Momentum, heat and mass transport processes leading to rollover of density-stratified liquid layers in a vessel are investigated numerically. The main purpose of the study is to clarify the effect of initial concentration difference on the onset of rollover. We have calculated a number of cases in which the upper and lower fluids have initially different concentrations and different heating conditions. The result reveals that the initial concentration difference greatly influences the time elapsed before the onset of rollover. If the heating conditions are equal and the initial concentration difference is small, the rollover onset time is shortened. When the initial concentration difference is the same and the heating condition is changed, the rollover onset time is shortened with increasing of wall heat flux. The processes leading to rollover are as follows. Initially, two convection are induced in the upper and lower fluids separately, this situation being continued for a certain period, while the concentration is diffused with the convection. Finally, a large amount of the lower high-density fluid reaches the top surface, and then the fluids are suddenly mixed together.
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