High Electron Beam Research Articles

Comparison of the Al back contact deposited by sputtering, e-beam, or thermal evaporation for inverted perovskite solar cells

In this work, we present inverted perovskite solar cells with Al top electrodes, which were deposited by three different methods. Besides the widely used thermal evaporation of Al, we also used the industrially important high deposition rate processes sputtering and electron beam evaporation for aluminium electrodes and examined the influence of the deposition method on the solar cell performance. The current–voltage characteristics of as grown solar cells with sputtered and e-beam Al electrode show an s-shape due to damage done to the organic electronic transport layers (ETL) during Al deposition. It can be cured by a short annealing step at a moderate temperature so that fill factors >60% and power conversion efficiencies of almost 12% with negligible hysteresis can be achieved. While solar cells with thermally evaporated Al electrode do not show an s-shape, they also exhibit a clear improvement after a short annealing step. In addition, we varied the thickness of the ETL consisting of a double layer ([6,6]-Phenyl-C61-butyric acid methyl ester and bathocuproine) and investigated the influence on the solar cell parameters for the three different Al deposition methods, which showed distinct dependencies on ETL thickness.

Application of MOSkin detector for in vivo dosimetry on total skin electron therapy (TSET)

Currently, TLDs and Gafchromic EBT3 film are commonly used for skin dose measurement during Total Skin Electron Therapy. However, measurements using these dosimeters are time consuming due to post-irradiation processing requirements. The MOSkin has advantages of being a small physical size with a 0.55 μm thick gate oxide and a water equivalent depth of 0.07 mm while providing real-time dosimetry. Measurements of the MOSkin’s dosimetric characteristics were performed using a 6 MeV electron beam with an Elekta Infinity linear accelerator. For the TSET measurements, doses measured with the MOSkin were directly compared to TLDs and Gafchromic EBT3 film using a 6 MeV high dose rate electron beam. A 6 mm Perspex spoiler was placed and aligned perpendicularly to the beam in order to lower the effective beam energy and improve dose homogeneity. The MOSkin showed good dose linearity (R2 = 0.9986) and dose rate independence for a 6 MeV electron beam and behaved very similarly to the other types of dosimeters that are commonly used in vivo dosimetry. For the TSET measurements, all three detector types showed a very similar trend of dose readings over the range of measurement points. Therefore, the MOSkin is an effective skin dosimeter for TSET dosimetry.

Magnetic fixtures for enhancement of smoothing effect by electron beam melting

In large-area electron beam (EB) irradiation method developed recently, high energy density EB can be obtained without focusing the beam. Therefore, large-area EB of 60mm in diameter can be used for instant melting and evaporation of the wide area material surface, and high efficient surface finishing is possible. However, if the workpiece has a hole shape, the EB concentrates in the entrance edge or inside wall of the hole. Thus, it is difficult to smooth the hole bottom surface. Previous study showed that the surface smoothing and micro-deburring effects for non-magnetic workpiece could be improved by setting a magnetic block under the workpiece, since the electrons tend to concentrate the magnetic block along magnetic lines. In this study, smoothing of hole bottom surface was experimentally investigated by setting a magnetic block under a workpiece in large-area EB irradiation. Expansion of smoothing area of the bottom surface was also tried by setting a through hole at the center of the magnetic block. It was clarified that wide area of hole bottom surface could be smoothed by large- area EB irradiation by setting the magnetic block under workpiece. The surface roughness decreased to less than 3.0μmRz at the area of hole bottom surface. When the hole diameter was 20mm and hole depth was less than 40mm, smoothing area of 10mm in diameter was obtained by using the magnetic block. Moreover, the smoothing area was sufficiently expanded by setting a through hole with an appropriate diameter in magnetic block.

Thermal limits on MV x-ray production by bremsstrahlung targets in the context of novel linear accelerators.

To study the impact of target geometrical and linac operational parameters, such as target material and thickness, electron beam size, repetition rate, and mean current on the ability of the radiotherapy treatment head to deliver high-dose-rate x-ray irradiation in the context of novel linear accelerators capable of higher repetition rates/duty cycle than conventional clinical linacs. The depth dose in a water phantom without a flattening filter and heat deposition in an x-ray target by 10 MeV pulsed electron beams were calculated using the Monte-Carlo code MCNPX, and the transient temperature behavior of the target was simulated by ANSYS. Several parameters that affect both the dose distribution and temperature behavior were investigated. The target was tungsten with a thickness ranging from 0 to 3 mm and a copper heat remover layer. An electron beam with full width at half maximum (FWHM) between 0 and3 mm and mean current of 0.05-2 mA was used as the primary beam at repetition rates of 100, 200, 400, and 800 Hz. For a 10 MeV electron beam with FWHM of 1 mm, pulse length of 5 μs, by using a thin tungsten target with thickness of 0.2 mm instead of 1 mm, and by employing a high repetition rate of 800 Hz instead of 100 Hz, the maximum dose rate delivered can increase two times from 0.57 to 1.16 Gy/s. In this simple model, the limiting factor on dose rate is the copper heat remover's softening temperature, which was considered to be 500°C in our study. A high dose rate can be obtained by employing thin targets together with high repetition rate electron beams enabled by novel linac designs, whereas the benefit of thin targets is marginal at conventional repetition rates. Next generation linacs used to increase dose rate need different target designs compared to conventional linacs.

One-step radiolytic synthesis of heteroatom (N and S) co-doped graphene for supercapacitors

A novel, rapid, one-step electron-beam (EB) based method for both reduction of graphene oxide (GO) and co-doping of nitrogen and sulfur to prepare N, S-codoped graphene layers (NSG) has been achieved. This synthesis process relies on the interaction of high energy EB rays from an electron accelerator with the water in the aqueous solutions containing l-cysteine as the precursor of nitrogen and sulfur, leading to the generation of highly reducing species that not only reduce the GO to reduced graphene oxide (rGO), but also dope nitrogen and sulfur into graphene. The as-prepared heteroatom doped graphene materials own a better dual-doping and reduction of the GO. The range of nitrogen and sulfur doping content could achieve 4.88–10.88 at% and 2.08–4.59 at%, respectively. The sample prepared under the irradiation dose of 210 kGy (NSG-210) exhibits the highest specific capacitance of 227.94 F g−1 at a scan rate of 10 mV s−1 and stable cycling performance with a capacitance retention of 83% after 25,000 cycles at a current density of 10 A g−1. These results exhibit an eco-friendly and simple design of electrode materials for high performance supercapacitors.

Structural phase states and properties of the layer surfaced on low-carbon steel with Fe‒C‒Cr‒Nb‒W powder-core wire followed by electron-beam processing

Structural phase states and tribological properties of the coating surfaced onto Hardox 450 martensite low-carbon steel with powder wire Fe‒C‒Cr‒Nb‒W and modified by subsequent electron-beam processing are studied by methods of modern physical material science. It is shown that irradiation of ~5 thick surfaced layer with high intensity pulsed electron beams results in the formation of ~20 μm thick surface layer with the master phases of α-Fe and NbC, Fe3C and M6C(Fe3W3C) carbides. The main difference of the surface layer modified with electron-beam processing from the unmodified volume of the surfacing is the morphology and dimensions of the second phase inclusions. In the modified layer of the surfacing the inclusions have smaller dimensions and are located in the form of interlayers along the grain boundaries. In unmodified surfacing the particles of the faceted shape located chaotically in the grain volume are the basic morphological type of the inclusions. It is noted that the small value of crystal lattice Nb parameter observed in the experiment may be caused by the high level of vacant interstitial sites having the smaller size in comparison with the occupied interstitial sites. It is established that wear resistance of the surfaced layer after electron-beam processing increases more than 70-fold relative to wear resistance of Hardox 450 steel and friction coefficient decreases significantly (~3-fold).

Weak quasielastic electroproduction of hyperons with polarization observables

With the availability of high luminosity electron beam at the accelerators, there is now the possibility of studying weak quasielastic hyperon production off the proton, i.e. $e^-p \to \nu_e Y(Y=\Lambda,\Sigma^0)$, which will enable the determination of the nucleon-hyperon vector and axial-vector transition form factors at high $ Q^2$ in the strangeness sector and provide test of the Cabibbo model, G-invariance, CVC, PCAC hypotheses and SU(3) symmetry. In this work, we have studied the total cross section, differential cross section as well as the longitudinal and perpendicular components of polarization of the final hyperons ($ \Lambda$ and $\Sigma^0$ produced in these reactions) and presented numerical results for these observables and their sensitivity to the transition form factors.

Highly sensitive and scalable AAO-based nano-fibre SERS substrate for sensing application

Well-ordered periodic nanostructures are excellent substrates for many surface-enhanced Raman spectroscopy (SERS) applications. Conventional fabrication approaches such as high precision electron beam lithography or focused ion beam produce high resolution nano-features with great reproducibility at the expense of low throughput. In this work, a highly sensitive and scalable AAO-nano-fibre (ANF) SERS substrate is demonstrated by optimising the second anodisation time of the standard two-step anodisation of aluminium and performing an additional wet etching step on the resulting AAO substrate. The optimised ANF substrate exhibits SERS sensitivity that surpasses the AAO nanoholes and the metal-film-on-nanoparticles substrates. A detection limit of 0.1 nM is achieved with a signal-to-noise ratio of 2.6–3 using a low excitation power of 0.1 mW. The ANF substrate exhibits an enhancement factor of 9.28 × 106 and a standard deviation of no more than 8%. The results indicate that the highly sensitive and scalable ANF substrate is a promising substrate for commercial SERS application.

Electron beam dose dependence of surface recombination velocity and surface space charge in semiconductor nanowires

The characterization of nanowires (NWs) often requires the use of scanning electron beam techniques because of their high spatial resolution. However, the impact of the high energetic electron beam on the physical parameters under investigation is rarely taken into account. In this work, a combination of optical and electrical techniques is involved for the measurement of the electron beam dose (EBD) dependence of cathodoluminescence intensity, exciton diffusion length and electrical resistance in ZnO NWs. Large EBD dependences of these key parameters are observed and their reversibility is investigated. The results are discussed in terms of bulk and surface reversible modifications. In particular, the behaviors of surface recombination velocity and surface space charge under electron beam exposure are determined and simulated. This study points out that caution must be taken and experimental protocols must be well defined when measuring physical parameters of NWs using electron beam techniques.

Study of linearity of LYSO crystal for the high energy cosmic radiation detection (HERD) facility

The high energy cosmic-radiation detection (HERD) facility is a space mission designed for detecting cosmic ray (CR) electrons, $$\gamma $$ -rays up to tens of TeV and CR nuclei from proton to iron up to several PeV. The main instrument of HERD is a 3-D imaging calorimeter (CALO) composed of nearly ten thousand lutetium yttrium orthosilicate (LYSO, with cerium doping) crystal cubes. A large dynamic range of single HERD CALO Cell (HCC) is necessary to achieve HERD’s PeV observation objectives, which means that the response of HCC should maintain a good linearity from minimum ionizing particle (MIP) calibration to PeV shower maximum. In order to study the linearity of HCC over such a large energy range, a beam test has been implemented at the E2 and E3 beam lines of BEPC. High intensity pulsed electron beam provided by E2 line is used for producing high energy density within HCC; $$\pi ^{+}$$ /proton provided by E3 line are used for HCC calibration. The results show that no saturation effect occurs and the linearity of HCC is better than 10% from 30 MeV (1 MIP) to $$1.1\times 10^{3}$$ TeV (energy density is 93 TeV/cm $$^{3})$$ , which can meet the requirement mentioned above.

Production of high-angular-momentum electron beams in laser-plasma interactions.

It was shown that in the interactions of ultra-intense circularly polarized laser pulse with the near-critical plasmas, the angular momentum can be transferred efficiently from the laser beam to electrons through the resonance acceleration process. The transferred angular momentum increases almost linearly with the acceleration time t_{a} when the electrons are resonantly accelerated by the laser field. In addition, it is shown analytically that the averaged angular momentum of electrons is proportional to the laser amplitude a_{L}, and the total angular momentum of the accelerated electron beam is proportional to the square of the laser amplitude a_{L}^{2} for a fixed parameter of n_{e}/n_{c}a_{L}. These results are verified by three-dimensional particle-in-cell simulations. This regime provides an efficient and compact alternative for the production of high angular momentum electron beams, which may have many potential applications in condensed-matter spectroscopy, new electron microscopes, and bright x-ray vortex generation.

Design and development of high pressure high temperature water circulation system for HHFTF

High Heat Flux Test Facility (HHFTF) at Institute for Plasma Research in Bhat in India is established for testing thermal performance of plasma facing materials and components under intense heat loads expected in plasma fusion devices. It mainly consists of the following sub-systems like vacuum system, high power electron beam system, diagnostic and calibration system, data acquisition & control system and high pressure high temperature water circulation system (HPHT-WCS). In order to test the water cooled test mock-ups or components at ITER like relevant parameters in HHFTF, HPHT-WCS is established that can supply water at desired pressures, temperatures and flow rates. HPHT-WCS, is capable of providing demineralised water up to 160°C temperature, 60bar pressure and 4.85kg/s mass flow rate. The loop is designed on a skid base frame which has piping connected to various process components and the system is operated remotely through a data acquisition and control system. The main requirements and characteristics, design and development of the HPHT-WCS are presented.

Responsivity calibration of the extreme ultraviolet spectrometer in the range of 175-435 Å

We reported the relative responsivity calibration of the grazing-incidence flat-field EUV spectrometer between 175 and 435 Å by means of two methods. The first method is implemented by measuring the diffraction efficiency of the grating with synchrotron radiation light source. Considering the transmission efficiency and quantum efficiency of the other optical components in the spectrometer, the total responsivity was then obtained. The second one was carried out by measuring line emissions from C3+, N4+ and O3+ ions at Shanghai high temperature super conductor electron beam ion trap (SH-HtscEBIT). The EUV spectra were also simulated theoretically via a collisional radiative model. In the calculation, the second-order relativistic many-body perturbation theory approach based on the flexible atomic code was used to calculate the energy levels and transition rates; the close-coupling R-matrix approach and relativistic distorted wave method were utilized to calculate the collision strength of electron impact excitation. In comparison with the spectroscopic measurements at EBIT device, the differences between the measured and simulated relative line intensities were obtained. The responsivity calibration for the spectrometer was then achieved by a 3rd degree polynomial function fitting. Our measurement shows that the responsivity between 175 and 435 Å varies by factor of ∼ 46. The two results of calibration demonstrated a consistency within an average deviation of 24%. In addition, an evaluation of our calculations on C iv, N v and O iv line emissions in this wavelength region was given.

Structure and chemistry of epitaxial ceria thin films on yttria-stabilized zirconia substrates, studied by high resolution electron microscopy

We have applied aberration-corrected transmission electron microscopy (TEM) imaging and electron energy loss spectroscopy (EELS) to study the structure and chemistry of epitaxial ceria thin films, grown by pulsed laser deposition onto (001) yttria-stabilized zirconia (YSZ) substrates. There are few observable defects apart from the expected mismatch interfacial dislocations and so the films would be expected to have good potential for applications. Under high electron beam dose rate (above about 6000 e-/Å2s) domains of an ordered structure appear and these are interpreted as being created by oxygen vacancy ordering. The ordered structure does not appear at lower lose rates (ca. 2600 e-/Å2s) and can be removed by imaging under 1 mbar oxygen gas in an environmental TEM. EELS confirms that there is both oxygen deficiency and the associated increase in Ce3+ versus Ce4+ cations in the ordered domains. In situ high resolution TEM recordings show the formation of the ordered domains as well as atomic migration along the ceria thin film (001) surface.

Hydrogen Balmer Line Broadening in Solar and Stellar Flares

The broadening of the hydrogen lines during flares is thought to result from increased charge (electron, proton) density in the flare chromosphere. However, disagreements between theory and modeling prescriptions have precluded an accurate diagnostic of the degree of ionization and compression resulting from flare heating in the chromosphere. To resolve this issue, we have incorporated the unified theory of electric pressure broadening of the hydrogen lines into the non-LTE radiative transfer code RH. This broadening prescription produces a much more realistic spectrum of the quiescent, A0 star Vega compared to the analytic approximations used as a damping parameter in the Voigt profiles. We test recent radiative-hydrodynamic (RHD) simulations of the atmospheric response to high nonthermal electron beam fluxes with the new broadening prescription and find that the Balmer lines are over-broadened at the densest times in the simulations. Adding many simultaneously heated and cooling model loops as a "multithread" model improves the agreement with the observations. We revisit the three-component phenomenological flare model of the YZ CMi Megaflare using recent and new RHD models. The evolution of the broadening, line flux ratios, and continuum flux ratios are well-reproduced by a multithread model with high-flux nonthermal electron beam heating, an extended decay phase model, and a "hot spot" atmosphere heated by an ultrarelativistic electron beam with reasonable filling factors: 0.1%, 1%, and 0.1% of the visible stellar hemisphere, respectively. The new modeling motivates future work to understand the origin of the extended gradual phase emission.

Design and performance of vacuum system for high heat flux test facility

High heat flux test facility (HHFTF) at IPR is used for testing thermal performance of plasma facing materials or components. It consists of various subsystems like vacuum system, high power electron beam system, diagnostic and calibration system, data acquisition and control system and high pressure high temperature water circulation system. Vacuum system consists of large D-shaped chamber, target handling system, pumping systems and support structure. The net volume of vacuum chamber is 5 m3 was maintained at the base pressure of the order of 10-6 mbar for operation of electron gun with minimum beam diameter which is achieved with turbo-molecular pump (TMP) and cryo pump. A variable conductance gate valve is used for maintaining required vacuum in the chamber. Initial pumping of the chamber was carried out by using suitable rotary and root pumps. PXI and PLC based faster real time data acquisition and control system is implemented for performing the various operations like remote operation, online vacuum data measurements, display and status indication of all vacuum equipments. This paper describes in detail the design and implementation of various vacuum system for HHFTF.

The Atmospheric Response to High Nonthermal Electron Beam Fluxes in Solar Flares. I. Modeling the Brightest NUV Footpoints in the X1 Solar Flare of 2014 March 29

Abstract The 2014 March 29 X1 solar flare (SOL20140329T17:48) produced bright continuum emission in the far- and near-ultraviolet (NUV) and highly asymmetric chromospheric emission lines, providing long-sought constraints on the heating mechanisms of the lower atmosphere in solar flares. We analyze the continuum and emission line data from the Interface Region Imaging Spectrograph (IRIS) of the brightest flaring magnetic footpoints in this flare. We compare the NUV spectra of the brightest pixels to new radiative-hydrodynamic predictions calculated with the RADYN code using constraints on a nonthermal electron beam inferred from the collisional thick-target modeling of hard X-ray data from Reuven Ramaty High Energy Solar Spectroscopic Imager. We show that the atmospheric response to a high beam flux density satisfactorily achieves the observed continuum brightness in the NUV. The NUV continuum emission in this flare is consistent with hydrogen (Balmer) recombination radiation that originates from low optical depth in a dense chromospheric condensation and from the stationary beam-heated layers just below the condensation. A model producing two flaring regions (a condensation and stationary layers) in the lower atmosphere is also consistent with the asymmetric Fe ii chromospheric emission line profiles observed in the impulsive phase.

In Situ Transmission Electron Microscopy Study of Electron Beam-Induced Transformations in Colloidal Cesium Lead Halide Perovskite Nanocrystals.

An increasing number of studies have recently reported the rapid degradation of hybrid and all-inorganic lead halide perovskite nanocrystals under electron beam irradiation in the transmission electron microscope, with the formation of nanometer size, high contrast particles. The nature of these nanoparticles and the involved transformations in the perovskite nanocrystals are still a matter of debate. Herein, we have studied the effects of high energy (80/200 keV) electron irradiation on colloidal cesium lead bromide (CsPbBr3) nanocrystals with different shapes and sizes, especially 3 nm thick nanosheets, a morphology that facilitated the analysis of the various ongoing processes. Our results show that the CsPbBr3 nanocrystals undergo a radiolysis process, with electron stimulated desorption of a fraction of bromine atoms and the reduction of a fraction of Pb2+ ions to Pb0. Subsequently Pb0 atoms diffuse and aggregate, giving rise to the high contrast particles, as previously reported by various groups. The diffusion is facilitated by both high temperature and electron beam irradiation. The early stage Pb nanoparticles are epitaxially bound to the parent CsPbBr3 lattice, and evolve into nonepitaxially bound Pb crystals upon further irradiation, leading to local amorphization and consequent dismantling of the CsPbBr3 lattice. The comparison among CsPbBr3 nanocrystals with various shapes and sizes evidences that the damage is particularly pronounced at the corners and edges of the surface, due to a lower diffusion barrier for Pb0 on the surface than inside the crystal and the presence of a larger fraction of under-coordinated atoms.

Effective NOx remediation from a surrogate flue gas using the US NRL Electra electron beam facility

Nitric oxide (NOx) emission is under restrictive federal regulations because of its negative impact on atmosphere, biosphere, and human health. Therefore, its removal has been a subject of extensive research to develop new efficient and cost effective techniques that can be applied on an industrial scale. In this work, we study both experimentally and theoretically an effective removal of NOx pollutants from a surrogate flue gas (SFG) using high power electron beam (e-beam) pulses. SFG is a simulant for exhaust from coal combustion power plants (82% N2, 6% O2, 12% CO2, and ∼100 ppm of NOx). The pulsed electron beam is generated using the United States Naval Research Laboratory Electra facility, which delivers e-beams with energies of ∼500 keV and a power pulse duration of ∼140 ns. During the e-beam irradiation, the energetic electrons generate a non-equilibrium plasma containing chemically active species, which then react with NOx to form harmless substances. A non-equilibrium time-dependent model is developed to describe NOx remediation from SFG. The model combines e-beam deposition rates obtained by solving the electron Boltzmann equation and extensive plasma chemistry modeling, which follows the species on a time scale from sub-nanoseconds to a few seconds. NOx decomposition as a function of electron beam parameters is studied. It is demonstrated experimentally that short (ns) pulses are the most efficient for NOx removal. A sharp reduction of NOx was measured with e-beam power deposition increasing, following the trend predicted by the model, achieving a 20 fold reduction to ∼5 ppm at energy deposition ∼20 J/l.

Advanced post-acceleration methodology for pseudospark-sourced electron beam

During its conductive phase, a pseudospark discharge is able to generate a low energy electron beam with a higher combined current density and brightness compared with electron beams formed from any other known type of electron source. In this paper, a configuration is proposed to post-accelerate an electron beam extracted from a single-gap pseudospark discharge cavity in order to achieve high quality high energy intense electron beams. The major advancement is that the triggering of the pseudospark discharge, the pseudospark discharge itself, and the post-accelerating of the electron beam are all driven by a single high voltage pulse. An electron beam with a beam current of ∼20 A, beam voltage of 40 kV, and duration of ∼180 ns has been generated using this structure. The beam energy can be adjusted through adjusting the amplitude of the voltage pulse and the operating voltage of the whole structure, which can be varied from 24 to 50 kV with an efficient triggering method under fixed gas pressure below ∼10 Pa.