High MgO Contents Research Articles

The diamond-poor nature of corundum-bearing eclogite and Karoo-type overprint of deep eclogite sources beneath the Kimberley region (Kaapvaal craton)

Abstract Decades of studies have shown that the petrogenesis of kimberlite-borne cratonic eclogite and pyroxenite xenoliths reflects the endemics of their crustal protoliths and local lithosphere evolution. Detailed investigations of the origin and metasomatic history of individual eclogite xenolith suites are thus required to understand how cratonic eclogite reservoirs - and their diamond inventory - evolve in the regional tectonomagmatic context. Here, we investigate a little-studied eclogite and pyroxenite xenolith suite from the Balmoral kimberlite in the Kimberley area of the Kaapvaal craton, which, like eclogite suites in neighbouring kimberlites, likely originated as subducted Archaean oceanic crust. Detailed petrographic observations and mineral major- and trace-element analyses, combined with published data for eclogite xenoliths and eclogitic inclusions in diamond, show that this sample suite records at least two distinct episodes of metasomatic overprint: (1) Metasomatism by a kimberlite-like melt caused a decrease in clinopyroxene jadeite component and garnet grossular component and imparted high MgO and Cr2O3 contents, recorded dominantly by pyroxenite xenoliths. Comparison to Kaapvaal kimberlites and lamproites confirms that the geochemical trends cannot be reconciled with bulk kimberlite-eclogite mixing but require formation of diopside-rich clinopyroxene from the melt instead. This metasomatic style is recognised world-wide, and at Balmoral is notably restricted to the shallow lithosphere (110-150 km). (2) A distinct metasomatic event generated eclogites with extreme Y-HREE enrichment, at Balmoral restricted to the deep lithosphere (150-200 km). We propose that this enrichment style reflects garnet breakdown, with the liberation of these garnet-compatible elements to the metasomatic melt. This signature is identified in eclogite xenoliths both from early Cretaceous lamproite (Bellsbank) and late Cretaceous kimberlite (Balmoral, Kimberley) localities, tentatively ascribed to interaction with melts forming the Karoo large igneous province. Balmoral corundum-bearing eclogites derive from depths overlapping high-Ca eclogites showing a Karoo-type overprint, which significantly diluted the Al2O3 content in the bulk rock and increased silica activity as gauged by the decrease in Al[IV] in clinopyroxene, thereby destabilising corundum. Craton-wide, preserved corundum-bearing eclogites record diamond-stable ƒO2 and pressure conditions, yet show little compositional overlap with inclusions in eclogitic diamond. This may reflect the low propensity of COH fluids to reach carbon saturation in this lithology. The preserved corundum-bearing eclogites have reconstructed bulk major-element compositions, which, combined with small to absent Eu anomalies, suggest protoliths representing deep oceanic crustal (>0.5 GPa) cumulates of two pyroxenes plus only minor plagioclase that contained a significant melt component. The identification of such deep hybridised crustal rocks may reflect higher mantle potential temperatures and the formation of thicker oceanic crust in the Archaean.

Tracking magmatism and metasomatism in continental arc crust root: Significance from western Central Qilian belt in NE Tibet, China

Abstract Mantle peridotites and pyroxenites from arc crust root record vital information about petrogenetic processes in supra–subduction environments, which are commonly obscured by subsequent metamorphic and/or metasomatic overprints. The Heigou Complex from the western Central Qilian arc root (NE Tibet, China) consists of peridotites and pyroxenites. Petrography, bulk–rock and mineral geochemistry, zircon and titanite U–Pb ages, and bulk–rock Sr–Nd–Hf isotopes are presented to decipher its petrogenetic and metasomatic history. The peridotites display highly refractory compositions of low SiO2, Al2O3, CaO, but high MgO contents. Geochemical modeling indicates that these are the residues after up to ~22% melt extraction. The geochemical and isotopic data (87Sr/86Sr i = 0.7116–0.7179, εNd(t) = –4.2~–7.1 and εHf(t) = –5.3 ~ –5.4) suggest the pyroxenitic protoliths were derived from a subduction-metasomatized mantle source. Combining petrographic and fractional crystallization simulation, the pyroxenites formed as cumulates through 50–80% differentiation of primitive basaltic magma in the arc root at ca. 523 Ma. Elevated LILEs (Rb, Sr, Pb, etc.) and LREE in bulk-rock and mineral compositions, together with microstructure evidence, suggest that mantle peridotite experienced mantle metasomatism. Subsequent hydrous melt (fluid) metasomatism during exhumation then reacted with the preexisting clinopyroxenite, leading to local Mg-hornblende, titanite and epidote formation. The timing of retrograde melt infiltration is constrained by a titanite U–Pb crystallization age of ca. 485 Ma. The combined evidence reveals a picture of continental arc magmatism and metasomatism at arc crust roots. Dehydration of the Proto-Tethys oceanic slab could induce flux melting in the mantle wedge that had undergone metasomatism, resulting in the generation of hydrous arc magmas. These arc magmas intruded the overlying lithospheric mantle, segregating pyroxenite cumulates. The ultramafic rocks at the arc crust root were subsequently modified by hydrous melt (fluid).

Petrogenesis and Geochemistry of Upper Paleozoic Komatiites (Mashhad, NE Iran)

Abstract Upper Paleozoic, probably Permian, komatiites have been found in the Paleo Tethys suture zone in NE Iran. These rocks are divided into three groups: (i) differentiated and undifferentiated komatiite lava flows, (ii) komatiitic basalts, and (iii) ultramafic-mafic pillow lavas. The rocks have a wide range of textures including random olivine spinifex, layered olivine spinifex, random and string-beef pyroxene spinifex, micrographic intergrowths of plagioclase and clinopyroxene, and cumulate textures. MgO contents range from 7.1 wt% in basalts and gabbros in differentiated flows to 38.0 wt% in cumulates, flow margins and samples with olivine spinifex textures. The MgO content of the parental melt is estimated using the Fo content of olivine (89-91) to be between 20 and 25 wt%, and the higher MgO content in spinifex samples (30 to 36 wt%) is attributed to accumulation of olivine. The rocks have low Al2O3/TiO2 and are relatively depleted in heavy rare earth elements. They therefore are classified as Al-depleted komatiite, the first report of this magma type in a Phanerozoic locality. These characteristics are attributed to the presence of garnet in the source during mantle melting and melt extraction. The rocks also have relatively low contents of the more incompatible trace elements indicating derivation from a depleted source. Our study indicates that the parental magma formed by 10- (about) 20% partial melting in a mantle plume at pressures of about 4-5 GPa (depths of 120-150 km). Ascent of the plume into the Late Paleozoic subduction zone at the margin of the Paleo-Tethys ocean is a possible petrogenetic model for the generation of these komatiites.

GEOCHEMISTRY OF THE UPPER CRETACEOUS SHALES FROM GOMBE FORMATION, GONGOLA BASIN, UPPER BENUE TROUGH, NIGERIA: IMPLICATIONS FOR PROVENANCE AND TECTONIC EVOLUTION

The Gombe Formation, situated in the northeastern region of Nigeria, contains shales in addition to various sedimentary lithologies such as sandstones, mudstones, and coals. Nonetheless, the comprehensive geochemical analyses of the major oxides of these shales remain inadequately documented to date. The current study aimed to elucidate the geochemical significance of major oxides of the shales from the Gombe Formation in the Upper Benue Trough, Nigeria, using x-ray fluorescence spectrometry (XRF) within the context of provenance, tectonic settings, and paleosalinity. The average concentration of the major oxides ranged from 0.02 to 34.93 % in the shales. Among the twenty-four (24) major oxides detected, the shales exhibit elevated concentrations of SiO2, with Al2O3>Fe2O3>SO3>MgO>CaO>SrO>BaO>K2O>TiO2>Sb2O3>CeO2>MnO, whereas the remaining oxides exhibited low concentrations. This observation implies that the shales were predominantly composed of quartz minerals and deposited in marine environments. The relatively high concentrations of Fe2O3 (with an average value of 3.36 %) and MgO (with an average value of 2.48 %) in the samples suggest that the source rocks were likely of a mafic to ultramafic nature. The values of Al2O3/TiO2 and SiO2/Al2O3 in the shales ranged from 1.75 to 11.02 and 6.95 to 38.44, respectively. These values indicated their derivation from a mixture of felsic igneous and mafic igneous rocks and mixed compositional maturity in proximity to the active continental margin. This study demonstrated that major oxides serve as a robust tool for assessing the provenance and tectonic characteristics of the shales from the Gombe Formation within the Gongola Basin, Nigeria.

The Effects of CaO and MgO on Thermal, Mechanical and Optical Properties of Porcelain Tiles by Utilizing Blast Furnace Slag

In this study, the Blast Furnace Slag (BFS) of Zonguldak Eregli Iron and Steel Factories was used as a recycling raw material for the porcelain tile samples. A kind of clay with high MgO content was also used in the porcelain tile recipes. Maximum 10% of BFS was used instead of Na-feldspar. Sintering temperature for all samples was 1205°C for 50 minutes in the industrial roller kiln. Technological properties such as shrinkage, water absorption, colour measurement, and flexural strength were investigated as well as sintering properties and microstructures of the green and the sintered samples. As a result of the study, the addition of BFS did not adversely affect the technical properties of porcelain tile bodies. Particularly, the addition of BFS up to 3% contributed to an increase in flexural strength, and whiteness values of all samples increased because of the formation of anorthite and diopside compared to the reference body. The phase transformations and crystal formations such as anorthite and diopside resulted in a decrease in the firing shrinkage. Although the anorthite formation and diopside formation in the investigated samples had an adverse effect on condensation, it was found that they showed similar sintering behaviours compared to the reference body. This study showed that an industrial waste material can be converted into an environmentally friendly raw material that can create added value and provide energy efficiency.

Geology, geochemistry and zircon SHRIMP U–Pb geochronology of Mesoarchean high-Mg granitoids: constraints on petrogenesis, emplacement timing and deformation of the Água Limpa suite in the Carajás Province, SE Amazonian Craton

Determining the age, geochemical characteristics and conditions of deformation of Mesoarchean sanukitoids is crucial in unravelling the petrogenesis and tectonic significance of mantle-derived rocks. We report the whole-rock major and trace element contents, zircon U–Pb geochronology and geochemical modelling of samples from the Água Limpa sanukitoid suite in the Sapucaia subdomain (the Carajás Province, Amazonian Craton). This suite includes two plutons, named Água Limpa and Água Azul, which are exposed across east–west transpressive sinistral shear zones that act as boundaries between the Rio Maria and Carajás domains. These plutons are composed of porphyritic granodiorites, tonalites and subordinate monzogranites, with amphibole, biotite and epidote as the main mafic mineral components. They are characterized by high contents of Cr (102–383 ppm), Ni (32–117 ppm), MgO (2.50–4.78 wt%), Sr (477–912 ppm) and Ba (519–1966 ppm), with high Mg# values of 49–64. The rare earth element patterns show significant fractionation of the heavy rare earth elements, with high La N /Yb N (18–170) ratios and no or weak Eu anomalies (Eu/Eu* 0.66–1.21). The studied rocks are predominantly medium-K, calc-alkaline and metaluminous, and are geochemically distinct from tonalite–trondhjemite–granodiorites (TTGs) and Archean leucogranodiorites. The Água Limpa and Água Azul plutons yield coeval crystallization ages of 2870 ± 4 and 2872 ± 5 Ma, respectively, with other zircon population ages of 3063 ± 6, 2926 ± 12 and 2849 ± 12 Ma. The first of these other zircon populations is interpreted as xenocrysts, the second as crystals inherited from the modelled TTG-type source and the third as crystals reflecting the age of metamorphism. Most of the suite fractionated from a common mafic parent through 20% partial melting of a mantle previously enriched by 32% TTG-type melt in the garnet stability zone and under oxidized conditions. The combined dataset indicates that the studied sanukitoids are syntectonic intrusions, with distinct pulses of magma transfer facilitated by shear zone reactivation and subordinate small-scale dyking.

Petrogenesis of the > 2.90 Ga komatiite in the Sujiagou region of the North China Craton: Implications for Archean mantle source and geodynamic setting

Komatiite, characterized by high MgO content and low H2O concentration, is crucial to understanding the Archean magma processes and crust–mantle differentiation. Although well preserved in most cratons, Archean komatiites are scarce in the North China Craton (NCC). The Sujiagou komatiites, as the most typical Archean komatiites in China, were exposed in the Luxi terrane, but their geochronology and petrogenesis types remain controversial. In this study, our new Re–Os data indicate the Sujiagou komatiites originated before 2.90 Ga. The felsic zircons discovered in the komatiites, coupled with Nb–Th–La simulation, suggest ∼ 2 % crustal contamination of the komatiites. Thus, the least-altered, spinifex- and massive-texture samples that underwent unconspicuous crustal contamination were selected as proximate proxies for the primary magma composition. The Al/Ti ratios of the Sujiagou komatiites are comparable to or slightly exceed those of chondrite, suggesting they were aluminium-undepleted komatiites and formed at ∼ 8 GPa. The primitive mantle-normalized rare earth element (REE) patterns show depleted light REE and flat heavy REE, suggesting approximately 50 % partial melting based on REE simulation. Additionally, the komatiites exhibit slightly depleted Os isotope ratios, with an average γOs(t) value of -0.3, indicating the magma source is comparable to or slightly depleted to chondrite. Simulation of the relevant Nb/Zr and La/SmPM ratios further suggests the mantle source became slightly depleted due to ca. 1 % melt extraction. Furthermore, the Mg isotopic composition of the Sujiagou komatiites (δ26Mg = -0.23 ± 0.03 ‰) is consistent with that of the primitive mantle, indicating the absence of recycled carbonate material in the mantle source. Both Re–Os and Mg isotopes reveal limited involvement of crustal or carbonate material in the mantle source, implying the absence of oceanic slab subduction in the Luxi terrane during this time. The formation of the Sujiagou komatiites can be attributed to a hot mantle plume, resulting from high potential and eruption temperature. The identification of felsic zircons in the Sujiagou komatiites indicates the presence of an ancient continental nucleus in the Luxi terrane. Combined with the spatially adjacent terrigenous clastic sedimentary rocks, we suggest that the Sujiagou komatiites erupted most likely in a continental margin of the old terrane.

Origin of the Oligocene–Miocene Sailipu ultrapotassic volcanic rocks in southern Tibet: Melting of Asian mantle pyroxenites triggered by eastward tearing of the subducting Indian continental slab

Widely distributed Oligocene−Miocene ultrapotassic volcanic rocks in the Lhasa terrane of southern Tibet have been associated with the melting of the lithospheric mantle, plateau uplift, and porphyry Cu-Au mineralization. This study presents the mineral chemistry of olivine and clinopyroxene phenocrysts, whole-rock major and trace element data, and zircon U-Pb geochronological and Hf isotopic data for the Sailipu primitive ultrapotassic volcanic rocks. The Sailipu volcanic rocks exhibit high MgO (5.6−11.4 wt%), Cr (386−981 ppm), Co (22−43 ppm), and Ni (95−423 ppm) concentrations and have highly fractionated rare earth elements [REEs; (La/Yb)N = 23−73] and high-Fo (89.1−90.8) olivine phenocrysts containing elevated NiO (up to 0.59 wt%), which suggests a pyroxenitic mantle source that partially melted in the garnet stability field. Their high K2O contents (4.8−8.0 wt%) and global subduction sediment-like trace element patterns suggest that the metasomatic agents, which reacted with mantle peridotites to form phlogopite-bearing pyroxenites, were dominantly derived from the melting of subducted continental sediments. Their high whole-rock Ba/La and Th/Nd ratios are consistent with this hypothesis. The Sailipu ultrapotassic volcanic rocks also exhibit low initial 176Hf/177Hf ratios that resemble those of Himalayan leucogranites, and high Ca contents in olivine phenocrysts, which is consistent with contributions from the subducted carbonate-rich sedimentary strata on top of the thinned Greater Indian continental crust. The zircon U-Pb chronological data yielded concordant ages of 24.33 ± 0.19 Ma, 21.20 ± 0.62 Ma, and 17.05 ± 0.31 Ma for different exposures of the Sailipu volcanic rocks, which establishes a maximum age of ca. 24 Ma for these rocks. The northwest−southeast spatial distribution and the southeastward decrease in age (80°E−90°E) suggest west-to-east tearing of the thinned Greater Indian slab, which caused asthenospheric upwelling and melting of the Tibetan lithospheric mantle. Geothermometric calculations show relatively high primary magma temperatures (∼1250 °C) that are consistent with asthenospheric upwelling. We propose a mechanism that could genetically link the coeval Cu-Au ore-forming granitoids with the ultrapotassic magmatism of the Gangdese belt. The ultrapotassic rocks supply a large-volume of external magmatic volatiles, particularly H2O, which could trigger melting of the Tibetan lower crust and lead to the generation of the ore-forming granitoids and the establishment of oxidizing conditions for porphyry deposits. The oxygen fugacity (log ƒO2 values of ΔFMQ) of the primitive Sailipu ultrapotassic volcanic rocks (ΔFMQ = 0.48 ± 0.51 based on the Dol/melt V oxybarometer and ΔFMQ = 0.33 ± 1.19 according to the magmatic zircon U-Ce-Ti oxybarometer) is slightly lower than that of porphyry Cu-Au ore-forming granitoids in the eastern Gangdese (ΔFMQ = +0.8 to +2.9), which suggests that the direct injection of ultrapotassic melts into ore-forming granitoids played a limited role in changing oxygen fugacity, but more oxidized fluids/volatiles exsolved from these ultrapotassic melts may have facilitated the remelting of sulfide-bearing lower crust and/or directly scavenged sulfides from the mush-state reservoirs of the ore-forming granitoids in the middle−upper crust.

Petrogenesis and tectonic setting of the proto-tethyan dachaidan ophiolite, North China: insights from clinopyroxene chemistry and whole-rock Sr–Nd–Pb and zircon Hf isotopes

IntroductionThe Dachaidan ophiolites outcrop within an ultrahigh-pressure metamorphic belt along the northern margin of the Qaidam Basin. However, their age, source, and tectonic setting remain still in debate.MethodIn this study, we investigated the geochemistry and geochronology of the Dachaidan ophiolitic gabbros.Results and DiscussionZircon U–Pb dating yielded a crystallization age of 510.0 ± 2.8 Ma and 510.0 ± 2.9 Ma for the gabbro. The gabbros have low SiO2 contents (47.15–50.10 wt.%) and high MgO contents (6.35–9.04 wt.%) and Mg# values (55–74). The total rare earth element (∑REE) contents are 8.35–28.07 ppm, lower than those of normal-type mid-ocean ridge basalts (MORBs), and the gabbros exhibit light REE depletion or flat REE patterns, with small positive Eu anomalies (Eu/Eu* = 1.06–1.40). Trace element patterns are depleted to enriched in Nb and Ta, similar to island arc rocks and MORB. Clinopyroxene thermobarometry indicates the parental magma of the gabbros formed by high-temperature (1,318°C–1,363°C) and medium-pressure (1.27–1.64 GPa) partial melting in a mantle wedge. The gabbros have depleted Sr–Nd–Pb-Hf isotopic compositions, with (87Sr/86Sr)i = 0.704586–0.707441, εNd(t) = 4.7–6.6, and zircon εHf(t) = 7.6–11.4. The age-corrected Pb isotope ratios of these volcanic rocks are variable, with 206Pb/204Pb(t) = 18.085–18.253, 207Pb/204Pb(t) = 15.595–15.614, and 208Pb/204Pb(t) = 37.880–38.148, which are similar to the isotopic compositions of typical Indian MORBs. The source of the Dachaidan ophiolite is inferred to have been depleted mantle. The Dachaidan ophiolite likely formed in a forearc oceanic setting along the northern margin of the Qaidam Basin, during the initial subduction of an oceanic plate.

Petrogenesis and an Evaluation of the Melting Conditions of the Late Permian ELIP Picrites, SW China: Constraints Due to Primary Magma and Olivine Composition

The late Permian Emeishan large igneous province (ELIP) in SW China is a melting product of the Emeishan mantle plume. Recently, it has been debated whether peridotite or pyroxenite is the dominant lithology of the mantle source in the ELIP. To address this, systematic analyses of bulk-rock and coexisting spinel and olivine compositions were conducted on picrites from Lijiang–Yongsheng, Dali–Binchuan, Yumen, Muli, and Ertan. The ELIP picrites exhibit positive TiO2–CaO and negative MgO–CaO correlations, as well as low FC3MS values (−0.24–0.1), supporting a peridotite-dominated mantle source. This lithology of the mantle source is also supported by the high 100 × Mn–Fe (1.43–1.73) and Mn–Zn (13.6–18.4) values but low 10,000 × Zn–Fe (8.0–12.7) ratios of the olivine phenocrysts. The estimated mantle potential temperature for Lijiang, Yongsheng, Yumen–Ertan, Muli, and Dali–Binchuan picrites decreased away from Lijiang and Yongsheng, suggesting that the Lijiang and Yongsheng areas were the center of the ELIP. The Lijiang–Yongsheng primary magma shows similar SiO2 content but lower Al2O3 contents (average of 8.24 wt.%) and higher MgO contents (average of 21.42 wt.%) than those of Dali–Binchuan primary magma (Al2O3: 9.86 wt.%; MgO: 19.02 wt.%). Also considering the high Gd–Yb (average of 3.05) and La–Yb (average of 14.61) ratios and mantle potential temperature (average of 1599 °C), we proposed that Lijiang–Yongsheng lavas are produced via the melting of a garnet–peridotitic mantle. In contrast, the Dali–Binchuan lavas with low Gd–Yb (average of 1.91) and La–Yb (average of 5.88) ratios can be explained by their formation in the garnet–spinel transition zone of a peridotitic mantle. The Yumen–Ertan primary magma displays similar mantle potential temperature (average of 1600 °C), Al2O3 and FeO content, and Gd–Yb ratios to those of Lijiang–Yongsheng lavas, indicating that YumenvErtan primary magma may be attributed to the partial melting of garnet with minor peridotite. Therefore, heterogeneous plume-head mantle sources lead to the evaluation of melting conditions of the late Permian ELIP picrites.

Geochemistry and conditions of formation of Mesoarchean banded iron formations (BIF-1) from the Kostomuksha Greenstone belt, Karelian Craton

Three variably old groups of banded iron formation (BIF) are known in the Kostomuksha Greenstone belt (KGB) of the Karelian Craton. This paper deals with the earliest of them, Mesoarchean (2.87–2.81 Ga) – BIF-1. BIF-1 occurs among the komatiite-basalt unit of the KGB. BIF-1 consists mainly of quartz and magnetite, with varying amounts of amphibole, biotite, and garnet; they contain 48.3-58.6 SiO2 and 21.34–33.82 wt. %, Fe2O3T, suggesting that the rocks are BIF. BIF-1 of the KGB, as well as most Archean BIFs, contain high Fe2O3T, concentration, display a contrasting positive Eu anomaly, lost of Ce anomaly, the depletion of LREE relative to HREE. However, they stand out among other BIFs with high Al2O3, TiO2, MgO, K2O, Cr, Ni, Zr, Ba, Cu and Zn concentrations. BIF-1 was formed in a marine basin in an anoxic atmosphere due to hydrothermal fluids, the proportion of which varies from 20 to 80 %, and a terrigenous component derived mainly from basalts, komatiites, and dacites in host rocks. Mesoarchean BIF-1 of the KGB s was formed in a small rift within an oceanic volcanic plateau, the formation of which is associated with the influence of a mantle plume on the oceanic lithosphere.

1.38 Ga magmatism and the extension tectonics in East Kunlun, northern Tibetan Plateau

Numerous Paleo- to Mesoproterozoic magmatic rocks were emplaced during the assembly, accretion and break-up of the Columbia supercontinent, and are keys to illustrating the supercontinent circle. The geological, petrological, geochronological and geochemical data of the newly discovered meta-felsic and meta-mafic magmatic rocks from the Wulonggou area are presented in this study to shed light on the Mesoproterozoic geodynamic setting of the Central Kunlun Belt and the Qaidam Block. Zircon U-Pb geochronological results indicate that the crystallization ages of the meta-felsic samples are 1385–1376 Ma, and the meta-mafic is 1379 ± 25 Ma (MSWD=0.17). Samples from the meta-felsic unit have SiO2 contents of 68.37–73.03 wt% and belong to the high-K calc-alkaline series. They exhibit similar REE distribution patterns and display enrichment in light rare earth elements (LREES) and negative Eu anomalies. Enrichments in Rb, Ba, Th, U and K, depletion in Nb, Ta, Sr, P and Ti are seen in the primitive mantle-normalized trace element pattern diagram. Magmatic zircons from different meta-felsic samples yield variable εHf(t) values of −8.14 to + 9.37 corresponding to ca. 1.7–2.0 Ga two-stage Hf model ages. Samples from the meta-mafic unit have low SiO2 concentrations of 49.87–50.43 wt%, high contents of Fe2O3T, MgO, CaO and TiO2, and Mg# values of 52–58. They show low total REE concentrations of 19.8–30.4 µg/g, and depletion in LREES, flat HREES distribution patterns with (La/Yb)N of 0.27–0.53 and insignificant Eu anomalies. Flat distribution pattern of high field strength elements (HFSEs) is observed in the primitive mantle-normalized trace element pattern diagram. They display similar immobile elements’ concentrations and distribution patterns, low Ti/Y, Nb/Y, La/Yb, and high Nb/La ratios, comparable with the present-day normal middle ocean ridge basalt. Zircons from the meta-mafic sample have mostly positive εHf(t) values ranging from −0.10 to + 4.10 with a single stage Hf model ages of ca. 1.7–2.0 Ga. The geochemical result implies that the meta-felsic unit was generated by partial melting of the Paleoproterozoic juvenile mafic lower-crustal material with mantle attributions, and the meta-mafic unit was probably from partial melting of the lithospheric mantle. Synthesizing the above evidences, Wulonggou Mesoproterozoic meta-magmatic rocks are a bimodal suite formed in a continental extensional tectonic setting which is probably related to the break-up of the Columbia supercontinent.

A comprehensive evaluation of crumb rubber modified asphalt-aggregate interfacial behavior and the effect of water: Molecular dynamics simulation and experimental investigation

The incorporation of crumb rubber (CR) makes the asphalt-aggregate interfacial properties highly complex and uncertain, while water is a key environmental factor causing interfacial failure. This paper aims to evaluate the characteristics of crumb rubber modified asphalt (CRMA)-aggregate interaction and the interfacial failure mechanism under the influence of different material properties and water at ambient temperature. Firstly, the CRMA-aggregate interfacial behavior before and after water intrusion is investigated using molecular dynamics simulations at the molecular scale. Next, the failure process and characteristics of the CRMA-aggregate interface were analyzed using the disk-shaped compact tension (DCT) test at the macro scale. Finally, the effect of water intrusion on the interface failure mode was analyzed through image processing. The results show that CR enhances binder cohesion and significantly affects its adhesion to aggregates with high CaO and MgO contents regardless of the presence of water. The asphalt concentration distribution on the CaO and MgO surfaces is more concentrated with higher peak concentration, leading to superior interfacial adhesion and water damage resistance with binder, while Al2O3 and SiO2 were inferior. The use of asphalt with higher creep stiffness, high-strength alkaline aggregates, and smaller CR particle size is beneficial for enhancing the CRMA binder-aggregate interfacial fracture performance. Water intrusion severely affected the interfacial adhesion, resulting in a significant increase in the proportion of adhesion failure, which is the main cause of the deterioration of the interface properties. The findings of this study provide insights into the factors affecting the CRMA-aggregate interfacial behavior, which facilitate the accurate design and application of high-strength durable CRMA mixtures.

Pre-eruptive magmatic processes at Taranaki volcano from an amphibole perspective

Amphibole phenocrysts in post-1 ka lava domes deposits of Taranaki volcano, an andesite arc volcano in New Zealand, provide an opportunity to explore late-stage changes in melt composition and volatiles in the run up to eruption. Amphibole is a subordinate phase (0–7% of modal phenocrysts) and the phenocrysts display three types of growth history. Type 1 are large compositionally and texturally uniform phenocrysts that have low MgO (<13 wt%) and high K2O (∼1–1.4 wt%) contents. In contrast, Type 2 have similar cores but have been partially resorbed and overgrown by a mafic rim distinguished by high MgO (up to 15 wt%) and low K2O (<1.0 wt%) contents. Type 3 are the least common, and have either normal zoned or concentrically zoned interiors with respect to MgO and FeO. Overall, elemental substitutions and zonation patterns are related to periods of resorption and regrowth that are best explained by changes in melt composition. Based on calculated equilibrium melt compositions, the amphibole crystallisation is consistent with an incrementally grown andesitic to dacitic (SiO2 58–67 wt%) crystal mush that was periodically recharged with more mafic magma (SiO2 ∼ 55 wt%). The melts span a compositional gap (SiO2 ∼ 60–65 wt%) that is not represented in eruption products from the last 8 ka. Such melts were likely brief stages during ongoing fractional crystallisation and magma mixing. Each recharge event disrupted an evolving system and mixed crystals from different parts of it. This concept supports triggering of eruptions by recharge of mafic melts, as also inferred from plagioclase zonation for some eruptions from Taranaki. The outermost rims (0–5 μm) of many amphibole phenocrysts are enriched in fluorine (up to 1.9 wt%) and surrounded by a thick opacitic decomposition growths. We interpret this as the result of slow magmatic ascent and extensive crystallisation that produced a late-stage halogen-rich interstitial melt. This likely extended the conditions for amphibole stability to lower pressure. If F enrichment was accompanied by comparable enrichments in other halogens that preferentially partition into an aqueous phase, then extensive degassing would have occurred during the dome extrusions.

New data and insights on the secondary glass workshop of Comacchio (Italy): MgO contents, steatite crucibles and alternatives to recycling

This study introduces a collection of 33 glass samples, encompassing production indicators (blocks, fluidity tests, drops, cuts and wastes) and finished products (mainly goblets and probably a lamp) dating to the second half of the 7th century, except for a single more recent specimen (12th-14th). Additionally, a fragment was taken from a crucible bearing a thin layer of glass inside it. This new collection complements the investigation of glass materials from the Comacchio workshop previously analysed by Bertini et al. (2020).Measurements were performed using scanning electron microscopy, electron microprobe, laser ablation inductively coupled plasma mass spectroscopy on all samples and Sr–Nd isotopic analyses on 5 blocks.The results showed how the entire collection can be classified as natron-based silica-soda-lime glass and that the high MgO contents frequently observed are due to contamination with the steatite crucible. Contextually, the hypothesis of using plant ash-based glass mixed with natron-based glass formulated in the previous literature seems to have run out, along with the use of plant ash-based glass itself, further weakened by the very low representativeness of this latter type of glass on the site.The technological investigation further elucidated that recycling may not singularly account for the Comacchio glass technology. Discernible correlations may suggest the introduction of different types of metals, indicating a specialised control over the production process. Notably, the preference for green–blue glass emerges as a distinctive hallmark, underscoring the deliberate pursuit of a specific aesthetic taste.Lastly, the provenance analysis showed that over three-quarters of production was based on semi-finished products from Egypt, while only the remaining quarter came from the Levantine coast.

Early Jurassic A-type granite and monzodiorite from the Baoji batholith: Implication for tectonic transition from post-collision to post-orogenic extension in the Qinling Orogenic Belt, China

Introduction: The early Jurassic granitoids in the Qinling Orogenic Belt (QOB) play a crucial role in understanding the tectonic implications for the geological evolution of China. To elucidate the early Jurassic tectonic setting of QOB, we performed a comprehensive analysis of zircon U-Pb ages, whole-rock geochemistry, and in situ zircon Lu-Hf isotopes from early Jurassic monzodiorite and Kfeldspar granite within the Baoji batholith in western QOB.Geochronology Method and Results: The intrusions yielded zircon U-Pb ages of 186 ± 2 Ma and 188 ± 2 Ma, respectively.Geochemistry Results: The monzodiorites are characterized by relatively high MgO, Rb, Th, U, and LREE contents, as well as low P, Ti, and HREE contents. They also exhibit high Nb/Ta ratios (20.6–23.4). The zircon εHf(t) values for the monzodiorite sample range from −4.36 to 6.47, indicating significant contributions from a fertile continental lithospheric mantle with the involvement of crustal components. The K-feldspar granites are enriched in K2O+ Na2O, Rb, Zr, Hf, and Nb, and lower Ba, Sr, Ti, and P. They exhibit high Nb/Ta and Ga/Al ratios but low Y/Nb and Yb/Ta ratios. Their geochemical characteristics reveal an A-type granite affinity with elevated zircon saturation temperatures (848°C–900 °C). Additionally, the K-feldspar granite exhibits REE and trace element patterns similar to those observed in the monzodiorite. However, a wide range of zircon εHf(t) values (−4.72 to 3.98), differing from those of the monzodiorite, indicate that the parental magma of the K-feldspar granite experienced magma mixing between a monzodioritic magma and a crustal-derived felsic magma.Discussion: These findings suggest that both A-type K-feldspar granite and monzodiorite likely formed during post-orogenic processes. Additionally, the QOB commenced its postorogenic evolution as an extensional tectonic environment during the early Jurassic period.

Effect of MgO content and CaO/Al2O3 ratio on melting temperature and viscosity of CaF2–CaO–Al2O3–MgO slag for electroslag remelting

During electroslag remelting (ESR), high MgO contents are typically added to CaF2–CaO–Al2O3 slag to control magnesium content in iron- and nickel-based alloys. The melting temperature and viscosity of ESR slag are pivotal for energy consumption, production efficiency, smooth operation, and ingot quality. However, there is currently a notable scarcity of research on the melting temperature and viscosity of CaF2–CaO–Al2O3–MgO slag with high MgO levels. Thus, the melting temperatures and viscosity of CaF2–CaO–Al2O3–MgO slags with varying MgO contents and CaO/Al2O3 (C/A) ratios were investigated. The results show that as the MgO content increases from 7.83 % to 13.18 %, the final precipitation content of the MgO phase significantly increases, resulting in an increase in the melting temperature from 1306 °C to 1319 °C. With the increase in the C/A ratio from 0.86 to 1.16, the precipitation completion temperatures of the Ca12Al14F2O32 and MgO phases significantly decrease and the MgAl2O4 phase transforms into the CaO phase. Hence, the melting temperature decreases from 1329 °C to 1314 °C. Further increasing the C/A ratio to 1.40, the final precipitation content of the CaO phase increases, resulting in a decrease in the melting temperature from 1314 °C to 1282 °C. Moreover, as the MgO content and C/A ratio increase, the slag viscosity exhibits different change trends within various temperature ranges. This depends on which of the depolymerization of the slag structure and the precipitation and clustering of the MgO phase has a greater effect on the slag viscosity.

Physical and chemical properties of CaF2−CaO−Al2O3−MgO slag for electroslag remelting of Mg-containing GH3128 superalloy

During electroslag remelting, Mg in the electrode reacts with some components in the slag, resulting in its serve oxidation loss. The CaF2−CaO−Al2O3−MgO slags with high MgO content are generally used for remelting Mg-containing Fe- and Ni-based alloys. However, there is a scarcity of foundational data available on the physical and chemical properties of the slags, posing a challenge in developing a suitable slag for remelting Mg-containing GH3128 superalloy. Hence, this paper conducted a comprehensive study on the melting temperature, viscosity, and reactivity of four known slags. The results show that D2 slag (50%CaF2–20%CaO–20%Al2O3–10%MgO) has the lowest melting temperature of 1588 K due to containing fewer high-melting-point phases and possesses lower viscosity because of simpler aluminate structures. Additionally, the D2 slag has the highest activity ratio, enabling the superalloy to achieve the highest equilibrium Mg content of 0.0174%. The D2 slag exhibits a heightened MgO activity and facilitates the release of more Mg2+ ions, thereby exerting a pronounced inhibitory effect on the diffusion of Mg2+ ions from the slag–metal interface to the slag. The superalloy attains a highest Mg yield of about 30%. Therefore, the D2 slag emerges as the most suitable choice for remelting the Mg-containing GH3128 superalloy.

Investigation of Slagging-Fouling and Mineral Contents in Low-Rank Coals for Improved Combustion Performance

ABSTRACT Despite the problems associated with low-rank coal, this type of coal is still widely used in various applications including the power generation sector. In this study, three low-rank coals (LRC) with high mineral content of SiO2, Al2O3, and MgO were selected and comprehensively investigated. Investigations include ash fusion temperature (AFT), theoretical calculation, combustion experiment with drop tube furnace (DTF), and ash analysis using scanning electron microscope (SEM) and x-ray diffraction (XRD). The investigation revealed that T-Coal with high SiO2 and P-Coal with high Al2O3 mineral produce ash deposition which did not adhere on the probe surface of either slagging or fouling area. T-Coal ash consists of fine and solid particles, but the presence of the dominant albite mineral, 29.09% in slagging probe and 28.71% in fouling probe, may have a negative impact on ash deposition. P-Coal ash is dominated by fine particles with a predominance of quartz and other high-melting minerals. A-Coal with high MgO mineral has good results in slagging aspects. However, the high Fe2O3 on A-Coal results in low ash fusion and produces more hematite mineral (17.70%) in the fouling probe. This study shows that several types of LRC have good evaluation on ash-related problems which potentially can be used as coal blending for further utilization in power generation.

Petrogenesis of K-rich and high-mg adakitic rocks in the North Dabie terrane, China: products of early cretaceous orogenic collapse

ABSTRACT Understanding orogenic collapse is key to comprehending the evolution of continental collision orogens. The Dabie orogen is a collapsed continental collision orogen that provides an ideal window for revealing orogenic collapse. Here, we conduct fieldwork, whole-rock geochemistry, and zircon U-Pb dating of the Daoshichong pluton in the North Dabie terrane to elucidate the collapse mechanism of the Dabie orogen. The Daoshichong pluton is composed of quartz monzodiorite and mafic microgranular enclaves (MMEs) with an Early Cretaceous (~130 Ma) crystallization age. The Daoshichong pluton is strongly deformed and ductile, displaying a gneissic structure. The quartz monzodiorites are K-rich and high-Mg adakitic rocks. They contain 60.2–63.3 wt.% SiO2 and have high K2O (2.88–3.42 wt.%) and MgO (2.08–3.04 wt.%) contents with relatively high Mg# values (44.4–49.3). They exhibit high Sr (673–819 ppm) and low Y (11.4–20.9 ppm) and heavy rare earth elements (e.g. Yb: 0.94–1.87 ppm) contents, resulting in high Sr/Y (35.1–72.0) and (La/Yb)N (15.7–36.1) ratios. The MMEs exhibit geochemical characteristics similar to those of the Early Cretaceous mafic – ultramafic rocks of the Dabie orogen. They have low SiO2 contents (48.1–51.9 wt.%) and high MgO contents (3.27–5.62 wt.%) with high Mg# values (47.3–51.2). They also exhibit relatively high Ni (16.6–63.6 ppm), Cr (30.5–164.6 ppm), Y (18.2–25.8 ppm) and Yb (1.50–1.94 ppm) contents and high Sr/Y ratios (53.7–109.5). Evidence from fieldwork and geochemistry distinctly indicates magma mixing during magma evolution between the MMEs and the quartz monzodioritic host. Thus, the Daoshichong quartz monzodioritic host and the MMEs can be interpreted as a mixture of mantle-derived magma and over-thickened lower continental crust-derived adakitic melt. Previous studies suggest that the Early Cretaceous (~130 Ma) high-Mg adakite-like rocks are distributed only along the eastern margin of the Dabie orogen (i.e. along the Tan – Lu Fault). This study is the first to report a homochronous (~130 Ma) K-rich and high-Mg adakite-like pluton in the core of the Dabie orogen. Our results suggest that a whole delamination of the over-thickened orogenic root caused the orogenic collapse, subsequently triggering crust – mantle interactions, dome structure, and magmatism in the Dabie orogen.