Zircon Hf Isotopic Analyses Research Articles

Age, petrogenesis, and tectonic setting of granitic gneiss and amphibolite from the Weizigou gold deposit, Heilongjiang Province, NE China: Constraints from geochronology and geochemistry

The Weizigou gold deposit is located in the western Jiamusi Massif, Northeast China. Gold mineralization is hosted in the amphibolite, which intruded the granitic gneiss. Although the deposit shows similarities to iron-oxide–copper–gold deposits, the detailed ore-forming process remains uncertain. To determine the formation age, petrogenesis, and tectonic setting of the granitic gneiss and amphibolite, LA–ICP–MS zircon, titanite, and monazite UPb dating, whole-rock major- and trace-element analyses, and LA–ICP–MS in situ zircon Hf isotope analyses were conducted on samples from these rocks. The granitic gneiss yielded two age populations of 951–882 Ma, and ca. 500 Ma, with a monazite UPb concordia age of 501.5 ± 5.1 Ma. The amphibolite yielded a crystallization age of 292 Ma, consistent with the results for magmatic titanite UPb dating, and a metamorphic age of 272–258 Ma. The granitic gneiss contains typical aluminum-rich minerals, such as garnet and muscovite, mean SiO2 = 73.31 wt%, and molar ratio Al2O3/(CaO + K2O + Na2O) values of 1.02–1.07, indicating an S-type granite protolith. The amphibolite belongs to the tholeiitic basalt series and has low SiO2 and high MnO contents. These results, together with εHf(t) values and two-stage model ages ranging from −9.5 to 2.3 and − 0.3 to 5.7, and from 2010 to 1659 Ma and from 1331 to 947 Ma, respectively, allow us to infer that the parental magmas of the granitic gneiss and amphibolite were derived from the partial melting of Paleoproterozoic lower crust and the partial melting of metasomatized depleted mantle, respectively. The granitic gneiss is characterized by positive Th and Hf anomalies, and negative Nb, Ta, Sr and Ti anomalies, whereas the amphibolite is enriched in K, Rb, and depleted in Ba, Nb, Ti, and Zr. These geochemical features suggest that the S-type granite was formed in an active continental margin during the Neoproterozoic and underwent granulite-facies metamorphism during the early Paleozoic. The protolith of the amphibolite was gabbro that formed in an extensional setting (e.g., a backarc basin) associated with westward subduction of the Paleo-Pacific oceanic plate beneath the eastern Jiamusi Massif during the early Permian. The gold mineralization can most likely be attributed to contact metasomatic metamorphism of gabbro during the middle–late Permian.

Archean to Paleoproterozoic crustal evolution of the southern Yangtze Block (South China): U–Pb age and Hf-isotope of zircon xenocrysts from the Paleozoic diamondiferous kimberlites

Crustal zircon xenocrysts from mantle-derived magmatic rocks have the potential to probe the deep crust. Here we present integrated U–Pb dating and Hf-isotope analyses of zircons from a Paleozoic diamondiferous kimberlite dike in the Maping area of Zhenyuan County (southeastern Guizhou Province), with implications for the tectonothermal evolution of unexposed continental crust beneath the southern Yangtze Block, South China. All zircons (n = 236) show a wide range of U–Pb ages between Mesoarchean and middle Carboniferous. Among them, 96 zircons with 90–110% concordance yield concordant ages from 2942 ± 8 Ma to 342 ± 2 Ma, and form major age peaks at ∼2.9 Ga, ∼2.6 Ga and ∼2.0 Ga. The overwhelming majority of zircons are dominated by Mesoarchean–Paleoproterozoic U–Pb ages regardless of their concordance degrees. The zircon populations mainly consist of magmatic zircons, with minor metamorphic grains (Th/U < 0.10). The youngest magmatic zircon (Th/U = 0.43) with a well concordant 206Pb/238U age of 342 ± 2 Ma (M1-16) is interpreted as the maximum emplacement age of the Maping diamondiferous kimberlites. Most zircons with pre-eruption ages are considered to be xenocrysts, and they may be derived from the deep-seated continental crust through which kimberlite host magmas have passed. Their U–Pb ages and Hf isotopic compositions suggest the possible existence of a highly evolved Archean basement beneath the southern Yangtze Block, South China, which is much older than its known surface rocks. A lot of magmatic zircon xenocrysts reveal complex Precambrian crustal evolution in the southern Yangtze Block. These processes involved the important growth of continental crust at 2.6–2.5 Ga, and in the meantime, crustal reworking could be intermittently proceeding at 3.0–2.6 Ga. In addition, a group of xenocrystic zircons are identified to be of metamorphic origin, indicating that the proposed Archean basement beneath the southern Yangtze Block likely experienced a metamorphic event around 2.0 Ga. This geologically significant episode is consistent with the well-developed coeval metamorphism in other places of the Yangtze Block (e.g., Kongling Terrane), which has been considered to link to the assembly of the Paleoproterozoic Nuna/Columbia supercontinent. Our zircon data implies that the unexposed Archean basement beneath the southern Yangtze Block was affected by multiple thermal activities.

Late Indosinian granitoids in the Zhacanggou, Guide Basin, NW China: Whole‐rock geochemistry, zircon U–Pb geochronology, Lu–Hf isotopes, and implications for magma mixing

The Guide Basin, located in the West Qinling orogen of central China, is a typical geothermal field. However, the granodiorites occurring in the Zhacanggou area have been poorly restricted. Herein, we report new isotopic compositions of whole‐rock major‐trace elements, zircon U–Pb, and Lu–Hf, on the host granodiorites and their microgranular enclaves (MEs) in the Zhacanggou area. Zircon U–Pb dating for the host rocks (porphyritic granodiorite and granodiorite) revealed ages of 230.5 ± 1.4 Ma and 229.0 ± 1.6 Ma, similar to those (230.5 ± 1.5 Ma and 231.4 ± 1.4 Ma) of the MEs. Zircon Hf isotope analyses for the granodiorite and MEs yielded εHf(t) values from −11.0 to −1.5 and from −7.8 to −0.7, with corresponding TDM2 ages of 1,355–1,959 and 1,304–1,755, respectively. The MEs possess plagioclase phenocrysts, acicular apatites, and chilled borders. They were characterized by relatively low SiO2 (58.39–65.24 wt%) and high Cr, Ni, and MgO contents, leading to relatively high Mg# values (44–59) and low Sr/Y (14.23–19.84) ratios. The host granodioritic rocks show similar adakitic geochemical characteristics with SiO2 = 64.23–68.57 wt%, MgO = 1.29–2.22 wt%, Mg# = 48–53, Sr = 340–596 ppm, Y = 11.3–13.7 ppm, Sr/Y = 28.39–47.89, and no obvious Eu anomalies. These geochemical and isotopic data, combined with the mineralogical features, indicate that the granodiorites in the Zhacanggou area were produced by the mixing of high‐Mg# melts originating from an enriched lithospheric mantle source, and felsic magmas deriving by the partial melting of the normal lower continental crust with the tectonic regime transition from a syn‐collision to a post‐collision setting.

Mantle versus crustal contributions in crustal-scale magmatic systems (Sesia Magmatic System, northern Italy) from coupling Hf isotopes and numerical modelling

The growth and evolution of crustal-scale magmatic systems play a key role in the generation of the continental crust, the largest eruptions on Earth, and the formation of metal resources vital to our society. However, such systems are rarely exposed on the Earth’s surface, limiting our knowledge about the magmatic processes occurring throughout the crust to indirect geochemical and petrographic data obtained from the shallowest part of the system. The Hf isotopic composition of accessory zircon is widely used to quantify crust-mantle evolution and mass transfers to and within the crust. Here we combine single-grain zircon Hf isotopic analysis by LA-MC-ICP-MS with thermal modelling to one of the best-studied crustal-scale igneous systems (Sesia Magmatic System, northern Italy), to quantify the relative contribution of crustal- and mantle-derived magmas in the entire system. Zircons from the deep gabbroic units define a tight range of εHf (−2.5 ± 1.5). Granites and rhyolites overlap with this range but tail towards significantly more negative values (down to −9.5). This confirms that the entire system consists of hybrid magmas that stem from both differentiation of mantle-derived magmas and melting of the crust. Thermal modelling suggests that crustal melting and assimilation predominantly occurs during emplacement and evolution of magmas in the lower crust, although melt production is heterogeneous within the bodies both spatially and temporally. The spatial and temporal heterogeneity resolved by the thermal model is consistent with the observed Hf isotope variations within and between samples, and in agreement with published bulk-rock Sr–Nd isotopic data. On average, the crustal contribution to the entire system determined by mixing calculations based on Hf isotopic data range between 10 and 40%, even with conservative assumptions, whereas the thermal model suggests that this space- and time-averaged contribution does not exceed 20%. However, spatial and temporal variations in the crustal melt proportion (from 0 up to 80% as observed in the thermal model) may impart significant isotopic variability to different batches of magma observed on the outcrop scale, emphasizing the need to consider a magmatic system as a whole, i.e., by integrating all spatial and temporal scales, to more precisely quantify crustal growth vs. reworking.

Mantle control on magmatic flare-ups in the southern Coast Mountains batholith, British Columbia

AbstractThe southern Coast Mountain batholith was episodically active from Jurassic to Eocene time and experienced four distinct high magmatic flux events during that period. Similar episodicity has been recognized in arcs worldwide, yet the mechanism(s) driving such punctuated magmatic behavior are debated. This study uses zircon Hf and O isotopes, with whole-rock and mineral geochemistry, to track spatiotemporal changes in southern Coast Mountains batholith melt sources and to evaluate models of flare-up behavior and crust formation in Cordilleran arc systems. Zircon Hf isotope analysis yielded consistently primitive values, with all zircon grains recording initial εHf between +6 and +16. The majority (97%) of zircons analyzed yielded δ18O values between 4.2‰ and 6.5‰, and only five grains recorded values of up to 8.3‰. These isotopic results are interpreted to reflect magmatism dominated by mantle melting during all time periods and across all areas of the southern batholith, which argues against the periodic input of more melt-fertile crustal materials as the driver of episodic arc magmatism. They also indicate that limited crustal recycling is needed to produce the large volumes of continental crust generated in the batholith. Although the isotopic character of intrusions is relatively invariant through time, magmas emplaced during flare-ups record higher Sr/Y and La/Yb(N) and lower zircon Ti and Yb concentrations, which is consistent with melting in thickened crust with garnet present as a fractionating phase. Flare-ups are also temporally associated with periods when the southern Coast Mountains batholith both widens and advances inboard. We suggest that the landward shift of the arc into more fertile lithospheric mantle domains triggers voluminous magmatism and is accompanied by magmatic and/or tectonic thickening. Overall, these results demonstrate that the magmatic growth of Cordilleran arcs can be spatially and temporally complex without requiring variability in the contributions of crust and/or mantle to the batholith.

Paleo - position of the South China Craton in the Rodinia Supercontinent: Evidence from the U - Pb age and Hf isotope of detrital zircon from the Nam Co Complex

To constrain the paleo - positions of the South China Cratons in the Rodinia Supercontinent during the Neoproterozoic, the in - situ U - Pb dating, and Hf isotope analysis of the detrital zircon from the Nam Co Complex, Song Ma Suture zone, northwestern Vietnam was performed. The U - Pb isotopic dating on detrital zircons shows that the Nam Co Complex demonstrates the major population (&gt;50%) of around ~850 Ma while the minor population is scattered between ~1.2÷3.0 Ga. The Neoproterozoic age spectrum exhibits a large range of the εHf(t) from strongly negative to positive values ( - 17.418022÷ 14.600527), indicating that the source of the magma for this age range has been not only derived from reworking of the Archean basement rocks, but also generated from the juvenile material. The U - Pb age distribution patterns and Hf isotopic data of the detrital zircon in the Nam Co Complex are compatible with those of the South China Craton rather than those of the Indochina Craton. The data also indicate that sedimentary protoliths of the Nam Co Complex were deposited in a convergent - related basin along the southwestern margin of the South China Craton during the Neoproterozoic. Combined with the similarities of the detrital zircon age between western Cathaysia, Indochina, East Antarctica and East India, it is proved that the South China Craton was situated at the margin of the Rodinia Supercontinent and in close proximity to the Indochina, East Antarctica and East India.

Detrital zircon U-Pb and Hf constraints on provenance and timing of deposition of the Mesoproterozoic to Cambrian sedimentary cover of the East European Craton, part II: Ukraine

We present the U-Pb geochronology and Hf isotope analysis of detrital zircons from the Ediacaran/Cambrian sediments of Podillya and south Volyn in western Ukraine, supplemented by the bulk rock XRD mineralogy of the host rocks. Such a combined analytical approach allows for identifying the source areas supplying detritus to sediments and for constraining an age of deposition. Our provenance analysis is based on fourteen samples collected from six exposures, mostly in the valley of the Dniester river. 84 mudstone samples were also examined by the XRD method. U-Pb dating of detrital zircons yielded two sets of maximum depositional ages: 578–546 Ma and 547–523 Ma, for the Mohyliv-Podilsky and Kanyliv Series, respectively. This suggests that the Ediacaran-Cambrian boundary in Podillya coincides with a major erosional gap, with a major change in provenance, and the disappearance of the Ediacaran fauna at the base of the Kanyliv Series, with implications for the stratigraphy and paleogeography of the entire East European Platform. Zircon U-Pb age spectra from the lower part of the Mohyliv-Podilsky Series include a large quantity of 2.2 to 1.9 Ga grains that reveal predominantly negative to nearly chondritic ɛHf values, jointly suggesting detritus supply from the crystalline basement of Sarmatia. Both U-Pb and mineralogical data also indicate a major contribution of volcanic detritus from the Volyn flood basalts. The younger Nagoryany rocks yielded zircon age spectra with peaks at c. 1.80 and 1.49 Ga, implying a shift of the catchment area to Fennoscandia. Above an erosional gap, the zircon age spectra in the Kanyliv and Baltic Series are dominated by peaks at 560–535 Ma. These data and ɛHf values ranging from negative to chondritic and juvenile suggest, in line with the mineralogical data, detritus supply from a continental magmatic arc and collisional orogen. Thus, we interpret the Kanyliv Series as infill of an early Cambrian foreland basin that was established in front of the Scythides and Santacrucides orogens, overriding the SW margin of Baltica.

Finding of Ca. 1.6 Ga Detrital Zircons from the Mesoproterozoic Dagushi Group, Northern Margin of the Yangtze Block

The middle Mesoproterozoic is a crucial time period for understanding the Precambrian tectonic evolutionary history of the northern Yangtze Block and its relationship with the supercontinent Columbia. The Dagushi Group (Gp) is one of the Mesoproterozoic strata rarely found at the northern margin of the Yangtze Block. U–Pb geochronology and Lu–Hf isotopic analyses of detrital zircons were analyzed for three metamorphic quartz sandstone samples collected from the Luohanling and Dangpuling formations of the Dagushi Gp. These metasandstones yielded major zircon populations at ~2.65 Ga and ~1.60 Ga, respectively. The ~1.60 Ga ages first discovered yield a narrow range of ɛHf(t) values from −1.8 to +1.8, which lie above the old crust evolutionary line of the Yangtze Block, suggesting the addition of mantle material. Trace element data indicate that ~1.60 Ga detrital zircons share a basic provenance, whereby they have low Hf/Th and high Nb/Yb ratios. Zircon discrimination diagrams suggest that the ~1.60 Ga detrital zircon source rocks formed in an intra-plate rifting environment. Dagushi Gp provenance studies indicate that the ~1.60 Ga detrital zircon was most likely sourced from the interior Yangtze Block. Thus, we suggest that the late Paleoproterozoic to early Mesoproterozoic continental break-up occurred at the northern margin of the Yangtze Block.

Genesis of the Lakang'e porphyry Mo (Cu) deposit, Tibet: Constraints from geochemistry, geochronology, Sr-Nd-Pb-Hf isotopes, zircon and apatite

The Lakang'e porphyry Mo (Cu) deposit, intermediate to large in size, is located in the eastern part of the southern Gangdese metallogenic belt. It is associated with a Miocene granodiorite porphyry (GDP). The alteration styles are mainly potassic and phyllic alteration, with minor argillic, chlorite, and carbonation alteration. In this study, we present whole-rock geochemical compositions, zircon LA-ICP-MS U-Pb data, zircon Hf isotope analyses, and zircon and apatite major and trace element compositions for the ore-bearing GDP and postmineralization quartz diorite porphyry (QDP) to constrain the formation of the Lakang'e Mo (Cu) deposit. The ore-bearing GDP, with a zircon U-Pb age of 13.83 ± 0.20 Ma, was intruded after mineralization by the QDP, which was emplaced at 13.00 ± 0.16 Ma. The GDP and QDP are high-K calc-alkaline series rocks with adakite-like features characterized by high contents of K2O and Al2O3, high Sr/Y ratios, strongly fractionated REE patterns, LILE enrichment, and HFSE depletion. The GDP and QDP have relatively low (87Sr/86Sr)i values (0.7051–0.7054) and high εNd(t) values (−0.87 to 0.59). Zircon grains from the QDP have high εHf(t) values (7.0–9.6), while zircon grains from the GDP show large εHf(t) variations ranging from −4 to 9.6, indicating that the magma source of the ore-bearing GDP included more continental crust than that of the postmineralization QDP. The zircon Ce4+/Ce3+ and Eu/Eu* ratios and apatite Mn and SO3 contents indicate that the postmineralization QDP had higher oxygen fugacity than the ore-bearing GDP. The oxygen fugacity of the ore-bearing magma present during apatite crystallization (generally below the Ni-Ni-O (NNO) buffer), was lower than that present during zircon crystallization (above the hematite-magnetite (HM) buffer). The F, Cl, and S contents in apatite show that the GDP and QDP were F and S rich and that the GDP had a higher F content than the QDP. A high oxygen fugacity, a F- and S-rich magma and a Mo-rich crustal source were the key factors for the formation of the Lakang'e porphyry Mo (Cu) deposit.

Late Paleozoic tectonic evolution of the Kangguer Shear Zone and Yamansu Arc Belt, Eastern Tianshan (NW China): Constraints from structure, petrogenesis and geochronology of granitoids

Despite abundant research efforts, no consensus exists about the Carboniferous tectonic evolution of the Eastern Tianshan. The tectonic environment of the Yamansu arc belt and the geodynamic mechanisms of the Kangguer shear zone are not fully understood. To refine the proposed tectonic history, we studied three granitoids with a variety of shear deformation characteristics and emplacement relationships in the Yamansu–Kangguer area. Bulk geochemistry indicates that the mylonitic granite porphyry is I-type, while the undeformed two-mica granite and quartz porphyry are S-type granites. Zircon UPb dating results give concordant ages of the granite porphyry, two-mica granite, and quartz porphyry at 336.4 ± 2.3 Ma (MSWD = 1.9, n = 16), 331.5 ± 6.1 Ma (MSWD = 2.6, n = 6), and 332.8 ± 1.7 Ma (MSWD = 1.5, n = 25), respectively, suggesting an emplacement age in the middle Carboniferous. The whole-rock SrNd and zircon Hf isotopic analyses of the three granitoids indicate that the granitic magmas were derived from a Mesoproterozoic to Neoproterozoic crustal basement. The whole rock geochemical and isotopic data of the studied granitoids indicate partial melting with insignificant crustal contamination (except the two-mica granites) and fractional crystallization during magma origin and evolution. These granitoids show enrichment of LILEs (e.g., Rb, Ba, K) and Pb, depletion of Nb, Ta, P, Ti, and P, with low Sr/Y ratios (3–73) and Sr contents (33–160 ppm), displaying affinities to arc magma, and they were classified as continental arc granites. By combining the structural analysis and geological evidence, we propose that southward subduction of the Kangguer Ocean in the middle–late Carboniferous resulted in the ductile shear deformation of strata in the Kangguer shear zone and voluminous magmatism in the Yamansu–Kangguer continental arc–fore-arc basin system.

Detrital zircon constraints on late Paleozoic tectonism of the Bogda region (NW China) in the southern Central Asian Orogenic Belt

The Chinese North Tianshan (CNTS) in the southern part of the Central Asian Orogenic Belt (CAOB) has undergone multistage accretion-collision processes during Paleozoic time, which remain controversial. This study addresses this issue by tracing the provenance of Late Paleozoic sedimentary successions from the Bogda Mountain in the eastern CNTS through U–Pb dating and Lu–Hf isotopic analyses of detrital zircons. New detrital zircon U–Pb ages (N ​= ​519) from seven samples range from 261 ​± ​4 ​Ma to 2827 ​± ​32 ​Ma. The most prominent age peak is at 313 ​Ma and subordinate ages vary from 441 ​Ma to 601 ​Ma, with some Precambrian detrital zircon ages (~7%) lasting from 694 ​Ma to 1024 ​Ma. The youngest age components in each sample yielded weighted mean ages ranging from 272 ​± ​9 ​Ma to 288 ​± ​5 ​Ma, representing the maximum depositional ages. These and literature data indicate that some previously-assumed “Carboniferous” strata in the Bogda area were deposited in the Early Permian, including the Qijiaojing, Julideneng, Shaleisaierke, Yangbulake, Shamaershayi, Liushugou, Qijiagou, and Aoertu formations. The low maturity of the sandstones, zircon morphology and provenance analyses indicate a proximal sedimentation probably sourced from the East Junggar Arc and the Harlik-Dananhu Arc in the CNTS. The minor Precambrian detrital zircons are interpreted as recycled materials from the older strata in the Harlik-Dananhu Arc. Zircon ɛHf(t) values have increased since ~408 ​Ma, probably reflecting a tectonic transition from regional compression to extension. This event might correspond to the opening of the Bogda intra-arc/back arc rift basin, possibly resulting from a slab rollback during the northward subduction of the North Tianshan Ocean. A decrease of zircon ɛHf(t) values at ~300 ​Ma was likely caused by the cessation of oceanic subduction and subsequent collision, which implies that the North Tianshan Ocean closed at the end of the Late Carboniferous.

Petrogenesis and tectonic significance of the late Devonian‐early Carboniferous Jianxiashan pluton in the western domain of the eastern Kunlun Orogen, northern Tibetan Plateau

The Eastern Kunlun arc activities were interrupted by repeated continent–continent collision followed by ocean opening along the older suture zones previous created in the Neoproterozoic. The first report of the later Devonian‐early Carboniferous arc magmatism has played a vital role in constraining the evolution of the Eastern Kunlun Orogen. We undertook zircon U–Pb dating, Hf isotopic compositions, whole‐rock geochemical and Nd–Sr isotopic analyses of the Jianxiashan pluton in the western end of the Eastern Kunlun Range. The pluton is composed of tonalite, granodiorite, and monzogranites. Our new data suggest that the pluton formed during the late Devonian‐early Carboniferous with ages of 339–358 Ma. These rocks have high A/CNK = 1.06–1.30, with 1.11–3.80% of normative corundum and are characterized by negative Eu anomalies and strong depletion in Ba, Nb, and Sr elements. The zircon Hf isotopic analyses give predominantly negative εHf(t) values (−9.25 to −2.80), whereas the values of inherited zircons are various from −25.84 to +8.80. The U–Pb age and Hf isotopic data of these inherited zircons are similar to the widespread meta‐sediments of Kuhai Group basement. The peraluminous granitoids have negative εNd(t) values (−7.1 to −5.1) and relatively high initial 87Sr/86Sr ratios (0.71009). These isotopic compositions suggest that the Kuhai Group could possibly be the source rocks of these peraluminous granitoids. We suggest the tonalite and granodiorite are I‐S transition type, whereas the monzogranite is highly fractionated S‐type formed in a back‐arc extensional tectonic setting, which was possibly related to the northern subduction of the Paleo‐Kunlun oceanic lithosphere.

Detrital zircon U–Pb geochronology and Lu–Hf isotopic analysis of the Neoproterozoic Penglai Group and their comparisons with coeval sedimentary strata of the southeastern North China Craton: provenance, tectonic affinity and implications

The results of U–Pb dating and Hf isotopic analyses of detrital zircons from the Penglai Group in the Jiaobei terrane of the North China Craton (NCC) gave age populations of 1300–1000, 1500–1300, 1700–1500, 1800–1700 and &gt;1800 Ma. The age spectra, variations in U and Th contents, Th/U ratios and Hf isotopic compositions of the detrital zircons of the Penglai Group are identical to those of the Tonian strata of the southeastern NCC. The Penglai Group rocks also have a similar litho- and biostratigraphy and tectonic setting to these Tonian strata, suggesting that the Penglai Group has a tectonic affinity with the NCC and was deposited during the Tonian. The detrital zircon age populations of the Penglai Group are consistent with the multiple magmatic and thermal metamorphic events in the NCC, especially the 1300–1000 Ma intermediate–acid and/or acid igneous rocks of the Korean Peninsula, and we therefore propose that the Penglai Group is mainly sourced from the NCC. The detrital zircon populations of 1300–1000, 1500–1300, 1700–1500 and 1800–1700 Ma show both positive and negative ε Hf(t) values, which, combined with late Paleoproterozoic–Neoproterozoic basic magmatism represented by large volumes of diabase sills in the NCC, suggests that the NCC experienced strong crust–mantle interactions that might have triggered continuous, multi-stage rifting in the NCC during the late Paleoproterozoic (1.8 Ga)–Neoproterozoic. Supplementary material: LA-ICP-MS U-Th-Pb analyses data and Lu-Hf isotopes analytical data are available at: https://doi.org/10.6084/m9.figshare.c.4816317

U–Pb Age and Hf Isotope Geochemistry of Detrital Zircons from Cambrian Sandstones of the Severnaya Zemlya Archipelago and Northern Taimyr (Russian High Arctic)

U–Pb and Lu–Hf isotope analyses of detrital zircons collected from metasedimentary rocks from the southern part of Kara Terrane (northern Taimyr and Severnaya Zemlya archipelago) provide vital information about the paleogeographic and tectonic evolution of the Russian High Arctic. The detrital zircon signatures of the seven dated samples are very similar, suggesting a common provenance for the clastic detritus. The majority of the dated grains belong to the late Neoproterozoic to Cambrian ages, which suggests the maximum depositional age of the enclosing sedimentary units to be Cambrian. The εHf(t) values indicate that juvenile magma mixed with evolved continental crust and the zircons crystallized within a continental magmatic arc setting. Our data strongly suggest that the main provenance for the studied clastics was located within the Timanian Orogen. A review of the available detrital zircon ages from late Neoproterozoic to Cambrian strata across the wider Arctic strongly suggests that Kara Terrane, Novaya Zemlya, Seward Peninsula (Arctic Alaska), Alexander Terrane, De Long Islands, and Scandinavian Caledonides all formed a single tectonic domain during the Cambrian age, with clastics predominantly sourced from the Timanian Orogen.

Petrogenesis and tectonic setting of the Middle Devonian Beitashan Formation volcanic rocks in the northern East Junggar, NW China: Insights from geochemistry, zircon U–Pb dating, and Hf isotopes

The Devonian volcanic rocks are widely distributed in the East Junggar (Xinjiang, NW China), preserving important magmatic records for investigating Palaeozoic tectonic evolution. The Beitashan Formation is mainly composed of pyroclastic rocks and sedimentary rocks in the lower section and intermediate–basic volcanic lava and pyroclastic rocks in the upper section. In this paper, we present geochronological, geochemical, and in situ Lu–Hf isotopic data for Beitashan Formation volcanic rocks from the East Junggar. Zircon U–Pb analyses from a basalt sample by laser ablation inductively coupled plasma mass spectrometry yielded a weighted mean age of 387.8 ± 4.5 Ma, indicating that it was generated in the Middle Devonian. The basic–intermediate volcanic rocks are tholeiitic to calc‐alkalic and are characterized by MgO (2.29–5.91 wt.%), low TiO2 (0.75–1.36 wt.%), and relatively high Al2O3 (15.82–16.73 wt.%). Furthermore, they display enrichment in light rare‐earth elements and large‐ion lithophile elements (such as Ba and Sr) and depletion in Nb, Ta, and Ti, along with slightly positive Eu anomalies (δEu = 0.83–1.15) and Ce anomalies (δCe = 1.00–1.11). In addition, in situ zircon Hf isotopic analyses from basalt samples show εHf(t) values ranging from +4.33 to +15.2, indicating a depleted mantle source with minor crustal contamination. They also show relatively low Nb/Zr (0.04–0.06), Th/Yb (0.67–3.83), and Ba/La (6.79–67.53) and high Ce/Th (7.71–18.94), Ba/Rb (21.39–294.28), and Ba/Th (31.42–486.58). The geochemical data suggest these rocks were likely derived from 10% to 30% partial melting of a garnet‐rich with minor spinel‐bearing Iherzolite depleted mantle metasomatized by slab‐derived fluids, with crustal contamination. Combined with the geological setting and previous studies, we suggest that the northern East Junggar was in a northward‐subducted island‐arc setting in the Devonian.

Petrogenesis of the Cretaceous granitoids in Zhejiang, northeast South China Block and their implications for episodic retreat and roll-back of the Paleo-Pacific Plate

Abstract Two Cretaceous granitoid belts (i.e., the northwest and southeast belts) have been identified in Zhejiang, northeast South China Block. In this study, seven granitoid plutons from both the two belts were collected for zircon U-Pb dating, whole-rock geochemistry, Sr-Nd isotope, and zircon Hf isotope analyses. Chronologically, the Longyou (132 Ma), Sucun (136 Ma), Shanghekou (131 Ma), and Huangshitan (ca. 126 Ma) plutons from the northwest belt display older magma crystallization age than those of the Xiaoxiong (100 Ma), Zhujiajian (108 Ma), and Qingbang island (108 Ma) plutons from the southeast belt. The Sucun quartz monzonite and the Longyou, Shanghekou, Zhujiajian, and Qingbang island granites therein are fractionated I-type granites (i.e., partial melting of meta-igneous rocks) with relatively moderate-low Zr saturation temperature (723–823 °C) and pronouncedly evolved Nd and Hf isotopic compositions (εNd(t) = –8.17 to –5.67 and εHf(t) = –15.07 to –5.67), indicating that they are derivatives of ancient crustal melt-dominated magmas. The Huangshitan granite shows A-type granitic (i.e., granites that are alkaline and anhydrous and from anorogenic setting) features with high Ga/Al (3.47–5.58), rare earth element (REE) content (271–402 ppm), and Zr saturation temperature (781–889 °C). It holds less enriched Nd and Hf isotopic compositions (εNd(t) = –4.13 to –3.60 and εHf(t) = –5.90 to –2.16) and is attributed to partial melting of mature crustal materials with minor basaltic magma incorporation. The Xiaoxiong (quartz) syenitic porphyry is characterized by moderate SiO2 content (60.68–69.92 wt%), high alkali (9.03–11.66 wt%) and REE contents with fractionated REE pattern [(La/Yb)N = 13.8–26.1]. Its relatively depleted Nd and Hf isotopic compositions (εNd(t) = –3.67 to –3.42 and εHf(t) = –5.76 to –2.25) imply that it could be a derivative of basaltic magma from K-rich metasomatized mantle. Available geochronological data indicate that there were two episodic magmatic pulses at ca. 140–120 Ma and ca. 110–85 Ma associated with the Paleo-Pacific Plate underthrusting beneath the northeast South China Block. Here we put forward an episodic slab retreat and roll-back model to account for generation of these magmatic rocks. Firstly, the subducting Paleo-Pacific slab roll-back initiated at ca. 140 Ma and reached climax at ca. 130–120 Ma, which led to formation of the Longyou, Sucun, and Shanghekou I-type granites and the Huangshitan A-type granite, respectively. Subsequently, a flat slab subduction stage occurred with eastward trench retreat, causing a period of magmatic quiescence from ca. 120 to 110 Ma. The following second slab roll-back started at ca. 110 Ma and reached climax at ca. 100 Ma, giving rise to the earlier Zhujiajian and Qingbang island I-type granites and the later Xiaoxiong (quartz) syenitic porphyry.

Crustal growth as revealed by integrated U–Pb and Lu–Hf isotope analyses of detrital zircons from the Ganjiang River, southeastern China

AbstractThe Ganjiang River, one of eight major tributaries of the Yangtze River, located in the western hinterland of the Cathaysia Block, SE China, has a length of 823 km and a drainage area of 82 809 km2, whose detrital zircons provide a valuable means to trace sediment provenances of the river and explore the crustal growth and evolution of the Cathaysia Block. In the current study, 389 concordia zircon U–Pb age spots and rare earth element (REE) contents, in combination with 201 Lu–Hf isotope analyses, have been determined. Oscillatory zoning, high Th/U ratios and REE distribution patterns indicate that most detrital zircon grains are of magmatic origin. The age can be further divided into seven groups: 130–185 Ma with a peak at 153 Ma (7 %); 217–379 Ma with a peak at 224 Ma (16 %); 390–494 Ma with a peak at 424 Ma (37 %); 500–698 Ma with a peak at 624 Ma (5 %); 716–897 Ma with a peak at 812 Ma (10 %); 902–1191 Ma with a peak at 976 Ma (13 %); and 2232–2614 Ma with a peak at 2471 Ma (5 %). The sources of almost all the zircon age groups can be found from the exposed rocks. In particular, Yanshanian, Hercynian to Indosinian, Pan-African, Grenvillian and Palaeoproterozoic–Archaean zircons can be mainly sourced from the northern Guangdong – southern Jiangxi – western Fujian region, while Caledonian zircons come from southern and central Jiangxi, and Jinningian zircons are from central and northern Jiangxi. Most determined zircon grains exhibit negativeεHf(t) values and TDM2ages of 797 to 4016 Ma with a wide peak at 1500–2100 Ma and a keen peak at 1824 Ma, suggesting that most zircons are sourced from the reworked ancient crustal materials or crust–mantle mixing. The zircon Hf model age cumulative probability diagram shows that rapid crustal growth took place at the Palaeo- to Mesoproterozoic and that about 90 % of the crust of the Cathaysia Block was formed before 1.5 Ga.

Late Paleozoic–Early Mesozoic southward subduction-closure of the Paleo-Asian Ocean: Proof from geochemistry and geochronology of Early Permian–Late Triassic felsic intrusive rocks from North Liaoning, NE China

Many studies have confirmed the existence of Late Paleozoic–Early Mesozoic accretionary arc and subduction complex belt to the south of the Solonker-Xar Moron-Changchun-Yanji Suture (SXCYS) zone. Nevertheless, since the suture from the east is covered by the Songliao Basin, until now there have been no completed reports focused on the Late Paleozoic–Early Mesozoic intrusive rocks of this area. Recently, a sequence of granitoid intrusions was identified in the Faku area, northern Liaoning. Zircon (SHRIMP) U-Pb dating results show that there are eight groups of felsic intrusions in the study area, and the intrusions formed at 283–227 Ma (Early Permian to Late Triassic). Together with study of regional events, A four-stage tectonic evolution scenario was recommended during Permian-Triassic in the Faku area: Early Permian magmatism in an activity continental margin setting (293–274 Ma); Middle-Late Permian magmatism in a setting where subduction is translated into collision (270–255 Ma); Early-Middle Triassic magmatism in a setting where collision is translated into detachment of the oceanic slab (255–242 Ma); and Middle to Late Triassic magmatism recorded procedure of post-collision orogeny transformed into extensional environment (241–215 Ma). The Early Permian–Late Triassic felsic intrusions documented the extension-collision of the convergent continental margin and the subduction-extinction of the Paleo-Asian Ocean. Zircon Hf isotopic analyses yield εHf(t) values of −2.03–15.80, almost all of which are positive (with two points being negative), indicating the depleted characteristics of the source area. According to emplacement time and occurrence location, the plutons are interpreted to have been generated by the subduction-collision of the Paleo-Asian oceanic crust beneath the North China Craton (NCC). This study provides strong evidence for Late Paleozoic–Early Mesozoic tectonic evolution and the characterization of the eventual closure of the Paleo-Asian Ocean in the Songliao Basin overlying the northern margin of the NCC.

Timing of late Neoarchean to late Paleoproterozoic events in the North China Craton: SHRIMP U–Pb dating and LA-ICP-MS Hf isotope analysis of zircons from magmatic and metamorphic rocks in the Santunying area, eastern Hebei

Santunying is an important area for revealing nature of the late Neoarchean tectono-magmato-thermal events in the eastern Hebei part of the North China Craton. It is mainly composed of meta-intrusive rocks. Supracrustal rocks sporadically occur in the meta-intrusive rocks. The meta-intrusive rocks are subdivided into the Santunying tonalitic gneiss, Qiuhuayu tonalitic-trondhjemitic gneiss, Xiaoguanzhuang dioritic gneiss and Qingyangshu meta-gabbro. Respectively, SHRIMP U–Pb zircon dating on fourteen samples yielded weighted mean 207Pb/206Pb ages of 2525–2537, 2532–2546, 2530–2544 and ∼2531 Ma for magmatic zircons from them. Dioritic gneiss of the Xiaoguanzhuang gneiss contain abundant 2544–3487 Ma xenocrystic zircons. SHRIMP U–Pb dating on a garnet-biotite gneiss sample yielded a weighted mean 207Pb/206Pb age of 2537 Ma for detrital zircons. All rocks underwent strong metamorphism, deformation and anatexis, resulting in formation of leucosomes and residues, with some leucosomes concentrating to form large veins. They record a strong late Neoarchean event by metamorphic zircon ages of 2489–2519 Ma. Some rocks also record metamorphic zircon ages of 1772–1843 Ma. Magmatic zircons from the magmatic rocks show large variations in εHf(t) values ranging from −1.7 to +8.7. Combined with early studies, conclusions are: 1) Intrusive rocks with the involvement of mantle-derived materials have a narrow range of magmatic zircon ages from 2525 to 2546 Ma, and supracrustal rocks were formed during the same period. 2) Ancient crustal remnants (>2600 Ma) are present, consistent with the late Neoarchean arc magmatism involving older continental crust, similar to Phanerozoic Andean margins. 3) The Archean basement underwent a strong tectonothermal event at the end of the Neoarchean, with the metamorphic zircon ages being 10–30 million years younger than the timing of magmatism, a common feature of the North China Craton. 4) A late Paleoproterozoic tectonothermal event widely occurred in the western part of eastern Hebei, which is linked with regional ductile deformation.

Detrital zircon U-Pb and Hf constraints on provenance and timing of deposition of the Mesoproterozoic to Cambrian sedimentary cover of the East European Craton, Belarus

The sedimentary cover of the East European Craton (EEC) is unique because of its low degree of diagenetic alteration that allows preservation of the original “source to sink” relationships. The present study provides U-Pb and Hf zircon data for the entire Proterozoic sedimentary section of the EEC based on samples from five boreholes in Belarus within the Volyn-Orsha Basin, one of the most important sedimentary basins of the craton. Twenty-one samples of mudstones and sandstones were selected for detrital zircon U-Pb geochronology, supplemented by the Hf isotope analyses of zircons from 6 samples representing different U-Pb age spectra and bulk rock XRD mineralogy of all mudstone samples collected from the studied boreholes. Five clastic successions in the Volyn-Orsha Basin are characterized by different sources of detrital material: (1) The Mesoproterozoic Pinsk Suite with a narrow population of c. 2.0 Ga zircons, (2) The Orsha Suite with a broad 1.3–3.2 Ga zircon age distribution, (3) Glacial sediments of the Vilchitsy Series with an age spectra similar to the Orsha Suite, except for a c. 1.0 and 1.2 Ga cluster, (4) The Volyn and Valdai Series, including lowermost Cambrian, with a narrow trimodal population of 0.5, 1.5, and 1.8 Ga zircons, and (5) lower Cambrian (?) sediments with a diffused zircon age spectrum, including a 500–700 Ma cluster. Maximum depositional ages were constrained for the Vilchitsy Series at 977 ± 6 Ma and for the Volyn Series at 579–545 ± 4 Ma. Combined Hf zircon data indicate four episodes of new continental crust generation at 3.3, 2.8, 2.1–2.3 and 1.8 Ga, suggestive of source terrains within the crust of the present-day EEC. These sources experienced subsequent reworking of crust at c. 1.8 Ga and 550–600 Ma. Only a lower Cambrian sample lacks any trend or clustering within the Hf data probably due to mixing of zircons from exotic and local sources. Paleogeographic models explaining these provenance signals in terms of intracratonic erosion and sediment transport are presented.