H2O Abundance Research Articles

Herschel water maps towards the vicinity of the black hole Sgr A*

Aims. We study the spatial distribution and kinematics of water emission in a ~8 × 8 pc2 region of the Galactic center (GC) that covers the main molecular features around the supermassive black hole Sagittarius A* (Sgr A*). We also analyze the water excitation to derive the physical conditions and water abundances in the circumnuclear disk (CND) and the “quiescent clouds”. Methods. We presented the integrated line intensity maps of the ortho 110 − 101, and para 202 − 111 and 111 − 000 water transitions observed using the On the Fly mapping mode with the Heterodyne Instrument for the Far Infrared (HIFI) on board Herschel. To study the water excitation, we used HIFI observations of the ground state ortho and para H218O transitions toward three selected positions in the vicinity of Sgr A*. In our study, we also used dust continuum measurements of the CND, obtained with the Spectral and Photometric Imaging REceiver (SPIRE) instrument. Using a non-local thermodynamical equilibrium (LTE) radiative transfer code, the water line profiles and dust continuum were modeled, deriving H2O abundances (XH2O), turbulent velocities (V t), and dust temperatures (Td). We also used a rotating ring model to reproduce the CND kinematics represented by the position velocity (PV) diagram derived from para 202 − 111 H2O lines. Results. In our H2O maps we identify the emission associated with known features around Sgr A*: CND, the Western Streamer, and the 20 and 50 km s−1 clouds. The ground-state ortho water maps show absorption structures in the velocity range of [−220,10] km s−1 associated with foreground sources. The PV diagram reveals that the 202 − 111 H2O emission traces the CND also observed in other high-dipole molecules such as SiO, HCN, and CN. Using the non-LTE code, we derive high XH2O of ~(0.1–1.3) × 10−5, V t of 14–23 km s−1 , and Td of 15–45 K for the CND, and the lower XH2O of 4 × 10−8 and V t of 9 km s−1 for the 20 km s−1 cloud. Collisional excitation and dust effects are responsible for the water excitation in the southwest lobe of the CND and the 20 km s−1 cloud, whereas only collisions can account for the water excitation in the northeast lobe of the CND. We propose that the water vapor in the CND is produced by grain sputtering by shocks of 10–20 km s−1, with some contribution of high temperature and cosmic-ray chemistries plus a photon-dominated region chemistry, whereas the low XH2O derived for the 20 km s−1 cloud could be partially a consequence of the water freeze-out on grains.

The metal-rich atmosphere of the exo-Neptune HAT-P-26b

Transmission spectroscopy is enabling precise measurements of atmospheric H2O abundances for numerous giant exoplanets. For hot Jupiters, relating H2O abundances to metallicities provides a powerful probe of their formation conditions. However, metallicity measurements for Neptune-mass exoplanets are only now becoming viable. Exo-Neptunes are expected to possess super-solar metallicities from accretion of H2O-rich and solid-rich planetesimals. However, initial investigations into the exo-Neptune HAT-P-26b suggested a significantly lower metallicity than predicted by the core-accretion theory of planetary formation and solar system expectations from Uranus and Neptune. Here, we report an extensive atmospheric retrieval analysis of HAT-P-26b, combining all available observations, to reveal its composition, temperature structure, and cloud properties. Our analysis reveals an atmosphere containing 1.5(+2.1)(-0.9)% H2O, an O/H of 18.1(+25.9)(-11.3)x solar, and C/O < 0.33 (to 2$\sigma$). This updated metallicity, the most precise exo-Neptune metallicity reported to date, suggests a formation history with significant planetesimal accretion, albeit below that of Uranus and Neptune. We additionally report evidence for metal hydrides at 4.1$\sigma$ confidence. Potential candidates are identified as TiH (3.6$\sigma$), CrH (2.1$\sigma$), or ScH (1.8$\sigma$). Maintaining gas-phase metal hydrides at the derived temperature (~560 K) necessitates strong disequilibrium processes or external replenishment. Finally, we simulate the JWST Guaranteed Time Observations for HAT-P-26b. Assuming a composition consistent with current observations, we predict JWST can detect H2O (at 29$\sigma$), CH4 (6.2$\sigma$), CO2 (13$\sigma$), and CO (3.7$\sigma$), improving metallicity and C/O precision to 0.2 dex and 0.35 dex. Furthermore, NIRISS observations could detect several metal hydrides at >5$\sigma$ confidence.

HDO and SO2 thermal mapping on Venus

Since January 2012 we have been monitoring the behavior of sulfur dioxide and water on Venus, using the Texas Echelon Cross-Echelle Spectrograph (TEXES) imaging spectrometer at the NASA InfraRed Telescope Facility (IRTF, Mauna Kea Observatory). We present here the observations obtained between January 2016 and September 2018. As in the case of our previous runs, data were recorded around 1345 cm−1 (7.4 μm). The molecules SO2, CO2, and HDO (used as a proxy for H2O) were observed, and the cloudtop of Venus was probed at an altitude of about 64 km. The volume mixing ratio of SO2 was estimated using the SO2/CO2 line depth ratios of weak transitions; the H2O volume mixing ratio was derived from the HDO/CO2 line depth ratio, assuming a D/H ratio of 200 times the Vienna Standard Mean Ocean Water (VSMOW). As reported in our previous analyses, the SO2 mixing ratio shows strong variations with time and also over the disk, showing evidence of the formation of SO2 plumes with a lifetime of a few hours; in contrast, the H2O abundance is remarkably uniform over the disk and shows moderate variations as a function of time. We performed a statistical analysis of the behavior of the SO2 plumes, using all TEXES data between 2012 and 2018. They appear mostly located around the equator. Their distribution as a function of local time seems to show a depletion around noon; we do not have enough data to confirm this feature definitely. The distribution of SO2 plumes as a function of longitude shows no clear feature, apart from a possible depletion around 100E–150E and around 300E–360E. There seems to be a tendency for the H2O volume mixing ratio to decrease after 2016, and for the SO2 mixing ratio to increase after 2014. However, we see no clear anti-correlation between the SO2 and H2O abundances at the cloudtop, neither on the individual maps nor over the long term. Finally, there is a good agreement between the TEXES results and those obtained in the UV range (SPICAV/Venus Express and UVI/Akatsuki) at a slightly higher altitude. This agreement shows that SO2 observations obtained in the thermal infrared can be used to extend the local time coverage of the SO2 measurements obtained in the UV range.

H and Cl isotope characteristics of indigenous and late hydrothermal fluids on the differentiated asteroidal parent body of Grave Nunataks 06128

The paired achondrites Graves Nunataks (GRA) 06128 and 06129 are samples of an asteroid that underwent partial melting within a few million years after the start of Solar System formation. In order to better constrain the origin and processing of volatiles in the early Solar System, we have investigated the abundance of H, F and Cl and the isotopic composition of H and Cl in phosphates in GRA 06128 using secondary ion mass spectrometry. Indigenous H in GRA 06128, as recorded in magmatic merrillite, is characterised by an average δD of ca. −152 ± 330‰, which is broadly similar to estimates of the H isotope composition of indigenous H in other differentiated asteroidal and planetary bodies such as Mars, the Moon and the angrite and eucrite meteorite parent bodies. The merrillite data thus suggest that early accretion of locally-derived volatiles was widespread for the bodies currently populating the asteroid belt. Apatite formed at the expense of merrillite around 100 million years after the differentiation of the GRA 06128/9 parent body, during hydrothermal alteration, which was probably triggered by an impact event. Apatite in GRA 06128 contains 5.4–5.7 wt.% Cl, 0.6–0.8 wt.% F, and ∼20 to 60 ppm H2O, which is similar to the H2O abundance in merrillite from which apatite formed. The apatite δD values range between around +100‰ and +2000‰ and are inversely correlated with apatite H2O contents. The Cl isotope composition of apatite appears to be homogeneous across various grains, with an average δ37Cl value of 3.2 ± 0.7‰. A possible scenario to account for the apatite chemical and isotopic characteristics involves interaction of GRA 06128/9 with fumarole-like fluids derived from D- and HCl-rich ices delivered to the GRA 06128/9 parent-body by an ice-rich impactor.

Analysis of the origin of water, carbon monoxide, and carbon dioxide in the Uranus atmosphere

Context. We present here an analysis of the potential sources of oxygen species in the Uranus atmosphere. Aims. Our aim is to explain the current measurements of H2O, CO, and CO2 in the Uranus atmosphere, which would allow us to constrain the influx of oxygen-bearing species and its origin in this planet. Methods. We used a time-dependent photochemical model of the Uranus atmosphere to ascertain the origin of H2O, CO, and CO2. We thoroughly investigated the evolution of material delivered by a cometary impact, together with a combined source, i.e. cometary impact and a steady source of oxygen species from micrometeoroid ablation. Results. We find that an impactor in the size range ~1.2–3.5 km hitting the planet between 450 and 822 yr ago could have delivered the CO currently seen in the Uranus stratosphere. Given the current set of observations, an oxygen-bearing species supply from ice grain ablation cannot be ruled out. Our study also indicates that a cometary impact cannot be the only source for rendering the observed abundances of H2O and CO2. The scenarios in which CO originates by a cometary impact and H2O and CO2 result from ice grain sublimation can explain both the space telescope and ground-based data for H2O, CO, and CO2. Similarly, a steady influx of water, carbon monoxide, and carbon dioxide, and a cometary impact delivering carbon monoxide give rise to abundances matching the observations. The time evolution of HCN also delivered by a cometary impact (as 1% of the CO in mass), when discarding chemical recycling of HCN once it is lost by photolysis and condensation, produces a very low stratospheric abundance which could be likely non-detectable. Consideration of N2-initiated chemistry could represent a source of HCN allowing for a likely observable stratospheric mixing ratio. Conclusions. Our modelling strongly indicates that water in the Uranus atmosphere likely originates from micrometeroid ablation, whereas its cometary origin can be discarded with a very high level of confidence. Also, we cannot firmly constrain the origin of the detected carbon monoxide on Uranus as a cometary impact, ice grain ablation, or a combined source due to both processes can give rise to the atmospheric mixing ratio measured with the Herschel Space Observatory. To establish the origin of oxygen species in the Uranus atmosphere, observations have to allow the retrieval of vertical profiles or H2O, CO, and CO2. Measurements in narrow pressure ranges, i.e. basically one pressure level, can be reproduced by different models because it is not possible to break this degeneracy about these three oxygen species in the Uranian atmosphere.

H2O abundances and cloud properties in ten hot giant exoplanets

Transmission spectroscopy of exoplanets has the potential to provide precise measurements of atmospheric chemical abundances, in particular of hot Jupiters whose large sizes and high temperatures make them conducive to such observations. To date, several transmission spectra of hot Jupiters have revealed low amplitude features of water vapour compared to expectations from cloud-free atmospheres of solar metallicity. The low spectral amplitudes in such atmospheres could either be due to the presence of aerosols that obscure part of the atmosphere or due to inherently low abundances of H$_2$O in the atmospheres. A recent survey of transmission spectra of ten hot Jupiters used empirical metrics to suggest atmospheres with a range of cloud/haze properties but with no evidence for H$_2$O depletion. Here, we conduct a detailed and homogeneous atmospheric retrieval analysis of the entire sample and report the H$_2$O abundances, cloud properties, terminator temperature profiles, and detection significances of the chemical species. Our present study finds that the majority of hot Jupiters have atmospheres consistent with sub-solar H$_2$O abundances at their day-night terminators. The best constrained abundances range from $\mathrm{log(H_2O)}$ of $-5.04^{+0.46}_{-0.30}$ to $-3.16^{+0.66}_{-0.69}$, which compared to expectations from solar-abundance equilibrium chemistry correspond to $0.018^{+0.035}_{-0.009}\times$ solar to $1.40^{+4.97}_{-1.11}\times$ solar. Besides H$_2$O we report statistical constraints on other chemical species and cloud/haze properties, including cloud/haze coverage fractions which range from $0.18^{+0.26}_{-0.12}$ to $0.76^{+0.13}_{-0.15}$. The retrieved H$_2$O abundances suggest sub-solar oxygen and/or super-solar C/O ratios, and can provide important constraints on the formation and migration pathways of hot giant exoplanets.

Photochemistry of water in the martian thermosphere and its effect on hydrogen escape

Recent SPICAM IR solar occultations reveal significant abundances of water vapor up to ≈80 km near Mars perihelion. These abundances are stimulated by dust that heats the atmosphere and precludes condensation of water. This phenomenon correlates with detections of high escape of hydrogen near perihelion using the H Lyman-alpha in the SPICAM UV and HST observations. Here we present a self-consistent photochemical model of the martian neutral and ion composition at 80–300 km that accounts for variations of the atmospheric composition with solar activity and water abundance at 80 km. The model involves vertical transport by eddy, molecular, and ambipolar diffusion and both thermal and nonthermal escape of light species. The model predicts rather stable hydrogen escape of ≈1.9 × 108 cm−2 s−1 at 250 km during the most of the martian year beyond the perihelion period at LS = 200–330°. The reaction between H2 and CO2+ remains here the key process that determines the hydrogen escape. Therefore the HST observation of D and the FUSE observation of H2 at LS = 68 and 160°, respectively, do not need revision. Appearance of water in the thermosphere during the perihelion period results in significant increase in production of hydrogen by photolysis of water and reactions of its ions. Photolysis of H2O is the most effective at 160–180 nm and weakly depends on solar activity. Reactions of water ions start chiefly by charge exchange between CO2+ and H2O and end by recombination of H3O+. Both H2O photolysis and its ion reactions proceed near 100 km, and just a small part of the hydrogen production can escape. The calculated hydrogen escape at 250 km may be approximated by ΦH (cm−2 s−1) = 1.6 × 108 + 1.4 × 107fH2O (ppm). Here fH2O is the H2O mixing ratio at 80 km that is reduced to 150 km by a factor of 5 by the photolysis and ion reactions. Therefore the observed high hydrogen escape up to 109 cm−2 s−1 requires the dayside-mean water abundances up to 60 ppm at 80 km that are within those observed by the SPICAM IR solar occultations. The significant H2O abundances do not deplete densities of HCO+ and are compatible with the MAVEN/NGIMS ion composition. The H Lyman-alpha observations reflect mostly the dayside-mean photochemistry, and our one-dimensional model may adequately respond to the problem.

Modeling the albedo of Earth-like magma ocean planets with H2O-CO2 atmospheres

During accretion, the young rocky planets are so hot that they become endowed with a magma ocean. From that moment, the mantle convective thermal flux control the cooling of the planet and an atmosphere is created by outgassing. This atmosphere will then play a key role during this cooling phase. Studying this cooling phase in details is a necessary step to explain the great diversity of the observed telluric planets and especially to assess the presence of surface liquid water. We used here a radiative-convective 1D atmospheric model (H2O, CO2) to study the impact of the Bond albedo on the evolution of magma ocean planets. We derived from this model the thermal emission spectrum and the spectral reflectance of these planets, from which we calculated their Bond albedos. Compared to Marcq et al. (2017), the model now includes a new module to compute the Rayleigh scattering, and state of the art CO2 and H2O gaseous opacities data in the visible and infrared spectral ranges. We show that the Bond albedo of these planets depends on their surface temperature and results from a competition between Rayleigh scattering from the gases and Mie scattering from the clouds. The colder the surface temperature is, the thicker the clouds are, and the higher the Bond albedo is. We also evidence that the relative abundances of CO2 and H2O in the atmosphere strongly impact the Bond albedo. The Bond albedo is higher for atmospheres dominated by the CO2, better Rayleigh scatterer than H2O. Finally, we provide the community with an empirical formula for the Bond albedo that could be useful for future studies of magma ocean planets.

A spectral synergy method to retrieve martian water vapor column-abundance and vertical distribution applied to Mars Express SPICAM and PFS nadir measurements

Up to now, all attempts to retrieve martian water vapor from nadir observations have focused their analysis on a single spectral domain and comparison between the results of various experiments showed the difficulty to reconcile the water vapor datasets together. Inspired by a methodology recently developed for the analysis of Earth observations, a spectral synergy approach has been tested on the water vapor extraction from the measurements of two instruments onboard Mars Express. These instruments cover near-infrared (NIR) and thermal infrared (TIR) domains within which water vapor possesses diagnostic absorption/emission signatures. Since the two instruments have operated concomitantly around Mars, co-located measurements could be selected and processed to create a dataset exploitable by synergy. The synergy relies on a Bayesian inference algorithm to find the best fitting values of water vapor and other parameters (e.g. atmospheric and surface temperature, dust opacity) simultaneously for both NIR and TIR intervals. Results demonstrate that synergy augments the information content about water vapor by up to >50% compared to traditional non-synergistic methods. Not only does the synergy provide an unbiased estimate of the total column abundance of H2O but it also provides a correspondingly unbiased estimate of H2O abundance in the first 5 km of the boundary layer, an atmospheric region long remained unexplored although being known for hosting key mechanisms controlling the fate of volatiles on Mars. Using synergy, the scientific return of nadir observations of current and future missions at Mars (such as the ExoMars Trace Gas Orbiter) can be fully optimized.

Determining the effects of clumping and porosity on the chemistry in a non-uniform AGB outflow

Context. In the inner regions of asymptotic giant branch (AGB) outflows, several molecules have been detected with abundances much higher than those predicted from thermodynamic equilibrium chemical models. The presence of the majority of these species can be explained by shock-induced non-equilibrium chemical models, where shocks caused by the pulsating star take the chemistry out of equilibrium in the inner region. Moreover, a non-uniform density structure has been detected in several AGB outflows. Both large-scale structures, such as spirals and disks, and small-scale density inhomogeneities or clumps have been observed. These structures may also have a considerable impact on the circumstellar chemistry. A detailed parameter study on the quantitative effects of a non-homogeneous outflow has so far not been performed. Aims. We examine the effects of a non-uniform density distribution within an AGB outflow on its chemistry by considering a stochastic, clumpy density structure. Methods. We implement a porosity formalism for treating the increased leakage of light associated with radiation transport through a clumpy, porous medium. We then use this method to examine the effects from the altered UV radiation field penetration on the chemistry, accounting also for the increased reaction rates of two-body processes in the overdense clumps. The specific clumpiness is determined by three parameters: the characteristic length scale of the clumps at the stellar surface, the clump volume filling factor, and the inter-clump density contrast. In this paper, the clumps are assumed to have a spatially constant volume filling factor, which implies that they expand as they move outward in the wind. Results. We present a parameter study of the effect of clumping and porosity on the chemistry throughout the outflow. Both the higher density within the clumps and the increased UV radiation field penetration have an important impact on the chemistry, as they both alter the chemical pathways throughout the outflow. The increased amount of UV radiation in the inner region leads to photodissociation of parent species, releasing the otherwise deficient elements. We find an increased abundance in the inner region of all species not expected to be present assuming thermodynamic equilibrium chemistry, such as HCN in O-rich outflows, H2O in C-rich outflows, and NH3 in both. Conclusions. A non-uniform density distribution directly influences the chemistry throughout the AGB outflow, both through the density structure itself and through its effect on the UV radiation field. Species not expected to be present in the inner region of the outflow assuming thermodynamic equilibrium chemistry are now formed in this region, including species that are not formed in greater abundance by shock-induced non-equilibrium chemistry models. Outflows whose clumps have a large overdensity and that are very porous to the interstellar UV radiation field yield abundances comparable to those observed in O-rich and C-rich outflows for most of the unexpected species investigated. The inner wind abundances of H2O in C-rich outflows and of NH3 in O-rich and C-rich outflows are however underpredicted.

Exploring H2O Prominence in Reflection Spectra of Cool Giant Planets

Abstract The H2O abundance of a planetary atmosphere is a powerful indicator of formation conditions. Inferring H2O in the solar system giant planets is challenging, due to condensation depleting the upper atmosphere of water vapor. Substantially warmer hot Jupiter exoplanets readily allow detections of H2O via transmission spectroscopy, but such signatures are often diminished by the presence of clouds composed of other species. In contrast, highly scattering water clouds can brighten planets in reflected light, enhancing molecular signatures. Here, we present an extensive parameter space survey of the prominence of H2O absorption features in reflection spectra of cool (T eff &lt; 400 K) giant exoplanetary atmospheres. The impact of effective temperature, gravity, metallicity, and sedimentation efficiency is explored. We find prominent H2O features around 0.94 μm, 0.83 μm, and across a wide spectral region from 0.4 to 0.73 μm. The 0.94 μm feature is only detectable where high-altitude water clouds brighten the planet: T eff ∼ 150 K, g ≳ 20 ms−2, f sed ≳ 3, m ≲ 10× solar. In contrast, planets with g ≲ 20 ms−2 and T eff ≳ 180 K display substantially prominent H2O features embedded in the Rayleigh scattering slope from 0.4 to 0.73 μm over a wide parameter space. High f sed enhances H2O features around 0.94 μm, and enables these features to be detected at lower temperatures. High m results in dampened H2O absorption features, due to water vapor condensing to form bright, optically thick clouds that dominate the continuum. We verify these trends via self-consistent modeling of the low-gravity exoplanet HD 192310c, revealing that its reflection spectrum is expected to be dominated by H2O absorption from 0.4 to 0.73 μm for m ≲ 10× solar. Our results demonstrate that H2O is manifestly detectable in reflected light spectra of cool giant planets only marginally warmer than Jupiter, providing an avenue to directly constrain the C/O and O/H ratios of a hitherto unexplored population of exoplanetary atmospheres.

New measurements of D/H on Mars using EXES aboard SOFIA

The global D/H ratio on Mars is an important measurement for understanding the past history of water on Mars; locally, through condensation and sublimation processes, it is a possible tracer of the sources and sinks of water vapor on Mars. Measuring D/H as a function of longitude, latitude and season is necessary for determining the present averaged value of D/H on Mars. Following an earlier measurement in April 2014, we used the Echelon Cross Echelle Spectrograph (EXES) instrument on board the Stratospheric Observatory for Infrared Astronomy (SOFIA) facility to map D/H on Mars on two occasions, on March 24, 2016 (Ls = 127°), and January 24, 2017 (Ls = 304°), by measuring simultaneously the abundances of H2O and HDO in the 1383–1391 cm−1 range (7.2 μm). The D/H disk-integrated values are 4.0 (+0.8, −0.6) × Vienna Standard Mean Ocean Water (VSMOW) and 4.5 (+0.7, −0.6) × VSMOW, respectively, in agreement with our earlier result. The main result of this study is that there is no evidence of strong local variations in the D/H ratio nor for seasonal variations in the global D/H ratio between northern summer and southern summer.

Ground-based detection of a cloud of methanol from Enceladus: when is a biomarker not a biomarker?

ABSTRACTSaturn's moon Enceladus has vents emerging from a sub-surface ocean, offering unique probes into the liquid environment. These vents drain into the larger neutral torus in orbit around Saturn. We present a methanol (CH3OH) detection observed with IRAM 30-m from 2008 along the line-of-sight through Saturn's E-ring. Additionally, we also present supporting observations from the Herschel public archive of water (ortho-H2O; 1669.9 GHz) from 2012 at a similar elongation and line-of-sight. The CH3OH 5(1,1)-4(1,1) transition was detected at 5.9σ confidence. The line has 0.43 km s−1 width and is offset by +8.1 km s−1 in the moon's reference frame. Radiative transfer models allow for gas cloud dimensions from 1750 km up to the telescope beam diameter ~73 000 km. Taking into account the CH3OH lifetime against solar photodissociation and the redshifted line velocity, there are two possible explanations for the CH3OH emission: methanol is primarily a secondary product of chemical interactions within the neutral torus that: (1) spreads outward throughout the E-ring or (2) originates from a compact, confined gas cloud lagging Enceladus by several km s−1. We find either scenario to be consistent with significant redshifted H2O emission (4σ) measured from the Herschel public archive. The measured CH3OH:H2O abundance (&gt;0.5%) significantly exceeds the observed abundance in the direct vicinity of the vents (~0.01%), suggesting CH3OH is likely chemically processed within the gas cloud with methane (CH4) as its parent species.

Gas and dust in the star-forming regionρOph A

We investigate to what degree local physical and chemical conditions are related to the evolutionary status of various objects in star-forming media. rho Oph A displays the entire sequence of low-mass star formation in a small volume of space. Using spectrophotometric line maps of H2, H2O, NH3, N2H+, O2, OI, CO, and CS, we examine the distribution of the atomic and molecular gas in this dense molecular core. The physical parameters of these species are derived, as are their relative abundances in rho Oph A. Using radiative transfer models, we examine the infall status of the cold dense cores from their resolved line profiles of the ground state lines of H2O and NH3, where for the latter no contamination from the VLA 1623 outflow is observed and line overlap of the hyperfine components is explicitly taken into account. The stratified structure of this photon dominated region (PDR), seen edge-on, is clearly displayed. Polycyclic aromatic hydrocarbons (PAHs) and OI are seen throughout the region around the exciting star S1. At the interface to the molecular core 0.05 pc away, atomic hydrogen is rapidly converted into H2, whereas OI protrudes further into the molecular core. This provides oxygen atoms for the gas-phase formation of O2 in the core SM1, where X(O2)~ 5.e-8. There, the ratio of the O2 to H2O abundance [X(H2O)~ 5.e-9] is significantly higher than unity. Away from the core, O2 experiences a dramatic decrease due to increasing H2O formation. Outside the molecular core, on the far side as seen from S1, the intense radiation from the 0.5 pc distant early B-type star HD147889 destroys the molecules. Towards the dark core SM1, the observed abundance ratio X(O2)/X(H2O)>1, which suggests that this object is extremely young, which would explain why O2 is such an elusive molecule outside the solar system.

High-precision multiwavelength eclipse photometry of the ultra-hot gas giant exoplanet WASP-103 b

We present 16 occultation and three transit light curves for the ultra-short period hot Jupiter WASP-103b, in addition to five new radial velocity measurements. We combine these observations with archival data and perform a global analysis of the resulting extensive data set, accounting for the contamination from a nearby star. We detect the thermal emission of the planet in both the z΄ and KS bands, the measured occultation depths being 699±110 ppm (6.4σ) and |$3567_{-350}^{+400}$| ppm (10.2σ), respectively. We use these two measurements, together with recently published HST/WFC3 data, to derive joint constraints on the properties of WASP-103b's dayside atmosphere. On one hand, we find that the z΄ band and WFC3 data are best fit by an isothermal atmosphere at 2900 K or an atmosphere with a low H2O abundance. On the other hand, we find an unexpected excess in the KS band measured flux compared to these models, which requires confirmation with additional observations before any interpretation can be given. From our global data analysis, we also derive a broad-band optical transmission spectrum that shows a minimum around 700 nm and increasing values towards both shorter and longer wavelengths. This is in agreement with a previous study based on a large fraction of the archival transit light curves used in our analysis. The unusual profile of this transmission spectrum is poorly matched by theoretical spectra and is not confirmed by more recent observations at higher spectral resolution. Additional data, in both emission and transmission, are required to better constrain the atmospheric properties of WASP-103b.

Origin of warm and hot gas emission from low-mass protostars: Herschel-HIFI observations of CO J = 16–15

(Abridged) Through spectrally unresolved observations of high-J CO transitions, Herschel-PACS has revealed large reservoirs of warm (300 K) and hot (700 K) molecular gas around low-mass protostars. We aim to shed light on the excitation and origin of the CO ladder observed toward protostars, and on the water abundance in different physical components using spectrally resolved Herschel-HIFI data. Observations are presented of the highly excited CO line J=16-15 with Herschel-HIFI toward 24 low-mass protostellar objects. The spectrally resolved profiles show two distinct velocity components: a broad component with an average FWHM of 20 km/s, and a narrower component with a FWHM of 5 km/s that is often offset from the source velocity. The average rotational temperature over the entire profile, as measured from comparison between CO J=16-15 and 10-9 emission, is ~300 K. A radiative-transfer analysis shows that the average H2O/CO column-density ratio is ~0.02, suggesting a total H2O abundance of ~2x10^-6. Two distinct velocity profiles observed in the HIFI line profiles suggest that the CO ladder observed with PACS consists of two excitation components. The warm component (300 K) is associated with the broad HIFI component, and the hot component (700 K) is associated with the offset HIFI component. The former originates in either outflow cavity shocks or the disk wind, and the latter in irradiated shocks. The ubiquity of the warm and hot CO components suggests that fundamental mechanisms govern the excitation of these components; we hypothesize that the warm component arises when H2 stops being the dominant coolant. In this scenario, the hot component arises in cooling molecular H2-poor gas just prior to the onset of H2 formation. High spectral resolution observations of highly excited CO transitions uniquely shed light on the origin of warm and hot gas in low-mass protostellar objects.

Mechanisms of the Formation of Adenine, Guanine, and Their Analogues in UV-Irradiated Mixed NH3:H2O Molecular Ices Containing Purine.

We investigated the formation mechanisms of the nucleobases adenine and guanine and the nucleobase analogues hypoxanthine, xanthine, isoguanine, and 2,6-diaminopurine in a UV-irradiated mixed 10:1 H2O:NH3 ice seeded with precursor purine by using ab initio and density functional theory computations. Our quantum chemical investigations suggest that a multistep reaction mechanism involving purine cation, hydroxyl and amino radicals, together with water and ammonia, explains the experimentally obtained products in an independent study. The relative abundances of these products appear to largely follow from relative thermodynamic stabilities. The key role of the purine cation is likely to be the reason why purine is not functionalized in pure ammonia ice, where cations are promptly neutralized by free electrons from NH3 ionization. Amine group addition to purine is slightly favored over hydroxyl group attachment based on energetics, but hydroxyl is much more abundant due to higher abundance of H2O. The amino group is preferentially attached to the 6 position, giving 6-aminopurine, that is, adenine, while the hydroxyl group is preferentially attached to the 2 position, leading to 2-hydroxypurine. A second substitution by hydroxyl or amino group occurs at either the 6 or the 2 position depending on the first substitution. Given that H2O is far more abundant than NH3 in the experimentally studied ices (as well as based on interstellar abundances), xanthine and isoguanine are expected to be the most abundant bi-substituted photoproducts. Key Words: Astrophysical ice-Abiotic organic synthesis-Nucleic acids-Origin of life-RNA world. Astrobiology 17, 771-785.

Dust ablation on the giant planets: Consequences for stratospheric photochemistry

Ablation of interplanetary dust supplies oxygen to the upper atmospheres of Jupiter, Saturn, Uranus, and Neptune. Using recent dynamical model predictions for the dust influx rates to the giant planets (Poppe et al., 2016), we calculate the ablation profiles and investigate the subsequent coupled oxygen–hydrocarbon neutral photochemistry in the stratospheres of these planets. We find that dust grains from the Edgeworth–Kuiper Belt, Jupiter-family comets, and Oort-cloud comets supply an effective oxygen influx rate of 1.0−0.7+2.2×107 O atoms cm−2−1 to Jupiter, 7.4−5.1+16×104 cm−2 s−1 to Saturn, 8.9−6.1+19×104 cm−2 s−1 to Uranus, and 7.5−5.1+16×105 cm−2 s−1 to Neptune. The fate of the ablated oxygen depends in part on the molecular/atomic form of the initially delivered products, and on the altitude at which it was deposited. The dominant stratospheric products are CO, H2O, and CO2, which are relatively stable photochemically. Model-data comparisons suggest that interplanetary dust grains deliver an important component of the external oxygen to Jupiter and Uranus but fall far short of the amount needed to explain the CO abundance currently seen in the middle stratospheres of Saturn and Neptune. Our results are consistent with the theory that all of the giant planets have experienced large cometary impacts within the last few hundred years. Our results also suggest that the low background H2O abundance in Jupiter’s stratosphere is indicative of effective conversion of meteoric oxygen to CO during or immediately after the ablation process — photochemistry alone cannot efficiently convert the H2O into CO on the giant planets.

Distribution of water in the G327.3–0.6 massive star-forming region

We aim at characterizing the large-scale distribution of H2O in G327.3-0.6, a massive star-forming region made of individual objects in different evolutionary phases. We investigate variations of H2O abundance as function of evolution. We present Herschel continuum maps at 89 and 179 $\mu$m of the whole region and an APEX map at 350 {\mu}m of the IRDC. New spectral HIFI maps toward the IRDC region covering low-energy H2O lines at 987 and 1113 GHz are also presented and combined with HIFI pointed observations of the G327 hot core. We infer the physical properties of the gas through optical depth analysis and radiative transfer modeling. The continuum emission at 89 and 179 {\mu}m follows the thermal continuum emission at longer wavelengths, with a peak at the position of the hot core, a secondary peak in the Hii region, and an arch-like layer of hot gas west of the Hii region. The same morphology is observed in the 1113 GHz line, in absorption toward all dust condensations. Optical depths of ~80 and 15 are estimated and correspond to column densities of 10^15 and 2 10^14 cm-2, for the hot core and IRDC position. These values indicate an H2O to H2 ratio of 3 10^-8 toward the hot core; the abundance of H2O does not change along the IRDC with values of some 10^-8. Infall (over ~ 20") is detected toward the hot core position with a rate of 1-1.3 10^-2 M_sun /yr, high enough to overcome the radiation pressure due to the stellar luminosity. The source structure of the hot core region is complex, with a cold outer gas envelope in expansion, situated between the outflow and the observer, extending over 0.32 pc. The outflow is seen face-on and centered away from the hot core. The distribution of H2O along the IRDC is roughly constant with an abundance peak in the more evolved object. These water abundances are in agreement with previous studies in other massive objects and chemical models.

Abundances and spatial distributions of H2O and CO2 at comet 9P/Tempel 1 during a natural outburst

On approach to comet 9P/Tempel 1, Deep Impact observed about one dozen natural outbursts. One of the largest occurred on 2 July 2005 and was also captured by Deep Impact's infrared spectrometer, HRI-IR. HRI-IR operates between 1.05 and 4.86µm, allowing it to detect H2O (2.67µm) and CO2 (4.27µm) emission bands simultaneously. In the hours leading up to the outburst, both H2O and CO2 behaved quiescently, consistent with previously published studies. During the outburst, CO2 abundance increased by 40% while H2O abundance stayed constant. No additional species were detectable during the outburst. The distribution of CO2 during the outburst is correlated with that of the dust, observed at the same time in the visible. The abundance of CO2 returned to quiescent levels within 3.6h of outburst onset. A slight enhancement in H2O was observed well after the outburst, though this does not appear to be correlated with the outburst. From this analysis, it is likely that CO2 was a driver of the 2 July 2005 outburst and that H2O was not.