A new failure mode in ferroelectric, non-volatile memories in a radiation environment has been identified. Exposure to ionizing radiation in combination with a series of unipolar pulses, which could be found in a read-only or read-mostly memory application, has been found to create a preferred memory state in the ferroelectric storage cell. This preferred memory state, or imprint, causes a significant asymmetry in the retention of polarization. While ferroelectric materials remain highly radiation tolerant, a new, more stringent testing method-should be adopted for hardness assurance. The creation of a preferential memory state, or 'imprint', in ferroelectric films and memories has previously only been reported in elevated temperature situations.