High Flux Research Articles

Tunable Wettability of a Dual-Faced Covalent Organic Framework Membrane for Enhanced Water Filtration.

Membrane technology plays a central role in advancing separation processes, particularly in water treatment. Covalent organic frameworks (COFs) have transformative potential in this field due to their adjustable structures and robustness. However, conventional COF membrane synthesis methods are often associated with challenges, such as time-consuming processes and limited control over surface properties. Our study demonstrates a rapid, microwave-assisted method to synthesize self-standing COF membranes within minutes. This approach allows control over the wettability of the surface and achieves superhydrophilic and near-hydrophobic properties. A thorough characterization of the membrane allows a detailed analysis of the membrane properties and the difference in wettability between its two faces. Microwave activation accelerates the self-assembly of the COF nanosheets, whereby the thickness of the membrane can be controlled by adjusting the time of the reaction. The superhydrophilic vapor side of the membrane results from -NH2 reactions with acetic acid, while the nearly hydrophobic dioxane side has terminal aldehyde groups. Leveraging the superhydrophilic face, water filtration at high water flux, complete oil removal, increased rejection with anionic dye size, and resistance to organic fouling were achieved. The TTA-DFP-COF membrane opens new avenues for research to address the urgent need for water purification, distinguished by its synthesis speed, simplicity, and superior separation capabilities.

A versatile sample-delivery system for X-ray photoelectron spectroscopy of in-flight aerosols and free nanoparticles at MAX IV Laboratory.

Aerosol science is of utmost importance for both climate and public health research, and in recent years X-ray techniques have proven effective tools for aerosol-particle characterization. To date, such methods have often involved the study of particles collected onto a substrate, but a high photon flux may cause radiation damage to such deposited particles and volatile components can potentially react with the surrounding environment after sampling. These and many other factors make studies on collected aerosol particles challenging. Therefore, a new aerosol sample-delivery system dedicated to X-ray photoelectron spectroscopy studies of aerosol particles and gas molecules in-flight has been developed at the MAX IV Laboratory. The aerosol particles are brought from atmospheric pressure to vacuum in a continuous flow, ensuring that the sample is constantly renewed, thus avoiding radiation damage, and allowing measurements on the true unsupported aerosol. At the same time, available gas molecules can be used for energy calibration and to study gas-particle partitioning. The design features of the aerosol sample-delivery system and important information on the operation procedures are described in detail here. Furthermore, to demonstrate the experimental range of the aerosol sample-delivery system, results from aerosol particles of different shape, size and composition are presented, including inorganic atmospheric aerosols, secondary organic aerosols and engineered nanoparticles.

Membranes Based on Aminated Graphene Oxide with High Selectivity Toward Organic Substances.

In this work, membranes based on graphene oxide, modified with oleylamine, have been prepared by a simple wet chemistry protocol without the use of complex equipment, elevated temperature, and additional reagents. The membrane material was characterized by a set of physicochemical methods: thermogravimetric analysis, Fourier transform infrared spectroscopy, X-ray diffractometry, and X-ray photoelectron spectroscopy. The prepared membranes are stable in both aqueous and organic media. The membranes have a high flux for organic substances and do not permeate water at room temperature and atmospheric pressure. The selectivity of the membranes toward organic substances increases with their thickness. The highest flux among the tested organic liquids is registered for methanol. The membranes have high selectivity toward ethanol/1-butanol and acetone/1-butanol pairs, which opens up the possibility of separating actual industrial mixtures. The membrane retains 90% of methylene blue from the alcohol solution. Our work expands the possibilities of using modified GO-based membranes in purification and filtration technologies.

On the intrusiveness of phosphor thermometry for metal surface temperature measurements in reciprocating engines: An experimental and heat conduction modeling study

Abstract Lifetime-based phosphor thermometry has been applied in a wide variety of surface temperature measurement applications due to its relative ease of implementation and robustness to background interference when compared to other optical temperature measurement methods. It is often assumed that the technique is minimally intrusive if the thickness of the applied phosphor coating is < 20 µm. To evaluate this assumption, high-speed phosphor surface temperature and thermocouple measurements were performed on 4140 steel substrates installed in the cylinder head of an optically-accessible internal-combustion engine for four operating conditions. For phosphor thermometry measurements, four substrates were studied, each coated with a phosphor layer of different thickness ranging between 6 µm and 47 µm. The phosphor thermometry measured temperature swings during combustion were shown to be heavily impacted by the presence of the phosphor coatings, increasing by roughly a factor of 2 - 2.5 when increasing the thickness from 6 µm to 30 µm. A technique was implemented which utilizes the temperature data in combination with a heat conduction model to provide estimates of the temperature swing and heat transfer flux in the absence of the phosphor coating. It was shown that even the 6 µm phosphor coating could lead to an order of magnitude increase in the temperature swing relative to the uncoated 4140 steel substrate. Despite the intrusiveness of phosphor thermometry for the surface temperature measurements, reasonable agreement was demonstrated between heat flux estimates determined with the heat transfer modeling technique and those deduced from temperature-swing measurements using two different high-speed thermocouples. The results indicate that phosphor surface thermometry can be a reliable surface temperature and heat flux diagnostic for transient high heat flux environments, as long as proper care is taken to account for the impact of the phosphor layer on the measurement.

Experimental investigation on spray cooling heat transfer properties of ethylene glycol-water-based nanofluids

Abstract Spray cooling is a practical solution for high heat flux heat dissipation problems. The spray cooling experiment was conducted with 50wt% ethylene glycol aqueous solution as the base liquid in this paper. The effects of the concentrations of copper nanoparticles, copper oxide nanoparticles, silica nanoparticles and surfactant Tween-20 on the heat transfer characteristics during spray cooling were investigated. The results showed that adding nanoparticles within a certain concentration range could enhance the effectiveness of spray cooling's heat transmission. Under the same conditions, adding copper nanoparticle has the best effect, followed by copper oxide nanoparticle, and silica nanoparticle has relatively poor effect. Among them, the heat transfer coefficient and heat flux of the nanofluid could be raised by 10.58% and 11.34% in comparison to the base liquid when the concentration of copper nanoparticles was 0.01wt%. As the concentration of nanoparticles rises higher, spray cooling's ability to transfer heat is hampered. Adding the surfactant Tween-20 could effectively improve the copper-water-ethylene glycol nanofluid's capacity for heat transmission. When the concentration is 3ppm, the heat transfer coefficient and heat flux of the nanofluid with Tween-20 were increased by 9.81% and 10.38% compared to the copper-water-ethylene glycol nanofluid.

The shoulder effect in the stagnation zone for temperature-controlled jet impingement transition boiling of submerged dielectric fluid

Two-phase jet impingement is capable of high heat transfer coefficients and high boiling critical heat flux (CHF) limits, making it a suitable technology for electronics immersion cooling applications. Previous studies have focused on the heat-flux-controlled nucleate boiling performance of an impingement jet up to the CHF. Exploration of other boiling regimes that occur under temperature-controlled surfaces is of equal fundamental importance. It has been shown for free jets that a high and consistent heat flux can be dissipated over a wide range of surface superheats in the transition boiling regime when the surface is temperature-controlled. This so-called “shoulder effect”, or heat flux shoulder, is strongest in the stagnation zone, directly beneath the jet. It has only observed using free jets of water as the cooling for interest in metals processing applications. To exploit operation in this unique boiling regime for potential applications in immersion cooling of electronics, the occurrence of this shoulder effect, as well as means for estimating the shoulder heat flux across different operating conditions, must be investigated for submerged jets and dielectric coolants. In this work, temperature-controlled submerged jet impingement is experimentally characterized using HFE-7100. A copper heater sized to be completely covered by the jet stagnation zone is increased in surface temperature via a PID controller, which allows for steady-state, temperature-controlled data to be acquired. The boiling curves, including CHF and shoulder heat flux, are measured for 0.5–3 m/s jet velocities and 5–30 K inlet subcooling. The shoulder effect is shown to exist in these conditions and high-speed imaging reveals that the shoulder heat flux effect is an enhanced film-like mode of transition boiling. It is observed that there is a proportionality between the CHF and the shoulder heat flux for the conditions investigated. The measured trends and dependencies of the shoulder heat flux on inlet subcooling and jet velocity are used to assess available predictive tools.

Impact of Diafiltration Media and Filtration Modes on Fouling and Performance in Skim Milk Microfiltration: A Comparative Study

This research utilized a customized laboratory setup to compare the filtration performance and fouling buildup during microfiltration with polymeric membranes of skim milk using 2 diafiltration media: ultrafiltration permeate and ultrapure water. Two filtration modes were evaluated: in stage 1, the diafiltration media was added in a 1:1 ratio, with the collection of permeate continuing until the initial protein concentration was restored. In stage 2, retentates and permeates were recycled to simulate fouling accumulation in a steady-state without altering the retentate composition. Utilizing water as the diafiltration medium resulted in higher flux and lower resistance values compared with using ultrafiltration permeate, irrespective of the filtration mode. The concentration had a significant impact on membrane resistance, with no noticeable time-dependent effect on fouling layer development after 60 min of filtration when the retentate composition remained constant. The protein composition of the permeate and extracted foulants were comparable between the 2 media, with caseins predominating in the fouling layer.

Superamphiphilic aerogels with 2D lamellar structure of gelatin-tuned 3D supramolecular network of collagen fibers for high-performance separation of surfactant-stabilized emulsified oily wastewater

Superwetting aerogel is a promising alternative for the remediation of emulsified oily wastewater for its high porosity combined with extreme wettability enabled high separation performances to emulsion wastewater. However, it remains challenging for superwetting aerogels to accomplish high-performance dual separation to surfactant-stabilized oil-in-water (O/W) and water-in-oil (W/O) emulsions with high stability. Herein, an environmentally benign superamphiphilic composite aerogel was prepared by a green synthesis route that relied on the utilization of natural amphiphilic biomass. Collagen fibers (CFs) were utilized to construct the three-dimensional (3D) supramolecular skeleton of aerogel to provide high storage capacity of water/oil and outstanding capillary effect to boost the mass transfer. The two-dimensional (2D) lamellar structure of gelatin (Gel) was further grown on the skeleton of CFs aerogel to play the role for simultaneously enhanced demulsifying capability and spreading of emulsions. The as-prepared superamphiphilic aerogel enabled the separation of highly stable surfactant-stabilized O/W and W/O emulsions with high separation efficiency and flux. Excellent recycling performances and anti-fouling performance were also confirmed. Our investigations therefore demonstrated that the structural engineering of superamphiphilic aerogel is a promising way to realize high-performance dual separation of surfactant-stabilized O/W and W/O emulsion wastewater.Graphical

Polyamidoamine dendrimer-modified polyvinylidene fluoride microporous membranes for protein separation

The separation efficiency of pressure-driven filtration membranes is primarily dictated by the membrane pore size. Membranes with larger pores typically demonstrate high flux but low or zero rejection when it comes to separating small molecules. In protein separation, ultrafiltration (UF) membranes with pore sizes smaller than the molecular dimensions of target proteins are commonly used for size rejection. Taking inspiration from the separation mechanism of nanofiltration (NF) membranes, we hypothesize that introducing charged groups into membranes of appropriate pore sizes could significantly enhance the electrical interaction between membrane charges and protein charges. This enhancement, occurring at the nanoscale distance when protein molecules approach or pass through charged nanoscale membrane channels, may enable the rejection of proteins substantially smaller than the pore size. Using membranes with relatively large pore sizes could lead to an increase in flux. To test this hypothesis, we conducted experiments involving the modification of polyvinylidene fluoride (PVDF) membranes with suitable pore sizes, using polyamidoamine (PAMAM) dendrimers to introduce negative charges to the membranes. The performance of the PVDF membranes and the modified membranes were investigated in the separation of whey proteins. To evaluate the contribution of steric and electrical hindrance to the solute separation, filtration experiments were performed using polyethylene oxide (PEO) and polyacrylic acid (PAA). The membranes were characterized using techniques such as Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR), X-ray Photoelectron Spectroscopy (XPS), and Scanning Electron Microscopy (SEM). The results indicate that the modification enhances the rejection efficiency of whey proteins. The whey protein rejection and permeate flux for PVDF membranes were 58.9% and 15.3 LMH, respectively. Following alkaline treatment or PAMAM-G3.5 dendrimer modification, the whey protein rejection increased to 97.3% and 98.8%, respectively. However, alkaline treatment and PAMAM-G3.5 dendrimer modification resulted in a reduction of permeate flux to 5.6 LMH and 2.3 LMH, respectively. This suggests that increasing membrane charge effectively enhances the separation ability of filtration membranes in charged macromolecule separation.

Shedding Light on the Origin of Pb204 , the Heaviest s -Process–Only Isotope in the Solar System

Asymptotic giant branch stars are responsible for the production of most of the heavy isotopes beyond Sr observed in the solar system. Among them, isotopes shielded from the r-process contribution by their stable isobars are defined as s-only nuclei. For a long time the abundance of Pb204, the heaviest s-only isotope, has been a topic of debate because state-of-the-art stellar models appeared to systematically underestimate its solar abundance. Besides the impact of uncertainties from stellar models and galactic chemical evolution simulations, this discrepancy was further obscured by rather divergent theoretical estimates for the neutron capture cross section of its radioactive precursor in the neutron-capture flow, Tl204 (t1/2=3.78 yr), and by the lack of experimental data on this reaction. We present the first ever neutron capture measurement on Tl204, conducted at the CERN neutron time-of-flight facility n_TOF, employing a sample of only 9 mg of Tl204 produced at the Institute Laue Langevin high flux reactor. By complementing our new results with semiempirical calculations we obtained, at the s-process temperatures of kT≈8 keV and kT≈30 keV, Maxwellian-averaged cross sections (MACS) of 580(168) mb and 260(90) mb, respectively. These figures are about 3% lower and 20% higher than the corresponding values widely used in astrophysical calculations, which were based only on theoretical calculations. By using the new Tl204 MACS, the uncertainty arising from the Tl204(n,γ) cross section on the s-process abundance of Pb204 has been reduced from ∼30% down to +8%/−6%, and the s-process calculations are in agreement with the latest solar system abundance of Pb204 reported by K. Lodders in 2021. Published by the American Physical Society 2024

In situ three-dimensional reconstruction and gradient-induced design of ultrastable Zn metal anodes in Zn-Se batteries

Zinc-selenium batteries have high specific and volumetric capacities, but practical development faces key challenge in achieving stable zinc metal anodes, and avoiding zinc dendrite growth, hydrogen evolution reaction (HER) and corrosion. Here, a zinc foam substrate is employed to fabricate three-dimensional gradient electrodes Zn foam@Cu@CuSe2 (ZFCCS) with gradient change of zincophilicity and conductivity. Experimental observations and simulations collectively confirm that the three-dimensional structure and gradient design effectively homogenize interfacial ion flux and diminish local current density. This optimization of the zinc deposition path synergistically fosters high flux and deep deposition of zinc metal while simultaneously preventing dendrite growth. The results demonstrate that the developed ZFCCS electrode produces an excellent Coulombic efficiency of 99.5 % over 1000 plating/stripping cycles, and the corresponding symmetric cell provides an ultra-long dendrite-free cycle life of 800 h at 5 mA cm−2 and 2 mAh cm−2 with a low overpotential of 27.4 mV. In addition, the Zn-Se full cell based on the designed ZFCCS composite anode exerts superior stable cycle life (358.1 mAh g−1 at 2 A g−1 after 1000 cycles). Therefore, the gradient design strategy based on 3D electrodes will be a reference for high performance energy storage devices.

Optimizing virus filtration for continuous processing using serial filtration at high area ratio.

Compared to batch operation, continuous bioprocessing can offer numerous advantages, including increased productivity, improved process control, reduced footprint, and increased flexibility. However, integration of traditional batch operations into a connected process can be challenging. In contrast to batch operations run at constant pressure or high flux, virus filtration in continuous processes may be operated at very low flux. This change in operating conditions may reduce the viral retention performance of the filter which has inhibited adoption of truly continuous virus filtration. To overcome this limitation, a novel approach is described that utilizes serial virus filtration, with a high area ratio between first to second stage filters, to achieve virus retention targets. In this study, virus filters were operated continuously (except for planned process interruptions) for 200 h in a serial configuration at a first to second stage filter area ratio of 13:1 and at a first stage flux of 5 L/m2/h. While the minute virus of mice (MVM) retention performance of the first stage filter was about 4 log reduction value (LRV), there was no virus detected in the second stage filtrate, translating to an MVM LRV across the filtration train of ≥6.7. The second stage filter was the dominant flow resistance at the start of the run but, as it was protected from foulants by the first stage filter, it suffered minimal fouling and the life of the filter train was controlled by the first stage. A theoretical case study projected that continuous virus filtration using serial configuration at high area ratio would have about 30% longer filter changeout time, 14% higher productivity, and virus retention nearly sixLRV greater than single stage operation. The findings of this research are expected to provide valuable insights into optimizing virus filtration in continuous bioprocessing.

Self-supporting and hierarchical porous membrane of bacterial nanocellulose@metal-organic framework for ultra-high adsorption of Congo red

The widespread use of synthetic dyes has serious implications for both the environment and human health. Therefore, there is an urgent need for the development of novel, high-efficiency adsorbents for these dyes. In this study, a Zirconium-based metal-organic framework (MOF) with controllable morphology was in-situ grown on bacterial nanocellulose (BC) via a solvothermal method. The resulting BC@MOF composite nanofibers have a high specific surface area of 651 m2/g and can be assembled into a self-supported porous membrane (BMMCa) through vacuum filtration with the assistance of calcium ions. The addition of Ca(II) significantly enhanced the mechanical properties of the membrane through dispersion effect and electrostatic interactions, as well as enhancing its adsorption performance through the salting-out effect. The BMMCa membrane, with its hierarchical porous structure and high flux, exhibits high selectivity for Congo red (CR) with an ultra-high adsorption capacity of 3518.6 mg/g. Furthermore, the self-supporting membrane achieved rapid and convenient removal of CR through circulating filtration adsorption. The adsorption mechanism and selectivity were verified through the molecular dynamics simulation calculations by Materials Studio (MS) software. This membrane-based adsorbent, with its ultra-high adsorption capacity, good selectivity, and recycling ability, has great potential for practical wastewater treatment applications.

Perspective of perovskite-based X-ray hybrid pixel array detectors

Compound semiconductors are playing a major role in the production of X-ray pixel detectors for the application in laboratories and beamlines at photon sources. The performance of these detectors has constantly been improved for the last decades but experiments are still limited by the properties of the detector material, especially under high flux illumination. The fast development of perovskite crystals opens the possibility for new materials to be used as highly efficient X-ray pixel detectors. The published data until now, of the transport properties, demonstrate the large potential of perovskite semiconductors. The achieved values are comparable with the ones of CdTe-based detectors. This paper presents potential perovskite-based detector materials and compares their performance with the state-of-the-art CdTe-based detectors. The perspectives of perovskite semiconductors are promising for the production of large area X-ray detectors but still some challenges remain.

Fabrication of high selectivity and high flux reverse osmosis membranes

Fabrication of high selectivity and high flux reverse osmosis membranes

Iron redox states in closed-basin lakes on early Mars: Its sensitivity to water chemistry, hydrology, and atmospheric composition

Mars has experienced drastic environmental evolution in terms of pH, redox, and desiccation. NASA’s Curiosity rover discovered that the sediments of the Pahrump Hills member of the Murray formation in Gale Crater contained different redox states of Fe oxides. To interpret the observations, understanding the factors that control iron redox states within early Gale lakes on Mars is needed. Here, we present the results of a one-dimensional geochemical model of a closed-basin lake that considers the Fe(II) photo-oxidation reaction. Depending on the source of Fe(II) (groundwater vs. river flow), lake pH, advection rate, and atmospheric composition, we defined four types of chemical profiles in the lake; namely, Fe(II) dominated, Fe(III) dominated, carbonate precipitating, and redox-stratified profiles. The Fe(III) dominated profile corresponds to the end member case in which photo-oxidation effectively oxidizes the supplied Fe(II). The redox-stratified profile, interpreted as an intermediate condition between Fe(III) dominated profile and Fe(II) dominated profile, appears in broad parameter set when Fe(II) is supplied from the groundwater, typically with a low to moderate Fe(II) input flux at acidic to alkaline pH (pH 5–9) conditions; however, the low water flux due to the nature of the groundwater may be unable to explain the measured abundance of Fe oxides in the sediments. Another endmember case, the Fe(II) dominated profile, which would also be expected to generate mixed valence Fe oxides, occurs when the pH is acidic (pH 4–5); nevertheless, the acidic pH is inconsistent with the mineral assemblages of the sediments. Carbonate precipitating profiles were limited to the case in which Fe(II) is supplied by groundwater with high Fe input flux and alkaline pH of 8–9. These results may imply either the Fe(II) input flux was high enough for the redox-stratified case or Fe(II) photo-oxidation was suppressed by turbidity or by dusty/cloudy atmosphere, or possibly that Fe(II) oxides found in the Pahrump Hills member are, at least partly, of detrital origin. Although numerous other factors (ex., effect of lake depth, variable pH throughout the lake water, detailed chemical speciation) remain unconsidered, the diverse profiles in Fe redox resulting from Fe(II) photo-oxidation reaction sheds light on interpreting the variety and the evolution of redox condition on early Mars.

Development and manufacturing of beryllium-armoring ITER enhanced heat flux FW toward series production in China

ITER’s enhanced heat flux (EHF) first wall (FW) provides thermal shielding to the other components behind it and limits its plasma boundary, consequently bearing high surface heat loads up to 4.7 MW m−2. China developed the EHF FW technologies in steady stages by making small mock-ups, semi-prototypes and a full-scale prototype (FSP), working toward series production at the Southwestern Institute of Physics. All the key technologies for bimetallic diffusion bonding, welding and assembly have been fully qualified. The Be armor tile size effects on thermal-fatigue performance have been evaluated using a pulsed high heat flux test with an EMS-400 electron beam facility. It was found that both the Be/CuCrZr bonding and its thermal-fatigue life are highly dependent on the tile size, and 12 × 12 mm2 Be tiles are acceptable for the required performance, either as individual tiles or in castellation by cutting larger ones. Small-scale mock-ups with such Be tiles survived 16 000 thermal cycles at 4.7 MW m−2, while EHF FW fingers with 16 × 16 mm2 Be tiles demonstrated unstable performance. In contrast, only BE tiles larger than 24 × 12 mm2 showed reliable diffusion bonding with the CuCrZr heat sink by hot isostatic pressing and consequently should be castellated into smaller ones. The manufacturing of the FSP finger goes through complex thermal cycles, using CuCrZr alloys in age-strengthening plus cold-rolling states, enabling it to maintain its tensile strength to the level of 285 MPa and its mean grain size less than 100 µm. The pipe welding for finger pairing and its assembly with the central beam are demonstrated, including enabling welding to be carried out twice for repair in a narrow space. The FSP showed good finger alignment, dimensional control and reliable vacuum tightness without any blockage of cooling channels.

Mesoporous silica modified alumina improves pressure stability of supported ionic liquid membranes

Supported liquid membranes (including those containing ionic liquids) offer the opportunity for high selectivity for a target gas imparted by the properties of the functional liquid or liquid mixture, along with high flux resulting from gas permeation through a liquid rather than a solid. One disadvantage of supported liquid membranes is limitations on the transmembrane pressure (TMP) they can sustain. Liquids held in the pores of the support by capillary forces are prone to “blow-out” at relatively modest TMP values. Here, we modify anodic aluminum oxide (AAO) membranes with uniformly sized ∼6–8 nm diameter cylindrical silica mesopores to improve the blow-out TMP. This modification increases the feasible TMP for various ionic liquids from ∼4 bar to more than ∼20 bar. Additionally, the liquid in the membrane at depths where the AAO membrane has not been modified (i.e., greater than a few microns) is expelled from the large pores, reducing the effective thickness of the liquid in the membrane and increasing permeance. This approach is analogous to asymmetric polymeric membranes, which are the standard of the commercial membrane industry. These findings open up the opportunity for investigation and use of supported liquid membranes at much higher TMPs than has been previously possible.

Numerical study and experimental validation of heat transfer capacity of flat-type divertor for fusion reactor

The divertor must simultaneously withstand unprecedented high heat fluxes of up to 20 MW/m2 and high-energy neutron irradiation of 14-MeV during fusion reactor operation. Accordingly, it is necessary to simultaneously meet the excellent heat dissipation capacity of the divertor and maintain good material performance in harsh neutron irradiation environments. The flat-type divertor demonstrates better heat transfer performance compared to monoblock divertor. Nevertheless, under the condition of a heat flux of 20 MW/m2, the heat transfer and thermal fatigue performance of flat-type divertor using advanced materials are still unidentified. In this study, we conducted a thorough analysis of the heat transfer capabilities and thermal fatigue characteristics of potassium-doped tungsten (KW)/Cu/Oxide dispersion strengthened copper (ODS-Cu)/reduced activation ferritic/martensitic (RAFM) divertor mockup adopts hypervaportron (HV) structure by numerical simulations combined with experiments. The numerical results indicate that the flat-type KW/Cu/ODS-Cu/RAFM divertor mockup expresses excellent heat transfer capacity. The contact area between the edge of the fins and the bottom surface of the ODS-Cu heat sink induces a significant increase in water flow velocity to ∼15 m/s. The peak temperature of loaded KW surface is only ∼985 °C under the flow rate of 5 t/h and inlet temperature of 20 °C. During the high heat flux tests, the prepared flat-type divertor mockup successful endured 1000 cycles of 20 MW/m2 with the peak temperature of 883 °C, and the surface temperature experienced a fluctuation of 2.4 % during the thermal fatigue tests. This study can provide a strong data reference and technical support for the development of fusion reactors, and is of great significance in advancing the commercialization of fusion energy.

Experimental investigation of heat transfer and pressure drop in copper manifold microchannel heat sinks

Over the past decade, various two-phase cooling solutions have been implemented to dissipate power in high heat flux electronic components. The manifold microchannel heat sink is an efficient thermal management solution that reduces heat resistance while also limiting the pumping power. However, there is limited work available on small form factor manifold microchannels with traditional heat sinking materials like copper. In this study, an experimental investigation is conducted to evaluate the heat transfer and pressure drop performance of copper manifold microchannel heat sinks using an environmentally friendly refrigerant, R1233zd(E), as the working fluid. A microchannel plate and a manifold plate, both made of oxygen-free copper, are sandwiched together to form the manifold microchannel test sample assembly. To compare the effects of geometric parameters, a total of six manifold microchannel test samples are investigated, including two types of manifold plates and three types of microchannel plates. The experiments are performed with refrigerant mass flow rates ranging from 5 to 15 g/s and inlet subcooling temperatures ranging from 3 to 10 K. The heat transfer coefficient increases with a decreasing number of manifolds and with an increase in the number and width of the microchannels. The pressure drop decreases in configurations with more microchannels, more manifolds, and larger microchannel widths. Compared to traditional microchannels, manifold microchannels significantly reduce the total pressure drop. However, their heat transfer performance at higher heat flux conditions is limited by the trapped bubbles phenomena. In comparison to traditional microchannels, manifold microchannels demonstrate much higher performance in dissipating the same amount of heat flux while limiting pumping power, as indicated by the COP.