High-performance Anode For Sodium-ion Batteries Research Articles

Hexagonal CuSe decorated with reduced graphene oxide as a stable anode for high-performance sodium-ion batteries

Hexagonal CuSe decorated with reduced graphene oxide as a stable anode for high-performance sodium-ion batteries

Sucrose-anthracite composite supplemented by KOH&HCl washing strategy for high-performance carbon anode material of sodium-ion batteries

Sodium-ion batteries represent a promising alternative to lithium-ion batteries, necessitating research into cost-effective synthesis of high-performance anode materials. Herein, this work proposes a facile method combining sucrose-anthracite composites with KOH&HCl decontamination to produce soft/hard carbon hybrids. This approach enhances the structural stability of the material to optimize the carbon yield and increases the interlayer spacing and microcrystalline disorder. The presence of numerous defect sites and C=O active double bonds within the structure, coupled with the flaky morphology, results in an outstanding carbon anode material, exhibiting a high specific capacity of 272 mAh g−1 with excellent rate performance (229 mAh g−1 at 10 C). Furthermore, the material maintains 80 % capacity over 1300 cycles at a high current density of 10 C. The optimization in structure and morphology, along with enhanced electronic conductivity and ionic diffusion kinetics, also ensures that the capacity of the material is dominated by plateau capacity at any current density, which is beneficial for increasing the energy density of full battery configurations and holds promise for high-performance sodium-ion battery anode materials.

Novel NiCo2S4 nanorod arrays grown on carbon nanofibers as high-performance anodes for sodium-ion batteries

Novel NiCo2S4 nanorod arrays grown on carbon nanofibers as high-performance anodes for sodium-ion batteries

Unveiling the Potential of Bi/FeS-G Nanocomposites: A Pioneering Approach to Dual-Functional Anodes for High-Performance Lithium-Ion and Sodium-Ion Batteries

Unveiling the Potential of Bi/FeS-G Nanocomposites: A Pioneering Approach to Dual-Functional Anodes for High-Performance Lithium-Ion and Sodium-Ion Batteries

Core–shell structured carbon@tin sulfide@hard carbon spheres as high-performance anode for low voltage sodium-ion battery

Core–shell structured carbon@tin sulfide@hard carbon spheres as high-performance anode for low voltage sodium-ion battery

Construction of MnS nanocubes confined in N, S co-doped carbon as high-performance anodes for sodium-ion batteries

Profiting from the huge natural abundance and high theoretical capacity, manganese sulfides (MnS) have triggered abundant interest and attention, which are expected as highly prospective anodes for sodium-ion batteries (SIBs). Nevertheless, their wide utilizations are seriously impeded by the drawbacks of low electric conductivity, extensive volumetric changes, and sluggish insertion/extraction kinetics, which often result in a rapid deterioration of the capacity and cyclic lifespan for SIBs. Herein, MnS nanocubes confined in N, S co-doped carbon (NSC) matrix are manufactured through a simple hydrothermal with the following sulfurization method. The incorporation of carbon improves the electric conductivity to accelerate electron transport and guards the structural integrality of MnS in the long-term cycling process via the confinement effect. The in situ formed sulfur-bridged bonds (C-S-Mn) provide an intimate affinity between the MnS nanocubes and NSC matrix, which effectively prevents the aggregation and mitigates the volumetric variation of MnS nanocubes in the sodiation/desodiation reactions. Moreover, the hierarchically porous structures in MnS@NSC offer rapid diffusion pathways for Na+ ions that effectively enhance the diffusion kinetics. Benefiting from the admirable synergistic effects between the hierarchically porous MnS nanocubes and conductive NSC framework, the MnS@NSC anode delivers satisfied sodium storage properties.

Conversion of waste denim fabrics into high-performance carbon fiber anodes for sodium-ion batteries

Conversion of waste denim fabrics into high-performance carbon fiber anodes for sodium-ion batteries

Biomass-derived hard carbon material for high-capacity sodium-ion battery anode through structure regulation

Economical and environmentally friendly hard carbon materials are attractive options for high-performance sodium-ion battery anode materials. Biomass-derived hard carbon materials have good economic benefits and environmentally friendliness as anode materials for sodium-ion batteries. In this work, we propose a new hard carbon material prepared from agricultural waste olive shells through a simple and environmentally friendly process. The effects of high-temperature treatments and pre-carbonization strategies on the pore structure and graphitization degree of the hard carbon materials were investigated. Combined with electrochemical performance tests, the influence of structural changes on the sodium storage properties of the olive shell-derived hard carbon was revealed. Under the optimized conditions of carbonization temperature and pre-carbonization strategy, the OSHC-Air electrode exhibits excellent sodium storage capacity with 87 % capacity remaining after 1000 cycles at 1000 mA g−1. The assembled PB//OSHC-Air sodium-ion full cell exhibits a high capacity of 216 mAh g−1. Our research provides a potential candidate for commercial anode materials for high-capacity sodium-ion batteries.

Tannic acid etching construction of hollow heterogeneous CoSe2-FeSe2@nitrogen-doped carbon rhombic dodecahedron for high-performance sodium storage

Metal selenides are very promising anode materials for sodium ion batteries (SIBs) due to their rich redox behaviors, low cost, high theoretical capacity, and environmentally benign. However, the poor cycle performance and rate capability greatly hinder their widespread applications. In this paper, we have proposed a tannic acid etching zeolitic imidazolate framework-67 (ZIF-67)-derived selenide strategy to construct hollow heterogeneous CoSe2-FeSe2@N-doped carbon rhombic dodecahedron (CoSe2-FeSe2@NC) as anode for high-performance SIBs. The special microstructural characteristics with hollow rhombic dodecahedron can reduce the Na+/electron migration path and alleviate the volume variations during cycling. The NC can improve conductivity and reduce volume effects during cycling. What’s more, the built-in electric fields (BIEF) at the CoSe2-FeSe2 heterointerfaces can modulate the electronic structure and accelerate the kinetics of ionic diffusion, resulting in the improvement electrochemical properties. When applied as anodes for SIBs, the CoSe2-FeSe2@NC can deliver a remarkable electrochemical performance in terms of sodium storage capacity (648.5 mAh g−1 at 0.2 A/g), initial coulombic efficiency (82.0 %), cycle performance (92.6 % capacity retention after 100 cycles), and rate capability of 450.6 mAh g−1 after 1000 cycles at a high rate of 1 A/g. The kinetic analysis indicates that the discharging-charging process of CoSe2-FeSe2@NC is ascribed to both capacitive behavior and controlled diffusion.

CVD-Synthesized Titanium Carbide Nanoflowers as High-Performance Anodes for Sodium-Ion Batteries.

Sodium-ion batteries (SIBs) have emerged as promising candidates for energy storage applications due to the abundance and low cost of sodium. However, the larger radius of sodium ions limits their diffusion kinetics within electrode materials and contributes to electrode volume expansion. Here, we successfully synthesized porous titanium carbide (TiC) nanoflowers through chemical vapor deposition (CVD). The TiC nanoflowers exhibit exceptional electrochemical performance as SIB anodes, with their porous structure enhancing the conductivity, mechanical stability, and Na-ion diffusion. The TiC nanoflowers demonstrate a high reversible specific capacity of 73.5 mAh g-1 at 1 A g-1 after 2500 cycles, corresponding to an impressive capacity retention of 80.81%. Additionally, we developed a full sodium-ion cell utilizing TiC nanoflowers as the anode and Na3V2(PO4)3 as the cathode, which demonstrates a substantial reversible capacity and outstanding cycling stability. Our work presents a promising strategy for synthesizing nanostructured TiC materials as anode electrodes for SIBs.

Nanoarchitectured Fe3C@N-Doped C/FeVO4 as High-Performance Anode for Sodium-Ion Batteries.

Ferric vanadate exhibits potential as an attractive anode material for sodium-ion batteries (SIBs) due to the multiple oxidation states of vanadium and natural abundances of iron. However, the design and fabrication of high-performance ferric vanadate-based SIB anode materials with unique composite nanostructures are still challenging. Herein, a facile self-template method is reported to synthesize 1D nanostructured Fe3C@N-doped C/FeVO4 (Fe3C@NC/FeVO4) anode materials by the combination of morphology regulation with hybrid composite construction, for the first time. To this end, a 1D Fe, N-doped carbon nanotube (FeNC) is used as a template, followed by etching and re-growth to obtain the 1D Fe3C@N-doped C/FeVO4 nanostructure. The introduction of Fe3C can improve its electronic conductivity and enhance capacitive behavior. Additionally, the 1D nanostructure can effectively shorten the ions transport path and alleviate volume expansion during the charge-discharge processes. With these advantages, the SIBs using such anodes show a remarkable rate performance with a capacity of 325.4mAhg-1 at 0.1Ag-1, 150.6mAhg-1 at 5Ag-1, and excellent cycling stability with a reversible capacity of 139.6mAhg-1 at 1Ag-1 after 1500 cycles. This work offers a new strategy for the future development of SIBs with ferric vanadate-based anode.

Pomegranate Peel-Derived Hard Carbons as Anode Materials for Sodium-Ion Batteries.

Exploring high-performance carbon anodes that are low-cost and easily accessible is the key to the commercialization of sodium-ion batteries. Producing carbon materials from bio by-products is an intriguing strategy for sodium-ion battery anode manufacture and for high-value utilization of biomass. Herein, a novel hard carbon (PPHC) was prepared via a facile pyrolysis process followed by acid treatment using biowaste pomegranate peel as the precursor. The morphology and structure of the PPHC were influenced by the carbonization temperature, as evidenced by physicochemical characterization. The PPHC pyrolyzed at 1100 °C showed expanded interlayer spacing and appropriate oxygen group content. When used as a sodium ion battery anode, the PPHC-1100 demonstrated a reversible capacity of up to 330 mAh g-1, maintaining 174 mAh g-1 at an increased current rate of 1 C. After 200 cycles at 0.5 C, the capacity delivered by PPHC-1100 was 175 mAh g-1. The electrochemical behavior of PPHC electrodes was investigated, revealing that the PPHC-1100 possessed increased capacitive-controlled energy storage and improved ion transport properties, which explained its excellent electrochemical performance. This work underscores the feasibility of high-performance sodium-ion battery anodes derived from biowaste and provides insights into the sodium storage process in biomass-derived hard carbon.

Steric Hindrance Engineering to Modulate the Closed Pores Formation of Polymer-Derived Hard Carbon for High-Performance Sodium-Ion Batteries.

The closed pores play a critical role in improving the sodium storage capacity of hard carbon (HC) anode, however, their formation mechanism as well as the efficient modulation strategy at molecular level in the polymer-derived HCs is still lacking. In this work, the steric hindrance effect has been proposed to create closed pores in the polymer-derived HCs for the first time through grafting the aromatic rings within and between the main chains in the precursor. The experimental data and theoretical calculation demonstrate that steric-hindrance effect from the aromatic ring side group can increase backbone rigidity and the internal free volumes in the polymer precursor, which can prevent the over graphitization and facilitate the formation of closed pores during the carbonization process. As a result, the as-prepared HC anode exhibits a remarkably enhanced discharge capacity of 340.3 mAh/g at 0.1 C, improved rate performance (210.7 mAh/g at 5 C) as well as boosted cycling stability (86.4 % over 1000 cycles at 2 C). This work provides a new insight into the formation mechanisms of closed pores via steric hindrance engineering, which can shed light on the development of high-performance polymer-derived HC anode for sodium-ion batteries.

Unravelling the anionic stability of an ether-based electrolyte with a hard carbon or metallic sodium anode for high-performance sodium-ion batteries

In hard carbon (HC) anodes, elucidating the relationship between the solid electrolyte interphase formation and the solvated Na+ co-intercalation mechanism is crucial, particularly considering different anionic salts in ether-based electrolytes. Here, we comprehensively explore the impact of different anionic salts on the electrochemical performance of HC/Na half-cell and elucidate the underlying mechanism through experimental studies and theoretical calculations. The surface morphology of the HC anode and its interphasial property are further investigated to evaluate the differences endowed by the presence of various anionic salts in diglyme (2G). The HC/Na half-cells with NaPF6-2G and sodium trifluoromethanesulfonate (NaCF3SO3)-2G display superior electrochemical performance with faster kinetics and lower interfacial resistance than those with NaClO4-2G, sodium bis-(fluorosulfonyl) imide (NaFSI)-2G and sodium bis-(trifluoromethanesulfonyl) imide (NaTFSI)-2G. NaClO4-2G forms a relatively thick interphase layer with high resistance at the electrode/electrolyte interface owing to its insufficient stability. NaFSI-2G and NaTFSI-2G exhibit severe side reactions with Na metal, producing a thick interphase layer on the HC surface with high interfacial resistance from excess electrolyte decomposition, thus deteriorating the electrochemical performance. In summary, the study on the stability of different anionic salts in ether-based electrolyte for the HC anode with the intercalation mechanism provides valuable insights for screening appropriate conductive salts for high-performance sodium-ion batteries, especially when considering Na metal counter/reference electrodes.

Dual carbon confining SnO2 nanocrystals as high-performance anode for sodium-ion batteries

The increasing global demand for sustainable energy sources has driven research into sodium-ion batteries (SIBs) for large-scale energy storage. However, their electrochemical performance is hindered by poor reaction kinetics and significant volume expansion in electrode materials. In this work, we developed a dual-carbon-confined SnO2 nanocrystal anode (CNTs@SnO2@NC) designed for high-performance SIBs. This innovative structure uses carbon nanotubes (CNTs) and a nitrogen-doped carbon (NC) coating to stabilize SnO2, ensuring structural integrity during charge/discharge cycles. The CNTs network in CNTs@SnO2@NC can alleviate the agglomeration of SnO2 nanocrystals to a certain extent; With its superior electronic conductivity, CNTs can enhance the anode's conductivity and function as an electronic highway; The sodiophilic properties and good electrical conductivity of CNTs enable sodium ions to migrate rapidly on the surface of the nanotubes. Moreover, numerous external defects and active sites generated by nitrogen doping enhance the sodium ion absorption capabilities; The existence of nitrogen-doped carbon coating can effectively accommodate the volume changes of SnO2 and enhance the structural stability of CNTs@SnO2@NC composites during the repeated charge and discharge cycles. As a result, the CNTs@SnO2@NC composite demonstrates excellent electrochemical performance, achieving capacity of 235 mAh g−1 at 0.1 A g−1 over 100 cycles and 102 mAh g−1 at 1.0 A g−1 over 300 cycles. In a full-cell configuration with a Na3V2(PO4)3 cathode, it delivers 38 mAh g−1 at 100th cycle at 0.1 A g−1. This study underscores the substantial improvements achieved by dual-carbon confinement for high-performance SIB anodes, offering a promising direction for future anode material design.

Microcrystalline Engineering of Anthracite-Based Carbon Via Salt-Assisted Ball Milling for Enhanced Sodium Storage Performance.

Coal-based carbon material, characterized by abundant resources and low cost, has gained considerable interests as a promising anode candidate for sodium-ion batteries (SIBs). However, the coal-based carbon generally shows inferior Na-storage performance due to its highly-ordered microstructure with narrow interlayer spacing. Herein, a salt-assisted mechanical ball-milling strategy is proposed to disrupt the polycyclic aromatic hydrocarbon structure in anthracite molecules, thereby reducing the microcrystalline regularity of the derived carbon during following pyrolysis process. In addition, the induced C─O─C bonds during ball-milling process can alter the pyrolysis behavior of anthracite and restrain the formation of surface defects. Consequently, in contrast to pristine anthracite-based pyrolytic carbon, which exhibits a Na-storage capacity of 198.4 mAh g-1 with a low initial Coulombic efficiency (ICE) of 65.1%, the ball-milling modified carbon assisted by NaCl salt (NAC), with enhanced structural disordering and reduced surface defects, demonstrate significantly improved Na-storage capacity of 332.1 mAh g-1 and ICE value of 82.0%. The NAC electrode also realizes excellent cycle and rate performance, retaining a capacity of 196.0 mAh g-1 at 1 C after 1000 cycles. Furthermore, when coupled with NaNi1/3Fe1/3Mn1/3O2 cathode, the assembled Na-ion full cell deliveres an exceptional electrochemical performance, highlighting its promising prospect as high-performance anode for SIBs.

Liquid Gallium-Assisted Pyrolysis of MOF Affording CNT Non-Hollow Frameworks in High Yields for High-Performance Sodium-Ion Battery Anode.

Carbon materials have great potential for applications in energy, biology, and environment due to their excellent chemical and physical properties. Their preparation by carbonization methods encounters limitations and the carbon loss during pyrolysis in the form of gaseous molecules results in low yield of carbon materials. Herein a low-energy (600°C) and high-yield (82wt.%) carbonization strategy is developed using liquid gallium-assisted pyrolysis of metal-organic frameworks (MOFs) affording the N-doped carbon nanotube (CNT) non-hollow frameworks encapsulating Co nanoparticles. The liquid gallium layer offers protection against air, promotes heat transfer, and limits the escape of small carbonaceous gaseous molecules, which greatly improve the yields of the pyrolysis reaction. Experimental and theoretical results reveal that the synergistic interaction between CNTs and N/O-containing groups gives a non-hollow framework composed of N/O-enriched and open CNTs (NOCNTF-15, 15 denotes the 15mm thickness of the liquid gallium layer during the pyrolysis) with high specific capacity (185mAhg-1 at 10Ag-1) and ultra-stable cyclability (stable operation at 10Ag-1 and 50°C for 20000 cycles). This study provides a unique approach to carbonization that facilitates the practical application of low-cost CNTs and other MOFs-derived carbon materials in high-performance sodium-ion batteries (SIBs).

CoO nanoparticles anchored on porous pinecone-derived activated carbon as anodes for high-performance lithium and sodium-ion batteries

In this work, a new nanocomposite system based on CoO nanoparticles (NPs) anchored on pinecone-derived activated carbon (PAC), denoted as CoO(x)@PAC, is synthesized by facile ball-milling and sonication processes followed by annealing. H3PO4 is employed as an activation agent to activate the porous carbon derived from pinecone. The loading amount of CoO is varied to obtain the optimum electrochemical performances. Among the nanocomposites, the CoO(20)@PAC delivers a discharge capacity of 886 mA h g−1 after 100 cycles at a current density of 100 mA g−1 when employed as an anode in lithium-ion batteries (LIBs). At higher current rate of 1000 mA g−1, the anode provides an enhanced discharge capacity of 456.6 mA h g−1 after 200 cycles with 99 % capacity retention compared to the 4th cycle capacity. In sodium-ion batteries (SIBs), the CoO(20)@PAC anode delivers a discharge capacity of 290 mA h g−1 at 50 mA g−1. The same nanocomposite anode provides a discharge capacity of 120 mA h g−1 after 900 cycles at a current density of 500 mA g−1. The CoO(20)@PAC nanocomposite shows a great potential as an anode for both LIBs and SIBs, due to its higher capacity, exceptional rate capability, longer cycle life, and a Coulombic efficiency exceeding 99 %.

Synergistic effect of in-situ carbon-coated mixed phase iron oxides and 3d electrode architectures as anodes for high-performance sodium-ion batteries

Due to the high theoretical capacity, iron-oxide-based Fe2O3 (1007 mAh g−1) and Fe3O4 (926 mAh g−1) materials can be a promising conversion-type anode material for Sodium-ion batteries (SIBs). However, the low electronic conductivity (10−14 S cm−1) and 200% volume expansion of iron oxide lead to poor cycle life and capacity retention, limiting its commercial application. In this work, carbon-coated mixed-phase iron oxide C-Fe2O3-Fe3O4 (C-IO) was synthesized by pyrolysis using ferrocene precursor. Subsequently, a 3D carbon fiber (CF) network was introduced to improve the electrochemical performance of the material by resolving the volume expansion and pulverization issues. Both the CF network and Fe3O4 provide an electron transport pathway. The conventional Cu-C-IO electrodes deliver a 2nd cycle capacity of 335 mAh g−1 at 250 mA g−1 and exhibit 61.5% capacity retention after 500 cycles. In contrast, the 3D-CF-based IO electrodes show 2nd cycle capacity of 607 mAh g−1 at 50 mA g−1 with 96.4% capacity retention after 35 cycles and 420 mAh g−1 with ∼85.4% capacity retention after 500 cycles at 250 mA g−1 (w.r.t. CF and C-IO active mass, CF contribute ∼ 27% and C-IO ∼ 73% capacity), making it a potential anode for SIBs.

Rational design of mangosteen-like bismuth nanospheres coated by N-doped carbon shell as superb composite anode for high-performance sodium-ion batteries

Metallic bismuth (Bi) anode materials are promising candidates for alkali-ion batteries due to its high theoretical gravimetric/volumetric capacity. However, the pronounced volume change from Bi to full sodiation phase Na3Bi, inducing the structural collapse, and ionic conduction interruption upon cycling, hinders their implementation in sodium-ion batteries (SIBs). Herein, a mangosteen-like bismuth nanosphere coated by N-doped carbon shell (Bi@NC) was designed and synthesized to address these limitations. Due to the nanosize of Bi core and in situ, generated N-doped carbon shell, this Bi@NC anode can not only effectively accommodate the volume change during the alloying/dealloying process but also provide high-speed channels for electron/ion transport to the highly active bismuth nanospheres. The Bi@NC electrode exhibits outstanding cycling stability (1000 cycles at 5 A g−1 with an impressive capacity retention of 96.5 %) and rapid sodium storage performance (392.8 mAh g−1 at 20 A g−1). Importantly, ex-situ techniques and kinetic analysis have revealed the distinctively sharp multiphase transitions and the “battery-capacitor dual-mode” sodium-storage mechanism. This research introduces a new approach to enhance the performance of bismuth-based anodes in advanced SIBs and demonstrates potential for practical applications.