The goal of the present work is to produce the efficient cutting of Ti-16Al-14Nb (α/β) alloy through wire-electric discharge machining and contemplate the terminologies such as machining ability, surface integrity and material removing capability. For this, the experimentation has been designed by considering three process parameters, pulse-on time ( Ton), pulse-off time ( Toff) and peak current ( Ip) at three significant levels (low, high, intermediate) in L27 order designed from design of experiments. The effect of these process variables on pulse characteristics, surface roughness ( Ra), kerfwidth ( Kw) and material removal rate ( MRR) is analyzed and mathematically modeled with analysis of variance. The results state that the highest MRR (0.521, 0.51, 0.506 mm3/sec) and low surface roughness (8.91, 8.89, 8.68 µm) values are observed at the highest level (110 µs, 15 µs, 8 A). If the pulse duration is kept at low ( Ton = 40µs, Toff = 3µs), the increase in peak current from 3 A to 8 A leads to a 64.54% increase in MRR and a 52.9% increase in Ra values. ANOVA results stated that Ton has contributed 20.4%, 35.8% and 19.3%, and Ip has contributed 43.1%, 30.5% and 46.6% influence on MRR, Kw and Ra respectively. The voltage–current characteristics studies confirmed that the strong intense pulses at a higher peak current (8 A) resulted in the increased MRR (0.521 mm3/sec) and Ra (8.43 µm) leading to the formation of swages and ridges. The surface integrity analysis derived from Abbott–Firestone curve agreed that the lowest level has shown better skewness ( Rsk = −0.274) and at highest level showed a larger deviation in skewness ( Rsk = +2.672) signifies that higher asymmetry (poor) of the surface.