Soil organic matter (SOM) plays an important role in agricultural production and arable land quality improvement. Hyperspectral technology enables frequent surveys over large areas. In this study, we explored the spectral heterogeneity of differences in soil types and SOM content, and proposed a method for measuring SOM content in large areas using spectroscopy. The results indicate regional variations in factors affecting soil spectral absorption peaks, with noticeable latitudinal disparities. The first-order differential partial-least-squares method provided the best prediction for the SOM inversion. The coefficient of determination (R2) for the SOM inversion model was 0.93, and the root mean square error (RMSE) was 3.42, with an 8.49 g/kg difference in the SOM content. When the difference in SOM content fell between 8 and 15 g/kg, the inversion effect model performed best. The optimal model R2 exceeded 0.95, and the RMSE was less than 5. The comprehensive analysis showed that the organic matter content was an important factor affecting the SOM content estimate and must be considered in the real process. In addition, it is crucial to categorize soil samples on the basis of distinct soil types while maintaining a consistent range of SOM content within the same soil type, ideally between 8 and 15 g/kg. Subsequently, the first-order differential partial least squares method is applicable. These results are expected to contribute to the acquisition of high-quality information on variations in the SOM of complex large-scale areas.
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