High Vapor Pressure Research Articles

Corrosion of Ni-based alloy coatings prepared by laser cladding in high-temperature chloride environment

Due to the complex incineration environment of waste incineration power generation boilers generates large amounts of acidic gases (such as Cl2 and HCl) and alkali metal chlorides (such as NaCl and KCl), leading to boiler corrosion failure. Herein, a new type of NiCrAlTi alloy coatings was deposited on 304 stainless steel surfaces by laser cladding technology. High-temperature corrosion experiments were then carried out at 650 °C for 64 h and the results were compared with those of traditional Inconel625 alloy coating. The high-temperature chloride corrosion mechanism and the corrosion resistance of alloy coatings were examined. The results revealed the decomposition of chlorides, such as HCl, NaCl, and KCl into Cl2 at high temperatures as the source of corrosion of high-temperature chlorides. The released C12 reacted with the metals present in the coating to form nonprotective metal chlorides. The low melting point and high vapor pressure of metal chlorides allowed their transition into a gaseous state to diffuse outward and oxidize into Cl2. In turn, the released Cl2 reacted with the metal to induce corrosion. During the corrosion process of NiCrAlTi alloy coating, a Cr depletion zone was induced, and a continuous Al2O3/TiO2/Cr2O3 three-layer protective film was formed on the coating surface, conducive to better alleviating the corrosion caused by the reaction between Cl2 passing through the film and the metal substrate. Under the conditions of this experiment, the corrosion resistance of NiCrAlTi alloy coating is 1.8 times that of the common material 304 stainless steel, and about 1.2 times that of Incon625 alloy coating. With the extension of the experiment, its corrosion resistance will be better. Overall, rich experimental data and theoretical guidance were provided for further research and development on high-temperature chloride corrosion-resistant alloys or coating materials for high-efficiency cost-effectiveness boilers.

Unraveling phenological and stomatal responses to flash drought and implications for water and carbon budgets

Abstract. In recent years, extreme droughts in the United States have increased in frequency and severity, underlining a need to improve our understanding of vegetation resilience and adaptation. Flash droughts are extreme events marked by the rapid dry down of soils due to lack of precipitation, high temperatures, and dry air. These events are also associated with reduced preparation, response, and management time windows before and during drought, exacerbating their detrimental impacts on people and food systems. Improvements in actionable information for flash drought management are informed by atmospheric and land surface processes, including responses and feedbacks from vegetation. Phenologic state, or growth stage, is an important metric for modeling how vegetation modulates land–atmosphere interactions. Reduced stomatal conductance during drought leads to cascading effects on carbon and water fluxes. We investigate how uncertainty in vegetation phenology and stomatal regulation propagates through vegetation responses during drought and non-drought periods by coupling a land surface hydrology model to a predictive phenology model. We assess the role of vegetation in the partitioning of carbon, water, and energy fluxes during flash drought and carry out a comparison against drought and non-drought periods. We selected study sites in Kansas, USA, that were impacted by the flash drought of 2012 and that have AmeriFlux eddy covariance towers which provide ground observations to compare against model estimates. Results show that the compounding effects of reduced precipitation and high vapor pressure deficit (VPD) on vegetation distinguish flash drought from other drought and non-drought periods. High VPD during flash drought shuts down modeled stomatal conductance, resulting in rates of evapotranspiration (ET), gross primary productivity (GPP), and water use efficiency (WUE) that fall below those of average drought conditions. Model estimates of GPP and ET during flash drought decrease to rates similar to what is observed during the winter, indicating that plant function during drought periods is similar to that of dormant months. These results have implications for improving predictions of drought impacts on vegetation.

Anhydrous volatile fatty acid extraction through omniphobic membranes by hydrophobic deep eutectic solvents: Mechanistic understanding and future perspective

Volatile fatty acids (VFAs) derived from arrested anaerobic digestion (AD) can be recovered as a valuable commodity for value-added synthesis. However, separating VFAs from digestate with complex constituents and a high-water content is an energy-prohibitive process. This study developed an innovative technology to overcome this barrier by integrating deep eutectic solvents (DESs) with an omniphobic membrane into a membrane contactor for efficient extraction of anhydrous VFAs with low energy consumption. A kinetic model was developed to elucidate the mechanistic differences between this novel omniphobic membrane-enabled DES extraction and the previous hydrophobic membrane-enabled NaOH extraction. Experimental results and mechanistic modeling suggested that VFA extraction by the DES is a reversible adsorption process facilitating subsequent VFA separation via anhydrous distillation. High vapor pressure of shorter-chain VFAs and low Nernst distribution coefficients of longer-chain VFAs contributed to DES-driven extraction, which could enable continuous and in-situ recovery and conversion of VFAs from AD streams.

Characterization of organic fouling on thermal bubble-driven micro-pumps

Thermal bubble-driven micro-pumps are an upcoming micro-actuator technology that can be directly integrated into micro/mesofluidic channels, have no moving parts, and leverage existing mass production fabrication approaches. These micro-pumps consist of a high-power micro-resistor that boils fluid in microseconds to create a high-pressure vapor bubble which performs mechanical work. As such, these micro-pumps hold great promise for micro/mesofluidic systems such as lab-on-a-chip technologies. However, to date, no current work has studied the interaction of these micro-pumps with biofluids such as blood and protein-rich fluids. In this study, the effects of organic fouling due to egg albumin and bovine whole blood are characterized using stroboscopic high-speed imaging and a custom deep learning neural network based on transfer learning of RESNET-18. It was found that the growth of a fouling film inhibited vapor bubble formation. A new metric to quantify the extent of fouling was proposed using the decrease in vapor bubble area as a function of the number of micro-pump firing events. Fouling due to egg albumin and bovine whole blood was found to significantly degrade pump performance as well as the lifetime of thermal bubble-driven micro-pumps to less than 104 firings, which may necessitate the use of protective thin film coatings to prevent the buildup of a fouling layer.

Numerical Analysis of a High-Pressure Spatial Chemical Vapor Deposition (HPS-CVD) Reactor for Flow Stability at High Pressures

Numerical Analysis of a High-Pressure Spatial Chemical Vapor Deposition (HPS-CVD) Reactor for Flow Stability at High Pressures

Compact colorimetric method for determining formaldehyde in indoor air: Applying to an environment contaminated with hand sanitizer vapor

Hand sanitizer, widely used during the COVID-19 pandemic, must contain at least 60 % ethyl alcohol (ethanol) as an active ingredient. Due to its high vapor pressure, ethanol is rapidly transformed into vapor after the application over any surface. However, depending on the indoor air conditions, ethanol can rapidly oxidize to formaldehyde near harmful concentration levels. This study describes a simple and sensitive method to determine parts-per-billion (ppb) of gaseous formaldehyde using a cuvette (1.5 mL polystyrene, path length: 10 mm) as a microimpinger. Indoor and outdoor air was collected by the microimpinger containing 500 μL of 3-Methyl-2-benzothiazolinone hydrazone (MBTH) (2.32 × 10−3 mol L−1) at 50 mL min−1, resulting in a blue product after 30 min of sampling. Absorbance was measured at 680 nm and is proportional to the sampling period, analyte concentration, and sampling flow rate. Under the established conditions, a limit of detection of 7.0 ppb was achieved, which can be improved using longer sampling times. The analytical method was used to evaluate the oxidation of ethanol vapor by ozone in the indoor air. 10 min after the application of hand sanitizer, the air sample taken over the next 30 min revealed a notable rise in the concentration of low molecular weight aldehydes, measured as formaldehyde equivalent, within the room's air, and can reach around 100 ppb, which may be responsible for effects such as watery eyes, burning sensations in the mucous membrane, and difficulty breathing. The present technique affords a simple, inexpensive measurement with very little reagent consumption. Besides, the method is selective and highly sensitive. This method could be used either in outdoor or indoor environments.

Performance improvement analysis of the regenerative dual-pressure organic flash cycle assisted by ejectors

We proposed a dual-ejector-based regenerative dual–pressure organic flash cycle (DEj–RDPOFC) with higher performance than the RDPOFC. The effects of high and low pressures and the entrainment ratio of the ejector on the DEj–RDPOFC performance were analyzed from the viewpoints of thermodynamics and thermoeconomics. An exergy-flow distribution diagram revealed why the DEj–RDPOFC outperformed the RDPOFC. Next, the performances of the DEj–RDPOFC and dual–pressure organic Rankine cycle (DORC) were compared under the same boundary conditions. Finally, the performance of the DEj–RDPOFC was optimized using the nondominated sorting genetic algorithm (NSGA-II). According to the results, the power output of the high-pressure (HP) turbine of the DEj–RDPOFC can be increased by replacing the HP throttling valve (TV) with an ejector (which increases the working fluid dryness of the HP vapor separator and the mass flow rate of the HP turbine) and the low-pressure (LP) TV with an ejector (which increases the HP turbine expansion ratio). The DEj–RDPOFC achieves a higher maximum net power output (Wnet) and a lower corresponding levelized cost of electricity (LCOE) than the DORC. Under the optimum condition, the Wnet and LCOE of the DEj–RDPOFC are 9.71 % higher and 6.59 % lower, respectively, than those of the RDPOFC.

Plasma membrane intrinsic proteins SlPIP2;5 gene regulates tolerance to high VPD in tomato

Plasma membrane intrinsic proteins (PIPs) play important roles in plant growth, development, and abiotic stress responses. However, the functions and regulatory mechanisms of PIPs under high vapor pressure deficit (VPD) stress are not yet well understood. In this study, we used tobacco rattle virus (TRV) - mediated virus-induced gene silencing (VIGS) technology to discover that SlPIP2;5 is involved in the acclimation process of tomato plants to high VPD. Under high VPD, the TRV-SlPIP2;5 strain exhibited improved growth compared to the TRV strain, and silencing SlPIP2;5 increased the enzyme activities of the antioxidant system of tomato plants and reduced the sensitivity of plants to atmospheric drought stress by eliminating reactive oxygen species produced by the plants. Additionally, leaf structure was improved, with decreased thickness of the epidermis and spongy tissue, leading to enhanced water transport efficiency. Furthermore, the TRV-SlPIP2;5 strain had increased stomatal length and individual stomatal area, which changed net assimilation rate and stomatal conductance to air drought. In addition, SlPIP2;5 was localized on the plasma membrane, and its promoter region contained numerous core elements and V-myb avian myeloblastosis viral oncogene homolog (MYB) binding sites. Yeast One-Hybrid Assay (Y1H) and Dual Luciferase (LUC) assays showed that the transcription factor SlMYB110 can bind to SlPIP2;5 and regulate its expression. qRT-PCR analysis revealed that high VPD inhibited the expression of SlMYB110, consistent with the expression pattern of SlPIP2;5. Therefore, we speculate that under high VPD, SlMYB110 negatively regulates the expression of SlPIP2;5, thereby modulating the tolerance of tomato plants to atmospheric drought. These findings provide a theoretical basis for improving tomato response to high VPD, and SlPIP2;5 was added to the high VPD-responsive gene pool as a valuable gene that could be used to improve high VPD tolerance in tomato through genetic engineering.

Study of LED Retrofit Lamps in HSPV Luminaires Based on Photometric Method for Road Lighting

Energy reduction is a great challenge in road lighting applications. Replacing high-pressure sodium vapor (HPSV) with light-emitting diodes (LED) is a viable approach to reducing energy consumption. However, a total replacement can incur a significant capital cost. This study aims to investigate the effects on light distribution by replacing HPSV lamps with LED lamps in HPSV luminaires using Light Intensity Distribution (LID) curve measurement and Backlight, Uplight and Glare (BUG) rating evaluation to reduce the adoption costs. While LED lamps have high illumination rates, the structural differences from HPSV lamps can affect the LID curve and original lighting design. Therefore, it is crucial to study photometric dispersion after retrofitting light sources. Both lamps were installed into similar HPSV luminaires to assess photometric performance using goniophotometer measurements. The HPSV lamp outperforms the LED lamp in terms of luminous flux (11.13%) and light intensity (7.69%), whereas the LED lamp outperforms the HPSV lamp in terms of efficacy rating (68.67%) and wattage used (47.61%). The findings indicate that retrofit LED luminaires have an LOR of 46.77% lower than the HPSV luminaires. The light distribution pattern is maintained but reduced to 40 to 50% for the main usable light angles. The reduced performance is caused by the lamp structure, which occupies a large area inside the luminaire housing, obstructing proper light distribution. Although overall energy consumption is reduced, similar illumination levels cannot be maintained. These outcomes can assist authorities and manufacturers with alternative methods of reducing costs while maintaining lighting levels.

More than three-fold increase in compound soil and air dryness across Europe by the end of 21st century

Increases in air temperature lead to increased dryness of the air and potentially develops increased dryness in the soil. Extreme dryness (in the soil and/or in the atmosphere) affects the capacity of ecosystems for functioning and for modulating the climate. Here, we used long-term high temporal resolution (daily) soil moisture (SM) and vapor pressure deficit (VPD) data of high spatial resolution (∼0.1° × 0.1°) to show that compared to the reference period (1950–1990), the overall frequency of extreme soil dryness, extreme air dryness, and extreme compound dryness (i.e., co-occurrence of extreme soil dryness and air dryness) has increased by 1.2-fold [0.8,1.6] (median [10th,90th percentile], 1.6-fold [1,2.3], and 1.7-fold [0.9,2.5], respectively, over the last 31 years (1991–2021) across Europe. Our results also indicate that this increase in frequency of extreme compound dryness (between reference and 1991–2021 period) is largely due to increased SM-VPD coupling across Northern Europe, and due to decreasing SM and/or increasing VPD trend across Central and Mediterranean Europe. Furthermore, under the RCP8.5 (Representative Concentration Pathways 8.5) emission scenario, this increase in frequency of extreme compound dryness would be 3.3-fold [2.0,5.8], and 4.6-fold [2.3,11.9] by mid-21st century (2031–2065) and late-21st century (2066–2100), respectively. Additionally, we segregated the changes in frequency of extreme dryness across the most recent (year 2021) land cover types in Europe to show that croplands, broadleaved forest, and urban areas have experienced more than twice as much extreme dryness during 1990–2021 compared to the reference period of 1990–2021, which based on the future projection data will increase to more than three-fold by mid 21st century. Such future climate-change induced increase in extreme dryness could have negative implications for functioning of ecosystems and compromise their capacity to adapt to rapidly rising dryness levels.

Numerical simulation analysis of high-temperature bent sodium heat pipes

Abstract High-temperature bent heat pipes are safety-level heat transfer components used in heat pipe cooled reactor, and their applications are becoming increasingly widespread. In this study, a comprehensive three-dimensional numerical model was established to evaluate the effects of different bending angles and radii on the performance of high-temperature heat pipes. The model solved for the temperature, pressure, and velocity fields in the wall, wick, and evaporator, considers the compressibility effect of the vapor. The study investigated parameters such as vapor pressure, vapor velocity, radial secondary flow field, wall temperature, wick temperature, and equivalent thermal resistance of powder sintered core sodium heat pipes with bending angles of 45°, 90°, 135°, 180°, and a bending radius under 90°. The results showed that when sodium vapor enters the bent pipe, the vapor flow deviates towards the outer side, resulting in higher vapor pressure at the outer side than the vapor pressure at the inner side, and the generation of radial secondary vortex. This leads to higher temperature in the evaporator and adiabatic sections of the bent heat pipe, while lower temperature in the condenser. Fractal patterns are observed in the outer and inner wall temperature curve in the adiabatic section, with lower temperatures on the inner side and higher temperatures on the outer side. The bent heat pipe exhibits higher equivalent thermal resistance than that of a straight heat pipe, and the equivalent thermal resistance increases with increasing bending angle, and the equivalent thermal resistance decreases with increasing bending radius.

Nanodiamonds: A Cutting-Edge Approach to Enhancing Biomedical Therapies and Diagnostics in Biosensing.

Nanodiamonds (NDs) have garnered attention in the field of nanomedicine due to their unique properties. This review offers a comprehensive overview of NDs synthesis methods, properties, and their uses in biomedical applications. Various synthesis techniques, such as detonation, high-pressure, high-temperature, and chemical vapor deposition, offer distinct advantages in tailoring NDs' size, shape, and surface properties. Surface modification methods further enhance NDs' biocompatibility and enable the attachment of bioactive molecules, expanding their applicability in biological systems. NDs serve as promising nanocarriers for drug delivery, showcasing biocompatibility and the ability to encapsulate therapeutic agents for targeted delivery. Additionally, NDs demonstrate potential in cancer treatment through hyperthermic therapy and vaccine enhancement for improved immune responses. Functionalization of NDs facilitates their utilization in biosensors for sensitive biomolecule detection, aiding in precise diagnostics and rapid detection of infectious diseases. This review underscores the multifaceted role of NDs in advancing biomedical applications. By synthesizing NDs through various methods and modifying their surfaces, researchers can tailor their properties for specific biomedical needs. The ability of NDs to serve as efficient drug delivery vehicles holds promise for targeted therapy, while their applications in hyperthermic therapy and vaccine enhancement offer innovative approaches to cancer treatment and immunization. Furthermore, the integration of NDs into biosensors enhances diagnostic capabilities, enabling rapid and sensitive detection of biomolecules and infectious diseases. Overall, the diverse functionalities of NDs underscore their potential as valuable tools in nanomedicine, paving the way for advancements in healthcare and biotechnology.

Strategies to Realize Efficient and Stable Broadband NIR Emission in Germinate Oxides

AbstractPhosphor‐converted light‐emitting diodes (pc‐LEDs) are efficient and cost‐effective ultrabroadband light sources for miniaturizing various optical systems, but they exhibit poor optical performance due to the lack of efficient near‐infrared (NIR) phosphors with a wide spectral coverage of 700−1100 nm. Although germanate oxides are a promising class of host materials for Cr3+ to generate broadband NIR light, the preferred formation of [CrO4]4− and the high vapor pressure of Ge element cause these Cr3+ activated phosphors to suffer from low internal quantum efficiency (IQE) and poor thermal stability. Here, highly efficient (IQE > 90%) and thermally stable broadband NIR emission of Cr3+ in the germinate garnet Ca2LuMgScGe3O12 (CLMSG) are obtained by exploiting a two‐step sintering method to achieve full reduction of Cr4+ to Cr3+. Further, efficient energy transfer from Cr3+ to Yb3+ is leveraged to significantly improve the emission intensity of CLMSG:Cr3+ in the shortwave infrared range of 900−1100 nm. Finally, an ultrabroadband NIR pc‐LED with a high NIR conversion efficiency (21.5%@10 mA) and high NIR power (116.4 mW@350 mA) is demonstrated to verify the strong capability of CLMSG:Cr3+, Yb3+ in blue‐to‐NIR light conversion. The results open up new ways to realize efficient ultrabroadband NIR‐emitting materials.

Study of essential oil extraction from Moroccan Rosmarinus officinalis L. by distillation based on quantum chemical calculation and molecular dynamics simulation

In this work, essential oils were extracted from rosemary leaves (Rosmarinus officinalis L.) from the eastern region of Morocco using hydrodistillation (Hd) and steam distillation (Sd). The yield, chemical composition, thermal stability, and antioxidant activity of the essential oils obtained by the two methods were compared. Determining the chemical composition of rosemary essential oil, with GC-MS, showed a significant qualitative and quantitative difference in certain components. The Sd method improved the extraction of sesquiterpene compounds with high molecular weight and low vapour pressure. The findings reveal that sesquiterpene and oxygenated monoterpenes in essential oils improved the antioxidant activity and thermal stability. Determining antioxidant activity using DPPH and the β-carotene bleaching assay showed that the Sd and Hd oils presented good radical scavenging activity (IC50 = 4960 μg/mL for Hd oil and 4570 μg/mL for Sd oil), capable of delaying β-carotene discolouration with 16.3 and 9.71% inhibition for Sd and Hd respectively. Thermal stability analysis of the oil products was performed using TGA/DTG analysis, and the results showed that the decomposition points of Hd oil and Sd oil were 362 and 368 K respectively. Furthermore, to identify intermolecular interactions and develop better knowledge of phenomena occurring during the extraction of the family of sesquiterpene compounds by water, quantum chemical calculation and molecular simulation by molecular dynamics (MD) were performed. The results suggested the relative stability of caryophyllene-water and the development of intermolecular bonding interactions of van der Walls and steric effect, improving extraction of the substance studied under steam distillation conditions.

Green Additives in Chitosan-based Bioplastic Films: Long-term Stability Assessment and Aging Effects.

Although biomass-based alternatives for the manufacturing of bioplastic films are an important aspect of a more sustainable future, their physicochemical properties need to be able to compete with the existing market to establish them as a viable alternative. One important factor that is often neglected is the long-term stability of renewables-based functional materials, as they should neither degrade after a day or week, nor last forever. One material showing high potential in this regard, also due to its intrinsic biodegradability and antibacterial properties, is chitosan, which can form stable, self-standing films. We previously showed that green additives introduce a broad tunability of the chitosan-based material properties. In this work, we investigate the long-term stability and related degradation processes of chitosan-based bioplastics by assessing their physicochemical properties over 400 days. It was found that the film properties change similarly for samples stored in the fridge (4 °C, dark) as at ambient conditions (20 °C, light/dark cycles of the day). Additives with high vapor pressure, such as glycerol, evaporate and degrade, causing both brittleness and discoloration. In contrast, films with the addition of crosslinking additives, such as citric acid, show high stability also over a long time, bearing great preconditions for practical applications. This knowledge serves as a stepping-stone to utilizing chitosan as an alternative material for renewable-resourced bioplastic products.

CO2 fluxes contrast between aquaculture ponds and mangrove forests and its implications for coastal wetland rehabilitation in Leizhou Peninsula, China

Coastal wetlands have great potential to mitigate climate change. However, in recent decades, the construction of aquaculture ponds has degraded coastal habitats, especially mangroves. Meanwhile, the lack of synchronized monitoring of carbon dioxide (CO2) fluxes in coastal ponds and mangroves hinders the promotion of carbon neutrality target through the implementation of coastal wetland rehabilitation. To address this issue, we deployed two eddy-covariance systems in the ponds and nearby mangroves to measure the net ecosystem CO2 exchange between atmosphere and ecosystems for two years. The results indicated that both the ponds and mangroves were CO2 sinks at the annual scale, with mean net ecosystem production (NEP) of 123 ± 39 and 1296 ± 32 g C m−2 year−1, respectively. During the 2-year period, the ponds acted as CO2 sources in certain seasons, while the mangroves displayed consistently high seasonal NEP. The construction of ponds by clearing mangroves would reduce NEP along the coasts of the Leizhou Peninsula by about 91% (96% for China), while abandoning all ponds for mangrove rehabilitation could have a significant CO2 mitigation benefit (i.e., 214.7 Gg year−1). Moreover, we compared how CO2 fluxes responded to global solar radiation and temperature by analyzing relevant parameters in the two ecosystems. Overall, the ponds showed lower light-saturated net CO2 exchange and Q10 values compared to the mangroves. Finally, we applied an advanced machine learning local interpretation algorithm to investigate the crucial drivers and their main effects on NEP. This analysis highlighted global solar radiation as the predominant driver for NEP in both ecosystems. High temperature and vapor pressure deficit inhibited mangrove NEP, particularly during summer, whereas pond NEP exhibited greater volatility in response to meteorological conditions such as temperature. Our findings provide insights for further proceeding with mangrove restoration and management to enhance the carbon sequestration capacity of coastal wetlands.

Australia's Tinderbox Drought: An extreme natural event likely worsened by human-caused climate change.

We examine the characteristics and causes of southeast Australia's Tinderbox Drought (2017 to 2019) that preceded the Black Summer fire disaster. The Tinderbox Drought was characterized by cool season rainfall deficits of around -50% in three consecutive years, which was exceptionally unlikely in the context of natural variability alone. The precipitation deficits were initiated and sustained by an anomalous atmospheric circulation that diverted oceanic moisture away from the region, despite traditional indicators of drought risk in southeast Australia generally being in neutral states. Moisture deficits were intensified by unusually high temperatures, high vapor pressure deficits, and sustained reductions in terrestrial water availability. Anthropogenic forcing intensified the rainfall deficits of the Tinderbox Drought by around 18% with an interquartile range of 34.9 to -13.3% highlighting the considerable uncertainty in attributing droughts of this kind to human activity. Skillful predictability of this drought was possible by incorporating multiple remote and local predictors through machine learning, providing prospects for improving forecasting of droughts.

V2O5 based nanocomposites with MOF and rGO for the adsorption and photocatalytic degradation of methylene blue dye

In the present work, vanadium pentoxide-metal organic framework (V2O5-MIL 125 MOF) and vanadium pentoxide-reduced graphene oxide (V2O5-rGO) nanocomposites were successfully synthesized using a facile low-temperature hydrothermal treatment. These nanocomposites were used as photocatalysts to study the adsorption capacity and photocatalytic degradation of methylene blue (MB) dye in an aqueous solutions, under dark and UV light conditions. The influence of adsorption on dye removal and its isotherm revealed that both the nanocomposites follow the Freundlich isotherm. The kinetics of adsorption indicated pseudo-second-order behaviour. V2O5-MIL 125 MOF and V2O5-rGO exhibited maximum dye adsorption capacities of 62 and 24 mg/g, respectively. The optimal values for maximum photocatalytic degradation were determined, and the mechanism of degradation was verified using radical scavengers. A 125 W high-pressure mercury vapour light was employed as the light source for all dye degradation studies. Maximum degradation was obtained at neutral conditions (pH 7.4) of the solution, ambient temperature (30±2˚C), and an initial dye concentration of 10 ppm. The synthesized photocatalysts V2O5-MIL 125 MOF and V2O5-rGO exhibited maximum degradation of 87% within 270 min and 82% within 300 min of UV light exposure, respectively. The adsorption and photocatalytic effects of V2O5-MIL 125 MOF and V2O5-rGO were also compared with pure vanadium pentoxide (V2O5), revealing superior activity in both cases.

Water Promotes Melting of a Metal-Organic Framework.

Water is one of the most reactive and abundant molecules on Earth, and it is thus crucial to understand its reactivity with various material families. One of the big unknown questions is how water in liquid and vapor forms impact the fast-emerging class of metal-organic frameworks (MOFs). Here, we discover that high-pressure water vapor drastically modifies the structure and hence the dynamic, thermodynamic, and mechanical properties of MOF glasses. In detail, we find that an archetypical MOF (ZIF-62) is extremely sensitive to heat treatments performed at 460 °C and water vapor pressures up to ∼110 bar. Both the melting and glass transition temperatures decrease remarkably (by >100 °C), and simultaneously, hardness and Young's modulus increase by up to 100% under very mild treatment conditions (<20 bar of hydrothermal pressure). Structural analyses suggest water to partially coordinate to Zn in the form of a hydroxide ion by replacing a bridging imidazolate-based linker. The work provides insight into the role of hot-compressed water in influencing the structure and properties of MOF glasses and opens a new route for systematically changing the thermodynamics and kinetics of MOF liquids and thus altering the thermal and mechanical properties of the resulting MOF glasses.

Photosynthetic responses of Larix kaempferi and Pinus densiflora seedlings are affected by summer extreme heat rather than by extreme precipitation

The frequency and intensity of summer extreme climate events are increasing over time, and have a substantial negative effect on plants, which may be evident in their impact on photosynthesis. Here, we examined the photosynthetic responses of Larix kaempferi and Pinus densiflora seedlings to extreme heat (+ 3 °C and + 6 °C), drought, and heavy rainfall by conducting an open-field multifactor experiment. Leaf gas exchange in L. kaempferi showed a decreasing trend under increasing temperature, showing a reduction in the stomatal conductance, transpiration rate, and net photosynthetic rate by 135.2%, 102.3%, and 24.8%, respectively, in the + 6 °C treatment compared to those in the control. In contrast, P. densiflora exhibited a peak function in the stomatal conductance and transpiration rate under + 3 °C treatment. Furthermore, both species exhibited increased total chlorophyll contents under extreme heat conditions. However, extreme precipitation had no marked effect on photosynthetic activities, given the overall favorable water availability for plants. These results indicate that while extreme heat generally reduces photosynthesis by triggering stomatal closure under high vapor pressure deficit, plants employ diverse stomatal strategies in response to increasing temperature, which vary among species. Our findings contribute to the understanding of mechanisms underlying the photosynthetic responses of conifer seedlings to summer extreme climate events.