High-field Magnetization Measurements Research Articles

Single crystal growth and magnetic properties in triangular chain compound Ni2SiO4

Sub-centimeter-scale Ni2SiO4 single crystals were grown by a flux method with K2MoO4 as the flux. The obtained crystals exhibit high quality and were characterized using X-ray diffraction, chemical analysis, and magnetic properties, including high magnetic field (H) magnetization (M) measurements. The results of magnetic susceptibility and specific heat of a single crystal reveal significant magnetic anisotropy and antiferromagnetic ordering below TN = 30 K. High-field magnetization up to 43 T of polycrystalline shows six magnetic phase transitions at H1 = 14 T, H2 = 18.4 T, H3 = 23 T, H4 = 29 T, H5 = 32.5 T, and H6 = 37 T, forming a complex magnetic phase diagram with seven phases. Notably, the M exhibits a linear relationship with H during phases V (H4 < H < H5) and VII (H > H6), showing intercepts at 0 and half of magnetization saturation respectively, implying the presence of a spin flop transition and a 1/2 magnetization plateau. These novel phenomena in such a triangular chain system highlight complex physical nature, making Ni2SiO4 a promising candidate for studying intricate magnetic interactions.

Tilted Spins in Chains of Molecular Switches on Pb(100).

A complex based on a Ni(II) porphyrin exhibiting spin crossover on Ag(111) is studied on Pb(100) by scanning tunneling microscopy at 0.3 K. Strong molecular interactions between the phenyl and pentafluorophenyl moieties lead to the formation of molecular chains and cause a faceting of the substrate surface. The chains are located along double and multiple substrate steps that deviate from high-symmetry directions. Tunneling spectroscopy reveals spin-flip excitations of an S = 1 system. Measurements in high magnetic fields are used to identify a tilt of the complex and its hard anisotropy axis with respect to the surface normal. Electron injection into the substrate near the molecular rows induces a transition to a state with larger inelastic cross section, leaving the spin state unchanged.

Field-induced Bose–Einstein condensation in zigzag spin chain KGaCu(PO4)2

Single crystals of GaKCu(PO4)2 were synthesized using the hydrothermal method, and subsequent measurements of specific heat, magnetic susceptibility, and high-field magnetization were performed. A broad peak is observed in the magnetic susceptibility and specific heat curves, with the maximum values appearing at about 11.5 K and 5.29 K, respectively. The highest maximum peak value of susceptibility is observed when the magnetic field is applied along the c-axis, followed by the a-axis, b-axis, and polycrystalline samples. These indicate that the system exhibits one-dimensional magnetism and the magnetic easy axis is the c axis. The magnetization at 2 K reveals the occurrence of a field-induced Bose–Einstein condensation (BEC) phase within the magnetic field range of approximately 8−12 T. High-field magnetization up to 40 T indicates that the compound reaches magnetization saturation as the field exceeds H s = 12 T. Through systematic measurements, a field-temperature (H−T) phase diagram was constructed, and dome-like phase boundaries were observed. The findings suggest that GaKCu(PO4)2 is a spin gap system and a promising candidate for studying BEC of magnons due to its phase transition boundary occurring at low magnetic fields.

Enhanced sensitivity distributed sensing of magnetic fields in optical fiber using random Bragg grating

We show that the use of random optical grating using UV exposure (ROGUE) can significantly reduce the noise floor of an optical frequency domain reflectometry (OFDR) measurement of Faraday rotation in the polarization. We compare it with unexposed spun fiber, which shows a S/P minimum ratio (signal noise floor) 20 dB higher than when using our ROGUE. High sensitivity magnetic field measurements are achieved by spatially filtering (setting a gage length) the derivative of the S/P ratio’s evolution. An example of a calibrated electromagnet spatially resolved B-field measurement is demonstrated, which can measure fields down to 10 mT with 10 cm spatial resolution. The potential for current sensing using the ROGUE apparatus is discussed and simulation shows a noise floor of ∼1 A with 40 probing loops spatial resolution.

Possible intermediate quantum spin liquid phase in α-RuCl3 under high magnetic fields up to 100 T

Pursuing the exotic quantum spin liquid (QSL) state in the Kitaev material α-RuCl3 has intrigued great research interest recently. A fascinating question is on the possible existence of a field-induced QSL phase in this compound. Here we perform high-field magnetization measurements of α-RuCl3 up to 102 T employing the non-destructive and destructive pulsed magnets. Under the out-of-plane field along the c* axis (i.e., perpendicular to the honeycomb plane), two quantum phase transitions are uncovered at respectively 35 T and about 83 T, between which lies an intermediate phase as the predicted QSL. This is in sharp contrast to the case with in-plane fields, where a single transition is found at around 7 T and the intermediate QSL phase is absent instead. By measuring the magnetization data with fields tilted from the c* axis up to 90° (i.e., in-plane direction), we obtain the field-angle phase diagram that contains the zigzag, paramagnetic, and QSL phases. Based on the K-J-Γ-{{{Gamma }}}^{{prime} } model for α-RuCl3 with a large Kitaev term we perform density matrix renormalization group simulations and reproduce the quantum phase diagram in excellent agreement with experiments.

A Measuring System for HTS Wires and Coils Properties at Low Temperatures

The use of high temperature superconducting materials (HTS) in various applications, requires knowledge of their critical parameters like critical current, critical magnetic field and critical temperature, in DC applications like high magnetic field generators, superconducting magnetic energy storage system (SMES), magnetic resonance imaging (MRI), magnets for particle accelerators, SC Maglev trains and other applications. Also, these parameters are important for specific properties in alternating current applications like fault current limiters, transformers, generators, motors, and power transmission lines. An important characteristic that needs to be tucked into consideration for AC applications is the power losses that occur in the HTS superconducting materials, which limits the maximum performance that the superconducting materials can attain for these applications. In order to measure these characteristics, which depend on the type of material used, but also on the temperature and other parameters, it is necessary to use an appropriate setup device that allows both obtaining the working temperature range (4.2 K to 300 K and other necessary parameters like high vacuum 10-6 mbar, high current supply (500 A), high magnetic field measurement system (1-10 T), etc. For the cryogenic cooling of the entire system, a closed cycle Gifford-McMahon type cryocooler is used, with two cooling stages, stage I at 50 K and second stage at 4.2 K (liquid Helium temperature). The set-up system used for measurement of the parameters of HTS superconducting materials (YBCO, BSCCO or MgB2) and the various coils made with them, is described in this article together with its functional parameters and some experimental results obtained by testing an YBCO coils system. The maximum generated magnetic flux density was 5 T in the centre of the coils system.

High field magnetic transport measurements of FeGe thin plates

Magnetic skyrmions have garnered considerable attention due to their topological properties and potential applications in information storage. These unique structures can be found in chiral magnets, including well-known compounds like MnSi and FeGe with a B20-type crystal structure. In this study, we utilized Lorentz transmission electron microscopy to investigate the influence of magnetic skyrmions on the Hall effect in FeGe under low magnetic fields. Additionally, we examined the magnetoresistance (MR) and Hall effect of FeGe under a high magnetic field of 28 T. Our findings reveal distinct mechanisms governing the MR at low and high temperatures. Notably, the anomalous Hall effect plays a significant role in the Hall resistivity observed at low magnetic fields. Meanwhile, the contribution of the skyrmion-induced topological Hall signal in the FeGe is ignorable. Furthermore, by employing a two-carrier model and fitting the carrier concentration of FeGe under high magnetic fields, we demonstrate a transition in the dominant carrier type from electrons to holes as the temperature increases. These results contribute to a deeper understanding of the intrinsic magnetic properties of FeGe.

Complex magnetic phase diagram with a small phase pocket in a three-dimensional frustrated magnet CuInCr4S8

Frustrated magnets with a strong spin-lattice coupling can show rich magnetic phases and the associated fascinating phenomena. A promising platform is the breathing pyrochlore magnet ${\mathrm{CuInCr}}_{4}{\mathrm{S}}_{8}$ with localized $S=3/2\phantom{\rule{4pt}{0ex}}{\mathrm{Cr}}^{3+}$ ions, which is proposed to be effectively viewed as an $S=6$ Heisenberg antiferromagnet on the face-centered-cubic lattice. Here we unveil that ${\mathrm{CuInCr}}_{4}{\mathrm{S}}_{8}$ exhibits a complex magnetic phase diagram with a small phase pocket ($A$ phase) by means of magnetization, magnetostriction, magnetocapacitance, and magnetocaloric-effect measurements in pulsed high magnetic fields of up to 60 T. Remarkably, the appearance of $A$ phase is accompanied by anomalous magnetostrictive and magnetocapacitive responses, suggesting the emergence of helimagnetism in contrast to the neighboring commensurate magnetic phases. Besides, the high-entropy nature is confirmed in the high-temperature side of $A$ phase. These features are potentially related to a thermal fluctuation-driven multiple-$q$ state caused by the magnetic frustration, which has been theoretically predicted but yet experimentally undiscovered in insulating magnets.

Magnetic and magnetoelastic properties of Er3Al2

We report on comprehensive investigations of ${\mathrm{Er}}_{3}{\mathrm{Al}}_{2}$ exhibiting a number of magnetic states. We observe three spontaneous antiferromagnetic transitions at 10, 14, and 24 K. Furthermore, our high-field magnetization and sound-velocity measurements reveal a number of crystal-electric-field (CEF) transitions. Additionally, the velocity of transverse acoustic waves shows a pronounced softening with decreasing temperature in the paramagnetic state. A CEF model that includes quadrupolar interactions explains the observed magnetic and elastic properties and provides a CEF scheme of ${\mathrm{Er}}_{3}{\mathrm{Al}}_{2}$. However, to explain some of the observations, a refined, more sophisticated model needs to be developed.

A lightweight magnetically shielded room with active shielding

Magnetically shielded rooms (MSRs) use multiple layers of materials such as MuMetal to screen external magnetic fields that would otherwise interfere with high precision magnetic field measurements such as magnetoencephalography (MEG). Optically pumped magnetometers (OPMs) have enabled the development of wearable MEG systems which have the potential to provide a motion tolerant functional brain imaging system with high spatiotemporal resolution. Despite significant promise, OPMs impose stringent magnetic shielding requirements, operating around a zero magnetic field resonance within a dynamic range of ± 5 nT. MSRs developed for OPM-MEG must therefore effectively shield external sources and provide a low remnant magnetic field inside the enclosure. Existing MSRs optimised for OPM-MEG are expensive, heavy, and difficult to site. Electromagnetic coils are used to further cancel the remnant field inside the MSR enabling participant movements during OPM-MEG, but present coil systems are challenging to engineer and occupy space in the MSR limiting participant movements and negatively impacting patient experience. Here we present a lightweight MSR design (30% reduction in weight and 40–60% reduction in external dimensions compared to a standard OPM-optimised MSR) which takes significant steps towards addressing these barriers. We also designed a ‘window coil’ active shielding system, featuring a series of simple rectangular coils placed directly onto the walls of the MSR. By mapping the remnant magnetic field inside the MSR, and the magnetic field produced by the coils, we can identify optimal coil currents and cancel the remnant magnetic field over the central cubic metre to just |B|= 670 ± 160 pT. These advances reduce the cost, installation time and siting restrictions of MSRs which will be essential for the widespread deployment of OPM-MEG.

Evidence for a Square-Square Vortex Lattice Transition in a High-T_{c} Cuprate Superconductor.

Using sound velocity and attenuation measurements in high magnetic fields, we identify a new transition in the vortex lattice state of La_{2-x}Sr_{x}CuO_{4}. The transition, observed in magnetic fields exceeding 35T and temperatures far below zero field T_{c}, is detected in the compression modulus of the vortex lattice, at a doping level of x=p=0.17. Our theoretical analysis based on Eilenberger's theory of the vortex lattice shows that the transition corresponds to the long-sought 45° rotation of the square vortex lattice, predicted to occur in d-wave superconductors near a van Hove singularity.

Analysis of multiscale structures at the quasi-perpendicular Venus bow shock

Context.Solar Orbiter is a European Space Agency mission with a suite of in situ and remote sensing instruments to investigate the physical processes across the inner heliosphere. During the mission, the spacecraft is expected to perform multiple Venus gravity assist maneuvers while providing measurements of the Venusian plasma environment. The first of these occurred on 27 December 2020, in which the spacecraft measured the regions such as the distant and near Venus magnetotail, magnetosheath, and bow shock.Aims.This study aims to investigate the outbound Venus bow shock crossing measured by Solar Orbiter during the first flyby. We study the complex features of the bow shock traversal in which multiple large amplitude magnetic field and density structures were observed as well as higher frequency waves. Our aim is to understand the physical mechanisms responsible for these high amplitude structures, characterize the higher frequency waves, determine the source of the waves, and put these results into context with terrestrial bow shock observations.Methods.High cadence magnetic field, electric field, and electron density measurements were employed to characterize the properties of the large amplitude structures and identify the relevant physical process. Minimum variance analysis, theoretical shock descriptions, coherency analysis, and singular value decomposition were used to study the properties of the higher frequency waves to compare and identify the wave mode.Results.The non-planar features of the bow shock are consistent with shock rippling and/or large amplitude whistler waves. Higher frequency waves are identified as whistler-mode waves, but their properties across the shock imply they may be generated by electron beams and temperature anisotropies.Conclusions.The Venus bow shock at a moderately high Mach number (∼5) in the quasi-perpendicular regime exhibits complex features similar to the Earth’s bow shock at comparable Mach numbers. The study highlights the need to be able to distinguish between large amplitude waves and spatial structures such as shock rippling. The simultaneous high frequency observations also demonstrate the complex nature of energy dissipation at the shock and the important question of understanding cross-scale coupling in these complex regions. These observations will be important to interpreting future planetary missions and additional gravity assist maneuvers.

Two-sublattice description of the dimer-trimer chain compound Li2Cu5Si4O14 : High-field magnetization and ESR studies

We carried out high magnetic field magnetization and electron spin resonance (ESR) measurements for the alternating dimer-trimer chain compound ${\mathrm{Li}}_{2}{\mathrm{Cu}}_{5}{\mathrm{Si}}_{4}{\mathrm{O}}_{14}$. The magnetization curve measured at 2 K exhibits a spin-flop transition at 2.6 T followed by a nonlinear increase in magnetization at high field up to 55 T. The antiferromagnetic ordering at ${T}_{\mathrm{N}}=22\phantom{\rule{0.16em}{0ex}}\mathrm{K}$ is well characterized by the temperature-dependent ESR spectra, and the anisotropic $g$ factors at the paramagnetic phase are determined. Intriguingly, our frequency-dependent ESR spectra at 2 K reveal the development of two collinear antiferromagnetic sublattices with biaxial anisotropy, which is quite unusual because ${\mathrm{Li}}_{2}{\mathrm{Cu}}_{5}{\mathrm{Si}}_{4}{\mathrm{O}}_{14}$ contains five sublattices. Thus, ${\mathrm{Li}}_{2}{\mathrm{Cu}}_{5}{\mathrm{Si}}_{4}{\mathrm{O}}_{14}$ is three-dimensionally ordered and its magnetism might be described by a pseudo-two-sublattice model composed of antiferromagnetically coupled dimer-trimer groups (\ensuremath{\uparrow}\ensuremath{\uparrow}, \ensuremath{\uparrow}\ensuremath{\downarrow}\ensuremath{\uparrow}) and (\ensuremath{\downarrow}\ensuremath{\downarrow}, \ensuremath{\downarrow}\ensuremath{\uparrow}\ensuremath{\downarrow}).

Nature of Electrostatic Fluctuations in the Terrestrial Magnetosheath

Abstract The high cadence plasma, electric, and magnetic field measurements by the Magnetospheric MultiScale spacecraft allow us to explore the near-Earth space plasma with an unprecedented time and spatial resolution, resolving electron-scale structures that naturally emerge from plasma complex dynamics. The formation of small-scale turbulent features is often associated to structured, non-Maxwellian particle velocity distribution functions that are not at thermodynamic equilibrium. Using measurements in the terrestrial magnetosheath, this study focuses on regions presenting bumps in the power spectral density of the parallel electric field at subproton scales. Correspondingly, it is found that the ion velocity distribution functions exhibit beam-like features at nearly the local ion thermal speed. Ion-cyclotron waves in the ion-scale range are frequently observed at the same locations. These observations, supported by numerical simulations, are consistent with the generation of ion-bulk waves that propagate at the ion thermal speed. This represents a new branch of efficient energy transfer at small scales, which may be relevant to weakly collisional astrophysical plasmas.

Defect-driven ferrimagnetism and hidden magnetization in MnBi2Te4

MnBi$_2$Te$_4$ (MBT) materials are promising antiferromagnetic topological insulators where field driven ferromagnetism is predicted to cause a transition between axion insulator and Weyl semimetallic states. However, the presence of antiferromagnetic coupling between Mn/Bi antisite defects and the main Mn layer can reduce the low-field magnetization, and it has been shown that such defects are more prevalent in the structurally identical trivial magnetic insulator MnSb$_2$Te$_4$ (MST). We use high-field magnetization measurements to show that the magnetization of MBT and MST occur in stages and full saturation requires fields of~$\sim$~60 Tesla. As a consequence, the low-field magnetization plateau state in MBT, where many determinations of quantum anomalous Hall state are studied, actually consists of ferrimagnetic septuple blocks containing both a uniform and staggered magnetization component.

Magnetic Properties of S = 1/2 Distorted Kagome Antiferromagnet CdCu3(OH)6Cl2 with Low-Symmetry Orbital Arrangement

The magnetic properties of the S = 1/2 distorted kagome antiferromagnet CdCu3(OH)6Cl2 have been studied by magnetic susceptibility, heat capacity, and high-field magnetization measurements. The mag...

Structure-property correlation in stabilizing axial magnetic anisotropy in octahedral Co(II) complexes

Stabilizing an easy axis of magnetization in an octahedral Co(II) complex is an extremely challenging task, which is evident from reports that more than 90% possess easy-plane anisotropy. Here, we report a six-coordinate complex, [Co(L 1 ) 4 (Cl) 2 ] (1, L 1 = thiourea [H 2 N-CS-NH 2 ]), that exhibits a D value of −63(10) cm −1 . The presence of an easy axis of magnetization associated with 1 is experimentally proven by detailed magnetic studies and polarized neutron diffraction studies, and the experimental observations are well corroborated by theoretical calculations. From the combined experimental and theoretical investigations (on 1 and many model systems), we unveil the parameters that control stabilization of negative D in a thermodynamically favorable and air-stable Co(II) ion in the common distorted octahedral geometry. This study paves the way for overcoming the current impediments to alleviate the easy axis of magnetization using rational ligand choice. A synthesized {CoS 4 Cl 2 } complex reveals design principles for stable negative D The SH parameters were confirmed by high-field pulse magnetization measurements The sign of D is determined unambiguously by polarized neutron diffraction Magneto-structural correlations developed by ab initio methods unveil the origin of D Stabilizing the easy axis of magnetization of octahedral Co(II) complexes that are thermodynamically and air stable is an uphill process. Tripathi et al. report a complex that not only overcomes the impediments in stabilizing negative D but also disclose the parameters that control the sign and magnitude of D.

Experimental determination of the magnetic interactions of frustrated Cairo pentagon lattice materials

We present inelastic neutron scattering measurements of the Cairo pentagon lattice magnets Bi$_2$Fe$_4$O$_9$ and Bi$_4$Fe$_5$O$_{13}$F, supported by high field magnetisation measurements of Bi$_2$Fe$_4$O$_9$. Using linear spin wave theory and mean field analyses we determine the spin exchange interactions and single-ion anisotropy in these materials. The Cairo lattice is geometrically frustrated and consists of two inequivalent magnetic sites, both occupied by Fe$^{3+}$ ions and connected by two competing nearest neighbour interactions. We found that one of these interactions, coupling nearest neighbour spins on the three-fold symmetric sites, is extremely strong and antiferromagnetic. These strongly coupled dimers are then weakly coupled to a framework formed from spins occupying the other inequivalent site. In addition we found that the Fe$^{3+}$ $S=5/2$ spins have a non-negligible single-ion anisotropy, which manifests as a spin anisotropy gap in the neutron spectrum and a spin-flop transition in high field magnetisation measurements.

Effect of the Cr5+ ion doping on the quantum transition of the spin-dimer compounds Ba3Mn2−xCrxO8 (x = 0, 0.01, 0.04 and 0.06)

Ba3Mn2O8 has a quantum-disordered paramagnet ground state formed by the singlet, and the excitation states with the triplon and quintuplet. We have investigated the magnetization behaviors of the single crystal samples Ba3Mn2−xCrxO8 (x = 0, 0.01, 0.04 and 0.06) with both the static and pulsed high magnetic field from zero up to 60 T. At the temperature TN, the magnetization decreases rapidly with the decrease of temperature, which is the evidence of the dimerization of spin dimers. The field-induced quantum magnetization plateaus (half of the saturation magnetization) and high-field polarization states show the excited triplet and quintuplet states appear with the change of temperature and the applied magnetic field. The high field magnetization and ESR measurement results confirm that the J0/kB value and the zero-field gap Δ/kB value are close to the reported value, which also indicates that Ba3Mn2−xCrxO8 is not a simple isolated dimer system.

Improved accuracy in high-frequency AC transport measurements in pulsed high magnetic fields.

We show theoretically and experimentally that accurate transport measurements are possible even within the short time provided by pulsed magnetic fields. For this purpose, a new method has been devised, which removes the noise component of a specific frequency from the signal by taking a linear combination of the results of numerical phase detection using multiple integer periods. We also established a method to unambiguously determine the phase rotation angle in AC transport measurements using a frequency range of tens of kilohertz. We revealed that the dominant noise in low-frequency transport measurements in pulsed magnetic fields is the electromagnetic induction caused by mechanical vibrations of wire loops in inhomogeneous magnetic fields. These results strongly suggest that accurate transport measurements in short-pulsed magnets are possible when mechanical vibrations are well suppressed.