We implemented heat pump technology of obtaining esters of fatty acids (of tolivia biodiesel) from vegetable oils, providing for the transesterification of oil with alcohol supercritical fluid and supercritical CO2-extraction of the cooled reaction mixture, its separation by centrifugal force to separate the glycerin from the target product, the separation of carbon dioxide gas-liquid separation with obtaining a purified biodiesel and the return of carbon dioxide to the extraction stage in closed loop thermodynamic cycle. A steam-ejector heat pump is used to prepare energy carriers of different temperature potentials. The physical and chemical parameters of the obtained biodiesel fuel corresponded to the regulatory documentation. The energy and environmental efficiency of using rapeseed ethyl ether (REE) obtained using the proposed technology and its mixtures with mineral diesel fuel when performing agricultural work with the Kirovets K-701 tractor was checked. During the test, it was found that in the same operating conditions, the tractor when working on REE and its mixtures with mineral diesel fuel at maximum power develop the same traction force. The use of biodiesel and its mixtures reduces environmental pollution and increases the purity of the exhaust compared to the operation of a tractor unit using mineral diesel fuel.