Zircon Hf Isotope Research Articles

Petrogenesis of 2.7–2.65 Ga TTGs in the Wutai Complex: Constraints on the Neoarchean crustal evolution of the North China Craton

The Wutai complex, located on the boundary between the Eastern and Western Blocks of the North China Craton (NCC), offers valuable insight into early crustal growth and evolution of the NCC. In this study, a suite of 2.7–2.65 Ga TTG gneisses has been identified in the Wutai complex. Zircon grains from eight samples indicate that their protoliths were emplaced between 2706 Ma and 2640 Ma. The trondhjemites have low K2O/Na2O, high La/Yb and Sr/Y ratios, and positive Eu anomalies. The observed trend of decreasing Dy/Yb and Dy/Dy* ratios with increasing La/Yb ratios support for an amphibole-dominated fractional crystallization process during the TTG formation. Zircon Hf and oxygen isotope analyses (εHf(t) = 3.5–7.0, TDM = 2.86–2.71 Ga; δ18O = 5.5–6.3 ‰) indicate that the parental magma may originate from juvenile crustal sources altered by surface water at low temperature. When combined with the previous studies of volcanic rocks and TTGs formed around 2.5 Ga, it becomes evident that the Wutai complex experienced significant crustal growth during the period from 2.7 to 2.5 Ga. The identification of 2.7–2.65 Ga magmatic activity as well as the older detrital/xenocryst zircons up to 3.6 Ga, provide increasing evidence that the Wutai complex has a much longer and nearly continuous geological history. Combined with geological evidence, zircon data compilations and the Re-depletion model age distribution of the mantle xenoliths of the NCC, it can be inferred that the period from 2.6 to 2.5 Ga was likely the most significant for the crustal generation within the NCC's geological history.

Zircon U-Pb-Hf Isotopes and Whole-Rock Geochemistry of the “Kulumudi Formation” from the Laofengkou Area (West Junggar): Implications of the Construction of a Juvenile Arc in the Junggar–Balkhash Ocean

The properties of ancient magmatic arcs are crucial for understanding the tectonic evolution of the Central Asian Orogenic Belt. The Middle Devonian Kulumudi Formation in the Laofengkou area of West Junggar lacks accurate chronological data constraints, which hampers the knowledge of the nature of the Late Paleozoic magmatic arcs in the West Junggar and circum-Balkhash areas. In this contribution, samples of pyroclastic rocks and sedimentary rocks were collected from the volcano–sedimentary strata of the Kulumudi Formation. Petrography, zircon U-Pb-Hf isotopic analysis and whole-rock geochemistry were carried out to constrain the age and the tectonic setting of the Kulumudi Formation. The zircon U-Pb age of the lithic crystal tuff from the Kulumudi Formation on the northeast side of the Alemale Mountains was 386 ± 2 Ma, accurately indicating that this rock unit formed during the Middle Devonian. However, the fine sandstone near the Huojierte Mongolian Township, originally assigned as the “Kulumudi Formation”, yielded a maximum depositional age of 341 ± 3 Ma. Combined with the stratigraphic contact, this rock unit was redefined to belong to the Lower Carboniferous Jiangbasitao Formation. According to the whole-rock geochemistry study, the lithic crystal tuff of the Kulumudi Formation was characterized as medium potassium–calc–alkaline series rock, which is relatively enriched in light rare earth elements and large ion lithophile elements (i.e., Rb, Ba, K) and depleted in high-field-strength elements (i.e., Nb, Ta, Ti), showing similar geochemical characteristics to the volcanic arc rocks. By contrast, the fine sandstone from the Jiangbasitao Formation had Al2O3/SiO2 (0.25–0.29) and K2O/Na2O (1.29–1.72) ratios close to those derived from the continental arc and active continental margin and was characterized as part of the continental arc field in the La-Th-Sc and Th-Sc-Zr/10 tectonic discrimination diagrams. Zircon Hf isotope analysis showed that the εHf(t) values of the Kulumudi Formation were +5.6–+12.8, and those of the Jiangbasitao Formation were +11.43–+15.48, both of which show highly positive juvenile characteristics. The above data indicate that the Kulumudi Formation and Jiangbasitao Formation both formed in a juvenile arc setting with ocean–continent subduction. Combined with the previous work, it was concluded that the southward subduction of the ocean basin represented by the Darbut–Karamay ophiolitic mélanges beneath the newly accreted arc crustal segments produced a juvenile arc with positive Hf isotope characteristics.

New early Oligocene age for the Mouding Basin, Southwestern China: Source and paleoenvironment

Sedimentary basins in the southeastern margin of the Tibetan Plateau yield valuable geophysical and fossil records, documenting the paleoenvironmental and biodiversity changes in the Tibetan Plateau and the Hengduan Mountains. Constraining the age of sediment deposition is fundamental in understanding the evolutionary history of biodiversity, climate (e.g. development of the monsoon), and regional landscape changes. Many basins in this area were originally considered as Miocene basins based on regional lithostratigraphic comparison and biostratigraphy, although this has been challenged recently for several basins (e.g. Lühe, Markma, Jianchuan, Wenshan and Relu basins). Here we report a new age for the Mouding Basin, Central Yunnan, China. We arrive at an early Oligocene (33 ± 1 Ma) instead of a Miocene age for the fossil-bearing strata of this basin. UPb and 40Ar/39Ar dating of a volcanic ash layer from the Mouding Basin and one from the Lühe Basin in combination with zircon Hf isotope data suggest that the early Oligocene Laojiezi eruption is a likely source for ash layers in both basins. Fossilized dicot leaves were used to reconstruct the paleoclimate and the paleo-elevation of the Mouding Basin. This paleoclimate reconstruction indicates that the paleoclimate in the Mouding Basin closely resembles that of the Lühe Basin. The paleoclimate between the two floras is in fact more similar than their respective modern climates. During the early Oligocene, the Mouding Basin experienced colder and more humid winters with a milder monsoonal climate compared to today. Despite this, the Mouding flora exhibits high floristic similarities with its contemporary Lühe and Markam floras, as well as with the modern vegetation in southwestern China, supporting that the modernization of the biodiversity in the SE margin of the Tibetan Plateau has initiated since the Paleogene.

Paleocene oceanic-island basalt−type magmatism in the Lhasa Block attests to decoupled mantle-crust deformation during Indian-Asian collision

The post-collisional evolution of the Tibetan lithosphere is of paramount significance to our understanding of collisional orogeny. It is generally postulated that the Lhasa lithospheric mantle was horizontally shortened and thickened coherently with the overlying crust to form a physical barrier, preventing Indian subduction beneath Tibet until the thickened mantle root was foundered during the Miocene. This study first identifies post-collisional oceanic-island basalt (OIB)-type magmatism in the Lhasa Block (LB), as attested by zircon U-Pb age (ca. 58 Ma) and geochemistry—positive Nb-Ta anomalies, high La/Yb, and depleted bulk-rock Sr-Nd and zircon Hf isotopes, of diabase in the northern (inboard relative to Indus Suture) part of this block. Coupled with extensive early Paleogene arc-type magmatism in the southern-central LB and thermodynamic modeling, we suggest that these diabases were formed by partially molten upwelling asthenosphere near the base of continental crust, where much of the underlying lithospheric mantle had been removed due to Neo-Tethyan slab rollback and lithospheric delamination. Compared to OIB-type magmatism worldwide, the diabases investigated here were emplaced peculiarly in a region where the continental crust was under horizontal compression and shortening by coeval thrusting. Our study thus implies a decoupled deformation between the crust and mantle of the LB during the early Indian-Asian collision.

Chronological and Mineralogical Records of the Langqi Pluton, Fuzhou: Constraints on the Magma Mixing Process

The mafic microgranular enclaves (MMEs) from Mesozoic intermediate-acid magmatic rocks, widely developed along the Fujian coast, are considered to be the results of large-scale crust–mantle interaction by magma mixing. This paper is based on zircon U-Pb chronology, along with zircon Hf isotope and mineral analyses for the host granite and MMEs from Langqi Island, in order to investigate the magma mixing mechanism of the Langqi pluton in Fuzhou, Southeast China. The results indicate that the MMEs were emplaced during the late Early Cretaceous (98.9 ± 2.2 Ma), identical to the age of the granite (100.1 ± 1.1 Ma) within the error range. The zircon εHf(t) values for the granite and MMEs are in the ranges of −2.1~0.0 and −1.7~+1.1. The zircon Hf isotope data indicate that both the granite and MMEs were predominantly derived from the ancient crustal basement of Cathaysia, with a partial mantle-derived contribution. The An values of plagioclase phenocrysts with oscillatory zoning patterns in the MMEs show oscillatory changes from the core to the rim, indicating multiple mixing events between the two magmas with different compositions. Amphiboles in the MMEs show characteristics of crust–mantle contamination, and the Ti migrated from the mafic magma with high concentration to the felsic magma with low concentration during the magma mixing process. Biotites in the host rock and MMEs belong to primary biotite, and they have relatively high MgO contents (ave. 12.78 wt.%) and relatively low FeOT/(MgO + FeOT) ratios (ave. 0.56), showing characteristics of crust–mantle contamination. The crust–mantle magma interaction in a crystal, mushy state played a significant role in controlling the formation and evolution of the Langqi pluton. The magmatism was predominantly sourced from mixing between the mantle-derived mafic magma and the crust-derived felsic magma during the subduction of the Paleo-Pacific Plate, resulting in the formation of the Langqi doleritic veins, granites, and MMEs.

Petrogenesis and Tectonic Setting of Early Cretaceous A-Type Granite from the Southern Great Xing’an Range, Northeastern China: Geochronological, Geochemical, and Hf Isotopic Evidence

The southern Great Xing’an Range is located in the eastern Central Asian Orogenic Belt, where voluminous igneous rocks developed during the Late Mesozoic period. The east slope of the southern Great Xing’an Range has been the topic of numerous debates on the level of influence of the Mongol-Okhotsk and the Paleo-Pacific regimes in the Late Mesozoic period. Therefore, this area is a suitable region in which to study the temporal changes in magma sources and tectono-magmatic evolution. In this paper, whole-rock geochemical data, zircon U-Pb geochronology, and zircon Hf isotope studies were carried out on the granitoids in the east slope area of the southern Great Xing’an Range. LA-ICP-MS zircon U-Pb dating revealed the ages of four granitoid samples: 135.0 ± 0.6 Ma, 130.7 ± 1.4 Ma, 130.4 ± 1.0 Ma, and 127.6 ± 0.8 Ma, respectively. The Hf isotope values 176Hf/177Hf = 0.282751–0.283015, εHf (t) = +2.0~+11.5, and T2DM = 583~1442 Ma suggest that the magma was generated by partial melting of Meso- and Neoproterozoic accreted and thickened low crust. The whole-rock geochemical data implied that these granitoids are A-type granite and their formation is closely linked to the subduction of the Paleo-Pacific Ocean plate. These geochemical, isotopic, and geochronological data suggest that the Early Cretaceous magmatism in the east slope area of the southern Great Xing’an Range formed in an extensional back-arc tectonic setting associated with the slab roll-back of the Paleo-Pacific plate subduction.

Late Neoarchean plume-induced crust-mantle interaction and crustal reworking: Evidence from the Jianping Complex, North China Craton

The Archean basement of the North China Craton (NCC) is predominantly composed of 2.6–2.5 Ga lithological assemblages, while the tectonic regime that governed the formation and evolution of these Neoarchean basement rocks has been a controversial issue. Based on field relationships, petrographical features, whole-rock chemistry and zircon Hf isotope data, diverse late Neoarchean granitoids exposed in the Jianping Complex of the NCC are categorized into TTGs, sanukitoids and potassic granites. Their petrogenesis are associated with partial melting of metabasalts, melting of metasomatized mantle, and melting of crustal lithologies including tonalite and metasediments, respectively. Zircon U-Pb results suggest that different types of Neoarchean granitoids in the Jianping Complex are nearly coeval with crystallization ages of ∼ 2.54–2.52 Ga and metamorphic ages of ∼ 2.49–2.48 Ga. New Hf isotopic data reveal that these granitoids show positive εHf(t) values, with the tonalitic gneisses of εHf(t) values closer to the depleted mantle than those of granodioritic gneiss, sanukitoids and potassic granite. This result reflects potentially more enriched source for other granitoids than the tonalitic gneisses, which is linked with increasing level of crustal-mantle interaction and crustal reworking the late Neoarchean. Integrating other evidence from geochemical, structural and metamorphic studies, it is inferred that the plume activities play an important role in the emplacement of late Neoarchean granitoids in the Jianping Complex, with TTGs formed through the partial melting of juvenile crust induced by plume activity, sanukitoids produced from melting of metasomatized mantle resulted from sagduction process, and potassic granites formed by reworking of earlier crustal lithology caused by sustained underplating of mantle material. Overall, we interpreted that the late Neoarchean crustal growth and crustal-mantle interaction in the Jianping Complex can be attributed to upwelling of mantle plume and potential sagduction process in a vertical tectonic regime.

Subduction initiation of Paleo-Pacific Ocean and final closure of Paleo-Asian Ocean: constraints from Triassic granitoids in Jiamusi Block, NE China

ABSTRACT The process of transformation and superposition from the Paleo-Asian Ocean to the Paleo-Pacific Ocean tectonic systems have been a critical scientific issue. However, the final closure of the Paleo-Asian Ocean and the initial subduction time of the Paleo-Pacific Ocean, together with the conversion between them in Northeast China, still remain controversial. The Triassic granites in the Jiamusi Block are located in the key position of Northeast China, recording the conversion process of two tectonic domains. Through systematic geochronology and geochemical studies, it can provide important constraints for revealing the superposition and conversion mechanism of the Paleo-Asian Ocean and the Paleo-Pacific Ocean and the early subduction history of the Paleo-Pacific Ocean plate. In this study, the granites in Jiamusi Block were formed in the Early–Middle Triassic (250–245 Ma), characterized by high Si, rich alkali, poor Mg, and are obviously enriched in light rare earth elements and large ion lithophile elements, depleting in high field strength elements such as Nb, Ta, and Ti. They have typical characteristics of continental magmatic arc, deriving from partial melting of amphibolite facies and garnet amphibolite facies mafic lower crust. Combined with zircon Hf isotope results, zircon εHf(t) values are −6.52 to + 9.79, and the two-stage Hf model ages are 0.6–1.7 Ga, indicating that the magma should be derived from a relative younger crustal source, and some ancient materials may be added. Moreover, based on the spatial-temporal framework and Hf isotope characteristics of magmatism in Northeast China, we believe that the Jiamusi Block belonged to an exotic block. Meanwhile, combined with geochronological and geochemical data of igneous rocks on the Jiamusi Block, we suggest that the evolution of Jiamusi Block was dominated by the Paleo-Pacific Ocean rather than Paleo-Asian Ocean during the Triassic, which means the subduction of Paleo-Pacific Ocean plate initiated at least in Early Triassic.

Paleoproterozoic crustal evolution of the Tarim Craton, NW China: Constraints from geochronology and geochemistry of orthogneisses and granitic veins in the Xingdi region of the Quruqtagh Block

The Archean–Paleoproterozoic basement rocks, exposed in the Xingdi region of the Quruqtagh Block, provide a great opportunity to characterize the early crustal evolution of the Tarim Craton and reconstruct the Columbia supercontinent. Here we report zircon U–Pb ages, Lu–Hf isotope compositions, and bulk-rock geochemical data of orthogneisses and granitic veins from the Xingdi region of the Quruqtagh Block in the northeastern margin of the Tarim Craton. The orthogneisses formed in the late Neoarchean to early Paleoproterozoic (2504 ± 33 Ma, 2419 ± 24 Ma and 2450 ± 27 Ma), and were metamorphosed in the late Paleoproterozoic (1789 ± 43 Ma and 1748 ± 35 Ma). The orthogneisses have relatively high Sr (312–710 ppm) contents, and low Y (5.3–13.8 ppm) and Yb (0.46–1.10 ppm) contents, resulting in high Sr/Y (32–118) and La/Yb (17–64) ratios that are characteristics of adakites. The relatively high Mg# (49–55) and depleted zircon Hf isotope characteristics (positive εHf(t), with TDM2 of ca. 2.5–2.8 Ga) indicate that the orthogneisses crystallized from partial melting of garnet-bearing amphibolite in a subduction environment. The granitic veins that intrude the orthogneisses formed during the late Paleoproterozoic (1760 ± 25 Ma), which is roughly contemporaneous with the metamorphic ages of the orthogneisses; the granitic veins are characterized by extremely high SiO2 (>80 %), enrichments in Rb, Ba and U, and depletions in Nb and Ta. It is inferred that the granitic veins formed by in situ anatexis of the orthogneisses during the late Paleoproterozoic. Based on the zircon ages with Hf isotope compositions, it is evident that the continental crust in the Xingdi region of the Tarim Craton largely formed between 2.5 and 2.8 Ga and was reworked at ca. 1.8 Ga; this evolutionary history is similar to that of the Dunhuang Block. Comparison of the Paleoproterozoic tectono-thermal events in the different terranes of the Tarim Craton, it is suggested that the Tarim Craton is composed of discrete terranes that detached from different ancient cratonic nuclei prior to the late Paleoproterozoic, and assembled within the Columbia supercontinent respectively.

Genetic link between Mesozoic magmatism and Makeng-type iron polymetallic deposits in the central Cathaysia Block, southeast China

Makeng-type Fe polymetallic deposits occur in the central Cathaysia Block, southeast China, and are an important part of the Wuyishan mineralization belt. To determine the origins of the deposits, we analyzed whole-rock geochemical, zircon U–Pb and molybdenite Re–Os geochronological, and zircon Lu–Hf and sulfide S–Pb isotopic data. The deposits are associated with granites that yield ages of 160–150 and 135–130 Ma. The Mo mineralization is genetically related to the younger granites (135–130 Ma), whereas the Fe mineralization is likely related to the older granites (160–150 Ma). The whole-rock geochemical and zircon Hf isotope data indicate the granites formed by the melting of Paleoproterozoic − Mesoproterozoic crustal materials. The S–Pb isotope data indicate that the ore-forming materials were derived mainly from the upper crust, with some input of mantle-derived material that was transported by deeply sourced fluids in the orogenic belt. Based on our results and previously published data, it is inferred that Fe mineralization occurred in a transitional tectonic setting (i.e., from compression to extension), whereas the Mo mineralization formed in an extensional setting associated with rollback of the Paleo-Pacific Plate.

Age and Tectonic Setting of Layered Lead–Zinc Ore Bodies in the Xiaohongshilazi Deposit: Constraints from Geochronology and Geochemistry of the Volcanic Rocks in Central Jilin Province, NE China

The newly discovered Xiaohongshilazi deposit located in Panshi City, central Jilin Province, NE China, is a medium-scale Pb–Zn–(Ag) deposit. The Pb–Zn–(Ag) orebodies are divided into layered and vein-type orebodies, which have different ore geneses. The layered Pb–Zn orebodies are mainly hosted within and spatially controlled by the volcanic rocks. To constrain the age and tectonic setting of the layered Pb–Zn mineralization, we completed laser-ablation–ICP–MS zircon U–Pb dating and whole-rock major and trace element analyses of the ore-bearing volcanic rocks. The dacite samples were confirmed as belonging to the Daheshen Formation and were the main ore-bearing volcanic rocks for the layered orebodies. They yielded concordia U–Pb ages of 278.1 ± 1.8 Ma and 278.3 ± 1.8 Ma, respectively, indicating that the volcanic rocks from the Daheshen Formation and related layered Pb–Zn mineralization were formed in the early Permian. The andesite and rhyolite located above the layered orebodies yielded concordia U–Pb ages of 225.0 ± 1.1 Ma, 225.3 ± 1.5 Ma, and 224.7 ± 1.2 Ma, respectively; these substances are considered to be of the Sihetun Formation and were first reported in the area. The dacite samples associated with layered Pb–Zn mineralization were high in SiO2 (62.54–65.02 wt.%), enriched in LREEs and LILEs (e.g., Rb, Ba, and K), and showed depletion in HFSEs (e.g., P and Ti). It showed slightly negative Eu anomalies (δEu = 0.60–0.65) and negative Nb anomalies, with Th/Nb (1.12–1.21) and La/Nb (2.8–4.7) ratios, presenting subduction-related arc magma affinity formed in an active continental margin setting. In agreement with previous studies on zircon Hf isotopes (εHf (t) = +0.23~ +10.60) of the volcanic rocks from the Daheshen Formation, we infer that they were derived from the partial melting of the depleted lower crust. In conclusion, mineralization characteristics, geochronological data, geochemical features, and regional tectonic evolution suggest that two Pb–Zn–(Ag) mineralization stages from the Xiaohongshilazi deposit occurred: the layered VMS-type Pb–Zn mineralization associated with the marine volcanic rocks from the early Permian Daheshen Formation, which was induced by the subduction of the Paleo-Asian oceanic plate beneath the northern margin of the North China Craton, and the vein-type Pb–Zn–(Ag) mineralization caused by the subduction of the Paleo-Pacific Plate in the early Jurassic. Considering this, along with the mineralization characteristics of the same-type polymetallic deposits in this region, we propose that the early Permian marine volcanic rocks have great prospecting potential for the VMS-type Pb–Zn polymetallic deposits.

Petrogenesis of Eocene Lamprophyre Dykes in Northern Qiangtang Terrane, Tibetan Plateau: Implications for the Tethyan Mantle Metasomatism and Tectonic Evolution

Post-collisional (ultra)potassic lamprophyre dykes are the key probes for understanding mantle metasomatism and reconstructing tectonic evolution. In this study, we present new petrological, geochronological, geochemical and zircon Lu-Hf isotopic data for lamprophyre dykes in the northern Qiangtang terrane (central Tibet), aiming to constrain their petrogenesis and geodynamic setting. The studied lamprophyres are minettes with phenocrysts of siderophyllite and phlogopite, which intrude into Triassic granite of 236.9 Ma. These lamprophyres yield zircon U-Pb ages of 39.7–40.9 Ma. They exhibit high contents of K2O (7.61–8.59 wt.%) and ultrapotassic features with high K2O/Na2O (11.43–14.38) ratios. They are characterized by increased values of Mg# (69.1 to 72.1) and high concentrations of compatible elements (e.g., Cr = 277–529 ppm, Ni = 232–322 ppm), which are diagnostic of mantle-derived primitive magma. The studied lamprophyres have a high abundance of rare earth elements (∑REE = 902–1061 ppm) with significantly fractionated REE patterns ((La/Yb)N = 66.3–100.6), and they are enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE), but depleted in high field strength elements (HFSE) (e.g., Nb, Ta and Ti) and heavy rare earth elements (HREE) with enriched zircon Hf isotopes (εHf(t) from −6.40 to 3.80). This indicates their derivation from an enriched mantle source which was metasomatized by subduction-related fluids and sediment-derived melts. A petrogenetic study suggests that the lamprophyres were generated by the partial melting of a phlogopite-bearing lherzolite within the garnet stability field. We propose that the Cenozoic ultrapotassic mafic rocks in the central Tibetan Plateau originated in the lithospheric mantle metasomatized by the subduction-related components, and are the magmatic response to the detachment of the subducted Tethyan slab.

Petrogenesis of Paleocene−Eocene gabbros in the Gangdese belt: Geochemical tracking of transitioning from oceanic subduction to continental collision related magmatism in southern Tibet

The composition of the sub-arc mantle and the mode and nature of geodynamic processes during the India-Asia collision that controlled the melt evolution beneath the Gangdese belt (southern Tibet) are still unclear. Here, we present new U-Pb ages and Hf isotopes of zircon, and whole-rock geochemical and Sr-Nd-Pb isotopic data of the Paleocene−Eocene Najinla gabbros from the East Gangdese magmatic belt, aiming to track the transitioning magmatism formed from oceanic subduction to continental collision in the region. Zircon U-Pb analyses of these mafic rocks yield emplacement ages of 54 ± 1 Ma and 63 ± 1 Ma. The gabbros are characterized by variable SiO2 (45.87−55.44 wt%), MgO (1.03−8.18 wt%), FeOT (3.74−12.33 wt%), and Al2O3 (13.45−25.45 wt%) contents. Most samples exhibit high Al2O3 (17.15−25.45 wt%) and relatively low MgO (1.03−6.11 wt%), similar to typical high-alumina basalts and high-alumina basaltic andesites. The Najinla gabbros show characteristic subduction-related signatures with enriched large-ion lithophile elements and depleted high field strength elements. They have depleted Sr-Nd isotopic compositions with low and relatively homogeneous initial 87Sr/86Sr isotopic ratios of 0.7045−0.7049 and positive εNd(t) ratios of +2.2 to +3.2. The Najinla gabbroic rocks also have positive zircon εHf(t) values, ranging from +5.6 to +10.9. These results collectively suggest that magmas of the gabbros formed by partial melting of the asthenosphere with negligible crustal contamination during their emplacement. We propose that the mantle source of the Najinla gabbros was strongly influenced and metasomatized by subducted Neotethyan oceanic crust-derived fluids in the mantle wedge. Rollback of the subducted Neotethyan slab in the early Eocene led to partial melting of the subduction-modified mantle and the formation of these gabbros.

The Singhbhum Craton (India) records a billion year of continental crust formation and modification

The petrogenesis of continental crust from its ultimate mantle source can be reconstructed from the element abundances and radiogenic isotope compositions of ideally pristine igneous rocks. The initial isotope compositions of igneous rocks provide geochemical constraints on the age, composition and evolution of their source(s). Determining initial isotope ratios for rock samples can be challenging, especially in rocks with a long and protracted thermal history. The Rb-Sr system is highly sensitive to parent-daughter element fractionation during magma differentiation. This makes the Rb-Sr isotope systematics ideal to trace the precursor composition of Archean felsic crust and constrain the time of element fractionation during the formation and subsequent modification of continental crust. Initial isotope compositions can be obtained directly from minerals that strongly prefer the daughter element and effectively exclude the parent element of the radio-isotope system of interest. Apatite, having a near zero Rb/Sr ratio, is ideal for preserving its initial 87Sr/86Sr and zircon records initial 176Hf/177Hf compositions. Combined modelling of Sr and Hf isotope data from granitoids of the Archean Singhbhum Craton, indicates that the older Paleoarchean granitoids, emplaced between 3.53 Ga and 3.44 Ga, were derived from a mafic precursor (∼52–54 wt% SiO2) sourced from a depleted mantle at ∼3.71 Ga. Initial 87Sr/86Sr isotope signatures of matrix apatite and apatite inclusions in zircon from the younger Paleoarchean granitoids (3.4–3.2 Ga) of the Singhbhum Craton indicate these younger granitoids were produced by mixing of magma generated from an older mafic source and partial melts derived from the older granitoids. The combined Sr-Hf isotope modelling links the timing of mantle extraction of the precursor material for Paleoarchean Singhbhum granitoids with a known mafic crust extraction event at ∼3.71 Ga. In combination, the new Sr isotope data from apatite combined with whole rock and zircon Hf isotope data from the literature reveal a ∼1 Ga protracted crustal growth and differentiation history of the nucleus of the Singhbhum Craton. By combining radio-isotope systems like 87Rb-87Sr and 176Lu-176Hf, the petrogenesis of Archean felsic crust from the extraction of mafic material from the mantle to reworking in an orogenic cycle to emplacement can be reconstructed. This approach can be applied to other greenstone-gneiss terranes to quantify the spatio-temporal and compositional evolution of voluminous felsic crust and the formation of cratons in the Archean.

The Nenjiang oceanic slab rollback in late Devonian: Constraints from Heihe granite and monzonite in the Xing’an block, NE China

Disputes regarding the subduction process, closure time, and the location of the Nenjiang Ocean have arisen due to limited exposure of late Paleozoic magmatic rocks in the Xing'an block. In this study, we present new zircon U-Pb age, zircon Hf isotope, zircon trace elements and whole rock geochemistry to reveal the evolution process of the Nenjiang Ocean in the late Paleozoic. The Heihe monzonite samples originated from the partial melting of a depleted mantle wedge metasomatized by subduction-related fluids and experienced fractional crystallization of plagioclase and amphibole. The Heihe granites show adakitic affinity, with low contents of compatible elements and U-shaped chondrite-normalized REEs patterns, indicating that the adakitic characteristics of the Heihe granites were formed by amphibole-dominated fractional crystallization. Geochemical modeling shows that the Heihe granite can be generated at a degree of 30–75 % amphibole-dominated fractional crystallization. The geochemical characteristics and genetic type of Heihe granites, associated with coeval sedimentary strata, imply extensional tectonic setting in late Devonian-early Carboniferous. By analyzing the spatiotemporal distribution and geochemical data of the 300–400 Ma magmatic rocks in the Xing'an block, and by conducting locally weighted regression fitting, we propose a geodynamic model. According to this model, the Nenjiang oceanic slab began to rollback at approximately 375 Ma, resulting in the production of the Heihe monzonite and granite. Subsequently, the closure of the Nenjiang Ocean, and collision between the Xing'an block and the Songnen block occurred at around 320 Ma.

Heavy silicon and oxygen isotope signatures of TTGs formed in distinct tectonic settings

Tonalite–trondhjemite–granodiorite suites (TTGs) are key components of Archean continental crust and are therefore crucial to understanding the evolution of Archean Earth. However, the tectonic settings of their formation remain unresolved. Here we present new in situ zircon Si–O–Hf isotopes and quartz Si–O isotopes from 2.95 to 2.54 Ga TTGs of the Jiaodong terrane in the North China Craton. Through first-principles calculations, the corresponding TTG melt δ30Simelt and δ18Omelt values are determined as –0.03 ‰ to 0.06 ‰ and 7.12 ‰ to 7.60 ‰, respectively, indicating heavier isotope signatures than those of mantle-derived juvenile rocks. The 2.95–2.93 Ga and 2.56–2.54 Ga TTGs have depleted Hf isotopes [εHf(t) = +3.7 to +4.9, and +2.5 to +5.5, respectively] and higher (La/Yb)N ratios compared with the 2.75–2.71 Ga TTGs, which have relatively less depleted Hf isotopes [εHf(t) = +0.9 to +2.0] and lower (La/Yb)N ratios. Although the heavy Si–O isotope compositions indicate the involvement of supracrustal materials in the melting sources of all studied TTGs, the variable zircon Hf isotopes and (La/Yb)N ratios suggest that these rocks formed in distinct tectonic settings. The 2.95–2.93 Ga and 2.56–2.54 Ga TTGs are inferred to have been generated in a subduction setting involving the melting of juvenile oceanic crust under high-pressure conditions, whereas the 2.75–2.71 Ga TTGs are inferred to have been derived from the melting of buried ancient oceanic crust under a mantle-plume-induced lower-pressure environment. We conclude that the heavy Si–O isotope signatures of Archean TTGs may not be directly related to plate-tectonic processes.

Archean to Paleoproterozoic magmatic and metamorphic evolution of the Lofoten – Vesterålen area in northern Norway through zircon U-Pb and Hf isotopic analysis

Neoarchean (2.8–2.5 Ga) and Paleoproterozoic (2.5–1.6 Ga) crust preserves a record of major crustal growth events, the oldest supercontinent assemblies, and the likely transition to modern plate tectonics. The Lofoten–Vesterålen area in Norway underwent a multistage tectono-magmatic history from the Neoarchean to the Paleoproterozoic. In this region three main components are distinguished: 1) a granulite facies zone (GFZ); 2) an amphibolite facies zone (AFZ); and 3) an anorthosite-mangerite-charnockite-granite (AMCG) suite. New zircon U-Pb and Lu-Hf isotope data are used to investigate the evolution of this 2.7–2.6 and 1.9–1.8 Ga crust and evaluate how the developments fit in the global context of Earth’s crustal evolution. In-situ LASS–MC-ICPMS analyses were conducted on zircons to simultaneously determine U-Pb ages and Hf isotope compositions. Solution Hf isotope compositions were additionally obtained on zircons previously dated by ID-TIMS. In general, there is a good agreement between solution and in-situ data. Samples from the GFZ and AFZ both yield Neoarchean (2.7–2.6 Ga) and Paleoproterozoic (1.9–1.8 Ga) populations. Neoarchean populations have εHf(i) of +0.9 to −0.3; Paleoproterozoic populations have εHf(i) around −16 and −7 at ∼1.80 and ∼1.87 Ga, respectively. The AMCG suite was emplaced in two magmatic pulses: the early one at 1.87–1.86 Ga characterized by εHf(∼1.87 Ga) ∼ −7, and the main pulse at 1.80–1.79 Ga has εHf(∼1.80 Ga) between −4.0 and −15.0. Metamorphic overprinting recorded within the GFZ and the AMCG at ∼1.80 Ga is absent in the AFZ, supporting the hypothesis of a tectonic boundary between these domains. The Hf isotope compositions suggest that Paleoproterozoic magmatism was sourced from a combination of juvenile material and incorporated ancient crust, probably in variable proportions, as suggested by the variation in the isotope composition of the AMCG suite. Broadly chondritic Hf isotope compositions in Neoarchean rocks indicate the absence of significantly older crust as a source component. Main crustal growth events recorded in the Lofoten–Vesterålen area coincide with global age peaks and zircon Hf isotope record. The AMCG suite was emplaced during the Columbia supercontinent assembly. Neoarchean and Paleoproterozoic crust in the Lofoten–Vesterålen area exemplifies the elevated preservation potential in collisional tectonic settings.

Zircon Hf isotopic compositions of the basement gneiss in Bayan Obo: Constraints on crustal evolution of the Yinshan Block in the North China Craton

Bayan Obo, located in the north margin of the Yinshan Block, North China Craton (NCC), contains the Archean to Paleoproterozoic basement rocks which may shed light on the early crustal evolution of the NCC. In this paper, to reveal the formation and modification of the basements, we report Hf isotope of zircons from the biotite plagiogneisses in Bayan Obo. Combined with the published U–Pb ages and Hf isotope compositions of the zircons from the Bayan Obo basement rocks, a comprehensive review was employed to provide new insights into the formation and modification of the basement in this area. The oldest formation age of the basement rocks was found to be approximately 2.6 Ga, with positive εHf(t) values indicating the contribution from the depleted mantle to the rocks. The age of ∼2.0 Ga marks the major formation period of the basement rocks. The varied εHf(t) values (−17.2 to +8.9) of the magmatic zircons suggest a mixture origin between the depleted mantle and crustal rocks for the gneiss. The basement went through extensive metamorphism during 1.95–1.9 Ga. In addition, zircon U–Pb–Hf isotope data of the Precambrian units in Guyang and Wuchuan, which are adjacent to Bayan Obo, were compiled for comparison. The comprehensive review on the data of the concordant magmatic zircons indicates the existence of 3.5 Ga crustal fragments in the Yinshan Block. The melting of the depleted mantle and the addition of juvenile materials into the crust at 2.6–2.9 Ga and 2.45–2.55 Ga were confirmed by the high positive εHf(t) values of the magmatic and inherited zircons. An increase in remelting of the crust at 2.0 Ga is deduced from the extremely unradiogenic Hf isotope of the magmatic zircons.

Building and reworking of Archean continental crust in the nucleus of the Yangtze Craton: Constraint from 3.4 Ga and 2.94 Ga granitoid gneisses in the Southern Kongling Complex

The TTG gneisses, a dominant lithological assemblage within Archean cratonic provinces, provide a window into the early evolution of the continental crust. The Kongling complex in South China preserves voluminous Archean granitoids, recording the early formation and evolution history of the Yangtze Craton. We present results of a comprehensive study involving field investigation, petrographic characterization, zircon U–Pb geochronology and Lu-Hf isotope tracing, and whole-rock geochemistry for the Archean granitoid gneisses from the Southern Kongling Complex. Igneous zircons from two granitic gneisses yielded weighted mean 207Pb/206Pb ages of 3399 ± 15 Ma (MSWD = 0.99, n = 24) and 3389 ± 12 Ma (MSWD = 1.02, n = 20). Zircons from the 3.4 Ga granitic gneiss also record a ca.3.0 Ga anatexis event which is contemporaneous with the widespread granitoid gneisses in the Kongling Complex. Geochemical and zircon Hf isotope data (εHf(t) values of − 3.41 to + 0.77 and two-stage Hf model ages of 3.65–3.80 Ga) for the granitic gneisses support a derivation from pre-existing Eoarchean (TDM2 = 3.73 Ga) crust. LA-ICP-MS zircon U-Pb dating yielded emplacement ages of 2948 ± 17 Ma for a migmatized trondhjemitic gneiss, and 2928 ± 14 Ma for a quartz monzonite gneiss. These two gneisses have similar zircon Hf model ages (TDM2 = 3.45 Ga) and both were emplaced during a major phase of mafic magma diapiric process that significantly reworked the old crust. The occurrences of 2.94 Ga trondhjemite and associated mafic blocks suggest intra-crustal differentiation by partial melting of low-K mafic rocks. We suggest that intra-crustal remelting and differentiation played a key role in the formation, evolution, and maturation of the micro-continents in Kongling during the Paleo- to Meso-Archean. The whole-rock geochemical and zircon Hf isotopic compositions of the different generations of granitoid gneisses from the Southern Kongling Complex are similar to those of the coeval gneisses (3.45 Ga and 2.95 Ga) from the northern part of the Kongling Complex, indicating a common tectono-magmatic history shared by both segments tracing back to as early as 3.4 Ga. The Archean granitoid gneisses from the Kongling Complex record remelting and differentiation of Eo- to Paleo-Archean crusts during the Paleo- to Meso-Archean, implying that Eoarchean crust is likely to have been preserved within the Kongling complex.

Tracing the crustal evolution of the Precambrian Southern Granulite terrane in East Gondwana: New insights from zircon U-Pb/Hf geochronology

The Precambrian Southern Granulite terrane of south India has a crustal evolution history broadly bracketed between the late Archean and Cambrian with records of polyphase deformation, metamorphism, and magmatism. The Southern Granulite terrane comprises distinct crustal blocks bounded by shear/suture zones that have been variably correlated with supercontinent fragments including Madagascar, Sri Lanka, Africa, Eastern Ghats, and Antarctica. However, the timing and mechanism of assembly of different crustal blocks within the Southern Granulite terrane and its linkages with counterparts in East Gondwana are highly debated. This study aimed to unravel the complex crustal evolutionary pattern of the terrane by generating robust zircon U-Pb/Hf isotopic data from basement charnockites, gneisses, granitoids, and alkaline intrusive units from the central part of Southern Granulite terrane and comparing these results with similar data from different East Gondwanan terranes. The study identified four distinct crustal growth episodes in the Madurai block: (1) Neoarchean−early Paleoproterozoic, (2) Rhyacian−Orosirian, (3) late Tonian, and (4) Ediacaran−Cambrian. Analysis of zircon Hf isotope data revealed that the first two events are marked by juvenile magmatic signatures, whereas the latter two are distinctly associated with intense reworking and remelting of older crust with no significant juvenile input. Our new results combined with existing data from other Gondwanan terranes suggest a common Paleoproterozoic ancestry for the Southern Granulite terrane and its corresponding Gondwanan fragments, proposing a revision to the existing geodynamic models.