High-k gate dielectrics are indispensable to overcome the shot-channel effect in scaled CMOS devices [1]. Besides the enhanced electrostatic control of the gate electrode, high-k/Si interface properties, including interface state density, fixed charges, dipoles, carrier mobility, reliability, and so on, need to meet the requirement levels. Rare earth oxides have been intensively studied for gate dielectric applications as these oxides react with Si to form a silicate layer, whereas, for the HfO2 case, a SiO2-based low-k interface layer is formed. One of the issues for rare earth oxide gate dielectrics is controlling the reaction amount while obtaining a good interface property. In this presentation, the interface reaction of rare-earth oxides and Si is modeled and controlled by the thermal treatment process. Furthermore, the influence of the metal gate electrode on the interface is assessed. A la-silicate interface layer is formed between the La2O3 film and Si interface. Although the La atom content in the reactively formed silicate layer generally depends on the annealing environment, a silicate/Si interface can be easily formed, which is advantageous for gate dielectric scaling. However, even under the same process, the La atom content in the silicate increases with the thinning of the initial La2O3 thickness, and the interface state density, flat-band voltage, and mobility degrade [2]. The reaction between La2O3 and Si can be modeled by oxygen atom supply from the environment, and the influence of the metal gate can explain the degradation of electrical properties. A La-rich silicate can be formed with nice interface properties by controlling the supplied oxygen atoms by selecting a proper metal gate stack [3]. The crystal grain size in the metal gate also affects the interface state density. A low interface state density can be obtained by adopting a metal gate material with nano-sized grains [4].In conclusion, an interface control process of La2O3 film on Si is presented by limiting the oxygen atom supply during the interface reaction. La-rich silicate, a high-k film, can be obtained by adopting a proper stacked gate structure. Also, nano-sized grains in the metal electrodes can exhibit a decent interface property.[1] J. Robertson, et al., Materials Science and Engineering R, 88, 1 (2015).[2] K. Kakushima, et al., Solid-State Electron., 54, 715 (2010).[3] T. Kawanago, et al., IEEE Trans. on ED, 59, 269 (2011).[4] K. Tuokedaerhan, et al., Appl. Phys. Lett., 104, 021601 (2014).
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