Absorption Heat Research Articles

A Review of Energy-Efficient Technologies and Decarbonating Solutions for Process Heat in the Food Industry

Heat is involved in many processes in the food industry: drying, dissolving, centrifugation, extraction, cleaning, washing, and cooling. Heat generation encompasses nearly all processes. This review first presents two representative case studies in order to identify which processes rely on the major energy consumption and greenhouse gas (GHG) emissions. Energy-saving and decarbonating potential solutions are explored through a thorough review of technologies employed in refrigeration, heat generation, waste heat recovery, and thermal energy storage. Information from industrial plants is collected to show their performance under real conditions. The replacement of high-GWP (global warming potential) refrigerants by natural fluids in the refrigeration sector acts to lower GHG emissions. Being the greatest consumers, the heat generation technologies are compared using the levelized cost of heat (LCOH). This analysis shows that absorption heat transformers and high-temperature heat pumps are the most interesting technologies from the economic and decarbonation points of view, while waste heat recovery technologies present the shortest payback periods. In all sectors, energy efficiency improvements on components, storage technologies, polygeneration systems, the concept of smart industry, and the penetration of renewable energy sources appear as valuable pathways.

Analysis of Energy Consumption of a Thermo-Technical System with an Absorption Heat Pump

Analysis of Energy Consumption of a Thermo-Technical System with an Absorption Heat Pump

Hydrated carboxylate ionic liquids as chemical CO2 sorbents of high capacity and moderate enthalpy of absorption

Tetralkylphosphonium carboxylate ionic liquids are herein presented as efficient carbon dioxide chemisorbents in the presence of water. The ionic liquids tetrabutylphosphonium formate and acetate, tributylmethylphosphonium formate and a series of triethylalkylphosphonium formates and acetates, have been prepared by various synthetic procedures either from hydroxide or methylcarbonate precursors, or via multiple steps starting from the parent triethylphosphine. Their physicochemical properties, namely melting or glass transition temperatures, thermal decomposition behaviour, densities and viscosities have been determined. As dry substances, they are viscous liquids or low-melting solids, whereas they show little tendency to solidify in their hydrated forms. They were used mostly as monohydrates in CO2 solubility measurements, exhibiting highest capacities (3 mol L−1, i.e. ≈ 0.9 molCO2 molIL−1, at 5 bar, 25 °C) at equimolar H2O/ionic liquid ratios, approaching those of commercial aqueous amine sorbents. Carbon dioxide chemisorption into hydrogencarbonate takes place, as demonstrated by infrared spectroscopy with isotopic labelling. CO2 absorption isotherms were recorded at various temperatures and the data used to estimate the heat of absorption according to three different thermodynamic models. Enthalpies of CO2 absorption depended heavily on the model used. Rationalisation of this was done on the grounds of the expected relevance of physical and chemical sorption processes. Average heats of CO2 absorption lie between −40 and −45 kJ mol−1, in accordance with mild chemical absorption albeit significantly lower than those for typical chemical sorbents such as amines. This reinforces the feasibility of hydrated carboxylate ionic liquids for CO2 capture technologies of low regeneration energies.

Theoretical approach of hydrogen absorption isotherms on C14–Zr(Cr0.5Ni0.5)2 Laves phases

Theoretical studies on the total energy, and hydrogen absorption thermodynamics on Zr(Cr0.5Ni0.5)2 intermetallic compound were performed using absorption models on the most stable sites. In the first stage, Density Functional calculations provide the absorption energies corresponding to hydrogen in different environments. From there, 28 hydrogen absorption locations were found and the corresponding absorption energies were specifically determined. Then, with this information, a theoretical approximation based on the concept of local absorption isotherm and Fermi-Dirac statistics was applied to study the thermodynamics of the system. In this case, and due to the absence of lateral interactions, exact expressions of the thermodynamic functions can be derived. The process was monitored by following the surface coverage as a function of the chemical potential (absorption isotherm), the energy and configurational entropy of the adsorbed phase and the differential heat of absorption. Interesting behaviours were observed and discussed in terms of the absorption microscopic properties (energy distribution of the absorption sites).

Comparative analysis of thermodynamic performance of high-temperature absorption heat transformers using various ionic liquids as working pairs

The study investigated six sets of ionic liquid (IL) working pairs based on high-temperature vapor-liquid equilibrium data. These sets were modeled using the NRTL activity coefficient model and integrated into a single-stage absorption heat transformer (AHT) for system cycle simulation analysis. A comparison was made with traditional H2O + LiBr working pairs commonly used in AHTs. The study aimed to assess the feasibility of using IL working pairs in high-temperature AHTs to achieve higher output temperatures when dealing with heat sources exceeding 120 °C. Compared to the traditional H2O + LiBr working pair, which has strong COP and ECOP but a limited temperature range, IL pairs offer advantages under various conditions. For instance, H2O + [HMIM][Cl] and H2O + [BMIM][Br] can operate at higher condensation temperatures, providing broader temperature ranges. H2O + [HMIM][Cl] has a wider operational temperature range, suitable for unstable waste heat sources. It also has the highest optimal ECOP value of 0.64 at 197 °C absorption temperature, and shows good cyclic performance, achieving temperature rises of about 78 °C. ILs can maintain stable COPs and circulation ratios over a wide range of absorption temperatures, thus achieving higher temperature rises or meeting the need for higher absorption temperatures. Notably, although the H2O + IL combination exhibits slightly higher exergy loss than the traditional H2O + LiBr pair when comparing exergy losses in the AHT system among different working pairs, its low corrosiveness, lack of crystallization, and wide operating temperature range make these drawbacks insignificant.

Experimental investigation of two-stage NH3–H2O resorption heat storage system with solution concentration difference

Widespread application of solar energy is severely restricted to its instability in time and space. Heat storage system is considered to be one of the most effective pathways to achieve long-term heat supply. Among all the heat storage technologies, solution concentration difference storage technologies stand out for low heat loss and high energy density. By substituting condenser and evaporator in conventional absorption cycle with a high-pressure absorber and low-pressure generator, a resorption cycle could be established. Compared with absorption heat storage cycle, working pressure of resorption heat cycle is lower, making it possible to utilize low-pressure heat source. Two-stage heat source cycle is further proposed to lower working pressure and upgrading supply water temperature. Resorption energy storage cycle with solution concentration difference is established and studied. A prototype based on two-stage ammonia-water resorption heat storage cycle was set up and tested. The result shows that the constraint relation between ambient temperature and heat source temperature of the proposed system. In single-stage mode, the lowest working ambient temperature is 5 °C when heat source temperature is 90 °C. The lowest working ambient temperature could be declined to 0 °C when heat source temperature rises to 120 °C. In two-stage mode, the lowest working ambient temperature is 0 °C when heat source temperature is only 110 °C, which proves the adaptability of two-stage cycle. The highest ESCOP appears in the 15 °C–120 °C single-stage mode, which is 0.742. The highest COP is 1.324 under the same condition. The highest energy density occurs in two-stage mode, which is 467.07 kJ/kg when ambient and heat source is set as 15 °C, 120 °C. The advantage that two-stage mode could enlarge solution concentration difference is verified.

Heat and mass transfer performance analysis of a vertical tubular ammonia/water bubble absorber based on CFD modeling

Bubble absorbers are highly efficient in mass transfer processes, but their popularization is limited by the risks associated with too much ammonia charging. In order to reduce the ammonia charge, it is essential to optimize the heat and mass transfer performance in the absorber. Existing models provide in-depth analysis of bubble motion and morphology, but insufficient attention has been paid to the concentration distribution and interfacial heat and mass transfer resistance. In this study, a two-dimensional axisymmetric vertical tubular ammonia/water bubble absorber was modeled based on Fluent and phase equilibrium, absorption heat data based on Aspen was imported. The relative deviations were 9%, 0.45%, and 4.1% in terms of the completely absorbed height, the liquid phase ammonia mass fraction, and the outlet temperature, respectively. The results showed that the mass transfer deterioration point was at the gas column closure and the heat transfer deterioration point was at the gas column contraction. Variable parameter studies have shown that turbulence effects at the gas–liquid interface can lead to enhancement and deterioration of local heat and mass transfer, which in turn cause local oscillations in the concentration and temperature profiles. While increasing the interphase mass transfer driving force promotes the interphase mass transfer process, it hinders the diffusion mass transfer process within the liquid phase. This effect is particularly pronounced in the absence of intense cooling, leading to an increase in the complete absorbed height.

Optimal Design of a Renewable-Energy-Driven Integrated Cooling–Freshwater Cogeneration System

This study presents a novel approach that will address escalating demands for water and cooling in regions vulnerable to climate change through the proposal of an optimal integrated cooling–freshwater cogeneration system powered by renewable energy sources. Comprising three subsystems (integrated multi-effect evaporation distillation, absorption heat pump, and vapor compression refrigeration (MAV); renewable energy unit incorporating solar panels, wind turbines, batteries, and hydrogen facilities (RHP/BH); and combined heat and power (CHP)), the system aims to produce both cooling and freshwater. By recovering cooling from combined desalination and refrigeration subsystems to chill the air taken into the gas turbine compressor, the system maximizes efficiency. Through the recovery of waste heat and employing an integrated thermo-environ-economic framework, a novel objective function, termed modified total annual cost (MTAC), is introduced for optimization. Using a genetic algorithm, parametric iterative optimization minimizes the MTAC. The results reveal that under optimum conditions, the MAV, RHP/BH, and CHP subsystems account for 67%, 58%, and 100% of total annual, exergy destruction, and environmental costs, respectively. Notably, the system exhibits lower sensitivity to fuel prices than renewable energy sources, suggesting a need for future research that will incorporate dynamic product prices and greater fuel consumption to produce enhanced operational robustness.

Particle scale modeling of heat transfer between mesoscale clusters and surfaces in fluidized beds

The distribution of heat absorption and the mechanisms of conductive, convective, and radiative heat transfers between cold particle clusters (Tp = 300 K) and high-temperature surfaces (Tw = 1173 K) in fluidized beds were investigated through numerical simulations using the MFiX-DEM approach. The influence of cluster characteristics (εc and Dc), restitution coefficients (ep and ew), and particle properties (dp, ρp, kp, and cp) on heat absorption and various heat transfers was examined. The simulations indicate that convection predominantly governed the heat transfer behavior during the process of mesoscale clusters impacting the surfaces. A significant increase in heat transfer can be attained by reducing the cluster volume fraction, cluster size, particle diameter, and particle density. Besides, decreasing the restitution coefficients allowed for a relatively small enhancement of heat absorption. The maximum difference in ep was 2.11 kW/kg, while the maximum difference in ew was 0.99 kW/kg. The specific heat capacity and thermal conductivity of the particle had little influence on the distribution of heat absorption and heat transfer with a maximum relative error of up to 5.8 %. Finally, the mathematical correlation during surface-to-cluster heat transfer was established. This work introduces a novel application of the MFiX-DEM approach to analyze surface-to-cluster heat transfer at the particle scale, providing valuable insights for optimizing fluidized bed systems.

Effect of binder phases on the microstructure and sliding wear properties of HVOF-sprayed WC-based coatings

This study aimed to evaluate the microstructure and wear properties of WC-10Co-4Cr, WC-12Co, and WC-17Co coatings on TC4 titanium alloy. The coatings were deposited using high velocity oxygen-fuel (HVOF) technique. To analyze the influence of binder phases, the coatings were thoroughly examined using scanning electron microscopy, X-ray diffractometer, microhardness tester, and friction and wear tester. The analysis of the results reveals that the primary phases in all three coatings consist mainly of WC, with smaller quantities of W2C and amorphous phases present. The WC-10Co-4Cr powder demonstrates a relatively even particle size distribution, high degree of sphericity, and rough porous surface, allowing for efficient heat absorption and uniform heat distribution, resulting in a dense coating. Notably, the WC-10Co-4Cr coating exhibits significantly smaller tungsten carbide grain size compared to the other coatings. Moreover, the microhardness of the WC-10Co-4Cr coating, measured at 1377.8 HV0.05, is significantly higher than that of the WC-12Co and WC-17Co coatings, which measured at 1258.8 HV0.05 and 1182.4 HV0.05, respectively. Additionally, the WC-10Co-4Cr coating demonstrates low friction coefficient and wear volume, indicating excellent wear resistance. Subsequently, a comprehensive analysis was conducted to determine the reasons for the relative enhancement in binder performance.

Use of an Absorption Heat Pump to Lift the District Cooling Waste Heat Temperature for the District Heating Supply in Tallinn: a Technical and Economic Analysis

Absorption heat pumps can lift a lower temperature waste heat source to a higher temperature useful output. In that process, it uses less electricity as an input compared to heat pumps with electrical compressors. Therefore, in some cases, it can be used to lift a lower temperature waste heat source to a higher temperature useful output with less electricity consumption. Absorption heat pumps are not very widely spread in district heating, mostly because there aren’t many suitable waste heat sources or conditions needed to run them. Tallinn has a district heating system with an annual generation of more than 2 TWh and a goal to make it an entirely carbon neutral district heating system by 2030. Tallinn has also started to develop a district cooling network, and by the end of 2023, the installed capacity was about 6 MW. District cooling capacity is estimated to grow to around 100 MW in 2030. This paper investigates different types of absorption heat pumps and the possibilities of integrating an absorption heat pump to a district cooling plant with the purpose of using waste heat from the cooling plant for renewable heat generation, that can be used in district heating. Different technical aspects are examined to find a suitable production solution, are presented as results. From an economical point of view, the cost of heat to cover peaks with an absorption heat pump is calculated. The effect of reducing fossil fuel use in the Tallinn district heating network with an absorption heat pump is estimated.

Triple effect absorption refrigeration systems for the deep recovery of low grade waste heat

With regard to energy conservation, low grade waste heat recovery technology is attracting significant interest. The absorption refrigeration can significantly utilize waste heat. The current researches have devoted little attention to the recovery of waste heat at lower temperature. This paper presents three triple effect absorption refrigeration systems for the deep recovery of low grade waste heat, which can make use of more waste heat as low as 60 °C. The involvement of absorption heat transformer cycle enables the proposed systems to exploit waste heat at lower temperature. The models of three systems are established using EES software. Energy, exergy and economic analysis of three systems are conducted. The results indicate that the best of three systems can achieve a coefficiency of performance of 0.178 and the maximum exergy efficiency is 0.190. The triple effect absorption refrigeration systems not only generate more cold energy, but also demonstrate better economic performance than the previous cascade absorption refrigeration system. Except for the first system, the other two systems achieve reductions of 8.7% and 15.2% in the cost of unit cold energy respectively. This paper provides three novel approaches for producing high grade cool energy from lower temperature of waste heat.

Development and performance evaluation of a high solar contribution resorption-compression cascade heat pump for cold climates

Absorption-resorption heat pumps (ARHPs) have great potential in utilizing low-temperature solar heat for efficient winter heating, but are limited by their weak adaptability to cold climates relative to absorption heat pumps (AHPs) and vapor compression heat pumps (VCHPs). In this work, a resorption-compression cascade system consisting of ARHP and VCHP subsystems is proposed and investigated, with the goal of achieving efficient winter heating with improved solar contribution in cold climates. Thermodynamic models of the two subsystems and of the whole cascade system are developed for system feasibility verification and performance evaluations. Feasible operation temperature and pressure conditions are identified in terms of internal subsystem matching. Based on these operation conditions, the primary energy ratio (PER) – which is a key performance evaluation index – is investigated over a range of solar fractions (f). The results show that for cases without solar contribution, the PER can be generally >0.95 under feasible operating conditions. In addition, the primary energy saving ratio (PESR) and heating capacity lift ratio (εlift), as well as the heat source temperature (Th) and ambient temperature (Tamb) restriction, are all investigated and compared to those of other, competing heating systems. The results show that the proposed system can reduce the Th demand to 69 °C (with a minimum Tamb of −21 °C) and extend the operational Tamb to −31 °C (with a minimum Th of 90 °C), while importantly achieving PESR > 0.20 and εlift > 20 % under the above extreme conditions. Moreover, when integrating the system with solar heat with f > 43 %, the proposed solar-assisted system has a clear PER advantage over an equivalent VCHP system in the Tamb range from −31 °C to 10 °C, highlighting the possibility of achieving higher solar contribution in cold climates.

Experimental and simulation study on a new gradient waste heat recovery system with a wider application range

This paper proposes a cascade sustainable waste heat recovery technology with low power consumption and the ability to recover waste heat in a wider temperature range, namely, the Absorption-Compression Coupled Heat Pump System. Experiments and simulations were conducted to reveal the effects of different factors on system performance. The results demonstrate that the coefficient of performance and exergy efficiency of the new system increase with an increase in generator outlet water temperature. The coefficient of performance of the new system decreases with an increase in supply heating water inlet water temperature, while the exergy efficiency increases with an increase in supply heating water inlet water temperature. As intermediate temperature increases, the coefficient of performance of new system shows a trend of first increasing and then decreasing, the total heating shows a trend of first increasing and then stabilizing, and the exergy efficiency shows a decreasing trend. Compared to single-effect absorption heat pump system, the new system can recover heat at lower heat source temperatures, and compared to compression heat pump system, it can reduce electricity consumption. Finally, by comparing with experimental data, it was found that the proposed model has good reliability, with a comprehensive error within ±7 %.

Performance Analysis of a New Cascade Waste Heat Recovery System With a Wider Range of Applications

Abstract This paper proposes a new cascade waste heat recovery system with low power consumption and the ability to recover waste heat in a wider temperature range, namely, the absorption–compression coupled heat pump system. Simulations were conducted to reveal the effects of generator inlet and outlet water temperatures, supply hot water inlet and outlet water temperatures, and intermediate temperature on system performance. The results demonstrate that the coefficient of performance and exergy efficiency of the new system increase with an increase in generator outlet water temperature. The coefficient of performance and exergy efficiency of the new system decrease with an increase in supply heating water outlet water temperature. The coefficient of performance of the new system decreases with an increase in supply heating water inlet water temperature, while the exergy efficiency increases with an increase in supply heating water inlet water temperature. As the intermediate temperature increases, the coefficient of performance of the new system shows an increasing trend, and the exergy efficiency shows a decreasing trend. In addition, compared to the single-effect absorption heat pump system, the new system can recover heat at lower heat source temperatures, and compared to the compression heat pump system, it can reduce electricity consumption.

Acceleration mechanisms of Fe and Mn doping on CO2 separation of CaCO3 in calcium looping thermochemical heat storage

The doping strategy with dark metallic oxide has proven effective in improving optical absorptions and heat storage performances of calcium-based materials for the direct solar-driven thermochemical energy storage system, but the microscopic mechanisms of accelerated decomposition of CaCO3 during heat storage process are still unclear. Carbide slag as an industrial waste with low cost and high CaO content is considered as a potential calcium-based precursor for large-scale thermochemical energy storage. Herein, the novel Fe-doped and Mn-doped calcium-based materials were synthesized from carbide slag and their optical absorption properties and heat storage performances were determined in the experiment. The optimum decomposition temperatures of CaCO3 during heat storage process decreased 10.5 °C and 18.6 °C due to Fe doping and Mn doping, respectively. The acceleration mechanisms by Fe doping and Mn doping for enhancing the CO2 separation of CaCO3 in the calcination stage of the heat storage process were investigated by density functional theory (DFT) calculations. The structural parameters, partial density of states, electron differential densities and energy barriers during CO32– dissociation in heat storage process on the doped CaCO3 and undoped CaCO3 surfaces were compared to clarify the effects of Fe doping and Mn doping on the CaCO3 decomposition. The energy barriers of Fe-doped material and Mn-doped material are 1.68 eV and 1.42 eV, respectively, which are 29.4% and 40.3% lower than that of undoped material. This work helps to understand the microscopic mechanisms of accelerated CaCO3 decomposition by Fe and Mn during heat storage process.

Open access, thermodynamically consistent, electrolyte NRTL model for piperazine, AMP, water, CO2 systems on Aspen Plus

This study developed a comprehensive, open-access, thermodynamically consistent, validated vapour-liquid equilibrium model for CO2 absorption into aqueous solutions of piperazine (PZ) activated 2-amino-2-methyl-1-propanol (AMP) on Aspen Plus. This solves a two-decade-old problem of inconsistent specification of PZ, and lacking AMP/PZ, thermodynamic models on Aspen Plus, supporting robust process modelling of AMP/PZ-based CO2 capture systems, considered the contemporary benchmark. The model coverage is wide: total amine concentrations from 30 wt% to 50 wt%, AMP/PZ mole ratios from 0.46 to 23.1, CO2 loadings from 0.04 to 1.07 mol CO2/mol amine, and temperatures from 20 °C to 160 °C. The significance lies in the model’s innovative treatment of the zwitterion PZH+CO2–, leading to accurate VLE predictions and closed charge balances. Absolute average relative deviations (AARD) are 16.6 % to 22.3 % for CO2 partial pressure predictions and 6.3 % to 7.7 % for absorption heats. Gibbs-Helmholz and flash calculated absorption heats consistently compare within 1.5 % to 7.0 %, signalling the model’s thermodynamic consistency.

A surface quality optimization strategy based on a dedicated melt-pool control via the dashed-scan contouring technique in electron beam powder bed fusion

Electron beam powder bed fusion (EB-PBF) is a key metal additive manufacturing (AM) technology known for its high energy absorption and low heat stress. However, the high surface roughness of EB-PBF parts has limited its broader application. To address this issue, this paper proposes a dashed-scan contouring strategy to obtain lower surface roughness in EB-PBF. This strategy involves melting the contour in the form of segmented staggered scans and employing high-frequency jumping of the electron beam (EB) to melt multiple positions synchronously. A comprehensive analysis, combining experimental investigations and multi-physical simulations, elucidates the intrinsic connection between control processes and melt pool stability. Results show that by controlling the length-to-width ratio of the melt pool, regulating overlap distances between melt pools, and fine-tuning cooling times, balling phenomena and Plateau-Rayleigh instabilities can be suppressed. Additionally, these measures effectively mitigate irregularities in track formation when compared to the traditional process. Experimental validation demonstrates the efficacy of the approach, achieving reduced surface roughness (Ra) of thin-walled Ti-6Al-4 V parts from over 25 μm to below 12.6 μm, while enhancing dimensional accuracy and reducing melt anomalies at corners. The proposed dashed-scan contouring strategy opens new avenues for AM of highly reliable and intricate structures, such as lattice sandwich structures, thin walls, and internal flow passages.

Enhanced thermal efficiency of solar liquid tin receiver with carbon black-reinforced carbon nanotube absorber

Carbon nanotube (CNT) heat absorbers were developed to enhance the direct solar heating of liquid tin as a heat-transfer fluid in ground solar receivers. To improve the thermal transfer of absorbed solar energy to tin, absorbers reinforced with carbon black (CB) were fabricated by compression molding. As the compressive strength increased, the CNT absorber formed denser nanotube arrays, which increased the thermal conductivity by 1.68 times. Increasing the CB content further enhanced the conductivity by 1.19 times through grape cluster-like structures. The thermal properties of CNT absorbers predominantly depend on the compressive strength and CB content, and a correlation is proposed for predicting the conductivity. The most effective absorber was prepared at 50 kPa with a CB/CNT ratio of 1.0. The heat absorption characteristics of the solar receivers (50 mm i. d., 60 mm high) with the prepared CNT absorbers were determined. Tin temperatures with CNT absorbers rose more steeply than in bare tin systems, exhibiting a higher temperature increase per irradiance. The efficiency of the bare tin system improved from 24.8 % to 45.4 % using absorbers at 50 kPa and to 46.4 % using a CB/CNT ratio of 0.75 at 20 kPa. Under wind-free conditions, the receiver with the highest thermal conductivity achieved 67.7 % efficiency, a 1.69-fold increase over a tin-only receiver. This study confirmed that the improved thermal conductivity of the CNT absorbers significantly enhanced the receiver efficiency by facilitating rapid solar-energy transfer to liquid tin.

A study on novel dual-functional photothermal material for high-efficient solar energy harvesting and storage

The solar-heat storage efficiency of devices based on phase change materials (PCMs) is limited due to the light absorption and internal heat transfer within the PCMs, unclear thermal conductivity-enhancement mechanism within nanocomposite PCMs, and uncontrollable photothermal-interface modulation. Therefore, a novel controllable strategy was proposed in this study to fabricate dual-functional photothermal storage three-dimensional (3D) phase change blocks (PCBs) with higher thermal conductivity (27.98 W/m·K) and spectral absorption (98.03 %) compared to those of most previously reported PCM-based devices. The as-synthesized PCBs contained millimeter-sized graphite plates with horizontal Van der Waals bonds and oriented micro/nanoscale graphite nanosheets. The structural properties of thin PCM layers between the PCB sheets have synergistically reduced the internal interfacial thermal resistance of the PCBs. Laser-controllable induction was used to fabricate integrated biomimetic-forest 3D optical absorbers on the high thermal conductivity interface of the PCBs, which significantly reduced the thermal resistance of the optical-thermal interface. The resulting 3D-PCBs, integrated with thermoelectric generators, powered portable electronic devices, expanding the applications of traditional PCM heat-storage devices. Therefore, this study will guide the future design of high-performance solar-thermal storage PCMs with a wide range of practical applications.