H2O2 Production Research Articles

Water/oil interfacial photocatalysis of amphiphilic CdS/Bi2WO6 S-scheme heterojunctions for efficient production and spontaneous separation of H2O2 and value-added organics

The photocatalytic co-production of H2O2 and value-added organics in a suitable water/oil biphasic system offers an intriguing strategy to address the challenges encountered in a single liquid-phase solution, including the efficient separation of H2O2 and organic products as well as the mitigation of undesirable secondary reactions. For this, exploring amphiphilic photocatalysts with high performance is highly required. Herein, an amphiphilic CdS/Bi2WO6 S-scheme heterojunction photocatalyst is designedly synthesized through a two-step solvothermal process, aiming to achieve efficient interfacial photocatalytic reactions at the water/oil interface for simultaneous generation and selective separation of H2O2 and organic products. The CdS/Bi2WO6 heterojunction photocatalyst exhibits enhanced light absorption in UV–visible region, increased electron-hole separation efficiency, and powerful charge carriers with high redox abilities. Moreover, the formation of S-scheme heterojunction improves the catalyst stability by preventing CdS from photocorrosion. As a result, the production rate of H2O2 reaches up to 216.76 mmol g−1 h−1, accompanied by the generation of organic products (benzaldehyde: 104.91 mmol g−1 h−1, benzoic acid: 49.88 mmol g−1 h−1, and benzyl benzoate: 38.01 mmol g−1 h−1), in a water/benzyl-alcohol biphasic system under simulated sunlight irradiation. The photocatalytic mechanism is elucidated based on the results of comprehensive experiments and characterizations. This study highlights a rational construction of amphiphilic photocatalysts and their application in organic/water interfacial photocatalytic reactions.

Effective removal of organic compounds by g-C3N4-AQ/Fe(III) via photocatalytic oxidation and photochemical cycling of iron

Anthraquinone-anchored graphitic carbon nitride (denoted as g-C3N4-AQ), which has been reported in the photochemical production of H2O2, demonstrated significant visible light photocatalytic activity with Fe(III) for the degradation of organic compounds. The synthesized g-C3N4-AQ exhibited a light absorption spectrum and crystallinity comparable to that of pristine g-C3N4. FT-IR and XPS analyses confirmed the covalent bonding between AQ and g-C3N4. The synthesized g-C3N4-AQ generated 12 μM of H2O2 within 2 h under visible light illumination, a quantity negligible for the degradation of organic compounds. However, in the combination with Fe(III), the system successfully degraded organic compounds, achieving degradation of 88 – 99 % in the presence of dissolved oxygen. It was also observed that the photochemical activity of g-C3N4-AQ/Fe(III) was non-selective towards the target organic compounds. Intriguingly, the visible light-illuminated g-C3N4-AQ/Fe(III) selectively degraded target organic compounds in the absence of dissolved oxygen. Experimental work employing reactive oxidant scavengers and oxidant probes revealed that •OH is the main reactive species responsible for the degradation of organic compounds in the presence of dissolved oxygen, whereas in its absence, the hole acts as the primary oxidant in the selective degradation of organic compounds. This finding provides important insights into the application of the g-C3N4-AQ/Fe(III) system for effective micropollutant removal.

Alkali metal cation adsorption–induced surface polarization in polymeric carbon nitride for enhanced photocatalytic hydrogen peroxide production

Photocatalytic hydrogen peroxide (H2O2) generation on the catalyst surface from oxygen is an electron-demanding process, making the construction of an electron-rich surface highly advantageous. In this study, a localized electric field was observed on the surface of polymeric carbon nitride (g-C3N4) when alkali metal cations were adsorbed onto it. These fields effectively inhibited surface carrier recombination and extended their lifespan, thereby enhancing H2O2 production. As a result, g-C3N4 achieved a superior H2O2 yield of 2.25 mM after 1 h in a 0.25 M K+ solution, which was 2.06 times greater than that (1.09 mM) achieved in a pure solvent. Notably, the increase in photocatalytic efficiency showed a remarkable dependence on ion species. At low concentrations, H2O2 generation efficiency was in the order of Li+ < Na+ < K+ < Rb+ < Cs+. However, after optimizing the ion concentration, the highest H2O2 production was achieved in a solution containing K+ instead of Cs+. Molecular dynamics simulations and temperature-dependent photocatalysis experiments revealed that the synergistic interaction between adsorption energy and adsorption distance was crucial in governing the extent to which alkali metal cation adsorption enhanced g-C3N4 photocatalytic H2O2 production. This study provides theoretical insights for the design of materials for electron-demanding photocatalysis and aids in understanding variations in photocatalytic behavior in natural waters.

Synergistic regulation of g-C3N4 band structure by phosphorus and sodium doping to enhance photocatalytic hydrogen peroxide production efficiency

In addressing the industrial need for a simple, equipment-minimal, and non-toxic method of in-situ hydrogen peroxide (H2O2) production, this paper presents a cost-effective, environmentally friendly photocatalyst. Our design strategy focuses on the dual-element doping of phosphorus and sodium into graphitic carbon nitride (g-C3N4), chosen to synergistically enhance photocatalytic performance. This approach yields a notable H2O2 production concentration of 3001.64 μmol·g−1·L-1 within 100 min, using isopropanol as a sacrificial agent, which was 61-fold increase compared to bulk g-C3N4. Density Functional Theory (DFT) calculations were performed to elucidate the alterations in the band structure of the catalyst induced by dual-element doping, which consequentially engendered an asymmetric intrinsic electric field. Additionally, oxygen’s transition state affinity due to phosphorus doping was also investigated to reveal the mechanisms of synergistic catalysis. This development contributes to meeting industrial demands for pollutant degradation via Fenton processes and presents a sustainable alternative to traditional H2O2 production methods.

Core-shell structured composite high-efficiency catalyst Co@Pd/TiO2 with a compressed-strain Pd shell for the direct synthesis of H2O2

Direct synthesis of H2O2 from H2 and O2 still faces the dilemma of low selectivity and productivity due to the O-O bond dissociation. To expedite the resolution of this issue, we introduce a core–shell structured catalyst Co@Pd/TiO2 with a compressed-strain Pd shell. The Co@Pd/TiO2 catalyst demonstrates a superior H2O2 productivity of 6.95 × 103 mmol·gPd-1·h−1 and H2O2 selectivity of 98.1 %, with enhancements of over 192 % and 139 %, respectively, when compared to Pd/TiO2. The construction of the compressed-strain Pd shell on the Co@Pd/TiO2 catalyst induces a winder width (wd) and a lower center (εd) of the Pd d-band, allowing the Co@Pd/TiO2 catalyst to achieve the following benefits for improving H2O2 selectivity and productivity: (1) Reducing the degree of electron back-donation to O2* (* denotes adsorbed state, the same below), thus inhibiting the cleavage of the O-O bond in O2*; (2) Showing a weaker Pd-O bond strength, which stabilizes the OOH* species and suppresses the breakage of the O-O bond therein; (3) Weakening the interaction between the catalyst and chemical substances, thereby restraining H2O2 degradation.

Fabrication of visible light responsive BaFe12O19/Ag/AgI composites with enhanced photocatalytic degradation of organic pollutants

A novel visible-light-driven (VLD) BaFe12O19/Ag/AgI photocatalysts were constructed through calcination and hydrothermal methods, in which BaFe12O19 of different mass ratios were introduced. The constructed Z-scheme heterojunction provided BaFe12O19/Ag/AgI composite catalytic with effective space carrier transport and higher redox ability. In particular, the as-prepared BaFe12O19/Ag/AgI degraded nearly 94% of 2- mercaptobenzothiazole within 30minutes of visible-light illumination, which was much superior to that of pure AgI (47%) and BaFe12O19 (3%). Moreover, BaFe12O19/Ag/AgI can be easily magnetically separated, so as to facilitate its efficient separation and recovery in practical application. Photocatalytic activity assays revealed that the as-synthesized BaFe12O19/Ag/AgI also exhibited good photodegradation capability towards Imidacloprid, Tetracycline and Carbamazepine. In particular, the complex had relatively high oxygen activation ability, and its photocatalytic H2O2 production performance was 1.29 times higher than that of the AgI monomer within 120minutes, thus realizing rapid water disinfection. Overall, the constructed efficient Z-scheme BaFe12O19/Ag/AgI photocatalysts provide a novel insight in sewage purification.

Novel electrocatalyst with abundant oxygen vacancies enabling efficient two-electron water oxidation reaction for H2O2 synthesis

In the realm of electrocatalytic two-electron water oxidation reaction, the quest for efficient and selective catalysts poses a significant challenge in balancing productivity and activity, hindering the decentralized generation of hydrogen peroxide (H2O2) through electrochemical means. Addressing this hurdle, our study introduces a novel approach to crafting an effective and stable electrocatalyst for the two-electron water oxidation reaction (2e-WOR). Through the synthesis of magnesium stannite tungstate from a mixture of MgSnO3 and WO3, the engineer of a material with abundant oxygen vacancies is crucial for catalytic activity. This catalyst demonstrates exceptional performance, ascribed to its distinctive oxygen vacancies proximal to the active center Sn and electronic modulation by tungsten. Notably, Mg1-xSnWO6-x700 exhibits a remarkably low overpotential of 70 mV at 10 mA cm−2, coupled with a high faradic efficiency of 84 % for 2e- WOR at 2.6 V vs. RHE, maintaining consistent performance over 35 h. Furthermore, the formation of oxygen vacancies and the associated electronic transfer underscore the novelty and promise of our material in advancing the field of two-electron WOR. In sum, our electrocatalyst presents a cost-efficient and selective solution for water oxidation, offering potential avenues for enhancing H2O2 production.

Undervalued role of Metal-Carbon junction in selective generation of H2O2: An example of the Zinc-Carbon junction edge Providing asymmetric active sites for Efficient oxygen reduction

The spontaneous oxygen reduction is a potential technology for in-situ H2O2 production, which gets rid of the dependence on electricity and solar energy. Previous some metal–carbon compounds reported are feasible to trigger oxygen reduction. These reports always claim the high H2O2 generation ability of metal–carbon composites, while rarely discuss the contribution of carbon and the carbon–metal junction to the oxygen reduction process. Inspired by the dual active sites, we infer that the role of interfacial carbon in metal–carbon composites is underestimated. By a heat treatment of the co-precipitate of zinc and glucose, the Zn-C junction is constructed in Zn-gc to achieve a spontaneous selective reduction of O2 to H2O2. The Zn-C interface edge is active site, where an asymmetric activation is achieved by bonding two O atoms from O2 to C and Zn, respectively. The Zn traction to one of the O atoms is mainly in xy plane, while the C traction to the other O atom is parallel to z-axis. The yield of H2O2 produced per gram of Zn increases from 27.89 mg to 122.21 mg, an improvement of 4.38 times. And the inertness of Zn and its oxygen-containing compounds towards H2O2 enables Zn-gc/O2 system to stabilize H2O2 over a long period of time. This work reveals the crucial role of neglected junction interfaces in oxygen reduction reactions in metal–carbon composites.

Combustion synthesis of TiO2/C composites for enhanced photocatalytic H2O2 production and solar steam evaporation efficiency

In this work, a simple combustion method was proposed for the controllable synthesis of TiO2/C composites, which can achieve both the efficient solar water evaporation at the interface and photocatalytic H2O2 production. Structural and morphological characteristic indicated the co-existence of carbon quantum dots and amorphous carbon, which were well distributed on the surface of the TiO2. TiO2/C composites displayed the enhanced visible light absorption and the rapid separation of photogenerated electron-hole pairs. TiO2/C-10 exhibited an excellent photocatalytic H2O2 production activity of 3068.46 μmol/g/h under simulated solar irradiation. Besides, its water evaporation rate reach up to 5.81 kg·m−2·h−1 under the simulated solar irradiation.

Magnetic field-enhanced two-electron oxygen reduction reaction using CeMnCo nanoparticles supported on different carbonaceous matrices

The current study illustrates the successful synthesis of Ce1.0Mn0.9Co0.1 nanoparticles, characterized through XRD, EPR, magnetization curves, and TEM/HRTEM/EDX analyses. These nanoparticles were then loaded into the carbon Vulcan XC72 and the carbon Printex L6 matrices in varying amounts (1, 3, 5, and 10 % w/w) via wet impregnation method to fabricate electrocatalysts for the 2-electron ORR. Before experimentation, the material was characterized via XPS and contact angle measurements. The electrochemical results produced significant findings, indicating that the electrocatalysts with the nanostructures modifying both carbon blacks notably augmented currents in rotating ring-disk electrode measurements, signifying enhanced selectivity for H2O2 production. Moreover, our research underscored the significant impact of Magnetic Field-Enhanced Electrochemistry, employing a constant magnetic field strength of 2000 Oe, on 2-electron ORR experiments. Particularly noteworthy were the observed results surpassing the ones without the magnetic field, demonstrating heightened currents and improved selectivity for H2O2 production (more than 90 %) facilitated by CeMnCo nanoparticles. These significant findings in electrocatalytic efficiency have practical implications, suggesting the potential for developing more efficient and selective catalysts for the 2-electron ORR.

Photocarrier behavior and photocatalytic H2O2 synthesis performance of amorphous/crystalline SrTiO3/BiVO4 layered heterostructures

BiVO4 (BVO), as a visible light responsive semiconductor material, has been widely employed in the field of photocatalysis. However, monoclinic BVO is afflicted by a high recombination rate of photogenerated charge carriers and poor charge transport capability, resulting in low charge utilization efficiency. Constructing heterostructures for interface modification of BVO is an effective strategy to improve photocatalytic performance. Herein, amorphous/crystalline SrTiO3/BiVO4 (STO/BVO) layered film nanoheterostructures have been successfully fabricated on the (001) yttrium stabilized zirconia substrate by magnetron sputtering. Under 440 nm monochromatic light irradiation, the H2O2 production rate of the composite film is increased by 1.2 times compared to pure BVO. The type II heterostructure composed of STO and BVO accomplishes selective interface hole transport from BVO to STO, promoting the separation of space charges. Additionally, the interaction between amorphous/crystalline interfaces effectively suppresses the photocorrosion of BVO and strengthens the stability of the film, which is of great significance for studying charge transport behavior and photocatalytic mechanisms.

Highly efficient electrosynthesis of hydrogen peroxide through reversible transformation between catechol and o-benzoquinone on polydopamine modified carbon black

Carbon-based materials are more promising catalysts for H2O2 electrochemical production. However, the common method for modifying carbon-based materials is surface functionalization with harsh and uncontrollable reaction conditions, hindering the precise regulation of the active sites. Herein, we proposed a carbon-based material modified by polydopamine (CB-PDA) that was easily prepared and used in air diffusion electrode system for H2O2 production. The rapid and reversible transformation between catechol and o-benzoquinone on PDA could improve the H2O2 selectivity from 75.5 % to 97.0 % during the electrocatalytic process. The detection of adsorbed *HOOH and *OOH in oxygen reduction reaction proved the preference of CB-PDA for the two-electron pathway. The H2O2 formation rate constant of CB-PDA increased significantly from 25.85 to 60.82 mM h−1. The highest cumulative H2O2 concentration could reach 10200 mg L−1 in 9 h. Long-term operation tests proved the good operational stability. Furthermore, this system was cost-effective without additional aeration energy consumption and could achieve rapid disinfection in 10 min, which would have great potential to be used in environmental remediation.

Indium oxide layer dual functional modified bismuth vanadate photoanode promotes photoelectrochemical oxidation of water to hydrogen peroxide.

The photoelectrochemical (PEC) dual-electron pathway for water oxidation to produce hydrogen peroxide (H2O2) shows promising prospects. However, the dominance of the four-electron pathway leading to O2 evolution competes with this reaction, severely limiting the efficiency of H2O2 production. Here, we report a In2O3 passivator-coated BiVO4 (BVO) photoanode, which effectively enhances the selectivity and yield of H2O2 production via PEC water oxidation. Based on XPS spectra and DFT calculations, a heterojunction is formed between In2O3 and BVO, promoting the effective separation of interface and surface charges. More importantly, Mott-Schottky analysis and open-circuit potential measurements demonstrate that the In2O3 passivation layer on the BVO photoanode shifts the hole quasi-Fermi level towards the anodic direction, enhancing the oxidation level of holes. Additionally, the widening of the depletion layer and the flattening of the band bending on the In2O3-coated BVO photoanode favor the generation of H2O2 while suppressing the competitive O2 evolution reaction. In addition, the coating of In2O3 can also inhibit the decomposition of H2O2 and improve the stability of the photoanode. This work provides new perspectives on regulating PEC two/four-electron transfer for selective H2O2 production via water oxidation.

Simultaneous efficient production of hydrogen peroxide, urea and H2 by bifunctional Cu-doped TiO2 electrocatalyst from CO2, N2 and water

The production of three separated, high-value chemicals (H2O2, urea and H2) from CO2, N2, and H2O represents a significant challenge. It is a prospective and innovative way to simultaneously produce these chemicals in an anion exchange membrane (AEM) electrolyzer, which couples anodic 2e- water oxidation (2e-WOR) and cathodic CO2, N2 and water reduction reaction (CNWRR), but has not yet been realized. Here, we found that bifunctional CuxTi1-xO2-y catalysts can be employed in the electrochemical production of H2O2, urea and H2 from CO2, N2 and water, and the optimized Cu0.12Ti0.88O2-y catalyst exhibits an excellent productivity of 11.8 μmol cm−2 min−1, 0.3 mg cm-2h−1 and 0.82 mmol cm-2h−1 for H2O2, urea and H2 at 4.0 V (50 mA cm−2) in AEM electrolyzer, respectively. Theoretical calculations reveal that the superior performance of the 2e-WOR and CNWRR is attributed to the Cu doping effect, which not only promotes the coupling of *OH but also optimizes the adsorption energy barriers of COOH* and NNH*. It is worth noting that the AEM electrolyzer assembled by bifunctional Cu0.12Ti0.88O2-y reaches a current density of 50 mA cm−2 with a cell voltage of 4.0 V and exhibits excellent stability of 50-hour continuous operation.

ZIF-67-derived Co3O4@CN-assisted g-C3N4 for efficient photocatalytic hydrogen peroxide production

The conversion of solar energy into chemical energy can be realized by photocatalytic technology, which is also used for hydrogen peroxide (H2O2) production because of its clean and eco-friendly properties. Here, g-C3N4 (GCN) was coupled with the ZIF-67 derivate (Co3O4@CN) by a thermal treatment to obtain the ZCN-X (X = 5, 10, 15 mg of ZIF-67) composite photocatalyst for H2O2 production for the first time. ZCN-10 showed the optimal photocatalytic H2O2 production efficiency of 531.1 μM (or 2655.3 µmol⋅g-1⋅h-1) in one hour, which was 3.49 times that of GCN (152.0 μM). ZCN-10 also showed relatively good stability of photocatalytic H2O2 production with a slight decrease after five cycles. The introduction of Co3O4@CN on GCN increases the catalyst's specific surface area, visible light adsorption, surface-adsorbed oxygen content, and separation efficiency of photogenerated carriers, which jointly cause a large increase in photocatalytic H2O2 production. The mechanism for H2O2 production was proved to be a two-step one-electron oxygen reduction reaction (ORR) pathway. This work would shed light on the fabrication of g-C3N4-based photocatalysts with high performance for H2O2 production.

Selective phthalate removal by molecularly imprinted biomass carbon modified electro-Fenton cathode

A novel molecularly imprinted biomass carbon (MIP@BC) catalyst functionalized with the virtual template of phthalates was designed as the cathode material which possesses excellent 2-electron oxygen reduction ability and H2O2 production capacity, which is suitable for targeted degradation of phthalates in the electro-Fenton system. Following molecularly imprinted modification, the adsorption capacity of MIP@BC for Dimethyl phthalate (DMP) increased by 40 %, reached 9.26 mg/g. Compared with non-imprinted biomass carbon (NIP@BC), the MIP@BC-mediated electro-Fenton process enhanced the degradation rate of DMP by 72 %. Additionally, the degradation rate of DMP rises by 51 % and 104 % respectively on the basis of river water and domestic sewage. The reactive oxygen species that induced DMP degradation were OH and O2− and targeted adsorption and catalysis exert a synergistic effect. This study provides a new insight into targeted degradation for high-toxicity of emerging contaminants from complex aqueous environment.

Boosted photocatalytic H2O2 production in pure water with amino-modified N, S-doped carbon dots

A simple hydrothermal method was adopted to modify N, S-doped carbon dots (N, S-CDs) with feathers as precursors and ammonia by amino modification. The as-prepared am-N, S-CDs in amino as in alkaline environments possessed shorter S-N bonds (S2-), which kinetically and effectively increased the rate of electron conduction and reduced the binding of electron-hole pairs. In addition, the amino modification in am-N, S-CDs effectively improved the O2 adsorption capacity, photocatalytic activity and cycling capacity of the catalysts, with the H2O2 yield (384.86 μM) being 3.73 times higher than that of the pristine N, S-CDs (103.12 μM). This study suggests a rational design strategy for chemical bonding to regulate the surface charge transfer of photocatalysts for photochemical-to-chemical energy conversion.

NADPH Oxidase 4: Crucial for Endothelial Function under Hypoxia-Complementing Prostacyclin.

Aim: The primary endothelial NADPH oxidase isoform 4 (NOX4) is notably induced during hypoxia, with emerging evidence suggesting its vasoprotective role through H2O2 production. Therefore, we aimed to elucidate NOX4's significance in endothelial function under hypoxia. Methods: Human vessels, in addition to murine vessels from Nox4-/- mice, were explored. On a functional level, Mulvany myograph experiments were performed. To obtain mechanistical insights, human endothelial cells were cultured under hypoxia with inhibitors of hypoxia-inducible factors. Additionally, endothelial cells were cultured under combined hypoxia and laminar shear stress conditions. Results: In human occluded vessels, NOX4 expression strongly correlated with prostaglandin I2 synthase (PTGIS). Hypoxia significantly elevated NOX4 and PTGIS expression and activity in human endothelial cells. Inhibition of prolyl hydroxylase domain (PHD) enzymes, which stabilize hypoxia-inducible factors (HIFs), increased NOX4 and PTGIS expression even under normoxic conditions. NOX4 mRNA expression was reduced by HIF1a inhibition, while PTGIS mRNA expression was only affected by the inhibition of HIF2a under hypoxia. Endothelial function assessments revealed hypoxia-induced endothelial dysfunction in mesenteric arteries from wild-type mice. Mesenteric arteries from Nox4-/- mice exhibited an altered endothelial function under hypoxia, most prominent in the presence of cyclooxygenase inhibitor diclofenac to exclude the impact of prostacyclin. Restored protective laminar shear stress, as it might occur after thrombolysis, angioplasty, or stenting, attenuated the hypoxic response in endothelial cells, reducing HIF1a expression and its target NOX4 while enhancing eNOS expression. Conclusions: Hypoxia strongly induces NOX4 and PTGIS, with a close correlation between both factors in occluded, hypoxic human vessels. This relationship ensured endothelium-dependent vasodilation under hypoxic conditions. Protective laminar blood flow restores eNOS expression and mitigates the hypoxic response on NOX4 and PTGIS.

Engineering nitrogen vacancies and cyano groups into C3N4 nanosheets for highly efficient photocatalytic H2O2 production

Thermal oxidation of bulky carbon nitride (C3N4, CN) to expose more active sites is an important method to improve the activity of the as-prepared CN nanosheets. Unfortunately, the yield of thermal oxidation is low. Herein, we report dual-deficient CN (DDCN) ultrathin nanosheets engineered with nitrogen vacancies and cyano groups by two-step bottom-up thermal polymerization of belt-like melamine with a high yield of 65%. Featured with abundant exposed active sites, short charge migration distance, wide visible-light absorption, quick charge separation/transfer, enhanced oxygen adsorption ability and 2e oxygen reduction reaction selectivity, the DDCN exhibits a high H2O2 production rate of ∼1031 μmol g1 h1, which is 19.5 times that of CN (53 μmol g1 h1) under visible light irradiation (λ ≥ 420nm). Specifically, the apparent quantum yield (AQY) of DDCN reached 10.7% at 420nm. This study provides a facile dual-defect engineering method to develop highly efficient ultrathin CN-based photocatalysts.

Platinum-induced nanolization and electron-deficient gold in platinum@gold cocatalyst for efficient photocatalytic hydrogen peroxide production

Simultaneous optimization of the number and intensity of oxygen (O2) adsorption on gold (Au) cocatalyst is highly required to greatly improve their interfacial hydrogen peroxide (H2O2)-production activity. However, it is a great challenge to realize the above effective modulation of Au by traditional photodeposition route. In this study, a platinum (Pt)-induced selective photodeposition method was designed to simultaneously regulate the particle size and electronic structure of Au cocatalyst for boosting the photocatalytic H2O2-production activity of bismuth vanadate (BiVO4) via the selective deposition of Pt@Au core–shell cocatalyst. The photocatalytic results indicate that the as-prepared BiVO4/Pt0.1@Au photocatalyst achieves a considerable H2O2-production activity with a rate of 2752.13 μmol L−1 (AQE = 13.76 %), which is obviously higher than that of BiVO4/Pt (137.63 μmol L−1) and BiVO4/Au (475.33 μmol L−1). It was found that the introduction of Pt successfully induced the formation of Au nanoparticles for enhancing the number of O2 adsorption. Meanwhile, the spontaneous transfer of free electrons of Au to Pt induces the generation of electron-deficient Auδ+ sites, which spontaneously enhances the O2-adsorption intensity for facilitating the 2-electron oxygen reduction reaction (ORR), resulting in efficient H2O2 production. The present strategy may be useful for more comprehensively regulating the intensity and number of O2 adsorption on cocatalysts to facilitate artificial photosynthesis.