Heating Process Research Articles

Improving Heat Efficiency of Aniline Production Process by Modifying Heat Transfer Fluid Looping System in Heating and Cooling Process

The nitrobenzene hydrogenation process is a highly exothermic reaction which causes the product temperature will increase and then needs to be cooled down with a heat exchanger. The modification process is needed to improve the heat efficiency of the nitrobenzene hydrogenation process by utilizing the heat from reactor product. Heat transfer fluid is used as a medium of heat transfer for both heating and cooling, so that will create a looping heat transfer process. The looping system of heat transfer fluid receives heat from reactor product and then reuses the heat to reheat the recycled hydrogen and for other utilities, so additional energy for these processes is not required. The process modification was simulated using Aspen HYSYS and the comparison of heat efficiency between the basic and the modified process is calculated using the net-energy formula. The results obtained that the net-energy (NE) value for both basic and modified process is 96,714,359.832 kJ/h and 9.869 kJ/h. This shows that the modified process has better energy efficiency compared to the basic process as the net-energy value is closer to zero. Therefore, this modification increases the heat efficiency of the aniline production through nitrobenzene hydrogenation process. Copyright © 2024 by Authors, Published by Universitas Diponegoro and BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

SHG Assisted Mixed-Phases Anatomizing in a Molecular Ferroelectric.

Anatomizing mixed-phases, referring to analyzing the mixing profiles and quantifying the phases' proportions in a material, which is of great significance in the genuine applications. Here, by using second-harmonic generation (SHG)polarimetry and piezoresponse force microscopy (PFM) techniques, this work elucidates the contributions and distributions of two different symmetric phases mixed in an archetype monoaxial molecular ferroelectric, diisopropylammonium chloride (DIPACl). The two competing phases are preferred in thermodynamics or kinetic process respectively, and this work evidences the switching behavior between the two competing phases facilitated by an external electrical field as opposed to a heating process. This research contributes novel insights into phase engineering in the field of molecular ferroelectrics and is poised to serve as a potent analytical tool for subsequent applications.

Multiwavelength radiation from the interaction between magnetar bursts and a companion star in a binary system

Magnetars are young, highly magnetized neutron stars that are associated with magnetar short bursts (MSBs), magnetar giant flares (MGFs), and at least some fast radio bursts (FRBs). In this work, we consider a magnetar and a main sequence star in a binary system and analyze the properties of the electromagnetic signals generated by the interaction between the magnetar bursts and the companion star. During the preburst period, persistent radiation could be generated by the interaction between the $e^+e^-$-pair wind from the magnetar and the companion or its stellar wind. We find that for a newborn magnetar, the persistent preburst radiation from the strong magnetar wind can be dominant, and it is mainly at the optical and ultraviolet (UV) bands. For relatively old magnetars, the re-emission from a burst interacting with the companion is larger than the persistent preburst radiation and the luminosity of the companion itself. The transient re-emission produced by the heating process has a duration of $0.1 - 10^5 s $ at the optical, UV, and X-ray bands. Additionally, we find that if these phenomena occur in nearby galaxies within a few hundred kiloparsecs, they could be detected by current or future optical telescopes.

Analytical Determination of Nusselt Numbers for Convective Heat Transfer Coefficients in Channel Macroporous Absorbers.

This article introduces a novel analytical equation for computing the Nusselt number within the macroporous structures of channel absorbers utilized in high-temperature solar receivers. The equation incorporates heat and mass transfer processes occurring within boundary layers as fluid flows through complex-shaped macroporous absorber channels. The importance of accounting for the length of the thermodynamic boundary layer within channel-type macroporous media when calculating heat transfer coefficients using the Nusselt equation is demonstrated. By incorporating proposed indicators of porosity and flow characteristics, this method significantly enhances the accuracy of heat transfer coefficient calculations for such media. Discrepancies observed in existing calculation relationships and experiments are attributed to the omission of certain proposed values in the Nusselt number for macroporous media. To address this, empirical coefficients for the Nusselt number are derived using statistical methods. The resulting semi-empirical equation is applied to macroporous absorbers in solar receivers. The findings enable more accurate predictions of future absorber characteristics, enhancing their efficiency. The derived equation is successfully validated against numerical data across various geometric structures of absorbers in concentrated solar power plants.

Solar Heating Modulated by Evaporative Cooling Provides Intermittent Temperature Gradients for Ionic Thermoelectric Supercapacitors

AbstractSolar heating is important for many applications but less attractive for concepts requiring intermittent heating, such as ionic thermoelectric supercapacitors (ITESCs). However, the heating process even at constant solar illumination can be converted to temperature oscillations through water infiltration and evaporation. Here, this process is demonstrated for a carbon nanotube‐cellulose membrane and used to induce temporally varying temperature gradients across an ITESC, which enables continuous operation through repeated charge and discharge cycles. A temperature variation of 10 K can be generated on the top electrode, which leads to a variation in the temperature difference across the ITESC of 7.5 K. Precise control over charge and discharge durations can be achieved by adjusting the volume and interval of the added water. The concept of temporarily adjusting temperatures by evaporative cooling may be extended to create intermittent heating also for other heat sources that are typically constant.

The Temperature of Pretreatment on Microstructure Change of Lump Ore and Improvement of Metallurgical Properties

Goethite is one of the most common minerals in iron ore, and is the main source of internal crystal water generated during the heating process of lump ore. To address this challenge, three measures are proposed: first, minimizing the decomposition of crystalline water upon the introduction of lump ores into the furnace; second, reducing the heat absorption of water vapor within the furnace; and third, increasing the proportion of lump ores being introduced into the furnace. With this in mind, the lump ore preheating treatment technology is introduced. By preheating the lumps at different temperatures, the influence of pretreatment on the reduction and soft melting of the lumps is studied. The results show that at different preheating temperatures, due to the transformation of FeOOH to Fe2O3, the natural goethite gradually changes from natural granular to spherical at higher preheating temperatures. When the preheating temperature is 400–700 °C, the coexisting phase of goethite and hematite in the pores changes obviously. The metallurgical properties of lump ore change dramatically. When the temperature is lower than 400 °C or higher than 700 °C, almost all goethite in lump ore is transformed into hematite, and the morphology does not change.

Analysis of microwave heating of copper powder compacts

The influence of the native oxide films, which is essential for the understanding of the microwave heating of metal powder, is analyzed numerically based on the experimental data on temperature, dilatation and resistance of compacted copper powder samples. The indicative thickness of the oxide films, determined from the resistivity data using an effective medium approximation, is shown to decrease from ≥1 μm to below 1 nm. The effective complex dielectric permittivity and magnetic permeability of the copper powder with oxide films on the particles are calculated within the recently developed models. The dielectric permittivity exhibits a percolation behavior in the temperature range of the oxide decomposition, viz. 210–250 °C when microwave heating is carried out in nitrogen and 330–375 °C – in argon. The efficiency of absorption of the incident 30 GHz microwave radiation in a slab of powder is assessed separately for the electric and magnetic-type losses, the contribution of the latter being predominant until the percolation transition. The energy flux density of the incident microwave radiation required to sustain the prescribed heating rate is shown to increase during the microwave heating process from ∼20 W/cm2 to >1 kW/cm2 due to increasing reflection. The additional microwave energy input required for the completion of the endothermic oxide decomposition reaction is shown to be significant at the initial stage of the process (below 200 °C).

Pronounced modification of the wetting and spreading behavior of molten Ag-Cu alloy on TC4 substrate in response to high magnetic fields

This study investigated the wetting of TC4 substrate by molten Ag-Cu alloy under various high magnetic fields (HMFs) during the heating process. By examining changes in melt morphology, variations in contact angle, and characterizing the interface microstructure, we elucidated the underlying mechanism through which HMFs affected wetting behavior. The findings suggest that higher magnetic flux density resulted in smaller contact angles and more extensive spreading at the same temperature, culminating in a greater final spreading diameter. However, there was no significant difference in the final contact angle under various HMFs. Moreover, higher magnetic flux density resulted in a longer precursor zone and thicker reaction layer. The composition of precursor zones and reaction layers remained consistent with and without an HMF. The spreading process was divided into two stages regardless of the presence or absence of an HMF. In the absence of an HMF, the sluggish formation and spreading of precursor zone led to a lower spreading rate in the first spreading stage. Subsequently, as temperature rose, interface reactions drove rapid melt spreading, accelerating the spreading rate during the second spreading stage. In the presence of HMFs, the strong thermo-electromagnetic convection within melt and at liquid/solid interface notably promoted interface reactions and rapid formation of precursor zones, leading to a substantially heightened spreading rate in the first spreading stage. The slowing reaction rate and the limited volume of the melt collectively resulted in a slower spreading rate in the second spreading stage. This study provides new insights into modifying reactive wetting, with potential applications in advanced brazing techniques.

Preparation and Experimental Research of Temperature Sensitive Expansion Gel Material for Fire Prevention and Extinguishing in Coal Mines

ABSTRACT In order to solve the problems of high viscosity at room temperature, easy dehydration and shrinkage of phase change gel, and poor plugging effect of traditional mine gel, a new type of temperature-sensitive expansion gel was developed by using hydroxypropyl methyl cellulose, chitosan, guar gum and sodium bicarbonate as raw materials, using orthogonal test and response surface analysis. The structural characterization, characteristics, fire prevention, and extinguishing performance of the temperature-sensitive expansion gel were tested. The experimental results show that the optimal ratio of temperature-sensitive swelling gel is 0.75 wt % chitosan, 0.5 wt % acetic acid, 2.5 wt % hydroxypropyl methyl cellulose, 0.4 wt % sodium bicarbonate, and 0.15 wt % guar gum. The phase transition temperature (LCST) of this ratio is 67°C. After standing at room temperature for 6 h, the gel viscosity is 5852 mpa·s, the expansion ratio is 0.846, and the strength is 319.525 N/m2. During the heating process of the coal sample after adding the temperature-sensitive expansion gel, the gel will undergo phase change and expansion in the high-temperature area of the coal, and the viscosity will increase. It can stay in the high-temperature area, wrap the coal block, and isolate the oxygen from entering, thus effectively inhibiting the coal spontaneous combustion process. In addition, the gel also produces inert gas carbon dioxide, which effectively suffocates the flame. Therefore, compared with the conventional inhibitor solution, the temperature-sensitive expansion gel has better fire extinguishing effect.

Describing the microwave heating performances of the main constitutes of biomass

Biomass is abundant, environmentally friendly, and an important renewable energy source, and it is mainly composed of cellulose, hemicellulose, and lignin. The microwave heating performances of the main constitutes of biomass is fundamental for the further applications of microwave-assisted technologies, i.e., pyrolysis, gasification, etc. In this study, the effects of reactor volume (50, 150, and 250 mL), material mass (5, 10, and 15 g), and microwave power (450, 550, and 650 W) on the microwave heating performances of biomass main constitutes (cellulose, hemicellulose, and lignin) were investigated. For cellulose, hemicellulose, and lignin, the average heating rates varied in the ranges of 1.14–10.50, 1.00–4.03, and 0.44–14.34 oC/s, respectively. Relationships with R2 values of 0.945–1.000 were proposed for forecasting and regulating the real-time temperatures of biomass main constitutes during the heating process.

Graphene Derived from Municipal Solid Waste.

Landfilling is long the most common method of disposal for municipal solid waste (MSW). However, many countries seek to implement different methods of MSW treatment due to the high global warming potential associated with landfilling. Other methods such as recycling and incineration are either limited to only a fraction of generated MSW or still produce large greenhouse gas emissions, thereby providing an unsustainable disposal method. Here, the production of graphene from treated MSW is reported that including treated wood waste, using flash Joule heating. Results indicated a 71%-83% reduction in global warming potential compared to traditional disposal methods at a net cost of -$282 of MSW, presuming the graphene is sold at just 5% of its current market value to offset the cost of the flash Joule heating process.

Selenium Content of Goose Breast Meat Depending on the Type of Heat Processing

Selenium Content of Goose Breast Meat Depending on the Type of Heat Processing

Electric-thermal collaborative control and multimode energy flow analysis of fuel cell hybrid electric vehicles in low-temperature regions

The energy flow distribution characteristics of electric vehicles operating in various propulsion modes and all climatic scenarios have not been thoroughly explored. To achieve effective electric-thermal collaborative energy management, intelligent control methods must be applied considering various climatic conditions to alleviate mileage anxiety. In this study, we developed a novel electric–thermal collaborative energy management strategy based on an improved deep neural network and energy quantification model to increase the global energy conversion efficiency. The complete energy consumption distribution characteristics are summarized under various strategies and propulsion modes based on an experiment data collected by the vehicle control unit that involves battery self-heating, cabin heating, acceleration consumption, and fuel consumption in the temperature range of −10°C-35 °C. Our findings indicate that, for a fuel cell hybrid bus in the cycle including the initial cabin heating process, the heating consumption in the pure electric mode was 9.9 kWh/cycle and 13 kWh/cycle when the ambient temperature is −2 °C and −10 °C, respectively, accounting for 33 % and 42 % of the total consumption, respectively. After using the waste heat from the fuel cell, the consumption of electric heating under the same conditions is only 3.7 kWh/cycle. In the high-temperature scenario, the cabin cooling consumption is 3.26 kWh/cycle, accounting for only 18 % of the total energy consumption. Finally, in low-temperature scenarios, the electric–thermal collaborative strategy reduced the cost by 14.7 % and 9.2 % in the pure electric and hybrid modes, respectively. Thus, our approach significantly improves energy utilization and conversion efficiency, especially at low temperatures.

Implementation of inverse method for identification of process parameters in a laser heating process

Changes in process parameters can alter the temperature data of a solid body during the laser heating process. This paper proposes an inverse method to determine the laser heating parameters, namely, sheet width, sheet thickness, laser power, and scan speed of the work specimen for the given temperature response which is assigned by the user. The method uses an analytical tool on moving heat source as a forward model capable of real-time temperature prediction of the sheet under the laser heating process. The effectiveness of the present forward model that incorporated the temperature-dependent material properties is tested by experimental findings performed on Al 6061-T6 sheets. Next, an iterative search process based on heuristic method is carried out for satisfying a prescribed temperature response by the optimization of unknown parameters. To illustrate the implementation and assess the practicality of the inverse method, two examples based on laser heating applications are used. The method proposed herein recover the unknowns for the prescribed temperature response after a few iterations, provides an efficient way to optimize the laser heating process. Additionally, the effect of measurement error on the findings of the inverse problem is addressed.

Electrochemical grand potential-based phase-field simulation of electric field-assisted sintering

An electrochemical grand potential functional was proposed to describe the sintering of an ionic ceramic green body. The resultant phase-field description enables simulation of the consolidation of an arbitrary number of granular particles and their interactions with the surrounding void phase. The model includes the effects of charged vacancies and the associated interactions between internal and applied electric fields. Defect segregation to grain boundaries is also accounted for, as well as enhanced interfacial defect mobilities. The model was parameterized for Y2O3. Simulations of two-particle systems showed that the applied electric field had an increasingly important impact on neck growth as particle size increased. A sudden rapid increase in temperature occurred for larger field strengths, which has been reported to be correlated to the onset of a flash event in flash sintering. Simulations of many particles showed that internal heat generation by Joule heating was localized at particle–particle contacts (grain boundaries), even though their conductivities were lower than nearby internal particle-void interfaces. A percolative path for ionic charge across the green body and the ceramic sintered solid was thus defined, accelerating the Joule heating process as the porosity of the green body is removed.

Nanometer – Thick titanium film as a silicon migration barrier

Diffusion of silicon atoms to the topmost film surface poses significant challenges in various technological applications. In an effort to address this issue, titanium films with varying thicknesses were deposited on a silicon substrate to evaluate the efficacy of a thin titanium barrier film in blocking silicon migration to the upper film surface. Subsequently, the films were subjected to a 1-hour heating process in air at an oxidizing temperature of 430 K. Atomic force microscopy and Raman spectroscopy were employed to characterize the morphological and structural changes among the investigated films. X-ray photoelectron spectroscopy was utilized to explore variations in chemical composition, determine oxidation states, and measure the thicknesses of the thin titanium oxide layers. The findings revealed that titanium films with a thickness < 50 nm experienced silicon diffusion to their upper film surface. Moreover, an increase in the thickness of the oxide layers over the titanium film on the silicon substrate significantly reduced the migration of silicon to the titanium film surface. At 430 K, the study found that oxide layers at least 6.87 nm thick formed on a 35-nm thick titanium layer, which together successfully prevented silicon migration to the top surface of the film.

Effect of current waveform in MIG arc on weld bead formation in plasma-MIG hybrid welding

Plasma-metal inert gas (MIG) hybrid welding enables to join thick steel plates in single pass. However, arc coupling occurring between the plasma and MIG arcs disturbs its heat source characteristics, lowering the welding quality. This arc coupling phenomenon is not yet understood due to the complexity. This study aims to clarify the effect of current waveform of arc on weld bead formation according to the arc coupling in plasma-MIG hybrid welding. The metal transfer characteristics and bottom side weld pool were observed for direct current (DC) and pulse-MIG current waveforms. In addition, Ni element was used for visualizing the transport process of high-temperature molten metal provided by MIG welding within the weld pool. From these results, the effects of differences in MIG arc current waveforms on heat and mass transport processes within the weld pool and also on weld bead formation on the bottom side through changes in the occurrence of arc coupling were discussed. As a result, it was clarified that the droplets after detachment from the wire were transferred to the weld pool surface under the wire tip for DC MIG current, while those were transferred along the wire axis to the weld pool surface behind the keyhole for pulse-MIG current. When the droplet was transferred to the weld pool region with the forward flow such as the pulse-MIG current case, the heat was transported to the bottom side together with the counter-clockwise eddy behind the keyhole, strongly contributing to increasing the penetration depth. In the case of pulse-MIG current, the plasma arc is oscillated due to the arc coupling. According to this oscillation, the accumulation of molten metal behind the keyhole is prevented to suppress the humping bead formation. Consequently, pulse-MIG current was found to be suitable for increasing the penetration depth and suppressing humping bead formation on the bottom side comparing with DC MIG current.

In-Depth Analysis of the Species and Transformations during Sol Gel-Assisted V2PC Synthesis.

The sol-gel reaction mechanism of 211 MAX phases has proven to be very complex when identifying the intermediate species, chemical processes, and conversions that occur from a mixture of metal salts and gelling agent into a crystalline ternary carbide. With mostly qualitative results in the literature (Cr2GaC, Cr2GeC, and V2GeC), additional analytical techniques, including thermal analysis, powder diffraction, total scattering, and various spectroscopic methods, are necessary to unravel the identity of the chemical compounds and transformations during the reaction. Here, we demonstrate the combination of these techniques to understand the details of the sol-gel synthesis of MAX phase V2PC. The metal phosphate complexes, as well as amorphous/nanocrystalline vanadium phosphate species (V in different oxidation states), are identified at all stages of the reaction and a full schematic of the reaction process is suggested. The early amorphous vanadium species undergo multiple changes of oxidation states while organic species decompose releasing a variety of small molecule gases. Amorphous oxides, analogous to [NH4][VO2][HPO4], V2PO4O, and VO2P2O7 are identified in the dried gel obtained during the early stages of the heating process (300 and 600 °C), respectively. They are carbothermally reduced starting at 900 °C and subsequently react to crystalline V2PC with the excess carbon in the reaction mixture. Through CHN analysis, we obtain an estimate of left-over amorphous carbon in the product which will guide future efforts of minimizing the amount of carbon in sol gel-produced MAX phases which is important for subsequent property studies.

Dielectric Characterization of Solutions of Galactomannan Extracted from Adenanthera pavonina L.: Effects of Purification and Ethanol Concentration.

Galactomannans are polysaccharides obtained from legume seed extraction. They present a chemical structure consisting of D-mannose chains linked by glycosidic bonds and galactose branches. The main focus lies in their use as thickeners in the food industry, aimed at improving the dielectric properties of food during heating processes within the radiofrequency and microwave ranges. In this work, the prepared galactomannan samples were electrically analyzed through impedance spectroscopy, which is a powerful physical technique. From the experimental measurements, the dielectric permittivity and loss tangent of the galactomannan solutions were analyzed and the electrical modulus formalism was used to study the dielectric relaxations. Crude galactomannans exhibited higher values of permittivity, conductivity, and losses compared to purified galactomannans. Increasing ethanol concentration in galactomannan purification causes an increase in the permittivity and conductivity of galactomannan solutions. In a 1% solution, at 1 kHz, the permittivity increased from 378.56 to 538.09, while in the 2% solution, this increase was from 656.22 to 1103.24. Regarding the conductivity, at the same frequency, the increase was from 1.6 × 10-3 to 3.3 × 10-3 Ω-1m-1 and from 2.9 × 10-3 to 5.5 × 10-3 Ω-1m-1, respectively. The rise of the ethanol concentration in galactomannan purification led to a decrease in the relaxation time, from 448.56 to 159.15 μs and from 224.81 to 89.50 μs in the solution with 1 and 2%, respectively. The results suggest that galactomannan from Adenanthera pavonina L. has potential for use in the food industry.

Phase change-related thermal property characterization and enhancement in carbon-based organic phase change composites

By utilizing the significant amount of energy absorbed and released during their phase transitions, phase change materials (PCMs) can capture and store thermal energy to fill gaps between supply and demand. Due to their many favorable properties, organic PCMs have gained attention in a wide range of applications. Nevertheless, their inherent low thermal conductivity has limited the direct use of organic PCMs in thermal energy storage (TES). Extensive research has been conducted on enhancing organic PCM thermal conductivity by incorporating high thermal conductivity materials. Owing to their high thermal conductivity and low density, carbon-based materials have been extensively used for thermal conductivity enhancement in phase change composites (PCCs). Carbon-based organic PCCs, which incorporate highly thermally conductive carbon allotropes and their direct chemical derivatives with organic PCMs, are a group of diverse PCCs with highly promising potential for TES applications. Adequate latent heat and shape stability performances are crucial to the success of the applicational performances of these PCCs. Much empirical research has pushed efforts to enhance these phase change properties, yet a logical understanding of these enhancement efforts based on the thermodynamics and intermolecular interactions of carbon-based organic PCCs has been elusive. In particular, the effect of characterization methods on the evaluation of phase change properties has been largely understudied. This review strives to provide novel physical and chemical insights into latent heat and shape stabilization evaluation processes and enhancement efforts in carbon-based organic PCCs through a detailed review and analysis of recent literature. The review provides an unprecedented comprehension of newly developed PCCs that challenge the traditional understanding that the latent heat of PCCs cannot exceed that of its base PCM. Efforts on phase change property enhancement driven by these new insights have the potential for carbon-based organic PCCs to succeed in a variety of TES applications, including solar-thermal harvesting, thermal management of batteries and electronics, thermoregulating textiles, and infrared stealth and infrared responsive materials.