High-resolution ( ∼ 7 eV at 2.3 keV) sulfur K α X-ray spectra have been obtained for a series of sulfur compound targets under heavy-ion impact at the Holifield Heavy Ion Facility. The spectra observed are dominated by a series of satellite peaks arising from varying degrees of L-shell ionization at the time of X-ray emission. Each spectral profile has been parameterized by a single variable p L, the apparent average L-shell ionization probability. Correlations are evident between p L and the corresponding sulfur atom chemical environment. Much stronger correlations are, however, found for variations of some individual peak intensities with specific chemical parameters. Comparison of results for Ar q+ and Kr q+ projectiles show that while L-shell ionization probability has increased, chemical sensitivity has apparently saturated.
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