Harvesting Low-grade Heat Research Articles

MXene Hollow Microsphere-Boosted Nanocomposite Electrodes for Thermocells with Enhanced Thermal Energy Harvesting Capability.

Thermal energy, constantly being produced in natural and industrial processes, constitutes a significant portion of energy lost through various inefficiencies. Employing the thermogalvanic effect, thermocells (TECs) can directly convert thermal energy into electricity, representing a promising energy-conversion technology for efficient, low-grade heat harvesting. However, the use of high-cost platinum electrodes in TECs has severely limited their widespread adoption, highlighting the need for more cost-effective alternatives that maintain comparable thermoelectrochemical performance. In this study, a nanocomposite electrode featuring Ti3C2Tx with hollow microsphere structures is rationally designed. This design addresses the restacking issue inherent in MXene nanosheets, increases the electrochemically active surface area, and modifies the original MXene surfaces with oxygen terminations, leading to improved redox kinetics at the electrode-electrolyte interface, particularly in n-type TECs employing Fe2+/3+ redox ions. The optimized n-type TEC achieved an output power of 84.55 μW cm-2 and a normalized power density of 0.53 mW m-2 K-2 under a ΔT of 40 K, outperforming noble platinum-based TECs by a factor of 5.5. An integrated device consisting of 32 TEC units with a p-n connection is also fabricated, which can be successfully utilized to power various small electronics. These results demonstrate the potential of MXene-based composite electrodes to revolutionize TEC technology by offering a cost-effective, high-performance alternative to traditional noble metal electrodes and contributing to efficient low-grade heat harvesting.

High density lath twins lead to high thermoelectric conversion efficiency in Bi2Te3 modules.

Thermoelectric (TE) generators based on bismuth telluride (Bi2Te3) are recognized as a credible solution for low-grade heat harvesting. In this study, an combinative doping strategy of both the donor (Ag) and the acceptor (Ga) in Ag9GaTe6 as dopants is developed to modulate the microstructure and improve the ZT value of p-type Bi0.4Sb1.6Te3. Specifically, the distribution of Ag and Ga in the matrix synergistically introduces multiple phonon scattering centers including lath twins, triple junction boundaries, and Sb-rich nanoprecipitates, leading to an obviously suppressed lattice thermal conductivity of 0.50 W m-1 K-1 at 300 K. At the same time, such unique microstructures of lath twins synergistically enhance the room-temperature power factor to 48.8 μW cm-1 K-2 and improve the Vickers hardness to 0.90 GPa. Consequently, a high ZT of 1.40 at 350 K and ZTave of 1.24 (300-500 K) are achieved in the Bi0.4Sb1.6Te3 + 0.03 wt% Ag9GaTe6 sample. Based on that, a competitive conversion efficiency of 6.5% at ΔT = 200 K is obtained in the constructed 17-couple TE module, which exhibits no significant change in the output property after 30 thermal cycle tests benefiting from the stable microstructure.

Entropic Analysis of the Maximum Output Power of Thermoradiative Cells

Abstract In this study, entropic analysis is combined with the detailed balance model to determine the maximum output power of thermoradiative (TR) cells, which are semiconductor devices that generate electric power from a heat source that emits photons to a cold reservoir. Previous studies used different models without addressing their interconnections and inherent assumptions. This work unifies these models by considering the modified Bose-Einstein distribution of photons and reveals the underlying relationship between different models. The findings provide useful insights on the application and optimization of emissive power generation devices for harvesting low-grade heat and space power generation.

Boosting Thermogalvanic Cell Performance through Synergistic Redox and Thermogalvanic Corrosion.

Thermogalvanic cells with organic redox couple (OTGCs) have received significant attention for low-grade heat harvesting due to their high thermopower, versatile molecular design, and tailorable physiochemical properties. However, their thermogalvanic conversion power output is largely hindered by slow kinetic rate, which limits practical applications. In this work, we demonstrate a high-performance liquid quinone/hydroquinone (Q/HQ) based OTGC by synergistic coupling redox reaction and thermogalvanic corrosion. By adding hydrochloric acid (HCl) into electrolyte solution, HCl not only boosts intrinsic redox kinetic rate of Q/HQ, but also induces rapid thermogalvanic corrosion of the copper electrode. Notably, these two processes reinforce each other kinetically. Consequently, the Q/HQ-based OTGC exhibits a rapid kinetic rate alongside an increased thermopower, leading to a significantly enhanced power output density. As a result, the Q/HQ-based OTGC achieves an enhanced effective electrical conductivity σeff of 4.22 S m-1 and a record high normalized power density Pmax (ΔT)-2 of 108.7 μW m-2 K-2. This strategy provides a feasible and effective method for development of high-performance OTGCs.

Solvent-assisted thermogalvanic cell for enhanced low-grade heat harvesting over an extended temperature range

In the pursuit of sustainable energy harvesting from low-grade heat, thermogalvanic cells (TGCs) have received considerable attention, but still confront profound challenges in efficiency and cost-effectiveness, limiting their real-world applications. To expedite the deployment of TGCs, this study delves into the mechanistic interplay of three crucial determinants: intrinsic temperature coefficient, concentration gradient, and activity coefficient of redox couples, elucidating their impact on TGCs' thermoelectric performance. We report a solvent-assisted liquid-state thermogalvanic cell (SA-LTC) by incorporating organic solvents into the sodium ferrocyanide-based TGCs system. With ethanol as a regulator to the concentration gradient and solvation structure, the temperature coefficient of [Fe(CN)6]3-/4- can be enhanced from − 1.39 to − 4.32 mV K−1, leading to a five-fold increase in thermoelectric power and efficiency. Meanwhile, ethanol imparts a lower freezing point and wider working temperature range to the system, showing its better environmental adaptability. In particular, SA-LTC performs better at lower temperatures, at which it achieved a record-high temperature coefficient of − 5.26 mV K−1 and a power density of 2.17 mW m−2 K−2 at 10–20 °C. This study not only provides useful guidance to the optimization of electrolyte design, but also highlights the potential of TGCs for sustainable energy conversion in varied thermal conditions for practical applications.

N-type and P-type series integrated hydrogel thermoelectric cells for low-grade heat harvesting

Low-grade heat is abundant and ubiquitous, but it is generally discarded due to the lack of cost-effective recovery technologies. Ion thermoelectric cells are an affordable and straightforward approach of converting low-grade heat into usable electricity for sustainable power. Despite their potential, ion thermoelectric cells face challenges such as limited Seebeck coefficient and required series integration. Here, we demonstrate that the N-type and P-type conversion of ion thermoelectric cells can be achieved through the phase transition of temperature-sensitive hydrogel containing the triiodide/iodide redox couple. Through the strong interaction between the hydrophobic region of the hydrogel and triiodide, the hydrophobic side selectively captures triiodide and the hydrophilic side repels triiodide, raising the concentration difference of triiodide and thereby increasing the Seebeck coefficient. Specifically, the Seebeck coefficient of the N-type ion thermoelectric cells is 7.7 mV K−1, and the Seebeck coefficient of P-type ion thermoelectric cells is −6.3 mV K−1 (ΔT = 15 K). By connecting 10 pairs of the N-type and P-type ion thermoelectric cells, we achieve a voltage of 1.8 V and an output power of 85 μW, surpassing the reported triiodide/iodide-based ion thermoelectric cells. Our work proposes a phase transition strategy for the N-P conversion of ion thermoelectric cells, and highlights the prospect of series integrated hydrogel ion thermoelectric cells for low-grade heat harvesting.

Electrode-dependent thermoelectric effect in ionic hydrogel fiber for self-powered sensing and low-grade heat harvesting

Ionic thermoelectric materials show great significance for wearable energy devices, owing to the capability of the conversion between thermal and electrical energy. The two-dimensional massive structure which is difficult to integrate with fabrics of ionic thermoelectric materials, however, prevent them from realizing their full potential when employed in wearable electronics. In this work, ionic thermoelectric 1D PAM/LiTFSI4 hydrogel fibers with high aspect ratio, inherent flexibility, conductivity, anti-freezing, self-adhesion and self-healing properties are constructed by free radical polymerization technology based on a template strategy, which contains a PAM polymer matrix and an LiTFSI conductive material. Based on thermal diffusion, owing to the ion size difference, the covalent cross-linked polymer network and the electrode-dependent effect promote rapid transport of the cations and boost ion concentration difference, resulting in a huge ionic Seebeck coefficient of 19.02 mV K−1. Meanwhile, embedding hydrogel fibers into the woven textile demonstrates a promising thermoelectric wristband with desirable human heat collection and electrical output capabilities. What’s more, thanks to the introduction of LiTFSI, the microstructure and molecular network system of hydrogel fibers are reshaped, which significantly improved the ionic conductivity of hydrogel fiber, and endowed them with anti-freezing, self-adhesion and self-healing properties. The PAM/LiTFSI4 hydrogel fiber also has excellent strain and temperature sensing properties, which enable a variety of human signal monitoring. Besides, the hydrogel fiber-based sensor can realize self-powered sensing by generating a thermovoltage. Thus, combining the merits of one-dimensional structure, superior thermoelectric performances, sensing at low temperature, excellent adhesion, self-healing and anti-freezing properties together, believing that the PAM/LiTFSI4 hydrogel fiber will render new numerous in human signal monitoring and low-grade heat harvesting applications like wearable electronics and wearable energy supply devices.

Efficient low-grade heat harvesting with flexible paper-based thermoelectric generators fabricated by facile process

The study presents the fabrication and characterization of paper-based thermoelectric generators (PTGs) using p-type Bi0.5Sb1.5Te3 (BST) and n-type Bi2Te2.7Se0.3 (BTS) thermoelectric (TE) materials, deposited via a novel cotton swab powder deposition technique. This method eliminates the need for complex equipment or high-temperature processes, reducing fabrication complexity and enabling large-scale production. The key advancements of this method are its simplicity, cost-effectiveness, and practical applicability, ensuring uniform coating and good material adherence to the paper substrate. The PTGs, consisting of five p-n pairs interconnected with various materials, were laminated for enhanced stability and humidity protection. Experimental measurements under temperature gradients(ΔTs) of 5–30 °C revealed an optimal configuration achieving an open-circuit voltage(Voc) of 42.60 mV, internal resistance(Rint) of 42.50kΩ, short-circuit current(Isc) of 1.00µA, and maximum power output(Pmax) of 10.65nW for the carbon paste/copper sheet interconnected PTG at ΔT of 30 °C. The obtained normalized power density is 5.68nWcm-2K-1pair-1, which is one of the best among the reported Bi2Te3-based PTGs. A preliminary demonstration on an arm showed the PTG generating an 11.95 mV output voltage in hot weather conditions (ΔT ≈ 8 °C), effectively harnessing body heat for wearable electronics. This work highlights a simple, cost-effective, and scalable method for fabricating PTGs for sustainable energy harvesting in low-power wearable applications. Future efforts will focus on optimizing materials, fabrication techniques, and novel designs to enhance efficiency and scalability.

Thermally-driven electrokinetic power generation system utilizing microporous NiO wicks and nanoporous AAO membranes for low-grade heat harvesting

Low-grade heat (T<100 ℃) exists ubiquitously in the environment, but it is difficult to harvest and utilize due to existing technology’s limitations. It would be significant to harvest this kind of energy through effective acquisition techniques. Here, we propose a micro/nano porous membranes low-grade heat harvesting system based on the thermoelectric effect, which uses the temperature gradient to induce the separation and transmission of electrolyte solution ions in the porous membrane to convert low-grade thermal energy into electrical energy. Two power generation materials of microporous nickel oxide (NiO) wicks and nanoporous anodic aluminum oxide (AAO) membranes were investigated experimentally. In the porous NiO wick experiment, it is observed that the wick significantly improves the thermoelectric conversion performance. In particular, when the temperature difference is 50 ℃, the open circuit voltage of the system reaches 215 mV, which is about 300 % higher than the case without the porous NiO wick. In addition, in the AAO porous membranes experiment, we found that at the low concentration, by collecting ambient heat with a temperature difference of 5 ℃, the system obtained the output power of about 6 nW, which improved the 2 ∼ 3 orders of magnitude compared with the previous research reports. This work offers a promising method for developing high-performance and low-cost low-grade heat harvesting systems.

A Review of Ionic Liquids and Their Composites with Nanoparticles for Electrochemical Applications

The current study focuses on reviewing the actual progress of the use of ionic liquids and derivatives in several electrochemical application. Ionic liquids can be prepared at room temperature conditions and by including a solution that can be a salt in water, or a base or acid, and are composed of organic cations and many charge-delocalized organic or inorganic anions. The electrochemical properties, including the ionic and electronic conductivities of these innovative fluids and hybrids, are addressed in depth, together with their key influencing parameters including type, fraction, functionalization of the nanoparticles, and operating temperature, as well as the incorporation of surfactants or additives. Also, the present review assesses the recent applications of ionic liquids and corresponding hybrids with the addition of nanoparticles in diverse electrochemical equipment and processes, together with a critical evaluation of the related feasibility concerns in different applications. Those ranging from the metal-ion batteries, in which ionic liquids possess a prominent role as electrolytes and reference electrodes passing through the dye of sensitized solar cells and fuel cells, to finishing processes like the ones related with low-grade heat harvesting and supercapacitors. Moreover, the overview of the scientific articles on the theme resulted in the comparatively brief examination of the benefits closely linked with the use of ionic fluids and corresponding hybrids, such as improved ionic conductivity, thermal and electrochemical stabilities, and tunability, in comparison with the traditional solvents, electrolytes, and electrodes. Finally, this work analyzes the fundamental limitations of such novel fluids such as their corrosivity potential, elevated dynamic viscosity, and leakage risk, and highlights the essential prospects for the research and exploration of ionic liquids and derivatives in various electrochemical devices and procedures.

Highly conductive triple network hydrogel thermoelectrochemical cells with low-grade heat harvesting

Quasi-solid thermoelectrochemical cells (TECs) are promising candidates for wearable energy harvesting devices as they enable the continuous conversion of low-grade heat into electricity. However, the TEC performance remains limited by inadequate ionic conductivity. Herein, a triple-network hydrogel consisting of polyacrylamide/poly(vinyl alcohol)/cellulose nanofiber (PAAM/PVA/CNF) is synthesized via a freeze-thaw method, and soaked in the thermogalvanic redox couple Fe(CN)63−/4– as the electrolyte. By optimizing the polymer composition and soaking time, a superior ionic conductivity of 168 mS cm−1 is achieved while maintaining a thermopower of ∼1.69 mV K−1. The high ionic conductivity is provided by the fractal microstructure of the hydrogel, as revealed by small-angle X-ray scattering (SAXS). Moreover, the as-fabricated thermoelectric generator array exhibits an exceptional power output of 28.7 μW at a temperature difference of 11.9 K. This work provides insights on the development of wearable thermoelectric materials for practical and reliable energy harvesting applications.

Bacterial Cellulose-Based ionogels with synergistically enhanced mechanical and thermoelectric performances for low-grade heat harvesting

Ionogels have a bright prospect for low-grade heat harvesting due to their advantages of non-volatility and high thermal stability. However, it is still challenging to develop ionogels with mechanical robustness and high thermoelectric properties. This work reports a carboxymethylated and Na+ doped bacterial cellulose-based ionogel (CBCIG-Na) with synergistically increased mechanical and thermoelectric performances. The enhancement of thermoelectric properties of ionogels is mainly attributed to the increase of ion transport pathways and the mobility difference between anions and cations in ionic liquid. After the modification, the CBCIG-Na ionogel with 0.5 mol% Na+ (CBCIG-Na0.5%) exhibits high Seebeck coefficient (45.02 mV K−1), ionic conductivity (21.2 mS cm−1) and ionic power factor (4296.82 μW m−1 K−2) when the relative humidity (RH) is 85 %. This is the highest ionic power factor ever reported for bacterial cellulose-based ionogels. Moreover, the CBCIG-Na0.5% shows high tensile strength (7.69 MPa) due to the larger 3D fiber network and enhanced intermolecular force, obvious adhesivity (9.28 kPa) and high transparence (76 %). After that, a flexible i-TE device containing 5 legs and packaged with polydimethylsiloxane (PDMS) was constructed. A high thermovoltage of 264.36 mV is generated when wearing the i-TE device (5 legs) on the forearm at room temperature (ΔT = 1.2 K). The outstanding performances, environmentally friendly and low-cost characters of CBCIG-Na0.5% ionogel indicating its great potential for low-grade heat harvesting.

Coordination enhanced high-seebeck coefficient n-type gel-based thermocells for low-grade energy harvesting and n-p type connected devices

Thermocells (TECs) have shown potential for commercial applications in low-grade heat harvesting, but the development of n-type TECs has always been lagging behind p-type TECs, hindering the practical utilization of integrated devices. Here, n-type and p-type TECs of polyacrylic acid (PAA) and bacterial cellulose (BC) composite hydrogel are developed, respectively. By coordinating Fe3+ with carboxyl groups, the thermal entropy difference between Fe2+ and Fe3+ increases, resulting in a record high Seebeck coefficient (S) of 2.51 mV K−1 of Fe3+/Fe2+ redox couple in n-type TEC. In p-type TEC, a S of −1.29 mV K−1 based on [Fe(CN)6]4‒/[Fe(CN)6]3‒ redox couple is achieved. The 22-pair n-p type connected device generated a voltage of 1.8 V at a temperature difference of 30 K, which is enough to power a calculator and light up an LED without an amplifier. This work offers a fresh perspective for enhancing the performance of n-type TECs and promoting the practical application of n-p type connected devices.

Zinc-iodine thermal charging cell engineered by cost-efficient electrolytes for low-grade heat harvesting

Emerging ionic thermoelectric devices (i-TEs), with synergistic effect of thermogalvanic effect and thermo-diffusion effect, are promising devices to achieve heat to electricity. We report a zinc-iodine thermal charging cell (ZITCC) enabled by cost-efficient electrolytes for low-grade heat harvesting. Efficient functional electrolytes are obtained through optimization from Zn(NO3)2, Zn(CH3COO)2 and ZnSO4 electrolytes and introducing redox species (I−/I3−). The ZITCCs generate electricity through thermo-diffusion effect of electrolyte ions, as well as the thermogalvanic effect involving I− to I3− conversion and Zn plating, enabling efficient heat-to-electricity conversion. The Seebeck coefficient of 19.2 mV K−1, a high output voltage of ∼1 V and superior normalized maximum power density of 0.44 mW m−2 K−2 is obtained at temperature difference of 15 K. Meanwhile, ZITCCs have good energy storage capacity. In addition, a quasi-solid-state device delivers an 8.5 mW m−2 output power and impressive performance at temperature difference of 8 K can be acquired. This work provides a good strategy for the design of high-Seebeck coefficient, cost-effective i-TEs for low-grade heat harvesting.

Low-grade heat recycling of vertical thermoelectric cells based on thermal-induced electric double layer

Employing electric double-layer (EDL) capacitors to harvest low-grade heat (LGH) is a novel technique in the high-efficiency energy absorption field. This work reports the fabrication of a vertical thermoelectric cell, based on a nanoporous graphene electrode immersed in low-concentration saline solution, for use as thermo-charging supercapacitors to convert LGH to electricity via thermally induced voltage. Because of a large specific area and a large number of micropores of nanoporous graphene films, the effective thermoelectric coefficient of the thermoelectric cell containing 0.01 M KCl solution can reach as high as 4.73 mV/°C. However, many factors, such as electrode materials, electrolyte solutions, and energy conversion device components, determine the efficiency of a thermoelectric conversion device. In summary, the device has a lower internal resistance and higher output voltage when the concentration of KCl solution is 0.05 M, and demonstrates higher thermoelectric conversion efficiency. Moreover, improving the conductivity of the electrolyte solution without affecting the device output voltage is also a way to reduce the internal power consumption of the device. The specific power and thermoelectric conversion efficiency of the device are increased by several orders of magnitude when uniformly dispersed silver nanoparticles are added to the potassium chloride solution to enhance the conductivity of the solution. The specific power underwent an increase from 0.50 mW g−1 to 42.37 mW g−1, and the thermoelectric conversion efficiency also increased from 0.0022% to 0.1358%.

Harvesting Thermal Energy through Pyroelectric and Thermoelectric Nanomaterials for Catalytic Applications

The current scenario sees over 60% of primary energy being dissipated as waste heat directly into the environment, contributing significantly to energy loss and global warming. Therefore, low-grade waste heat harvesting has been long considered a critical issue. Pyroelectric (PE) materials utilize temperature oscillation to generate electricity, while thermoelectric (TE) materials convert temperature differences into electrical energy. Nanostructured PE and TE materials have recently gained prominence as promising catalysts for converting thermal energy directly into chemical energy in a green manner. This short review provides a summary and comparison of catalytic processes initiated by PE and TE effects driven by waste thermal energy. The discussion covers fundamental principles and reaction mechanisms, followed by the introduction of representative examples of PE and TE nanomaterials in various catalytic fields, including water splitting, organic synthesis, air purification, and biomedical applications. Finally, the review addresses challenges and outlines future prospects in this emerging field.

Magneto-Induced Janus Adhesive-Tough Hydrogels for Wearable Human Motion Sensing and Enhanced Low-Grade Heat Harvesting.

Janus hydrogels with different properties on the two surfaces have considerable potential in the field of material engineering applications. Various Janus hydrogels have been developed, but there are still some problems, such as stress mismatch caused by the double-layer structure and Janus failure caused by material diffusion in the gradient structure. Here, we report a Janus adhesive-tough hydrogel with polydopamine-decorated Fe3O4 nanoparticles (Fe3O4@PDA) at one side induced by magnetic field to avoid uncontrollable material diffusion in the cross-linking polymerization of acrylamide with alginate-calcium. The magneto-induced Janus (MIJ) hydrogel has an adhesive surface and a tough bulk without an obvious interface to avoid stress mismatch. Due to the intrinsic dissipative matrix and the abundant catechol groups on the adhesive surface, it shows strong adhesion onto various substrates. The MIJ hydrogel has high sensitivity (GF = 0.842) in detecting tiny human motion. Owing to the synergy of Fe3O4@PDA-enhanced interfacial adhesion and heat transfer, it is possible to quickly generate effective temperature differences when adhering to human skin. The MIJ hydrogel achieves a Seebeck coefficient of 13.01 mV·K-1 and an output power of 462.02 mW·m-2 at a 20 K temperature difference. This work proposes a novel strategy to construct Janus hydrogels for flexible wearable devices in human motion sensing and low-grade heat harvesting.

Thermodynamics of Ionic Thermoelectrics for Low-Grade Heat Harvesting

Thermodynamics of Ionic Thermoelectrics for Low-Grade Heat Harvesting

Enhancing thermoelectric conversion efficiency of hydrogel-based supercapacitors by the three-dimensional ion channels hydration

Ionic thermoelectric (i-TE) supercapacitors are capable of converting low-grade heat directly into electricity, which has enormous potential for wearable power sources and the Internet of Things. However, the low thermoelectric conversion efficiency limits their applications. Here, we report a method for forming polar corona in a three-dimensional (3D) network based on chitosan-polyacrylamide‑silicon dioxide (PACS) hydrogel, significantly increasing the maximum thermogalvanic power density of 187.2 mW m−2 at a temperature difference (ΔT) of 5 K. The abundant functional groups on PACS confine free H2O molecules to the polymer network, forming polar corona, reducing the volume of thermally diffused ions, and enabling rapid conduction of lithium ions (Li+) in unsaturated coordination. In addition, demonstrating an impressive ionic conductivity of 50.2 mS cm−1 as well as a maximum thermal charging voltage of 200 mV (ΔT of 8 K), this work provides a new strategy for broadening applications of ionic thermally chargeable supercapacitors in harvesting low-grade heat and wearable devices.

Synthesis and enhanced room-temperature thermoelectric properties of CuO-MWCNT hybrid nanostructured composites.

This work presents the synthesis of novel copper oxide-multiwalled carbon nanotube (CuO-MWCNT) hybrid nanostructured composites and a systematic study of their thermoelectric performance at near-room temperatures as a function of MWCNT wt% in the composite. The CuO-MWCNT hybrid nanostructured composites were synthesized by thermal oxidation of a thin metallic Cu layer pre-deposited on the MWCNT network. This resulted in the complete incorporation of MWCNTs in the nanostructured CuO matrix. The thermoelectric properties of the fabricated CuO-MWCNT composites were compared with the properties of CuO-MWCNT networks prepared by mechanical mixing and with the properties of previously reported thermoelectric [CuO]99.9[SWCNT]0.1 composites. CuO-MWCNT hybrid composites containing MWCNTs below 5 wt% showed an increase in the room-temperature thermoelectric power factor (PF) by ∼2 times compared with a bare CuO nanostructured reference thin film, by 5-50 times compared to mixed CuO-MWCNT networks, and by ∼10 times the PF of [CuO]99.9[SWCNT]0.1. The improvement of the PF was attributed to the changes in charge carrier concentration and mobility due to the processes occurring at the large-area CuO-MWCNT interfaces. The Seebeck coefficient and PF reached by the CuO-MWCNT hybrid nanostructured composites were 688 μV K-1 and ∼4 μW m-1 K-2, which exceeded the recently reported values for similar composites based on MWCNTs and the best near-room temperature inorganic thermoelectric materials such as bismuth and antimony chalcogenides and highlighted the potential of CuO-MWCNT hybrid nanostructured composites for applications related to low-grade waste heat harvesting and conversion to useable electricity.