Global and local transient skin friction variations resulting from a large-eddy simulation study on ReΓ0=3000 vortex rings colliding with surface-mounted hemispheres of hemisphere-to-vortex-ring diameter-ratios of 0.5≤D/d≤2 are investigated here. Skin friction distribution changes due to the approaching primary vortex ring, formation of secondary/tertiary vortex rings, subsequent mutual interactions between various vortex ring structures, and azimuthal instabilities are clarified with a view to better establish their relationships when the relative hemisphere size varies. Results show that the primary vortex ring produces the highest skin friction levels when it is close to or collides with the hemisphere/flat wall. Additionally, entrainment of wavy secondary/tertiary vortex rings leads to them entangling around the primary vortex ring and resulting in segmented skin friction regions at later stages of the collision process, regardless of the diameter-ratio. Unlike smaller hemispheres, the largest D/d=2 hemisphere here restricts all skin friction changes along its surface with the flat wall unaffected. It is also revealed here that while the diameter-ratio governs the global skin friction distributions, how secondary/tertiary vortex rings interact with the primary vortex ring and how azimuthal instabilities manifest and evolve for all the various vortex rings confer strong influences on the breaking-up and dissipation of regions with high skin friction levels.