High-elevation Watershed Research Articles

Projections of 21st Century Sierra Nevada Local Hydrologic Flow Components Using an Ensemble of General Circulation Models1

Abstract: Sierra Nevada snowmelt and runoff is a key source of water for many of California’s 38 million residents and nearly the entire population of western Nevada. The purpose of this study was to assess the impacts of expected 21st Century climatic changes in the Sierra Nevada at the subwatershed scale, for all hydrologic flow components, and for a suite of 16 General Circulation Models (GCMs) with two emission scenarios. The Soil and Water Assessment Tool (SWAT) was calibrated and validated at 35 unimpaired streamflow sites. Results show that temperatures are projected to increase throughout the Sierra Nevada, whereas precipitation projections vary between GCMs. These climatic changes drive a decrease in average annual streamflow and an advance of snowmelt and runoff by several weeks. The largest streamflow reductions were found in the mid‐range elevations due to less snow accumulation, whereas the higher elevation watersheds were more resilient due to colder temperatures. Simulation results showed that decreases in snowmelt affects not only streamflow, but evapotranspiration, surface, and subsurface flows, such that less water is available in spring and summer, thus potentially affecting aquatic and terrestrial ecosystems. Declining spring and summer flows did not equally affect all subwatersheds in the region, and the subwatershed perspective allowed for identification for the most sensitive basins throughout the Sierra Nevada.

Soil Acid-Base Chemistry of a High-Elevation Forest Watershed in the Great Smoky Mountains National Park: Influence of Acidic Deposition

Understanding the acid-base chemistry of soil and the soil processes related to the release or retention of sulfate and nitrate is important in order to predict watershed recovery from long-term acid deposition. Soils were sampled from the Noland Divide Watershed (NDW), a small, high-elevation watershed in the Great Smoky Mountains National Park receiving high rates of acid deposition over several decades. Soil samples were measured for chemical properties related to acidification and used to conduct sulfate adsorption and nitrogen (N) incubation experiments. Shallow soil was higher in acidic and basic ions than deeper soils, and the mean effective cation exchange capacity was 8.07, 5.06, and 3.57 cmolckg �1 in the A, Bw, and Cb horizons, respectively. In all three soil horizons, the base saturation was equal to or below 7% and the ratio of Ca/Al was below 0.01, indicating that the NDW is very sensitive to acid deposition. Based on results from sulfate adsorption isotherms, the NDW has not reached its maximum sulfate adsorption saturation and is likely able to retain further additions of sulfate. Desorption of sulfate from NDW soils is expected if sulfate concentrations in soil solution drop below 50 μeq L �1 but is highly dependent on soil pH and organic carbon content. Total soil organic N was 500 times greater than inorganic N in the A soil horizon, and net N mineralization and nitrification remained constant during a 28-day incubation indicating a large reservoir of N substrate for soil microbes. Nitrogen experiment results suggest that nitrate export from the watershed is largely controlled by biological processes rather than by nitrate deposition flux. Soil data collected in this study contributes to our understanding of biogeochemical processes affecting the response of acid-impacted ecosystems such as the NDW to future changes in atmospheric deposition.

Rainfall characteristics for periglacial debris flows in the Swiss Alps: past incidences–potential future evolutions

Based on observational meteorological data since A.D. 1864 and tree-ring records of debris-flow activity, this paper assesses changes in rainfall characteristics and their impact on the triggering of geomorphic events in a high-elevation watershed of the Swiss Alps since the end of the Little Ice Age. No trends are visible in the frequency of heavy rainfall events, but we observe a reduced number of heavy, short-lived rainfalls in summer and a concentration of advective storms is recorded in late summer and early fall since the late 1980s. These changes in triggering meteorological conditions resulted in a cluster of debris flows in the early decades of the twentieth century and a lowering of debris-flow activity since the mid 1990s, and may be mirroring the observed changes in persistent high-pressure systems over the Alps. We also observe intra-seasonal differences in debris-flow system response reflecting the state of the permafrost body in the source area of debris flows, allowing for very small debris flows to be released by limited rainfall inputs (<20 mm) in June and July. The same quantities of rain will not trigger debris flows in August or September, when a thick active layer of the permafrost body is capable of absorbing water. With the projected amplitude of climatic change, seasonality, return intervals and volumes of debris flows are likely to be altered. RCM projections based on the IPCC A2 scenario suggest a decrease in heavy summer rainfalls which will most likely result in a (further) reduction of the overall frequency of debris flows, leaving more time for sediment to accumulate in the channel. Such an increase of channel accumulation rates along with the projected destabilization of the steep rock-glacier body is likely, in turn, to exert control ultimately on sediment volumes released from the source areas during future events. Observations from adjacent catchments suggest that extremely large debris flows, beyond historical experience, could occur at the study site and in similar debris-flow systems of the Valais Alps originating from periglacial environments.

Long-Term Annual and Seasonal Patterns of Acidic Deposition and Stream Water Quality in a Great Smoky Mountains High-Elevation Watershed

The recovery potential of stream acidification from years of acidic deposition is dependent on biogeochemical processes and varies among different acid-sensitive regions. Studies that investigate long-term trends and seasonal variability of stream chemistry in the context of atmospheric deposition and watershed setting provide crucial assessments on governing biogeochemical processes. In this study, water chemistries were investigated in Noland Divide watershed (NDW), a high-elevation watershed in the Great Smoky Mountains National Park (GRSM) of the southern Appalachian region. Monitoring data from 1991 to 2007 for deposition and stream water chemistries were statistically analyzed for long-term trends and seasonal patterns by using Seasonal Kendall Tau tests. Precipitation declined over this study period, where throughfall (TF) declined significantly by 5.76 cm year−1. Precipitation patterns play a key role in the fate and transport of acid pollutants. On a monthly volume-weighted basis, pH of TF and wet deposition, and stream water did not significantly change over time remaining around 4.3, 4.7, and 5.8, respectively. Per NDW area, TF SO42- flux declined 356.16 eq year−1 and SO42- concentrations did not change significantly over time. Stream SO42- remained about 30 μeq L−1 exhibiting no long-term trends or seasonal patterns. SO42- retention was generally greater during drier months. TF monthly volume-weighted NH4+ and NO3- concentrations significantly increased by 0.80 μeq L−1 year−1 and 1.24 μeq L−1 year−1, respectively. TF NH4+ fluxes increased by 95.76 eq year−1. Most of NH4+ was retained in the watershed, and NO3- retention was much lower than NH4+. Stream monthly volume-weighted NO3- concentrations and fluxes significantly declined by 0.56 μeq L−1 year−1 and 139.56 eq year−1, respectively. Overall, in NDW, inorganic nitrogen was exported before 1999 and retained since then, presumably from forest regrowth after Frazer fir die-off in the 1970s from balsam wooly adelgid infestation. Stream export of NO3- was greater during winter than summer months. During the period from 1999 to 2007, stream base cations did not exhibit significant changes, apparently regulated by soil supply. Statistical models predicting stream pH, ANC, SO42-, and NO3- concentrations were largely correlated with stream discharge and number of dry days between precipitation events and SO42- deposition. Dependent on precipitation, governing biogeochemical processes in NDW appear to be SO42- adsorption, nitrification, and NO3- forest uptake. This study provided essential information to aid the GRSM management for developing predictive models of the future water quality and potential impacts from climate change.

Rock-glacier dynamics and magnitude–frequency relations of debris flows in a high-elevation watershed: Ritigraben, Swiss Alps

A widespread risk in high mountains is related to the accumulation of loose sediments on steep slopes, which represent potential sources of different types of geomorphic processes including debris flows. This paper combines data on 50 yr of permafrost creep at the Ritigraben rock glacier (Valais, Swiss Alps) with magnitude–frequency (M–F) relationships of debris flows recorded in the Ritigraben torrent originating at the rock-glacier front. Debris production and volumetric changes at the rock-glacier front are compared with debris-flow activity recorded on the cone and potential couplings and feedbacks between debris sources, channel processes and debris sinks. The dataset existing for the Ritigraben rock glacier and its debris-flow system is unique and allows prime insights into controls and dynamics of permafrost processes and related debris-flow activity in a constantly changing and warming high-altitude environment. Acceleration in rock-glacier movement rates is observed in the (1950s and) 1960s, followed by a decrease in flow rates by the 1970s, before movements increase again after the early 1990s. At a decadal scale, measured changes in rock-glacier movements at Ritigraben are in concert with changes in atmospheric temperatures in the Alps. Geodetic data indicates displacement rates in the frontal part of the rock glacier of up to 0.6–0.9 m yr − 1 since the beginning of systematic measurements in 1995. While the Ritigraben rock glacier has always formed a sediment reservoir for the associated debris-flow system, annual horizontal displacement rates of the rock-glacier body have remained quite small and are in the order of decimeters under current climatic conditions. Sediment delivery from the rock-glacier front alone could not therefore be sufficient to support the 16 debris flows reconstructed on the cone since 1958. On the contrary, debris accumulated at the foot of the rock glacier, landslide and rockfall activity as well as the partial collapse of oversteepened channel walls have to be seen as important sediment sources of debris flows at Ritigraben and would represent 65–90% of the material arriving on the Ritigraben cone. There does not seem to exist a direct coupling between displacement rates of and sediment delivery by the rock-glacier body and the frequency of small- and medium-magnitude debris flows. In contrast, a direct link between source and sink processes clearly exists in the case of active-layer failures. In this case, failure processes at the rock-glacier snout and debris-flow events in the channel occur simultaneously and are both triggered by the rainfall event.

Long-Term Effects of Acidic Deposition on Water Quality in a High-Elevation Great Smoky Mountains National Park Watershed: Use of an Ion Input–Output Budget

Impacts from acidic deposition on stream water quality in the Great Smoky Mountains National Park (GRSM) have long been reported; however, a better understanding of the biogeochemical processes that regulate stream acidification is needed for resource management. Water quality monitoring of Noland Divide Watershed (NDW), a high-elevation watershed in the GRSM, was used to generate an ion input–output budget in order to evaluate what processes have influenced stream pH and acid neutralizing capacity (ANC) over the long term. NDW was equipped with wet deposition, throughfall, soil lysimeters, and stream collection stations, and monitoring began in 1991 and continues to the present. Using data from 1991 to 2006, this study found annual deposition fluxes of SO42− and NO3− averaged 1,735 and 863 eq ha−1 year−1, respectively. Data indicated that 61% of the net SO42− entering the watershed was retained, suggesting soil adsorption dominates as a biogeochemical process. Although net SO42− retention was observed, SO42− appeared to move rapidly through NDW during large precipitation events causing stream acidification, as evidenced by significant inverse correlations between biweekly throughfall SO42− flux and stream event pH and ANC. Nitrogen uptake by forest vegetation and nitrification play key roles in regulating NO3− export to the stream as observed by 32% retention of net inorganic nitrogen, and 96% of NH4+ input was converted to NO3− in the uppermost soil horizon. Net export of base cations (Ca2+, Mg2+, Na+) is observed and apparently moderates stream acidification. In contrast, 71% of net K+ input was retained, which is likely due to forest vegetation uptake. Net export of Ca2+ was 867 eq ha−1 year−1 compared to net throughfall of 790 eq ha−1 year−1. Long-term cation depletion from the NDW soils could limit recovery potential in stream water quality. Findings from this NDW study suggest that future stream acidification conditions in high-elevation GRSM watersheds are dependent on interrelated biogeochemical processes and precipitation patterns, illustrating the need to better understanding potential impacts of climate variability on stream water quality.

Evaluating Regional Patterns in Nitrate Sources to Watersheds in National Parks of the Rocky Mountains using Nitrate Isotopes

In the Rocky Mountains, there is uncertainty about the source areas and emission types that contribute to nitrate (NO3) deposition, which can adversely affect sensitive aquatic habitats of high-elevation watersheds. Regional patterns in NO3 deposition sources were evaluated using NO3 isotopes in five National Parks, including 37 lakes and 7 precipitation sites. Results indicate that lake NO3 ranged from detection limit to 38 microeq/L, delta18O (NO3) ranged from -5.7 to +21.3% per thousand, and delta15N (NO3) ranged from -6.6 to +4.6 per thousand. delta18O (NO3) in precipitation ranged from +71 to +78% per thousand. delta15N (NO3) in precipitation and lakes overlap; however, delta15N (NO3) in precipitation is more depleted than delta15N (NO3) in lakes, ranging from -5.5 to -2.0 per thousand. delta15N (NO3) values are significantly related (p < 0.05) to wet deposition of inorganic N, sulfate, and acidity, suggesting that spatial variability of delta15N (NO3) over the Rocky Mountains may be related to source areas of these solutes. Regional patterns show that NO3 and delta15N (NO3) are more enriched in lakes and precipitation from the southern Rockies and at higher elevations compared to the northern Rockies. The correspondence of high NO3 and enriched delta15N (NO3) in precipitation with high NO3 and enriched delta15N (NO3) in lakes, suggests that deposition of inorganic N in wetfall may affect the amount of NO3 in lakes through a combination of direct and indirect processes such as enhanced nitrification.

Mercury Transport in a High-Elevation Watershed in Rocky Mountain National Park, Colorado

Mercury (Hg) was measured in stream water and precipitation in the Loch Vale watershed in Rocky Mountain National Park, Colorado, during 2001–2002 to investigate processes controlling Hg transport in high-elevation ecosystems. Total Hg concentrations in precipitation ranged from 2.6 to 36.2 ng/L and showed a strong seasonal pattern with concentrations that were 3 to 4 times higher during summer months. Annual bulk deposition of Hg was 8.3 to 12.4 μ g/m2 and was similar to deposition rates in the Midwestern and Northeastern U.S. Total Hg concentrations in streams ranged from 0.8 to 13.5 ng/L and were highest in mid-May on the rising limb of the snowmelt hydrograph. Stream-water Hg was positively correlated with dissolved organic carbon suggesting organically complexed Hg was flushed into streams from near-surface soil horizons during the early stages of snowmelt. Methylmercury (MeHg) in stream water peaked at 0.048 ng/L just prior to peak snowmelt but was at or below detection (< 0.040 ng/L) for the remainder of the snowmelt season. Annual export of total Hg in Loch Vale streams ranged from 1.2 to 2.3 μ g/m2, which was less than 20% of wet deposition, indicating the terrestrial environment is a net sink of atmospheric Hg. Concentrations of MeHg in stream water and corresponding watershed fluxes were low, indicating low methylation rates or high demethylation rates or both.

Yields of Dissolved Organic C, N, and P. from Three High-Elevation Catchments, Colorado Front Range, U.S.A.

Ecosystem dynamics in high-elevation watersheds are extremely sensitive to changes in chemical, energy, and water fluxes. Here we report information on yields of dissolved organic C, N, and P for the 1999 snowmelt runoff season from three high-elevation catchments in the Colorado Front Range, U.S.A.: Green Lake 4 (GL4) and Albion townsite (ALB) on North Boulder Creek and the Saddle Stream (SS), a tributary catchment dominated by alpine tundra. Dissolved organic carbon (DOC) concentrations in stream waters ranged from <1 to 10 mg C L-1, with the highest values occurring at the SS site. Dissolved organic nitrogen (DON) concentrations ranged from below detection limits to 0.28 mg N L-1 and were again highest at the tundra-dominatedsite. Dissolved organic phosphorus (DOP) concentrations were at or near detection limits throughout the season in all three catchments indicating a strong terrestrial retention of P. OnlyDOC showed a significant relationship to discharge. Yields of DOC in the three catchments ranged from 10.6 to 11.8 kg C ha-1 while yields of DON and DOP ranged from 0.32 to 0.41 and 0.02 to 0.08 kg ha-1, respectively. The relatively highyield of organic N and P relative to C from the highest elevationsite (GL4) was somewhat surprising and points to either: (1) a source of dissolved organic material (DOM) in the upper reaches of the catchment that is enriched in these nutrients or (2) theselective uptake and processing of organic N and P downstream ofthe sampling site. Additionally, seasonal changes in the relativeimportance of DOM precursor materials appear to result in changesin the N content of DOM at both the GL4 and ALB sites.

VARIATION IN MAYFLY SIZE AT METAMORPHOSIS AS A DEVELOPMENTAL RESPONSE TO RISK OF PREDATION

Animals with complex life cycles often show large variation in the size and timing of metamorphosis in response to environmental variability. If fecundity increases with body size and large individuals are more vulnerable to predation, then organisms may not be able to optimize simultaneously size and timing of metamorphosis. The goals of this study were to measure and explain large-scale spatial and temporal patterns of phe- notypic variation in size at metamorphosis of the mayfly, Baetis bicaudatus (Baetidae), from habitats with variable levels of predation risk. Within a single high-elevation watershed in western Colorado, USA, from 1994 to 1996 we measured dry masses of mature larvae of the overwintering and summer generations of Baetis at 28 site-years in streams with and without predatory fish (trout). We also estimated larval growth rates and development times at 16 site-years. Patterns of spatial variation in mayfly size could not be explained by resource (algae) standing stock, competitor densities, or physical-chemical variables. However, size at metamorphosis of males and females of summer generation Baetis was smaller in fish streams than in fishless streams and decreased as densities of predatory stoneflies increased. Furthermore, overwintering individuals matured at larger sizes than summer generation Baetis, and the size of emerging Baetis declined over the summer, but predominantly in trout streams. Theoretical consideration of the effect of predation risk on size and timing of metamorphosis accurately predicted the observed temporal variation in size and timing of mayflies at emergence in fish and fishless streams. Baetis populations had similar growth rates but followed different developmental trajectories in high and low risk environments. In risky environments larval development was accelerated, resulting in metamorphosis of younger and smaller individuals, minimizing exposure of larvae to risk of mortality from trout predation, but at the cost of future reproduction. In safe environ- ments, larvae extended their development, resulting in larger, more fecund adults. Thus, we propose that large-scale patterns of variation in size and timing of metamorphosis represent adaptive phenotypic plasticity, whereby mayflies respond to variation in risk of predation, thereby maximizing their fitness in variable environments.

Variation in Mayfly Size at Metamorphosis as a Developmental Response to Risk of Predation

Animals with complex life cycles often show large variation in the size and timing of metamorphosis in response to environmental variability. If fecundity increases with body size and large individuals are more vulnerable to predation, then organisms may not be able to optimize simultaneously size and timing of metamorphosis. The goals of this study were to measure and explain large-scale spatial and temporal patterns of phenotypic variation in size at metamorphosis of the mayfly, Baetis bicaudatus (Baetidae), from habitats with variable levels of predation risk. Within a single high-elevation watershed in western Colorado, USA, from 1994 to 1996 we measured dry masses of mature larvae of the overwintering and summer generations of Baetis at 28 site-years in streams with and without predatory fish (trout). We also estimated larval growth rates and development times at 16 site-years. Patterns of spatial variation in mayfly size could not be explained by resource (algae) standing stock, competitor densities, or physical–chemical variables. However, size at metamorphosis of males and females of summer generation Baetis was smaller in fish streams than in fishless streams and decreased as densities of predatory stoneflies increased. Furthermore, overwintering individuals matured at larger sizes than summer generation Baetis, and the size of emerging Baetis declined over the summer, but predominantly in trout streams. Theoretical consideration of the effect of predation risk on size and timing of metamorphosis accurately predicted the observed temporal variation in size and timing of mayflies at emergence in fish and fishless streams. Baetis populations had similar growth rates but followed different developmental trajectories in high and low risk environments. In risky environments larval development was accelerated, resulting in metamorphosis of younger and smaller individuals, minimizing exposure of larvae to risk of mortality from trout predation, but at the cost of future reproduction. In safe environments, larvae extended their development, resulting in larger, more fecund adults. Thus, we propose that large-scale patterns of variation in size and timing of metamorphosis represent adaptive phenotypic plasticity, whereby mayflies respond to variation in risk of predation, thereby maximizing their fitness in variable environments.

Seasonal changes in the character and nitrogen content of dissolved organic matter in an alpine/subalpine headwater catchment.

We are studying the chemical quality of dissolved organic nitrogen (DON) in a high-elevation watershed in the Colorado Front Range. Samples were collected over the 2000 snowmelt runoff season at two sites across an alpine/subalpine ecotone to understand how the transition between the lightly vegetated alpine and forested reaches of the catchment influences the chemical character of DON. Samples were analyzed approximately weekly for dissolved organic material (DOM) content and chemical character. A subset of samples was analyzed for the elemental content of fulvic and hydrophilic acids. Concentrations of DON at both sites were highest in the spring at the initiation of snowmelt, decreased during snowmelt, and increased again during the late summer and fall. In contrast, concentrations of dissolved organic carbon (DOC) peaked on the ascending limb of the hydrograph and declined to seasonal minima on the descending limb of the hydrograph. The ratio of DOC:DON showed a seasonal shift at both sites with high values (40 to 55) during peak runoff in early summer and lower values (15 to 25) during low flows late in the runoff season. These results indicate that there was a seasonal change in the relative N content of DOM at both sites. Chemical fractionation of DOC showed that there were temporal and longitudinal changes in the chemical character of DOC. At the alpine site, the fulvic acid content of DOC decreased from 57% in June to 35% in September. The change in fulvic acid was less pronounced at the forested site, from 66% in June to 54% in September. Elemental analysis of fulvic and hydrophilic acids indicated that hydrophilic acids were N rich compared to fulvic acids. Additionally, fulvic and hydrophilic acids isolated at the alpine site had a lower C:N ratio than those isolated at the forested site. Similarly, the C:N ratio of organic acids at both sites was lower in September than in June during peak runoff. These differences appear to be a result of changes in both DOM precursor material and hydrologic flowpaths. Using C:N ratios of fulvic and hydrophilic acids, we estimate that nonhumic material carried between 54 to 73% of the organic N in surface water at the alpine site and 44 to 58% of the organic N in surface water at the subalpine site.

River Flow Response to Precipitation and Snow Budget in California during the 1994/95 Winter

A numerical study of precipitation and river flow from November 1994 to May 1995 at two California basins is presented. The Hopland watershed of the Russian River in the northern California Coastal Range and the headwater of the North Fork American River in the northern Sierra Nevada were selected to investigate the hydroclimate, snow budget, and streamflow at different elevations. Simulated precipitation and streamflow at the Hopland basin closely approximated observed values. An intercomparison between the semidistributed TOPMODEL and two versions of the lumped Sacramento model for the severe storm event of January 1995 indicates that both types of models predicted a similar response of river outflows from this basin, with the exception that TOPMODEL predicted a faster recession of river flow with less base flow after precipitation ended. Precipitation in this low-elevation watershed was predominantly in the form of rain, causing a fast streamflow response. The high-elevation Sierra Nevada watershed received most of its precipitation as snowfall. As a result, the frozen water held in surface storage delayed runoff and streamflow. Application of a simple elevation-dependent snowfall and rainfall partitioning scheme showed the significance of finescale terrain variation in the surface hydrology at high-elevation watersheds.

A Preliminary Assessment of Wet Deposition and Eposodic Transport of Total and Methyl Metcury From Low Order Blue Ridge Watersheds, S.E. U.S.A.

Results from a preliminary sampling program designed to investigate total (THg) and methyl Hg (MeHg) deposition, cycling and transport at the Coweeta Hydrologic Laboratory western North Carolina are presented. Wet deposition samples were collected in June and July 1994 and throughfall, seep and streamwaters were intensively collected during and after a rainfall event in June 1994. All water samples were collected using ultra clean trace sampling protocol. Low elevation Watershed 18 streamwater THg concentrations peaked with discharge, increasing 6 fold to 9 ng L-1. High elevation Watershed 27 which received less than one half the precipitation Watershed 18 received during the event, exhibited THg concentrations only 1.3 times over base flow conditions. Methyl Hg concentrations remained near detection limits (≤ 0.025 ng L-1) in both streams. Dissolved MeHg concentrations were higher in shallow seep (0.097 ng L-1), throughfall (0.135 ng L-1) and precipitation (0.16 – 0.035 ng L-1) than streamwaters. Initial estimates of annual THg and MeHg deposition and transport indicate >90% retention of Thg and a >80% retention or demethylation of wet deposition MeHg is occurring in these low order watersheds.

Acidic Deposition, Cation Mobilization, and Biochemical Indicators of Stress in Healthy Red Spruce

Dendrochemical and biochemical markers link stress in apparently healthy red spruce trees (Picea rubens) to acidic deposition. Acidic deposition to spruce forests of the northeastern USA increased sharply during the 1960s. Previous reports related visible damage of trees at high elevations to root and soil processes. In this report, dendrochemical and foliar biochemical markers indicate perturbations in biological processes in healthy red spruce trees across the northeastern USA. Previous research on the dendrochemistry of red spruce stemwood indicated that under uniform environmental conditions, stemwood concentrations of Ca and Mg decreased with increasing radial distance from the pith. For nine forest locations, frequency analysis shows that 28 and 52% of samples of red spruce stemwood formed in the 1960s are enriched in Ca and Mg, respectively, relative to wood formed prior to and after the 1960s. This enrichment in trees throughout the northeastern USA may be interpretable as a signal of increased availability of essential cations in forest soils. Such a temporary increase in the availability of Ca and Mg could be caused by cation mobilization, a consequence of increased acidic deposition. During cation mobilization, essential Ca and Mg as well as potentially harmful Al become more available for interaction with binding sites in the soil and absorbing roots. As conditions which favor cation mobilization continue, Ca and Mg can be leached or displaced from the soil. A measure of the interaction between Ca and Al is the Al/Ca binding ratio (molar charge ratio of exchangeable Al to exchangeable Ca). As the Al/Ca binding ratio in the root zone increased from 0.3 to 1.9, the foliar concentration of the biochemical stress marker putrescine also increased from 45 to 145 nm g−1. The correlation of the putrescine concentration to the Al/Ca binding ratio (adj. r2 = 0.68, P < 0.027) suggests that foliar stress may be linked to soil chemistry.

A Proposed Standard Fog Collector for Use in High-Elevation Regions

Abstract The collection of fog droplets by vegetation is an important wet deposition process. It can, in fact, dominate the chemical and hydrological input to certain high elevation watersheds. However, measurements of fog deposition are rarely made and, where they do exist, comparisons of deposition rates in different locations have been hampered by the use of innumerable types of collection devices. A simple, inexpensive, 1-m2 fog collector that can produce measurements of the deposition of fog water to a vertical surface is described here. The collector has been used successfully in five countries to investigate the variation of fog deposition in complex terrain and to estimate the deposition to trees and to much larger fog collectors. It is proposed that it be employed widely as a standard to quantify the importance of fog deposition to forested high elevation areas and to measure the potential collection rates in denuded or desert mountain ranges. The standard fog collector costs about the same as a ...

Mio-pliocene seasonality on the snake river plain: comparison of faunal and oxygen isotopic evidence

Analysis of fish faunas and oxygen isotopic composition of a fish otolith from lacustrine deposits of southwestern Idaho provide a means of evaluating regional Miocene and Pliocene climates. A disharmonious assemblage consisting of coldwater salmon and trout and warmwater sunfish and catfish from the Chalk Hills Formation of the Snake River Plain indicates that the climate of the late Miocene was warm and moist with cool summers and mild winters. Colonization of the lake by deepwater sculpins and whitefish in the Pliocence indicates that the climate was moist and equable, but with summers cooler than either the Miocene or Quaternary. Oxygen isotopic variation among seasonal growth rings in an aragonitic otolith of a Pliocene littoral sunfish suggests a seasonal range of temperatures locally more equable than at present. Extremely depleted values of δ 18O in carbonates suggest that the lake was maintained by tributaries from high-elevation watersheds, with locally low evaporation, rather than high precipitation.

Sulfur processing in soil from high and low elevation forests in the southern appalachians of the united states

Samples of A, E, and B horizons, collected from a high and a low elevation watershed, were analyzed for their capacity to adsorb sulfate, generate organic S and mobilize organic S. Sulfate adsorption potentials were significantly greater in soil from the high elevation watershed compared to that from the low elevation watershed. Only A horizon samples from the two watersheds were statistically different in their capacity to synthesize organic S, although when these samples were incubated at ambient soil temperatures, no statistical difference in organic S formation was observed. Soil moisture, carbon, pH and S constituents were quantified and relationships between these variables and S processing potentials were determined. With high elevation samples, carbon content was positively correlated with organic S formation rates ( r = 0.90; P < 0.005). Sulfonate S was the major S constituent of these soils; however, insoluble ester was the major S constituent in samples from the low elevation watershed. A 60–70% increase in organic S formation rates was observed after amendment with cellobiose with samples from all horizons of the low elevation watershed, indicating that soil from this watershed may be energy deficient in terms of organic S formation. Attempts were made to determine which S processes may be involved in ecosystem-level responses currently being observed with these watersheds.

ESTIMATING THE WATER RESOURCE FOR A HIGH SIERRA WATERSHED1

ABSTRACT: Competition for water, concerns for maintaining ground water quality, and compliance with legislative action require quantification of the water resource for high elevation watersheds in the Sierra Nevada. However, meager hydroclimatic data frequently hinder runoff assessments needed for formulating water development policies, and the selection of watershed models for estimating the water resource is limited to those requiring a minimum of observational data. A climatic water budget model and an energy slope and aspect model are employed to estimate the water resource for a small watershed in Sierra Valley north of Lake Tahoe. The models employ different assumptions and computational procedures, but the total water available estimated by both models is very similar. Measured runoff is estimated satisfactorily by the models, but streamflow is not representative of the total water resource because a substantial portion of the available water enters the regional ground water system. This conclusion is supported by hydrologic and geochemical evidence, and ground water recharge is estimated to be at least as great as measured runoff during dry years and nearly twice as large during wet years.

Aluminum Leaching Response to Acid Precipitation: Effects on High-Elevation Watersheds in the Northeast

Atmospheric inputs of sulfuric acid and nitric acid to noncalcareous higher-elevation watersheds in the White Mountain and Adirondack regions lead to comparatively high concentrations of dissolved aluminum in surface and ground waters. This phenomenon appears to result from modern increases in soil aluminum leaching. Transport of this aluminum to acidified lakes can lead to fish mortality. Combined results from areas of silicate bedrock in the United States and Europe suggest that aluminum represents an important biogeochemical linkage between terrestrial and aquatic environments exposed to acid precipitation.