Abstract Based on the experimental results, a 3-D Computational Fluid Dynamics investigation is carried out to evaluate the influence of ozone on the combustion process in spark ignition engine fueled with gasoline/air mixtures. Ozone (O3) is a chemically reactive species capable of improving the laminar flame speed, reducing the ignition delay time, and stabilizing combustion variability. With the aim of proposing a 3-D numerical model to simulate combustion of fuel mixtures under ultra-lean conditions, two numerical correlations are proposed to reproduce the chemical properties of gasoline/air/ozone mixtures in terms of laminar flame speed. A chemical kinetic mechanism for Toluene Reference Fuel oxidation (iso-octane, n-heptane, toluene, 63/20/17% by mol.) modified with an ozone sub-mechanism is used to perform several 1-D numerical simulations. The laminar flame speed correlation estimates an enhancement of 3.4% at 600 K and 10 bar under ultra-lean condition (ϕ = 0.6). For the 3-D numerical simulations, the G-Equation model is used to reproduce the premixed combustion process in internal combustion engines. The results suggest that the numerical correlations can predict the combustion properties of gasoline/air mixtures without and with ozone addition. The presence of ozone traduces in a higher laminar flame speed, leading to an increase in the in-cylinder pressure peak and the rate of fuel consumption. Furthermore, the numerical analysis reveals that the greatest improvement is observed for fluid regions within the cylinder characterized by low turbulent flame speed.
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