Due to the rapid development of electronic devices, the improvement of air–cooling methods for thermal management is urgent. In the present work, a promising way of coupling pulsating flow and vortex generators is proposed to eliminate the impacts of severe local high-temperature regions behind the vortex generators. Different from the traditional qualitative analysis, chaos is introduced to identify the quantitative impacts of the nonlinear dynamics of the coupling system. Particularly, the flow field was examined using the line stretching and the Poincaré map, and the chaotic characteristics of high-frequency pulsating flow were investigated. The results show that high-frequency pulsating flow enhances heat transfer mainly by promoting chaotic mixing. The chaotic fluid repeatedly stretches and folds, which increases the line stretching. Thus, the line stretching distribution can represent the heat transfer. Compared to the steady flow case, at Reynolds number of 1024 and pulsation frequency of 250 Hz, pulsating flow improves the Nusselt number by 5.82% and reduces friction factor by 2.62%, resulting in an improvement of thermal performance factor by 6.76%.
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