Heat Energy Research Articles

Techno-economic viability of sustainable solar co-generation using CPV cells in parabolic dish concentrators: A 20-year perspective

Solar co-generation is a cutting-edge technology that enables the instantaneous production of electricity and heat energy by employing concentrated solar power (CSP) systems. This study presents the development and experimental analysis of a novel small-scale solar co-generation system, utilizing concentrated photovoltaic (CPV) cells integrated into a solar paraboloidal dish concentrator (SPDC) for simultaneous electricity and heat production. The system, designed with a high concentration ratio, employs a CPV module composed of four 1 cm × 1 cm cells mounted on a flat receiver of a parabolic dish concentrator with an aperture area of 12.6 m2. Experimental results, obtained over three consecutive days, demonstrate that the CPV module achieves an electric power output ranging from 480 to 645 W daily, while the SPDC system generates thermal energy between 395 and 725 W. The economic analysis indicates a cost of ₹10.75 per unit of electricity, with a payback period of approximately 13.5 years, assuming a 20-year system lifespan. Additionally, the reliability of the CPV module and the impact of varying encapsulation materials were critically assessed, providing insights into potential improvements and long-term performance. The findings underscore the viability and economic potential of solar co-generation systems employing CPV technology, contributing to the advancement of sustainable energy solutions.

Exploring the theoretical minimum energy use in the U.S. office building sector

This paper explores the minimum energy that would be required to provide all energy-using services currently used the U.S. office building sector if they were all provided by thermodynamically ideal devices that do not violate physical law. Data from the U.S. DOE and the General Services Administration were used to identify office building workspace services, equipment, occupancy and schedules. Internal building loads were estimated after identifying or conservatively approximating the thermodynamically ideal power required for each service. The average thermodynamically ideal office building in the U.S. would use 2.2 kWh/m2-yr or less, which represents 1.0% of the current average end-use consumption in the sector. Such a large gap between the thermodynamic limit and today’s practice is related to the fact that the energy performance of all the internal gain producing equipment in buildings is far from ideal along with the HVAC equipment and envelope components. Ideal office buildings would use 69.7% of their energy for cooking and related domestic water heating and cooling; illumination accounts for a smaller portion, consuming 17.5%, while office equipment and cooling would use 6.9% and 5.9% of the total consumption, respectively. Dramatic reductions come from the elimination of heating energy and air distribution energy brought about by ideal adiabatic building envelopes and frictionless air distribution. Cooling energy is virtually eliminated by the combination of greatly reduced cooling loads and ideal Carnot equipment. But the thermodynamically ideal office equipment would use two orders of magnitude less energy than today as well.

Phonon polariton-mediated heat conduction: Perspectives from recent progress

AbstractIt has been well-accepted that heat conduction in solids is mainly mediated by electrons and phonons. Recently, there has been a strong emerging interest in the contribution of various polaritons, quasi-particles resulting from the coupling between electromagnetic waves and different excitations in solids, to heat conduction. Traditionally, the polaritonic effect on conduction has been largely neglected because of the low number density of polaritons. However, it has been recently predicted and experimentally confirmed that polaritons could play significant roles in heat conduction in polar nanostructures. Since the transport characteristics of polaritons are very different from those of electrons and phonons, polariton-mediated heat conduction provides new opportunities for manipulating heat flow in solid-state devices for more efficient heat dissipation or energy conversion. In view of the rapid growth of polariton-mediated heat conduction, especially by phonon polaritons, here we review the recent progress in this field and provide perspectives for challenges and opportunities. Graphical abstract

MoS2/porous carbon nanofiber heterostructures for efficient evaporation-driven generators.

Evaporation power generators (EPGs) based on natural water evaporation can directly convert heat energy from the surrounding environment into electrical energy. However, EPGs are difficult to commercialize due to the low charge generation and transport efficiency of single material systems, resulting in unsatisfactory open-circuit voltages and short-circuit currents. Here, we step by step prepared MoS2/porous carbon nanofiber (PCNF) heterogeneous systems by electrospinning and hydrothermal methods. Electron microscope measurements proven the uniform coating of high-crystalline quality MoS2 nanosheets on PCNF fabrics, and the uneven concave-convex surface increased the specific surface area. MoS2 covered PCNF fabrics retained good hydrophilicity, which was suitable for absorbing water and keeping the surface wet during long-term evaporation. Moreover, layered MoS2 with rich surface charge improved the charge transfer of the MoS2/PCNF fabrics. As a result, the open-circuit voltage and short-circuit current of the EPGs prepared with MoS2/PCNF fabrics were improved to 0.25 V and 75 μA, respectively, compared with those based on PCNF fabrics, which demonstrated that the MoS2 coatings improved the interaction area with water and the charge transfer effect of the EPGs. This heterogeneous combination strategy provides ideas for the preparation of high-performance EPG materials.&#xD.

Long-term price guidance mechanism for integrated energy systems based on gated recurrent unit - vision transformer prediction and fractional-order stochastic dynamic calculus control

Against the backdrop of global climate change, renewable energy (RE) performs significant effects in reducing carbon emissions. Nevertheless, volatile RE sources disrupt the energy supply-demand balance (ESDB) in the energy market. Flexible energy (FE) can effectively mitigate the problem with high flexibility and controllability. FE sources are widely distributed in integrated energy systems (IESs). However, existing methods guide scattered FE in IESs with insufficient accuracy. To accurately guide FE, this study proposes an improved long-term price guidance mechanism (ILPGM) based on gated recurrent unit (GRU)- vision Transformer (ViT) prediction and fractional-order stochastic dynamic calculus (FSDC) control. The ILPGM combines GRU and ViT for baseline load forecasting and applies the FSDC method. The ILPGM can optimize the energy consumption of IESs and promote the ESDB while decreasing energy costs. The ILPGM is applied to the IES at Arizona State University-Tempe. The experimental results indicate that: the average coefficient of determination of electrical and heat energy under ILPGM is 97.69 %, realizing flexible regulation of energy consumption; the ILPGM can save 26.36 % actual cost and 94.62 % potential cost savings for the IES; compared to the previous long-term price guidance mechanism, the ILPGM provides an additional 5.87 % total cost savings and 28.65 % potential savings.

A novel route of carburizing through microwave hybrid heating

Abstract Carburizing is a surface treatment process by diffusing carbon into the steel. These days, manufacturing industries demand highly efficient processes that consume low power. Microwave processing is a newly evolving process that consumes low power. This study proposes a novel route for carburizing mild steel (substrate) through experimental and simulation studies using a microwave heating. Charcoal powder was used as a susceptor to convert microwave energy into heat energy and to deposit carbon on the surface of the specimen. The mild steel specimens were exposed to the microwave power input of 900 W and 360 W for exposure time of 1500 s and 1980 s naming it as S2 and S3 respectively. The microstructural analysis of specimens S2 and S3 confirms the formation of pearlite structures at the surface. However, the amount of pearlite structure was significantly higher for the S3. The higher carbon content is confirmed through energy-dispersive x-ray spectroscopy (EDS) analysis of specimen S3. The average hardness of the S3 specimen was determined to be 220.8 HV, which shows an increase of 38.36% compared to the S1 (base metal). x-ray diffraction (XRD) results indicate the additional cementite peaks (Fe3C) and ferrite-confirming phase transformations for carburized samples. The wear analysis of S2 and S3 was conducted through pin-on-disk testing. The peak COF of 0.73 and 0.64 was observed for S2 and S3 respectively. The hard surface of S3 resists the penetration of the counter body to a greater extent due to the fine morphology of pearlite. From the FEM study, the maximum value of 7.96 × 10 3 (V/m) was determined at the center region for the electric field distribution in the microwave cavity, which is the optimum value for efficient heating. The maximum temperature of the mild steel obtained during the carburization process was 900 °C in 1800 s. The microwave carburizing process requires relatively less time than the conventional carburizing process which will save energy consumption.

Research on performance and potential of distributed heating system for peak shaving with multi-energy resource

Climate change and its negative effects are driving the global shift from fossil fuels to renewable energy sources. To tackle the dependency on traditional energy sources in harsh winter regions and improve heating quality during periods of thermal demand fluctuations, this paper proposes a new distributed heating peak shaving system (DHPS). The system combines municipal heat and clean energy within the secondary network while reducing the return water temperature in the primary network. It comprises solar collectors, electric thermal storage tanks (ETST), and absorption heat pump (AHP) units, integrated into conventional heat exchange stations. The system operates in two modes to manage peak and off-peak loads respectively, with TRNSYS simulation used to evaluate performance across a range of peak-shaving gradients. A multidimensional comprehensive assessment is conducted between the DHPS under optimal peak shaving coefficient (θ) conditions and conventional peak clipping boiler (PCB). Results indicate that DHPS achieves a high primary energy ratio (PER) of 1.251 at θ = 0.5, reducing combustion emissions by nearly 40%. The static payback period (PBP) of the system is 3.5 years. When the electricity price drops to 0.275 CNY, its operational costs are comparable to PCB. DHPS caters to the energy characteristics of cold regions where electricity supply exceeds demand. It enables flexible peak shaving while ensuring the complete utilization of clean energy and effectively utilizing waste heat from power plants.

The Impact of Residents’ Behaviors and Cognitive Factors on Household Heating Energy Consumption

The Impact of Residents’ Behaviors and Cognitive Factors on Household Heating Energy Consumption

Fuel Cell-Based Distributed Robust Optimal Scheduling for Combined Heat and Power Supply

At present, the safe operation of integrated energy systems is significantly affected by the considerable uncertainty inherent to wind and photovoltaic power generation. Based on this, this paper proposes an optimal scheduling model for integrated electricity, heat, and hydrogen-based energy systems on distributed robust optimization (DRO). Firstly, a combined heat and power microgrid system considering hydrogen energy systems was constructed based on the thermoelectric cogeneration characteristics of fuel cells and electrolyzers. Then, a data-driven two-stage distribution robust optimization scheduling model is built by combining typical historical data of wind power output, photovoltaic power output, and load. The results show that the distributed robust method reduces the running cost by 6% compared to the deterministic method. The proposed method and model are capable of meeting the demand for thermoelectric loads within the microgrid in a more cost-effective manner, thereby achieving stable and independent operation of the system.

Heat energy utilization of a double-flash geothermal source efficiently for heating/electricity supply through particle swarm optimization method

The principal aim of this article is to optimize the thermal and electrical efficiency of a geothermal combined heat and power system through metaheuristic particle swarm optimization (PSO) method. The objective of this research is to conduct a thorough analysis of the incorporation of metaheuristic PSO technique, with a specific emphasis on the potential advantages and obstacles associated with the utilization of metaheuristic approaches in improving the effectiveness of geothermal energy systems. The utilization of a double-flash geothermal system in conjunction with a transcritical carbon dioxide Rankine cycle is utilized for the co-generation of electricity and thermal energy. The research utilized a PSO method to enhance power generation, heating capacity, and overall system efficiency. The PSO algorithm was employed to determine the optimum operational parameters for a pressure level of 820 kPa and a pressure ratio of 1.59, leading to the maximization of power output to 2591.4 kW The PSO algorithm effectively identified the optimal operational parameters as a pressure of 820 kPa and a pressure ratio of 1.59, resulting in the achievement of a peak power output of 2591.4 kW. The methodology has determined that a pressure of 916.4 kPa and a pressure ratio of 1.5 represent the optimal parameters for achieving a maximum heating capacity of 12329.1 kW.

Initially reactive and concentrated generalized fluid wavy flow with the applications of disorder theory and magnetic field: A computational study

The wavy flow of generalized fluid namely, Cross fluid is mathematically formulated on a gravitationally affected vertical wavy surface with significant physical effects which is the main theme of this work. This particular dynamics of chemically reactive materials is further explored with an irreversible process. A significant heat transfer is measured through thermal resistance during the consideration of entropy optimization. Since entropy generation is associated with the mechanical systemenergy loss is more helpful in monitoring the entropy production in different engineering and industrial processes. Specifically, such irreversibility process appearance causing a noticeable low efficiency in the relevant practical sectors. For better performance in the minimization of friction on the wavy surface, flow is dissipated in terms of heat. However, the measure of loss in terms of work is introduced in the form of thermal radiation, viscous dissipation, magnetic field, and first-order chemical reaction. Additionally, the expected pressure drooping on the wavy surface is another goal of the entire study. The non-linear mathematical equations are determined by following the maximum viscosity approach. Relevant and important results are portrayed to show the various features of the newly developed work. The significant findings are approximated via one of the collocation methods while using MATLAB software. The Richardson number and buoyancy parameter enhanced the flow speed of the materials. The heat transfer rate is decreased by both Eckert number and wavy amplitude and the chemical reaction factor enhanced the mass transfer rate. The heat energy of the materials is escalated with the help of electromagnetic wave radiation and temperature ratio factor. Strengthening the chemical reaction factor declined the mass flow during the typical motion of the liquid. In the last, a comparison is provided to show the accuracy of the numerical approach.

Co-delivery of polyphyllin II and IR780 PLGA nanoparticles induced pyroptosis combined with photothermal to enhance hepatocellular carcinoma immunotherapy.

The clinical efficacy of immunotherapy for hepatocellular carcinoma (HCC) is significantly limited by the low immunogenicity of the tumor. Recent studies have revealed that both pyroptosis and photothermal therapy can effectively induce tumor immunogenic cell death (ICD) in liver cancer cells. Polyphyllin II (PPII), the major active component of Rhizoma Paridis, has been demonstrated for the first time to induce pyroptosis in tumor cells, while IR780 is activated by 808nm laser to transform light energy into heat energy, effectively eliminating tumor cells. However, both PPII and IR780 are afflicted with challenges such as low solubility and poor targeting, significantly limiting their utilization. To address these problems, the pyroptosis inducer PPII and photosensitizer IR780 were co-loaded in PLGA nanoparticles by precipitation method, and the aptamer AS1411 was modified on the surface of nanoparticles to construct the targeting nanoparticles (Apt/PPII/IR780-NPs). The nanoparticles exhibit a pH/NIR dual-response intelligent release feature, which realizes the targeted and controlled release of drugs in tumor site. Furthermore, it can rapidly release PPII to induce cell pyroptosis under laser irradiation, combining with IR780-based photothermal therapy exert a significant synergistic anti-tumor effect in vitro and in vivo. This process not only promotes maturation of DCs and activates effector T cells, thereby initiating adaptive immunity, but also generates enduring and effective immune memory. In addition, Apt/PPII/IR780-NPs significantly improved the Anti-PD-1 efficacy. In summary, chemo-photothermal therapy based on Apt/PPII/IR780-NPs can significantly enhance tumor ICD, which provides a promising new strategy for HCC immunotherapy.

Integrating MXene Film With Recyclable Polyethylene Glycol-co-Polyphosphazene Copolymer as Solid-Solid Phase Change Material for Versatile Applications.

Phase-change materials (PCMs) stand a pivotal advancement in thermal energy storage and management due to their reversible phase transitions to store and release an abundance of heat energy. However, conventional solid-liquid PCMs suffer from fluidity and leakage in their molten state, limiting their applications at advanced levels. Herein, a novel Zn2+-crosslinked polyethylene glycol-co-polyphosphazene copolymer (PCEPN-Zn) as a solid-solid PCM through dynamic metal-ligand coordination is first designed and synthesized. The as-synthesized PCEPN-Zn is further integrated with an MXene film to construct a double-layered phase-change composite through layer-by layer adhesion. Owing to the introduction of MXene film with low emissivity, good light absorptivity, and nonflammability, the resultant phase-change composite not only presents a high latent-heat capacity, good thermal stability, high thermal reliability, and excellent shape stability, but also exhibits a superior self-healing ability, good recyclability, high adhesivity, and good flame-retardant performance. It can be easily adhered to on most objects for various application scenarios. With a combination of the excellent functions derived from PCEPN-Zn and MXene film, the developed phase-change composite exhibits broad prospects for versatile applications in the thermal management of CPUs and Li-ion batteries, thermal infrared stealth of high-temperature objects, heat therapy in the clinic, and fire-safety for various scenarios.

Effectiveness of Screens Shading Opaque Facades in Terms of Building Thermal Modernisation

Screens used in modernizations of buildings to diversify the facade also provide shade on the walls. The article presents a comparison of the effectiveness of shades with different degrees of shading in terms of energy savings. On summer days, especially when there is a lot of sunlight and air temperatures are above 30°C, the covers reduce the temperature on the outer surface of the wall and, as a result, improve the microclimate of the rooms. Lower temperatures result in less heat accumulated during the day. The results were compared for various masonry materials. Less heat energy accumulated in the wall reduces the energy demand to cool the internal air. Energy savings were estimated over 50 years of building use. A method was proposed to quickly compare the effectiveness of the different shading shields.

Rationally designed photothermal-pyroelectric Fe0.9Ni0.1S2/ZnSnO3 Z-scheme heterojunction for promoting electrical charge polarization towards optimized photocatalytic H2 evolution and intermolecular N-N coupling reaction

Developing a photocatalytic composite system that can couple hydrogen (H2) evolution and benzylamine (BA) oxidation is a challenging task, especially while avoiding sacrificial agents and value-added chemicals. Here, a practical approach is reported to develop a photothermal-pyroelectric-Fe0.9Ni0.1S2/ZnSnO3 photocatalytic system with core–shell and Z-scheme heterostructure via hydrothermal and annealing methods. Although Fe0.9Ni0.1S2 nanoparticles (NPs) could convert most of near-infrared (NIR) light energy into heat energy to drive the pyroelectric effect of ZnSnO3, it also results in temperature fluctuations (ΔT) in the system, causing natural polarization and thermoelectric effects under the condensed water circulation. As a result, the as-designed Fe0.9Ni0.1S2/ZnSnO3-2 composites could yield up to 7.194 mmol g-1h−1 with exceptional photocatalytic H2 evolution under simulated sunlight. This result is 5.41 and 4.92-fold those of Fe0.9Ni0.1S2 and ZnSnO3, respectively, with 16.66 % apparent quantum yield (AQY) under 365 nm monochromatic light. At the same time, the composites could also oxidize BA and yield up to 6.640 mmol g-1h-1n-benzylidene benzylamine (NBBA) with a 90.2 % selectivity. Due to the synergistic effect of Z-scheme’s built-in electric field and photothermal-pyroelectric of Fe0.9Ni0.1S2/ZnSnO3, the surface charges released on them could direct the charge transfer pathways and restrain their recombination with accelerated electron transfer kinetics, thus extending the carrier lifetime. This work offers a new perspective for designing electrical charge polarized by the photothermal-pyroelectric effect, which can enhance H2 evolution and BA oxidation concurrently.

Modeling and experiments on plasma ignition of Ekibastuz coal in the form of dust

Due to the low cost of coal and the fact that it is readily available in most parts of the world, coal is a convenient fuel source. Despite the inefficiency of the systems when it comes to converting heat energy into electricity, new technologies are necessary in order to improve their efficiency. In contrast to traditional methods of starting-up boilers and stabilizing combustion, plasma ignition and combustion stabilization (PICS) of pulverized coal flames offers an effective and sustainable alternative to the use of fuel oil or gas. This technology involves heating the air-coal mixture with electric arc plasma until the coal devolatilizes and the coke residue partially gasifies. Consequently, low-rank coal is converted into a highly reactive two-component fuel (HRTF) consisting of combustible gas and coke residue. For these processes in a plasma-coal burner (PCB) using Ekibastuz coal in the form of dust, a kinetic analysis was conducted using the PlasmaKinTherm program. Modeling the kinetics of PICS of pulverized fuel allowed changes in temperature, velocity, and concentration to be determined along the length of a PCB. The composition, degree of carbon gasification, and temperature of a stable coal-dust flame were determined using plasma ignition of solid fuel. Based on the comparison between experimental and calculated data, it was found that the results were satisfactory.

Judicious combinations of gravity, magnetic, electrostatic separators and microwave heat energy on recovery of ilmenite from Humma lean grade beach placer deposit

Microwave heating is an eco-friendly and novel technique for sintering and heating minerals and materials as it has several advantages in terms of phase transformation, energy efficiency, enhancing speed, process simplicity, improved properties. Such heating provides the composite materials to absorb electromagnetic energy volumetrically and transform into heat and produces larger densities as compared to conventional heating. This study focuses on two main objectives: the recovery of ilmenite through a strategic combination of mineral processing equipment, including a spiral concentrator, followed by magnetic and electrostatic separation, and the enhancement of ilmenite concentrate using microwave heat energy on a cleaner magnetic product, followed by electrostatic separation. Continuous magnetic separation results indicate that among the dry high-intensity belt magnetic separator, box mag wet high-intensity magnetic separator and dry rare earth drum magnetic separators, the rare earth magnetic separator yielded the highest quality product. The application of microwave heat energy before the rare earth drum magnetic separator at 1.4 T, followed by high-tension separation, produced the best grade of ilmenite. The magnetic product obtained after microwave treatment contained 98.6% ilmenite, which was further upgraded to a 99.6% ilmenite concentrate through high-tension separation. Therefore, it is recommended that an effective combination of gravity separation, microwave heat energy, rare earth drum dry magnetic separation and high-tension separation be employed to achieve the highest grade of ilmenite concentrate.

Research on Energy-Saving Transformation of Rural Residential Building Envelope Structures and Heating Modes in Northeast China

Rural areas in Northeast China present a large demand for heating energy in winter, but there are problems in such areas with poor thermal performance of building envelopes and poor indoor thermal comfort. In addition, coal-fired boilers are still widely used. China’s “Dual-Carbon Goals” and “Clean Heating” policy call for the creation of a green and comfortable living environment for rural residential buildings. This paper considers the impact of the improvement of the thermal performance of envelope structures on the initial investment of the transformation program and the rated power of the ASHP and proposes an energy-saving transformation method to replace traditional coal-fired boilers with the ASHP on the basis of the improvement of the thermal performance of envelope structures. By establishing a typical rural residential building model in Northeast China, this energy-saving method is simulated based on TRNSYS. The results show that the payback period of investment of the transformation method of “envelope structure + heating system” is not superior to that of the transformation method of only improving the thermal performance of the envelope structure, but it has advantages in the comprehensive life-cycle benefits and it has great advantages in improving the satisfaction of rural residents in the use of heating systems.

A Battery Thermal Management System Integrating Immersion Preheating and Immersion Cooling.

The battery thermal management system (BTMS) depending upon immersion fluid has received huge attention. However, rare reports have been focused on integrating the preheating and cooling functions on the immersion BTMS. Herein, we design a BTMS integrating immersion cooling and immersion preheating for all climates and investigate the impact of key factors on the preheating/cooling performance. For the preheating mode, adopting an inlet flow rate of 2 L·min-1, an inlet temperature of 15 °C, and a preheating time of 600 s is optimal by considering both heating performance and energy efficiency under a low ambient temperature (T a) of -20 °C. The corresponding minimum temperature, average temperature, maximum temperature difference (ΔT max), and rate of temperature rise could achieve 11.81 °C, 14.1 °C, 3.18, and 3.18 °C·min-1, respectively. For the cooling mode, the immersion BTMS could effectively control the ΔT max and maximum temperature of the battery module below 3.08 and 28.48 °C, and 3.21 and 28.5 °C at a high-rate discharge of 3 C under a normal T a of 25 °C and a high T a of 40 °C, respectively.

Comprehensive Review on the Synthesis of [1,2,3]Triazolo[1,5-a]Quinolines.

This report outlines the evolution and recent progress about the different protocols to synthesize the N-heterocycles fused hybrids, specifically [1,2,3]triazolo[1,5-a]quinoline. This review encompasses a broad range of approaches, describing several reactions for obtaining this since, such as dehydrogenative cyclization, oxidative N-N coupling, Dieckmann condensation, intramolecular Heck, (3+2)-cycloaddition, Ullman-type coupling and direct intramolecular arylation reactions. We divided this review in three section based in the starting materials to synthesize the target [1,2,3]triazolo[1,5-a]quinolines. Starting materials containing quinoline or triazole units previously formed, as well as starting materials which both quinoline and triazole units are formed in situ. Different methods of obtaining are described, such as metal-free or catalyzed conditions, azide-free, using conventional heating or alternative energy sources, such as electrochemical and photochemical methods. Mechanistic insights underlying the reported reactions were also described in this comprehensive review.