic imbibition process in shale reservoirs unfolds in three stages: strong displacement and weak imbibition stage characterized by the rapid production of large pores and fractures under displacement action; weak displacement and strong imbibition stage involving the slow production of small pores under reverse imbibition; and dynamic equilibrium stage characterized by weak displacement and weak imbibition. When viewing the entire water flooding dynamic imbibition process as an organism, it becomes imperative to maximize the recovery of large pores while ensuring the recovery degree of small pores. High permeability contributes to better pore throat connectivity and a greater imbibition and displacement production degree. The contribution of the.two production modes to the recovery of small and large pores increased by 4.67 % and 3.17 %, respectively. A negative correlation was observed between high displacement pressure and imbibition recovery, yet it is conducive to the contribution of displacement to total recovery. Notably, fractures can effectively reduce oil-water seepage resistance, and increase the contribution of displacement to recovery by 21.65 %. Finally.a positive correlation was noted between increased imbibition amount and free oil recovery, while residual oil gradually shifted towards adsorbed and organic matter-dominated forms, leading to decreased recoverability. Effectively utilizing the bridge flow conductivity of fractures, fluid imbibition displacement, and carrying effect is crucial for achieving optimal EOR. The findings provide theoretical support for clarifying the interaction between matrix-fracture imbibition and displacement and for the efficient development of shale oil.

Recent advances on strategies and technologies for isolation of bovine milk-derived exosomes: An overview

Exosomes are small extracellular vesicles that play an important role in intercellular communication by facilitating the transfer of cell-specific constituents of the source cell to the recipient cell. They are secreted by various cell types and are available in all body fluids. Milk has been a part of the human diet since ages and is known to contain diverse bioactive components, including exosomes. Milk-derived exosomes (MDE) contain specific cargo with proteins, lipids, nucleic acids and other bioactive molecules that help in cell-to-cell communication and can alter the biological and physical processes of the recipient cells. These MDE can act as excellent nanocarriers for the delivery of drugs due to their stability and low immunogenicity. In this comprehensive review, the conventional isolation strategies based on ultracentrifugation, immunocapture, polymer-based precipitation, and chromatography and also the emerging technologies like microfluidic chips are discussed in detail. These provide functionally intact exosomes with high recovery rate. The available methods have one or the other limitations which pose challenges for the downstream analysis. Hence, integration of different methods is the most effective way to isolate exosomes with high recovery rate, purity and intact biological functions that open new avenues for exploring the therapeutic potential of MDE improving health and developing innovative medical interventions.

Affordable and sustainable clean energy generation potentials from municipal dumpsites: case study of Oke saje dumpsite, Abeokuta, Ogun State, Nigeria

The operating method of final waste disposal in Oke saje area of Abeokuta is direct open dumping and burning. This study was conducted at a major dumpsite in Abeokuta, to investigate the existing waste management systems, characterize solid wastes generated, and estimate for the sustainable energy generation potentials. Exploratory study design was adopted for a period of six (6) months, May to November, 2023. Seven (7) randomly selected plots of 1sq.m were located on Oke saje dumpsite, from where solid wastes were collected from top to the depth of 300 mm. Waste components were weighed to obtain the weight-based characterizations. Sorting into major waste components was in accordance with College and University Recycling Council (CURC) grouping system with modifications to accommodate peculiar waste stream generated in Oke saje dumpsite. Waste samples were taken to laboratory to carry our necessary physical, chemical and proximate analyses. Estimated total solid waste generation in Oke- saje, dumpsite was 3,718,832.03 kg (3718.83 tonnes). Estimated energy content of solid wastes was 46370.47MJ. This implies that there is possibility of electricity generation up to 12.881MWh from daily steam production. An integrated solid waste management concept adoptable to Oke- saje, dumpsite, has zero waste concept of about 46 % waste material recyclable (from composting, bio-fuel production and recyclables), with electricity generating potential of 5.923 KWh and 56 % energy recovery (from electricity generation, incineration-derived ash and residual ash for landfilling or soil enhancement), of about 6.956 KWh. Considering the high material recyclability, reusability and energy recovery potentials from solid wastes generated from Oke saje dumpsite, it was recommended that the Ogun State Waste Management Authority adopts affordable, sustainable and integrated waste management options of waste minimization and sorting from the source, reuse, recycling, and incineration of solid waste generated from the large communities within the state.

Study on UV-Curable Acrylic Clear Viscoelastic Materials with Grafted Structures

Flexible substrates are crucial for wearable electronic strain sensors, but achieving biocompatibility, low cost, and aesthetic appeal alongside good mechanical performance remains challenging. Acrylic-based clear viscoelastic films (CVFs) are gaining attention due to their excellent transparency and potential for enhanced mechanical properties. This study synthesized copolymers CVF1-4 with varying branch content using soft monomers 2-ethylhexyl acrylate (2-EHA), butyl acrylate (n-BA), and functional monomer acrylic acid (AA). Employing a "grafting-through" strategy, small molecule monomers, ATRP-synthesized oligomer pBA25, and photoinitiator 1,6-hexanediol diacrylate (HDDA) were in-situ polymerized under UV light to form transparent, flexible elastic films CVF1-4. Between -20 to 80 C, CVF1-4 demonstrated excellent mechanical properties such as low modulus (in the kPa range), low glass transition temperature (below -20 C), large deformation (500-600%), and high strain recovery rate (>95%). Among them, CVF3 with 15% branching showed a balanced comprehensive performance, exhibiting primarily elastic behavior at room temperature. Therefore, selecting appropriate molecular composition and grafting structure provides a simple and customizable solution for optimizing CVF properties.

In-situ Profiling of Environmental Hazardous Sulfamethoxazole in Aquatic and Artificial Saliva samples Using Perovskite Structured Bismuth Ferrite Incorporated Halloysite Nanotubes

Sulfamethoxazole (SMX), a widely used antibiotic, poses significant environmental and health risks due to its persistence and mobility in water systems, potentially leading to antibiotic resistance and ecological harm. Herein, we developed an electrochemical sensor based on Bismuth Ferrite (BiFeO3)/Halloysite Nanotube (BFO/HNT) composite for sensitive and selective SMX detection. The BFO/HNT composite was synthesized via a hydrothermal method and comprehensively characterized using EDS mapping, HRTEM, XRD, FT-IR, and XPS analysis. The BFO/HNT composite enhances the sensor’s performance due to its unique properties, such as increased electrochemical surface area (ECSA) and efficient electron transfer capability. The B-cation (Fe) in the BiFeO3 matrix plays a crucial role in boosting the electrochemical response by facilitating redox reactions. In addition, the HNTs provide a high surface area and excellent adsorption capabilities, which improve the sensor’s sensitivity by facilitating better interaction with SMX molecules. As the results, the prepared sensor demonstrates an impressive linear detection range of 0.01 to 2 µM and 22 to 122 µM, with a detection limit as low as 0.017 µM. Practical applications were validated by detecting SMX in tap water and artificial saliva, achieving high recovery rates of 98.87 % and 99.11 %.

Membrane compaction in batch reverse osmosis operation and its impact on specific energy consumption

Reverse osmosis (RO) membrane water permeability is measured under cyclic pressure loading conditions corresponding to batch and semi-batch operation modes. Due to the viscoelasticity of the membrane support layer, compaction effects carry forward across multiple pressurization cycles, with the intracycle behavior stabilizing after a large number of cycles. The average membrane permeability of semi-batch RO systems is lower than that of batch RO, since semi-batch RO spends a larger fraction of its cycle time at higher pressures. The instantaneous permeability in batch RO decreases during the cycle as pressure is increased, but at a lower rate than the steady-state permeability variation with applied pressure. Therefore, the batch permeability values are lower at low pressures and higher at high pressures than the corresponding steady-state values. Since more water is recovered in the initial low-pressure stages of a multi-stage RO system, compaction increases the specific energy consumption of batch RO more than that of staged systems. Other loss mechanisms such as channel and minor pressure losses and high-pressure motor+pump efficiency variation with load further result in batch RO becoming energetically inferior to two- or three-stage RO, especially for low-salinity, high recovery applications.

PH-Sensitive blue and red N-CDs for L-asparaginase quantification in complex biological matrices

A novel fluorometric method for the determination of L-asparaginase, an enzyme crucial in cancer therapy and food industry applications, is presented. This sensitive and selective approach utilizes L-asparagine and two pH-sensitive carbon dots (blue-N-CDs and red-N-CDs) as probes. The interaction between L-asparagine and L-asparaginase liberates ammonia, causing an increase in pH. This pH change simultaneously decreases the fluorescence of blue-N-CDs while enhancing the emission of red-N-CDs, enabling ratiometric detection of L-asparaginase. Comprehensive characterization of both carbon dots and investigation of their response mechanism towards L-asparaginase were conducted using ultraviolet–visible spectrophotometry, fluorescence spectroscopy, and transmission electron microscopy (TEM) imaging techniques. The designed approach demonstrates outstanding linearity (20 to 2000 U L-1) and a low detection limit (6.95 U L-1) for L-asparaginase quantification. Moreover, when tested to human serum samples, the detection system exhibits outstanding selectivity and high recovery rates (96.15% to 99.75%) with low standard deviation, underscoring its suitability for practical implementation in clinical diagnostics.

SWIEET-a salt-free alternative to QuEChERS.

The efficient extraction of various analytes from a wide spectrum of matrices with organic solvents is still a great challenge in analytical chemistry. Especially polar and charged compounds are hard to extract in combination with neutral analytes of intermediate to low polarity. The QuEChERS method is often chosen and has been adapted not only to the analysis of food samples, but also to environmental matrices (soil, wastewater) or biota. In this study, we overcome major drawbacks of QuEChERS such as low recoveries of charged analytes and impairment of downstream analysis by high salt loads. The new extraction method, applicable to liquid and solid samples, is called SWIEET (sugar water isopropanol ethyl nitrile extraction technique). Phase separation of the otherwise miscible extraction solvents water and acetonitrile is achieved by sugaring-out instead of salting-out. Extraction efficiencies were greatly improved by adding isopropanol to the acetonitrile phase. The concentrations of the additives glucose and isopropanol, as well as temperature, were optimized by a design of experiment. Further improvement was achieved through electro- or double-extractions. For all sample types tested (surface water, wastewater treatment plant effluent, tomato, soil, and oats), recoveries and precision were higher with SWIEET than with the established QuEChERS method. From wastewater treatment plant effluent, 75% recovery on average were achieved with our SWIEET method compared to 37% with QuEChERS for a model analyte mixture with polarities of logDpH7 = - 5.7 - 3.5. Higher recoveries and lower standard deviations compared to QuEChERS were achieved especially for polar and charged analytes such as metformin. Handling proved to be easy, since there was no additional solid phase and no tedious weighing of salts.

Kajian Teknis Kinerja Jig Primer terhadap Kadar Recovery dan Looses Bijih Timah pada SHP KIP Mitra Matras di Bidang Pengolahan Mineral Unit Pengolahan PT Timah Tbk

Bidang Pengolahan Mineral Processing Unit of PT Timah Tbk operates in the field of tin ore processing. The problem at the research location is that there is no standard operating standard for the Primary Jig tool for washing Processing Waste (SHP). The aim of this research is to determine the settings for the Primary Jig variables in order to obtain optimal levels, Sn recovery and looses. The research method used is Grafity Concentration. The feed used is SHP from KIP Mitra Matras. The experiment was carried out 21 times. Each experiment used 7 variations of Primary Jig stroke speed (300 rpm, 350 rpm, 400 rpm, 450 rpm, 500 rpm, 550 rpm, 600 rpm) and Bed thickness (70 mm, 80 mm, 90 mm). Grain Counting Analysis shows a feed Sn content value of 9.96%. GCA analysis shows that the minerals in the bait are cassiterite, ilmenite, monazite, zircone, pyrite, siderite, limonite, tourmaline, quartz and iron rust. Low stroke speed results in high concentrate Sn content with low Sn recovery and little looses wasted and vice versa. A high Bed thickness results in low Sn concentrate content, high Sn recovery, and a lot of looses is wasted, and vice versa. Setting the optimal Primary Jig operating variables with variations in punch speed of 450 rpm and Bed thickness of 80 mm obtained a Sn content of 41.36% and a Sn recovery of 60.11%. Based on the results of calculating the degree of liberation, the highest average value of the degree of liberation was obtained at mesh -100, indicating that the SHP KIP Mitra Matras concentrate is classified as having a fine grain size.

A novel strategy for sequential separation of Th(IV) from highly acidic wastewater based on solid phase extraction

The potential applications and advantages of thorium(Th) in the development of the nuclear industry make the effective separation of Th(IV) crucial for depleted fuel management and environmental safety. However, selectively capturing of Th(IV) from high-concentration nitric acid remains a challenging task. In this work, a novel solid-phase extraction resin (TOPO/XAD-7) was successfully synthesized by vacuum impregnation of trioctylphosphine oxide (TOPO) into an acrylic-based polymer (XAD-7 resin). It exhibited excellent adsorption abilities for Th(IV), including wide highly concentration acid tolerance (0.01–6 mol L−1 HNO3), high adsorption capacity of 59.79 mg g−1, fast adsorption kinetic (< 60 min) and super elevated selectivity. The adsorption mechanism of the resin involves neutral chelation extraction, with the PO group being the main adsorption binding site. Additionally, the resin was demonstrated good reusability and stability under extreme conditions (high acidity, high temperature and high radiation). Furthermore, dynamic column experiments conducted using an automated separation system validated the practical application of TOPO/XAD-7 resin for the separation of Th(IV) and U(VI)/Th(IV) in wastewater, achieving high element recovery (> 99.5%) and a high U(VI) decontamination factor (3.5 × 105). This work confirms the excellent potential of TOPO/XAD-7 resin for the separation and enrichment of Th(IV) in nuclear wastewater.

Analysis on temperature vacuum swing adsorption from wet flue gas carbon capture by using solid amine adsorbent with co-adsorption equilibrium models

Adsorption carbon capture has attracted extensive attention due to its low regeneration heat consumption, eco-friendly impacts and simplicity. However, there is a lack of comprehensive analysis of its energy consumption, economy and environment impact of adsorption carbon capture. This study aims to investigate the working performance using temperature vacuum swing adsorption (TVSA) from wet flue gas carbon capture utilizing co-adsorption equilibrium models for metal–organic framework (MOF) based amine materials. TVSA model is then carried out in terms of the continuous operational state, the dynamic changes in physical properties inside the bed, and the differences in properties at different positions within the bed layer. It is found that they often cannot simultaneously meet high CO2 recovery rates, productivity, and equivalent work. The analysis reveals that the optimal conditions, namely an adsorption temperature of 318 K and a CO2 component of 0.02 kmol during desorption, collectively result in reduced equivalent work and heightened productivity. The maximum productivity could reach 46.35 kg·m−3·h−1 for 5.6 v% water content and 308 K adsorption temperature. It is demonstrated that temperature vacuum swing adsorption for wet flue gas carbon capture using MOF based amine adsorbent is quite promising in terms of energy consumption and CO2 productivity in the future.

Sustainable urea treatment by environmental-friendly and highly hydrophilic vesicle-like iron phosphate-based carbon

Despite the versatile potential applications of urea, its unfavorable characteristics for conventional treatment methods hinder its utilization. Therefore, this study developed vesicle-like iron phosphate-based carbon (IP@C400) as a breakthrough urea removal and recovery material for a wide range of urea-containing sources. IP@C400 rapidly exhibited an exceptional capacity (2242 mg/g in 1 h) across a wide range of pH, even in synthetic hemodialysis wastewater with high urea concentrations and diverse co-existing components, compared with the 60 prominent adsorbents. The adsorption process followed dual Pseudo-kinetic, Langmuir-isotherm models with the involvement of primary robust physical (i.e., H-bonding and electrostatic interaction) and chemical mechanisms (i.e., hydrolysis). Remarkably, IP@C400 can maintain high urea removal (90 %) or recovery efficiency (95 %) even after 10 cycles with minimal leakages of Fe and P (far below WHO and EUWFD standards)—a significant improvement over disposable options. IP@C400 could also perform efficiently on batch and a new approach integrating with a naturally accessible material based on the fixed-bed column using low-range urea realistic samples, achieving 65.2 L water over 10 cycles with undetected urea, neutral pH, and well-aligned water safety standards with a minimal adsorbent dose (0.1 g.L−1) and economical cost ($0.05 L-1). Lastly, its environmentally friendly nature, which contains essential nutrients for plant growth, further enhances its recyclability after release. Thus, IP@C400 offers a solution to environmental sustainability and the urgent ultrapure water issue that industries are facing.

Optimization of iron flocculation for enrichment of CyHV-2 in aquaculture water

Cyprinid herpesvirus 2 (CyHV-2) is an important infectious virus endangering the farmed Carassius species industry. The enrichment and identification of CyHV-2 in the water is a vital means of early warning diagnostics, which is helpful to aquatic diseases prevention and control. In this study, we employed and optimized iron flocculation to enrich the concentrations of CyHV-2 in aquaculture water. Different Fe3+ concentrations (0.5, 1.0, and 10.0 mg/L), various membrane filters (mixed cellulose ester, glass fiber, nylon microporous filter membrane), different elution buffers containing reductants (ascorbate, citrate, DL-malate, and their combinations with EDTA or TE buffer) were compared to check the recovery yield of CyHV-2. Viral genome quantitation was determined using quantitative real-time PCR. The results showed that Fe3+ concentration of 1.0 mg/L, the glass fiber and citrate-TE were determined to have high efficiency and stable recovery yield. To evaluate infectious CyHV-2 viral titres, crucian carps (Carassius auratus) were intraperitoneally injected with CyHV-2. The mortality rate was 100 % at 9 days postinoculation (dpi) with the 96.7 % detection of CyHV-2 in the pooled tissues. The histopathological phenotype showed necrotic cell death in the liver, spleen and kidney. The CyHV-2 genome was ranging from 101.1 to 107.5 copies/μl in the deceased fish, and 101.4 to 103.0 copies/μl in the feeding water at various stages from latent infection to onset of disease. The field samples from Huzhou, Zhejiang Province on June 4th and 7th had higher detection rates, 87.5 % and 100 % respectively, corresponding to higher CyHV-2 detected in the aquaculture water. CyHV-2 viral load in cultured waters tends to increase prior to fish death, which provides a new indicator for the prediction of fish diseases. In summary, we have established a unified operational standard for enrichment of CyHV-2 in the aqueous environment by iron flocculation.

Single center experience with hourglass-like constriction neuropathy of suprascapular nerve.

Hourglass-like constriction (HGC) may occur in several peripheral nerves. However, data on the prognosis of motor weakness in patients with HGC of the suprascapular nerve (SSN) are limited compared with other nerves. Here, we aimed to describe the clinical and imaging features of HGC of the SSN. We retrospectively reviewed patients diagnosed with suprascapular neuropathy using magnetic resonance imaging (MRI) or electrodiagnostic studies over 16 years. After excluding extrinsic causes, patients with HGC of the SSN detected using MRI were included. Fourteen patients with HGC of the SSN were identified. MRI revealed that all HGCs were located between the origin of the SSN from the upper trunk of the brachial plexus and the suprascapular notch. Seven patients exhibited HGC precisely at the origin of the SSN from the brachial plexus. Four patients showed T2 hyperintensity of the SSN extending to the upper trunk of the brachial plexus or the extraforaminal cervical root. The initial treatments included observation (n = 1), steroid therapy (n = 12), suprascapular notch release (n = 1). Of the 12 patients with a sufficient follow-up period, nine fully recovered from motor weakness of the SSN with non-operative treatments. Six of the nine patients who recovered fully experienced their first clinical improvement more than 6 months after onset. Treatment strategies for HGC differ depending on the affected nerve. For HGC of the SSN, due to the high spontaneous recovery rate observed in our study, conservative management for at least 6 months should be initially considered.

Technological Advancements and Prospects for Near-Zero-Discharge Treatment of Semi-Coking Wastewater

This review examines the technological bottlenecks, potential solutions, and future development directions in the treatment and resource utilization of semi-coking wastewater (SCOW) in China. By comprehensively investigating the semi-coking industry and analyzing wastewater treatment research hotspots and existing projects, this study systematically explores the current status and challenges of each treatment unit, emphasizing the necessity for innovative wastewater treatment technologies that offer high efficiency, engineering feasibility, environmental friendliness, and effective resource recovery. This review highlights prospects and recommendations, including the development of novel extractants for phenol and ammonia recovery, a deeper understanding of biological enhancement mechanisms, exogenous bio-enhancement materials, and the creation of cost-effective advanced oxidation process (AOP)-based combined processes. Additionally, it underscores the potential for repurposing SCOW as a valuable resource through appropriate treatment, whether recycling for production or other applications.

Development of Dust Emission Prediction Model for Open-Pit Mines Based on SHPB Experiment and Image Recognition Method

Open-pit coal mining offers high resource recovery, excellent safety conditions, and large-scale production. However, the process generates significant dust, leading to occupational diseases such as pneumoconiosis among miners and adversely affecting nearby vegetation through dust deposition, which hinders photosynthesis and causes ecological damage. This limits the transition of open-pit mining to a green, low-carbon model. Among these processes, blasting generates the most dust and has the widest impact range, but the specific amount of dust generated has not yet been thoroughly studied. This study integrates indoor experiments, theoretical analyses, and field tests, employing the Split Hopkinson Pressure Bar (SHPB) system to conduct impact loading tests on coal–rock samples under pressures ranging from 0.13 MPa to 2.0 MPa. The results indicate that as the impact load increases, the proportion of large-sized blocks decreases while smaller fragments and powdered samples increase, signifying intensified sample fragmentation. Using stress wave attenuation theory, this study translates indoor impact loadings to field blast shock waves, revealing the relationship between blasting dust mass fraction and impact pressure. Field tests at the Haerwusu open-pit coal mine validated the formula. Using image recognition technology to analyze post-blast muck-pile fragmentation, the estimated dust production closely matched the calculated values, with an error margin of less than 10%. This formula provides valuable insights for estimating dust production and improving dust control measures during open-pit mine blasting operations.

Effects of cross-sectional shape on the low observability of double serpentine nozzles

When unmanned combat aerial vehicles (UCAVs) egress from the battlefield after attacking the target, the defensive radar systems detect signals reflected by the cavity structure of the nozzle and engine of the UCAVs, threatening their survivability. Infrared (IR) guided missiles can also threaten them by detecting the gaseous plume and hot engine parts. We present a comprehensive investigation of the effects of the cross-sectional shape of double serpentine nozzles on thrust, IR signature, and radar cross section (RCS), which are associated with propulsive performance and low observability. The fillet radius and cross-sectional shape of the nozzles were considered as the main design variables. The thermal flow field was analyzed using the compressible Navier-Stokes equations, while the IR signature was analyzed with the radiative heat transfer equation with a narrow band model. The RCS was calculated using a multi-level fast multipole method of full Maxwell's equations instead of the approximate methods often employed. The double serpentine (DS) nozzle with an elliptical cross-section showed high pressure recovery and a 9.66 % lower IR signature than the DS nozzle with a rectangular cross section. The maximum RCS and mean RCS were lowest for the DS nozzle with an elliptical cross section, with a maximum difference in maximum RCS of 383 % and mean RCS of 90 % compared with the DS nozzle with a rectangular cross section. The DS nozzle with an elliptical cross section distributes the current more evenly across the central part of the engine than the DS nozzle with a rectangular cross section. The DS nozzle with an elliptical cross-section showed excellent nozzle performance with a negligible difference in thrust. In addition, the results show that the cross-sectional shape of the nozzles has different levels of impact on thrust and pressure recovery (negligible), IR signature (limited), and RCS (significant).