Ion velocity distribution functions (ivdfs) are investigated by laser induced fluorescence in Ar–Xe and Ar–He expanding helicon plasmas as a function of gas composition. In the case of Ar–Xe plasma, it was found that in the helicon source, both the Ar+ and Xe+ vdfs are unimodal. Their parallel speeds are subsonic and unaffected by changes in gas composition. At the end of the source, the argon ivdf shows a bimodal structure indicative of an electric double layer upstream of the measurement location. The fast argon ion component parallel velocity increases with Xe fraction from 6.7 to 8 km/s as the Xe fraction increases from 0% to 4%. In the expansion region, the bimodal character of Ar ivdf is maintained with a supersonic fast component reaching parallel speeds of 10.5 km/s. For all the studied plasma conditions and different spatial locations, the Xe+ vdf exhibits a unimodal structure with a maximum parallel flow velocity of 2.2 km/s at the end of the source. For Ar–He plasma, the Ar ivdf is bimodal with the fast ion component parallel velocity increasing from 5.2 to 7.8 km/s as the He fraction increases from 0% to 30%. For the same He fraction range, the slow argon ion population distribution changes from a single Gaussian to a wide distribution extending all the way from the speed of the fast population to 0 m/s.