High-pressure Stage Research Articles

Thermodynamic Analysis of Two-stage Vapour Compression Refrigeration Systems Using Eco-friendly Refrigerants

As Nigeria continues to expand its industrial, commercial, and residential cooling needs, the demand for efficient and environmentally sustainable refrigeration systems is growing. However, the environmental impact of conventional refrigerants has raised concerns due to their high global warming potential and ozone depletion potential. This study presents a thermodynamic analysis of two-stage vapour compression refrigeration systems in Nigeria, utilizing eco-friendly refrigerants which offer low global warming potential and zero ozone depletion potential. The refrigeration system comprises a high-pressure stage compressor and a low-pressure stage compressor with the inter stage pressure taken to be the ideal inter stage pressure. Performance analysis of R-717, R-600, R-600a and R-290 two-stage vapour compression refrigeration systems were made using seven parameters. The effect of the variation of five operating/design parameters (evaporating temperature, condensing temperature, superheating temperature, sub cooling temperature and refrigerant mass flow rate) on Coefficient of Performance (COP) of two-stage vapour compression system was analysed using engineering equation solver software. The results showed that as evaporating temperature decreases from 0oC to -50oC, COP decreased for all the four refrigerants considered. R-717 gave the highest COP value of 7.636 at evaporating temperature of 0oC while R-600a gave the lowest value of 4.009 at the same temperature. The results also showed that the COP of all the four refrigerants increased with increase in sub cooling temperature and Superheating Temperature, whereas it decreased with increase in condensing temperature. The study revealed that, except for the mass flow rate, all other operating parameters significantly affect the COP of refrigeration systems considered.

Steam turbine high-pressure reaction stages; new 3D vortices breakdown and airfoil optimization method

Steam turbine high-pressure reaction stages; new 3D vortices breakdown and airfoil optimization method

Enhancing Combustion Efficiency: Utilizing Graphene Oxide Nanofluids as Fuel Additives with Tomato Oil Methyl Ester in CI Engines

The research aims to conduct a thorough examination of the combustion, injection, performance, and emission characteristics of a diesel engine below different engine loads, as well as the synthesis of graphene oxide (GO) nano fuels and their utilization in combination with Tomato Oil methyl ester (TOME) and diesel fuel blend. The graphene oxide, plays a vital role in the pre-mixed combustion phase of diesel engines. Addition of graphene oxide nano fuels enhances the high-pressure combustion stage, resulting in increased maximum pressure and heat release rate. TOME (B20GO75) and TOME (B20GO100) exhibit comparable heat release rate to diesel due to improved fuel characteristics and quicker ignition delay duration. While TOME (B20) shows a slight decrease in (BTE) compared to diesel, the addition of graphene oxide improves BTE, with TOME (B20GO50) displaying the highest BTE at full load, indicating enhanced combustion efficiency. Moreover, graphene oxide addition leads to a reduction in carbon monoxide (CO) and hydrocarbon (HC) emissions, with emissions decreasing as the concentration of graphene oxide increases. However, NoX emissions initially decrease with TOME (B20) compared to diesel but increase with higher graphene oxide concentration. Smoke emissions increase with TOME (B20) but decrease with higher graphene oxide dosages. Overall, the incorporation of graphene oxide nano fuels into Tomato Oil methyl ester blends demonstrates potential for improving engine performance and reducing emissions.

Two phases of granulite-facies metamorphism superimposied on retrograde eclogite: Constraints on the early Paleozoic tectonic evolution of the Qinling Orogenic Belt, central China

Existing studies provide adequate petrological evidences on ca. 500 Ma ultra-high pressure (UHP) metamorphism in the North Qinling Orogenic Belt (NQOB) in central China, but the genesis of 470–420 Ma multi-phase granulite-facies metamorphism in the NQOB and their relationship with the ca. 500 Ma UHP metamorphism remain controversial, resulting in the early Paleozoic evolution of the Qinling Orogenic Belt (QOB) highly debatable. In this study, we present mafic granulites and host felsic gneisses with a “red-eye socket” texture from the Shuanglong area, eastern NQOB, which recorded two phases of granulite-facies metamorphism superimposing on former eclogite-facies metamorphism. The former eclogite-facies metamorphism is indicated by eclogite-facies zircon trace element patterns and 496–495 Ma zircon ages, which are the same with those of the HP–UHP eclogite-facies metamorphic rocks in NQOB. The first granulite-facies metamorphism occurred at 460–448 Ma is characterized by coarse-grained minerals in matrix. Compositions and zonings of these minerals define an anticlockwise P–T path involving a prograde stage (751–763 °C), a high-temperature peak stage (9.2 kbar and 864 °C), and a near-isobaric cooling retrograde stage (8.3 kbar and 818 °C). The second granulite-facies metamorphism occurred at 422–421 Ma is represented by coronal garnet and coexisting fine-grained mineral aggregates. Coronal garnet compositional zonings suggest a clockwise P–T path consisting of a high-pressure peak stage (9.5–11.2 kbar and 748–783 °C) and a decompressing and heating retrograde stage (9.2–9.5 kbar and 789–800 °C). Combining dating results of leucosomes in these rocks and existing data, we proposed a new model for early Paleozoic tectonic evolution of the NQOB. The North Qinling Terrane (NQT), probably separated from the South China Block (SCB) during the breakup of Rodinia, drifted northwards and underwent UHP metamorphism at 500 Ma and then rapidly exhumed to crust level. Later, the Shangdan Ocean subducted northwards beneath the exhumed NQT at 470–440 Ma, resulting in the first granulite-facies metamorphism and contemporaneous migmatization and magmatism. Finally, the closure of the Shangdan Ocean led to collision between the NQT and South Qinling Terrane/SCB and the second granulite-facies metamorphism and anatexis at 422–418 Ma.

Thermo-economic investigation and comparative multi-objective optimization of dual-pressure evaporation ORC using binary zeotropic mixtures as working fluids for geothermal energy application

This contribution performs an energy, exergy, and exergoeconomic (3E) analysis of a dual-pressure evaporation organic Rankine cycle system employing twenty different binary zeotropic mixtures as working fluids for power production from a geothermal field. To this end, the designed system is modeled, invoking the mass and energy conservation laws and the exergy and cost balance analyses. Specific Exergy Costing (SPECO) procedure is utilized to provide practical insights into the exergoeconomic aspect of the system. Comparative optimization based on the multi-objective genetic algorithm is accomplished for each mixture in order to simultaneously maximize the exergy efficiency and minimize the total cost rate using the design variables of pressure factor in low-pressure and high-pressure stages, mixture fraction, pinch point temperature differences in low-pressure and high-pressure heat exchangers, and degree of superheat in the high-pressure heat exchanger. In this regard, the Pareto frontiers are drawn for the system with all twenty different binary zeotropic mixtures. The optimal point for each mixture is obtained via the decision-making technique of LINMAP. Subsequently, the LINMAP is re-utilized to find the preferred mixture. The optimization results suggest the R123/C2Butene (96.89/3.11) mixture for this system as the optimum working fluid, considering a trade-off between a low-cost rate of $88.0651 per hr and a high exergy efficiency of 64.07 %. Finally, the exergy flow diagram is plotted to provide the exergy flow rate and the amount of exergy destruction in each segment of the system considering the optimal working fluid. In the proposed system, exergy destruction chiefly occurs within the low-pressure preheater with a value of 1061 kW, followed by the low-pressure turbine and condenser with magnitudes of about 669 kW and 266 kW, respectively.

Matrix Compression and Pore Heterogeneity in the Coal-Measure Shale Reservoirs of the Qinshui Basin: A Multifractal Analysis

The application of high-pressure fluid induces the closure of isolated pores inside the matrix and promotes the generation of new fractures, resulting in a compressive effect on the matrix. To examine the compressibility of coal-measure shale samples, the compression of the coal–shale matrix in the high-pressure stage was analyzed by a low-pressure nitrogen gas adsorption and mercury intrusion porosimetry experiment. The quantitative parameters describing the heterogeneity of the pore-size distribution of coal-measure shale are obtained using multifractal theory. The results indicate that the samples exhibit compressibility values ranging from 0.154 × 10−5 MPa−1 to 4.74 × 10−5 MPa−1 across a pressure range of 12–413 MPa. The presence of pliable clay minerals enhances the matrix compressibility, whereas inflexible brittle minerals exhibit resistance to matrix compression. There is a reduction in local fluctuations of pore volume across different pore sizes, an improvement in the autocorrelation of PSD, and a mitigation of nonuniformity after correction. Singular and dimension spectra have advantages in multifractal characterization. The left and right spectral width parameters of the singular spectrum emphasize the local differences between the high- and low-value pore volume areas, respectively, whereas the dimensional spectrum width is more suitable for reflecting the overall heterogeneity of the PSD.

Multi-Fidelity Modelling of the Effect of Combustor Traverse on High-Pressure Turbine Temperatures

As turbine entry temperatures of modern jet engines continue to increase, additional thermal stresses are introduced onto the high-pressure turbine rotors, which are already burdened by substantial levels of centrifugal and gas loads. Usually, for modern turbofan engines, the temperature distribution upstream of the high-pressure stator is characterized by a series of high-temperature regions, determined by the circumferential arrangement of the combustor burners. The position of these high-temperature regions, both radially and circumferentially in relation to the high-pressure stator arrangement, can have a strong impact on their subsequent migration through the high-pressure stage. Therefore, for a given amount of thermal power entering the turbine, a significant reduction in maximum rotor temperatures can be achieved by adjusting the inlet temperature distribution. This paper is aimed at mitigating the maximum surface temperatures on a high-pressure turbine rotor from a modern commercial turbofan engine by conducting a parametric analysis and optimization of the inlet temperature field. The parameters considered for this study are the circumferential position of the high-temperature spots, and the overall bias of the temperature distribution in the radial direction. High-fidelity unsteady (phase-lag) and conjugate heat transfer simulations are performed to evaluate the effects of inlet clocking and radial bias on rotor metal temperatures. The optimized inlet distribution achieved a 100 K reduction in peak high-pressure rotor temperatures and 7.5% lower peak temperatures on the high-pressure stator vanes. Furthermore, the optimized temperature distribution is also characterized by a significantly more uniform heat load allocation on the stator vanes, when compared to the baseline one.

Research on Effect of Endwall Contouring of Vaned Diffuser on Stable Operating Range of Centrifugal Compressor

Abstract The study investigates the impact of diverse endwall contouring strategies on the operational stability of a high-pressure ratio centrifugal compressor stage. Employing numerical simulation techniques, this study examines the implications of contoured wall positions, specifically convex profiles at the pressure side and/or concave profiles at the suction side, as well as asymmetric endwall contouring, on both stage performance and internal flow field within the centrifugal compressor. And the stability enhancement mechanism of endwall contouring is clarified. The results demonstrate that employing full circular contoured vaned diffusers on the hub-side wall can achieve a maximum improvement in stall margin of 15.10%. Additionally, the diffuser featuring solely convex profiles at the pressure side on the hub-side wall exhibits an augmented stall margin by 8.39%, with a reduction in performance loss at low flow rate conditions. The asymmetric endwall contouring improves stall margin by 8.39%, and mitigates the performance loss across the entire operating range. At the near-stall point, the contoured endwalls redirect fluid towards the suction side, thereby mitigating the incidence at the vane leading edge and attenuating the interaction between the impeller trailing edge vortex and the diffuser leading edge vortex. Moreover, concave profiles serve to accelerate the fluid on the suction side along the flow direction, thereby suppressing the corner separation and weakening passage blockages. Simultaneously, the advantages of endwall contouring in vane diffusers extend to the improvement in the circumferential non-uniformity of flow fields and the enhancement in diffuser stability.

Blade tip clearance measurement technology in gas turbines

Many technologies are used for engine development and testing but no technology has been successfully adopted for long term monitoring over the life of the engine. The challenge is to find a technology that is suitable for long term, high temperature operation but that can also provide accurate and reliable measurement. Blade turbine monitoring is an important area of work for improvements in gas turbine operation. Blade tip clearance measurements offer improvement in engine efficiency by enabling active clearance control. However, this is a difficult measurement because of the harsh turbine environment. The high temperature microwave sensor presented in this paper is one of the most promising candidates for clearance measurement. It has been tested on the high pressure stage of a 25MW gas turbine engine during different operating modes

Instrumentation condition monitoring vibration and failure analysis of screw air compressor package in liquefied natural gas plant

Instrumentation, for conditioning monitoring on rotating equipment is vital for determining whether the equipment is running correctly or not. Measuring the bearing temperature or shaft vibration can identify any potential problems when running the equipment. Identification of a potential problem before it arises allows operating engineers to shut down the machine or make appropriate changes to the machine operation before the problem occurs. This is more economical as shutting down a machine and making the relevant alterations is cheaper than allowing it to fail and performing the repairs. This paper investigates several sources of vibration on a screw air compressor package in a liquefied natural gas (LNG) plant. Root cause failure analysis (RCFA) approach is used to analyse historical failure and vibration analysis data. The main vibration causes and consequent failures on compressor are: resonance of the interstage condensate separator, important levels of dynamic pressure and vibration at low pressure (LP) and high pressure (HP) compression stage frequencies and harmonics, excessive axial force exerted on the main rotor shaft causing the bearing to run on the back edge and subsequently failing due to the excessive axial forces, inferior axial bearings, failing due to poor design or inferior material composition. In order to avoid other failures, the interstage condensate separator was redesigned to shift its natural frequency and cancel the resonance, two broadband mufflers were designed, one muffler for each stage, centred on 1244 Hz for the LP muffler (3 times LP stage compression fundamental), and on 1816 Hz for the HP muffler (2 times HP stage compression, harmonic 2). Condition monitoring graphs, of vibrations, and excitation sources are presented to give an overview of the acceleration, pressure and velocity RMS (mm/s), spectrums on the compressor before and after the installation of the mufflers.

Influence of Rock Fabric on Physical Properties of Shale Oil Reservoir Under Effective Pressure Conditions

Abstract The physical properties of shale oil reservoirs under overburden pressure are of great significance for reservoir prediction and evaluation during exploration and development. Based on core, thin section, and SEM observations, as well as test data such as XRD, TOC, and porosity and permeability under pressure conditions, this study systematically analyzes the variation of physical properties of different lithofacies shales in the Jiyang depression and the influence of rock fabric on the physical variation under pressure. The porosity and permeability of shale samples significantly decrease under pressure. According to the phased reduction in porosity and permeability, the pressurization process is divided into three pressure stages: low pressure (<8 MPa), medium pressure (8–15 MPa), and high pressure (>15 MPa). The reduction of porosity is fastest in the low-pressure stage and slowest in the medium-pressure stage. The reduction of permeability is fastest in the low-pressure stage and the slowest in the high-pressure stage. The rock fabric has a significant impact on porosity and permeability under pressure conditions. The permeability of laminated shale and bedded shale is higher than that of massive shale under pressure, and the permeability loss rate is lower than that of massive shales. Especially under lower pressure, the difference can be 10–20 times. In addition, the reduction rate of porosity and permeability under pressure is negatively correlated with felsic minerals content, which is positively correlated with carbonate minerals content and clay minerals content. The contribution of clay minerals to the porosity reduction rate is dominant, followed by carbonate minerals. The contribution of carbonate minerals to the permeability reduction rate is dominant, followed by clay minerals. The TOC content has no significant impact on the porosity and permeability of shales under pressure in the study due to the low maturity.

Transonic Compressor Darmstadt Open Test Case: Experimental Investigation of Stator Secondary Flows and Hub Leakage

Abstract The future trend of clean sky aviation has led to a smaller core engine, resulting in highly loaded stages with increased relative tip gaps and leakage flows, which causes a reinforced influence of secondary flow phenomena. This article experimentally investigates the secondary flow effects in the 3D-optimized shrouded stator of the TUDa-GLR-OpenStage, representative of a transonic high-pressure compressor front stage, and its susceptibility to typical hub leakage flows. The impact of stator hub leakage on efficiency and total pressure ratio is investigated for several operating speeds, from subsonic to nominal transonic operating conditions. Steady five-hole probe and time-resolved virtual multi-hole probe measurements at different operating conditions at nominal speed are conducted to investigate the underlying loss mechanisms. The leakage mass flow is determined using the measured pressure difference within the fin seal. Steady results show that the optimized 3D stator effectively suppresses the hub corner separation compared to the predecessor 2D stator, but its performance is further limited by a near-tip separation. With the increased stator hub leakage (at a leakage-to-main flow ratio of about 0.4%), the compressor isentropic efficiency generally drops (by about −0.5%) at the full operating range due to an enhanced hub corner separation effect. However, the increased leakage also helps alleviate the tip-corner separation when operating near stall, leading to a smaller efficiency penalty under these conditions. Unsteady results reveal the sensitivity of transient compressor performance to the passing rotor wake, but limited interaction between this phenomenon and the increased leakage is observed. These findings provide insight into the stator hub leakage-related penalties on the compressor aerodynamics efficiency.

Fractal Evolution Characteristics on the Three-Dimensional Fractures in Coal Induced by CO2 Phase Transition Fracturing

To analyze the transformed effect of three-dimensional (3D) fracture in coal by CO2 phase transition fracturing (CO2-PTF), the CO2-PTF experiment under a fracturing pressure of 185 MPa was carried out. Computed Tomography (CT) scanning and fractal theory were used to analyze the 3D fracture structure parameters. The fractal evolution characteristics of the 3D fractures in coal induced by CO2-PTF were analyzed. The results indicate that the CO2 phase transition fracturing coal has the fracture generation effect and fracture expansion-transformation effect, causing the maximum fracture length, fracture number, fracture volume and fracture surface area to be increased by 71.25%, 161.94%, 3970.88% and 1330.03%. The fractal dimension (DN) for fracture number increases from 2.3523 to 2.3668, and the fractal dimension (DV) for fracture volume increases from 2.8440 to 2.9040. The early dynamic high-pressure gas jet stage of CO2-PTF coal influences the fracture generation effect and promotes the generation of 3D fractures with a length greater than 140 μm. The subsequent quasi-static high-pressure gas stage influences the fracture expansion-transformation effect, which promotes the expansion transformation of 3D fractures with a length of less than 140 μm. The 140 μm is the critical value for the fracture expansion-transformation effect and fracture generation effect. Five indicators are proposed to evaluate the 3D fracture evolution in coal caused by CO2-PTF, which can provide theoretical and methodological references for the study of fracture evolution characteristics of other unconventional natural gas reservoirs and their reservoir stimulation.

Study of the influence of different ignition times on detonation generation and shock wave propagation in high-pressure hydrogen leakage

Hydrogen is an efficient, clean, and renewable energy source. When determining a place for hydrogen energy storage and injection into vehicles, the main safety concern of hydrogen refueling stations is high-pressure hydrogen leakage. In this paper, the CFD method is used to study the effect of different ignition times on the explosion and shock wave propagation of high-pressure hydrogen gas leakage, analyze the distribution of flammable gas clouds, and evaluate the impact of combustion flames, temperature, and explosion-induced overpressure on refueling stations. The results show that the concentration of gas clouds ranges from 0 to 80% (volume concentration). Explosion and combustion phenomena occur at different ignition times during the high-pressure hydrogen gas leakage stage, with a maximum pressure of 2.6 bar and a high temperature of 1500–2400 K. After a high-pressure hydrogen leak, ignition can occur only as an explosive phenomenon. This generates a pressure of up to 3.1 bar and a short-lived high temperature. The pressure increases with the length of the leak, and the hazardous area varies depending on the time of ignition. This paper provides theoretical support for safety issues related to high-pressure hydrogen leakage in refueling stations.

Metamorphism and P-T Evolution of High-Pressure Granulites from the Fuping Complex, North China Craton

Granulite facies rocks provide important keys to evaluating collisional metamorphism in orogenic belts. The mafic granulites of Baoding in the Fuping Complex of the North China Craton occur within the Trans-North China Orogen (TNCO), a major Paleoproterozoic collisional orogen. Here, we present results from detailed investigations on newly discovered garnet pyroxenite, garnet two-pyroxene granulite, and garnet-bearing-plagioclase amphibolite using petrographic, mineralogical, geochemical, and zircon U-Pb dating methods. Our results show that the Fuping Complex metamorphic evolution in this study evolved in four stages: prograde (M1), high-pressure granulite facies (M2), granulite facies (M3), and retrograde (M4) stages. The mineral assemblage of the prograde stage (M1) consists of Amp + Pl + Q within garnet cores. The mineral assemblage of high-pressure granulite facies at the peak stage (M2) consists of Gt + Cpx + Pl + Q ± Amp, forming the garnet pyroxenite. The granulite facies stage M3 is characterized by the occurrence of orthopyroxene, with a mineral assemblage of Gt + Cpx + Opx + Amp+ Pl + Q. The early retrograde stage M4-1 includes clinopyroxenes scattered inside amphiboles, following the breakdown of garnet and clinopyroxene. The mineral assemblage of this stage comprises Amp + Pl + Q + Ilm ± Cpx. Later, in the late retrograde stage M4-2, the composition of amphiboles changed to actinolite, and epidote and chlorite started to appear in the matrix. Traditional geothermobarometry yielded P-T conditions of 700~706 °C and 6.0~6.2 kbar for prograde stage M1, 854~920 °C and 13.0~13.8 kbar for high-pressure granulite facies stage M2, 912~939 °C and 8.1~9.9 kbar for M3, 661~784 °C and 3.1~4.4 kbar for M4-1, and 637~638 °C, 1.1~1.3 kbar for M4-2, along a clockwise P-T path with a nearly isothermal decompression (ITD) and slight heating. Zircon LA-ICP-MS U-Pb dating constrains the timing of the high-pressure granulite facies metamorphic event to be between 1.83 and 1.86 Ga. Geochemical features suggest that the protoliths of the high-pressure granulites may have formed in an island arc environment within a convergent margin setting. Together with results from previous studies, our data suggest that the ~1.85 Ga metamorphic age recorded in the Fuping Complex represents a regional metamorphism in the TNCO, associated with the subduction–collision and assembly of the Eastern and Western Blocks of the NCC.

Evaluation of the prospects for the use of single-stage centrifugal compressors based on high-pressure stages with an inlet guide device at linear gas compressor stations

Evaluation of the prospects for the use of single-stage centrifugal compressors based on high-pressure stages with an inlet guide device at linear gas compressor stations

Heat pump technology for utilizing the heat of secondary energy resources in the catalytic method of obtaining biodiesel

Heat pump technology for utilisation of heat of secondary energy resources in catalytic method of production of biodiesel fuel is implemented. Algorithm for control of technological parameters at all stages of production of biodiesel fuel is proposed and analysis of parameters of its quality is performed. Heat pump system is represented in the form of two recirculation circuits of low-potential and high-potential heat carriers, preparation of which was carried out in stages of low and high pressure of heat pump. Exergetic analysis was performed, functional dependencies of exergy flows coming out of the considered types of process equipment were obtained. The obtained hybesel fuel complied with the requirements of GOST 23513-79. The proposed heat pump technology reduced specific energy consumption by 13-14%; improve environmental safety at all stages of the process; maximum reduction of spent heat carriers emission into the ambient atmosphere.

Experimental investigation of the impacts of supercritical carbon dioxide on acid-etching fracture morphology and conductivity in tight carbonate reservoir

Carbon dioxide (CO2) as energized fluid has been used for acid-fracturing in tight carbonate reservoir. CO2 is often pumped into the wellbore in liquid phase with acid systems, and transited into supercritical state under the high-temperature formation. While the effect of supercritical CO2 (SC-CO2) on acid-etched fracture morphology and conductivity have rarely been investigated. The acid-etching and conductivity experiments were conducted on the outcrops of the Ma5 sub-member of the Ordo Basin in China. The mixed phase reaction simulation device was developed firstly. These experiments involved the mixing of SC-CO2 with various fluids, including formation water and viscoelastic surfactant (VES) acid, as well as different SC-CO2 concentrations with VES acid. The results show that 100 % SC-CO2 is easy to activate natural fractures without dissolution. After 20%SC-CO2 mixed with formation water, the dissolution ability of the mixed solution and conductivity is only 11.8 % and 1 ∼ 2 % of VES acid respectively. Roughness of the morphology created by the mixture of SC-CO2 with VES acid, exhibits a reduction compared to VES acid-etching, accompanied by the presence of wormholes. Additionally, there is a decrease in conductivity and increase in its retention rate. With the increase of SC-CO2 concentration, the roughness of acid-etching fracture decrease and the injection pressure curve becomes more stable. While the reaction rate is also retarded nearly linearly as the SC-CO2 concentration increases. Especially, when the SC-CO2 concentration is up to 40 %, the acid-rock reaction rate reaches only 55 % of that of VES acid. The conductivity of mixed-acid-etched fracture exhibits a segmented characteristic. During the low-medium closure pressure stage, the acid-etched fracture by VES acid generates high conductivity, specifically when it is below 34.5 MPa. While the higher the SC-CO2 concentration in the mixed acid is, the greater the conductivity and retention rate are at pressures above 34.5 MPa during high closure pressure stage. The conductivity of SC-CO2 acid-fracturing fracture depends on the non-uniform etching of the acid solution. The increase in SC-CO2 concentration of the mixed acid not only enhances conductivity and retention rate under high closure pressure, but also reduces the acid volume required for acid-fracturing.

The onset of Neo-Tethys subduction in the Early Jurassic: evidence from the eclogites of the North Shahrekord Metamorphic Complex (Sanandaj-Sirjan Zone, W Iran)

AbstractGeodynamic models implying subduction of continental crust either consider this process happening during collision, when the continental margin of the lower plate attempts subduction, or in pre-collisional stages, when tectonic erosion of the upper plate or subduction of continental extensional allochthons drag continental crust in the subduction channel. In the Zagros orogen (W Iran), high-pressure rocks are known only from the Sanandaj-Sirjan Zone, NE of the Main Zagros Thrust. Here, eclogites of the North Shahrekord Metamorphic Complex suggest subduction of continental crust slices derived from the upper plate (Central Iran) during the onset of the Neo-Tethys subduction along the southern margin of Iran. Eclogites record a clockwise pressure-temperature-time path, with pre-eclogitic epidote-amphibolites-facies phase assemblages preserved in garnet cores, a high-pressure stage, and a subsequent retrogression at amphibolite-facies conditions. By means of forward thermodynamic modelling and 40Ar/39Ar geochronology, the peak metamorphism has been constrained at 1.9-2.1 GPa and 550-600 °C, in the 191-194 Ma time span. The following retrogression during exhumation lasted at least until 144 Ma. Our data suggest that the onset of the Neo-Tethys subduction traces back prior to 190 Ma, involving together with the Neo-Tethys oceanic lithosphere also slices of the upper plate continental crust scraped off by means of tectonic erosion processes.

Performance analysis, multiobjective optimization and working fluid selection for a DPORC system with geothermal source shunting

A dual-pressure ORC system with geothermal source shunting (GSS-DPORC) is proposed. The geothermal source at the outlet of the high-pressure evaporator is shunted so that one portion of it heats the high-pressure preheater and the other portion heats the low-pressure evaporator. Thermodynamic, economic, and environmental performance of the GSS-DPORC system are examined and contrasted with those of the DPORC system under different working fluids and conditions. Further, the EW-GRA-TOPSIS comprehensive evaluation method, which picks the optimal working fluid while attaining the best working conditions, is proposed. It fully assesses the working fluid based on the multiobjective optimization results generated by NSGA-II. The results indicate that the performance metrics of the GSS-DPORC system are superior to those of the DPORC system when the geothermal source inlet temperature is in the range of 373–423 K, the evaporation pressure of high-pressure stage ranges from 740 kPa to 1610 kPa, and the evaporation pressure of low-pressure stage ranges from 540 kPa to 1020 kPa. R227ea has better thermodynamic and economic performance, and R245fa has better economic performance. The R227ea has the best overall performance following a thorough review using the EW-GRA-TOPSIS method, while the R245fa has the poorest performance.