H2O Abundance Research Articles

Water vapor abundance near the surface of Venus from Venus Express/VIRTIS observations

Nightside observations of the 1.18‐μm atmospheric window by the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) aboard the Venus Express spacecraft were analyzed to measure and map the water vapor abundance in the lower atmosphere. Thermal emission in this window originates partly from the surface and partly from the first scale height (0–15 km) of the atmosphere. Constraints on the CO2 continuum absorption, which is the dominant source of gaseous opacity in the window, were obtained from the variation of the 1.185‐μm intensity with surface elevation. An absorption coefficient of 1 ± 0.4 × 10−9 cm−1 amagat−2 best fits the observed variation. We retrieved a water vapor mole fraction of 44 ± 9 ppm from various selections of VIRTIS spectra in the southern hemisphere, in agreement with previous analyses of the nightside emission. This value is somewhat larger than that previously determined at higher altitudes from the 2.3‐ and 1.74‐μm nightside windows, but the error bars still allow a constant with height H2O mole fraction from the surface up to 40 km. Using the intensity ratio in the two wings of the 1.18‐μm window as a proxy, we searched for horizontal variations of the H2O abundance in various VIRTIS observational sequences. We derived stringent upper limits for any possible latitudinal variations on the night side: ±1.5% in the range 60°S–25°N and ±3% for the broader range 80°S–25°N. The lack of detectable latitudinal variations is consistent with a constant with height water profile in the lower atmosphere and probably precludes any strong concentration gradient near the surface.

WATER, O2, AND ICE IN MOLECULAR CLOUDS

We model the temperature and chemical structure of molecular clouds as a function of depth into the cloud, assuming a cloud of constant density n illuminated by an external FUV (6 eV < E < 13.6 eV) flux G_0 (scaling factor in multiples of the local interstellar field). Extending previous photodissociation region models, we include the freezing of species, simple grain surface chemistry, and desorption (including FUV photodesorption) of ices. We also treat the opaque cloud interior with time-dependent chemistry. Here, under certain conditions, gas phase elemental oxygen freezes out as water ice and the elemental C/O abundance ratio can exceed unity, leading to complex carbon chemistry. Gas phase H2O and O2 peak in abundance at intermediate depth into the cloud, roughly A_V~3-8 from the surface, the depth proportional to ln(G_0/n). Closer to the surface, molecules are photodissociated. Deeper into the cloud, molecules freeze to grain surfaces. At intermediate depths photodissociation rates are attenuated by dust extinction, but photodesorption prevents total freezeout. For G_0 < 500, abundances of H2O and O2 peak at values ~10^(-7), producing columns ~10^(15) per cm^2, independent of G_0 and n. The peak abundances depend primarily on the product of the photodesorption yield of water ice and the grain surface area per H nucleus. At higher values of G_0, thermal desorption of O atoms from grains enhances the gas phase H2O peak abundance and column slightly, whereas the gas phase O2 peak abundance rises to ~10^(-5) and the column to ~2x10^(16) per cm^2. We present simple analytic equations for the abundances as a function of depth which clarify the dependence on parameters. The models are applied to observations of H2O, O2, and water ice in a number of sources, including B68, NGC 2024, and Rho Oph.

An upper limit of gaseous water abundance in Chamaeleon-MMS1 as observed with ODIN

Context. The determination of the gaseous water abundances in different intestellar environments is crucial for understanding the oxygen chemistry and its role in the molecular cloud evolution. Aims. The purpose of this study is to estimate water abundance in the protostellar core Cha-MMS1. Methods. The ground-state line of o-H20 at 557 GHz was observed with the ODIN telescope. Two observing runs performed in 2002 and 2003 resulted in an upper limit of TA = 16 mK. A model for the core density and temperature structure was constructed using a 1.3 mm continuum map from SEST/SIMBA. The water abundance profile through the cloud was derived and water line intensities expected from this model were calculated. Results. An upper limit of 7 × 10 −9 was derived for the average fractional o-H2O abundance (relative to H2). The non-detection is consistent with an abundance profile where a high fractional abundance (∼10 −7 ) is reached in the low-density envelope of the core. According to our radiative transfer calculations, the detection of the 557 GHz line from a quiescent core should severely be hampered by self-absorption. Therefore the present observations do not put hard contrainst on the H2O abundance.

Origin of oxygen species in Titan's atmosphere

The detection of O+ precipitating into Titan's atmosphere by the Cassini Plasma Spectrometer (CAPS) represents the discovery of a previously unknown source of oxygen in Titan's atmosphere. The photochemical model presented here shows that those oxygen ions are incorporated into CO and CO2. We show that the observed abundances of CO, CO2 and H2O can be simultaneously reproduced using an oxygen flux consistent with the CAPS observations and an OH flux consistent with predicted production from micrometeorite ablation. It is therefore unnecessary to assume that the observed CO abundance is the remnant of a larger primordial CO abundance or to invoke outgassing of CO from Titan's interior as a source of CO.

Sulfur‐induced greenhouse warming on early Mars

Mineralogical, geological, geophysical, and isotopic data recently returned from Mars suggest that the delivery of sulfur gases to the atmosphere may have played a significant role in the planet's early evolution. Using the Gusev Crater basalt composition and a batch melting model, we obtain a high sulfur solubility, approximately 1400 ppm, in Martian mantle melts. We proceed to explore different scenarios for the pulsed degassing of sulfur volatiles associated with the emplacement of near‐surface dikes during the late Noachian or early Hesperian, when surface pressures are thought to be substantially higher than present. We investigate background Martian atmospheres of 50 and 500 mbar CO2 with varying abundances of H2O and sulfur volatiles (H2S and SO2 mixing ratios of 10−3 to 10−6). Results suggest that these sulfur volatile influxes, alone, could have been responsible for greenhouse warming up to 25 K above that caused by CO2. Including additional water vapor feedback, this process could have raised the early surface temperature above the freezing point for brines and possibly allowed transient liquid water on the Martian surface. Each temperature rise was likely to have been short‐lived, however, due to brief residence times for sulfur volatiles in an optically thin atmosphere.

ABSTRACTS OF OTHER PAPERS FROM ACTA ASTRONOMICA SINICA 49/1 (2008)

Stability of hydrous phases and partial melt chemistry in 13.6 wt.% H2O bearing mantle peridotite are reported in a pressure range up to 24 GPa and a temperature range from 900 to 1400 °C. Various hydrous phases like phase E, phase D, superhydrous B, hydrous β and γ phases of olivine stoichiometry are observed between 14 and 24 GPa. The phase boundary between the β phase and γ phase of olivine under hydrous conditions is found to be at higher pressure than under the dry conditions. The H2O-undersaturated solidus temperature of a model mantle is estimated up to 11 GPa based on (1) the reported solubility of H in nominally anhydrous minerals and (2) linearity of H2O-undersaturated solidus between the dry and wet solidus [Science 276 (1997) 240] with respect to H2O abundance at a constant pressure.Under H2O-saturated conditions at pressures greater than 10 GPa, the (Mg+Fe)/Si atomic ratios of partial melts decrease with increasing temperature: from 2.5 at 1100 °C to 1.6 at 1300 °C at 14 GPa, from 3.3 at 1100 °C to 1.8 at 1300 °C at 17 GPa, and from 2.8 at 1200 °C to 1.7 at 1400 °C at 20 GPa. This is in contrast to the reported constant value of dry partial melts (1.1 between 10 and 18 GPa [J. Geophys. Res. 99 (1994) 17729]). A partial melt coexisting with Mg-perovskite at 24 GPa and 1400 °C has (Mg+Fe)/Si and Ca/Al atomic ratios of 2.2 and 11, respectively. Ultramafic hydrous melts similar to those observed experimentally under uppermost lower mantle conditions may have contributed to chemical differentiation between the upper and lower mantle.

The c2dSpitzerSpectroscopic Survey of Ices around Low‐Mass Young Stellar Objects. III. CH4

CH4 is proposed to be the starting point of a rich organic chemistry. Solid CH4 abundances have previously been determined mostly toward high-mass star-forming regions. Spitzer IRS now provides a unique opportunity to probe solid CH4 toward low-mass star-forming regions as well. Infrared spectra from the Spitzer Space Telescope are presented to determine the solid CH4 abundance toward a large sample of low-mass young stellar objects. A total of 25 out of 52 ice sources in the "Cores to Disks" (c2d) Legacy program have an absorption feature at 7.7 μm, attributed to the bending mode of solid CH4. The solid CH4/H2O abundances are 2%-8%, except for three sources with abundances as high as 11%-13%. The latter sources have relatively large uncertainties due to small total ice column densities. Toward sources with H2O column densities above 2 × 1018 cm−2, the CH4 abundances (20 out of 25) are nearly constant at 4.7% ± 1.6% . Correlation plots with solid H2O, CH3OH, CO2, and CO column densities and abundances relative to H2O reveal a closer relationship of solid CH4 with CO2 and H2O than with solid CO and CH3OH. The inferred solid CH4 abundances are consistent with models where CH4 is formed through sequential hydrogenation of C on grain surfaces. Finally, the equal or higher abundances toward low-mass young stellar objects compared with high-mass objects and the correlation studies support this formation pathway as well, but not the two competing theories: formation from CH3OH and formation in gas phase with subsequent freezeout.

Detection of Extended Hot Water in the Outflow from NGC 2071

We report the results of spectroscopic mapping observations carried out toward a ~1 min x 1 min region within the northern lobe of the outflow from NGC 2071 using the Infrared Spectrograph (IRS) of the Spitzer Space Telescope. These observations covered the 5.2-37 um spectral region and have led to the detection of a number of ionic, atomic, and molecular lines, including fine-structure emission of Si+, Fe+, S++, S, the S(0)-S(7) pure rotational lines of H2, the R(3) and R(4) transitions of HD, and at least 11 transitions of H2O. In addition, the 6.2, 7.4, 7.6, 7.9, 8.6 and 11.3 um PAH emission bands were also observed and several transitions of OH were tentatively detected. Most of the detected line transitions were strong enough to map including, for the first time, three transitions of hot H2O. We find that: (1) the water emission is extended; (2) the extended emission is aligned with the outflow; and, (3) the spatial distribution of the water emission generally follows that observed for H2. Based on the measured line intensities, we derive an HD abundance relative to H2 of 1.1-1.8 10^-5 and an H2O number density of 12-2 cm^3. The H2 density in the water-emitting region is not well constrained by our observations, but is likely between 3 10^4 and 10^6 cm^3, yielding an H2O abundance relative to H2 of between 2 10^-5 and 6 10^-4. Future observations planned for the Herschel Space Observatory should greatly improve the density estimate, and thus our knowledge of the H2O abundance, for the water-emitting regions reported here. Finally, we note a possible departure from the H2O ortho-to-para ratio of 3:1 expected for water formed in hot post-shocked gas, suggesting that a significant fraction of the water vapor we detect may arise from H2O sputtered from cold dust grains.

Parametrization of C-shocks. Evolution of the sputtering of grains

Context: The detection of narrow SiO lines toward the young shocks of the L1448-mm outflow has been interpreted as a signature of the magnetic precursor of C-shocks. In contrast with the low SiO abundances (<10E-12) in the ambient gas, the narrow SiO emission at almost ambient velocities reveals enhanced SiO abundances of 10E-11. This enhancement has been proposed to be produced by the sputtering of the grain mantles at the first stages of C-shocks. However, modelling of the sputtering of grains has usually averaged the SiO abundances over the dissipation region of C-shocks, which cannot explain the recent observations. Aims: To model the evolution of the gas phase abundances of SiO, CH3OH and H2O, produced by the sputtering of grains as the shock propagates through the ambient gas. Methods: We propose a parametric model to describe the physical structure of C-shocks as a function of time. Using the known sputtering yields for water mantles (with minor constituents like silicon and CH3OH) and olivine cores by collisions with H2, He, C, O, Si, Fe and CO, we follow the evolution of the abundances of silicon, CH3OH and H2O ejected from grains. Results: The evolution of these abundances shows that CO seems to be the most efficient sputtering agent in low velocity shocks. The velocity threshold for the sputtering of silicon from the grain mantles is reduced by 5-10 km s-1 by CO compared to other models. The sputtering by CO can generate SiO abundances of 10E-11 at the early stages of low velocity shocks, consistent with those observed in the magnetic precursor of L1448-mm. Our model also satisfactorily reproduce the progressive enhancement of SiO, CH3OH and H2O observed in this outflow by the coexistence of two shocks with vs=30 and 60kms-1 within the same region.

Circumstellar water vapour in M-type AGB stars: radiative transfer models, abundances, and predictions for HIFI

Aims: By performing a detailed radiative transfer analysis, we determine fractional abundances of circumstellar H2O in the envelopes around six M-type asymptotic giant branch stars. The models are also used to predict H2O spectral line emission for the upcoming Herschel/HIFI mission. Methods: We use Infrared space observatory long wavelength spectrometer spectra to constrain the circumstellar fractional abundance distribution of ortho-H2O, using a non-local thermal equilibrium, and non-local, radiative transfer code based on the accelerated lambda iteration formalism. The mass-loss rates and kinetic temperature structures for the sample stars are determined through radiative transfer modelling of CO line emission based on the Monte-Carlo method. The density and temperature profiles of the circumstellar dust grains are determined through spectral energy distribution modelling using the publicly available code Dusty. Results: The determined ortho-H2O abundances lie between 1e-4 and 1.5e-3 relative to H2, with the exception of WX Psc, which has a much lower estimated ortho-H2O abundance of only 2e-6, possibly indicating H_2O adsorption onto dust grains or recent mass-loss-rate modulations. The estimated abundances are uncertain by, at best, a factor of a few. Conclusions: The high water abundance found for the majority of the sources suggests that either the `normal' chemical processes are very effective in producing H2O, or else non-local thermal equilibrium atmospheric chemistry, grain surface reactions, or a release of H_2O (e.g. from icy bodies like Kuiper belt objects) play a role. We provide predictions for ortho-H2O lines in the spectral window of Herschel/HIFI.

Volatile Abundances in Basaltic Magmas and Their Degassing Paths Tracked by Melt Inclusions

The abundances of CO2, H2O, S and halogens dissolved in basaltic magmas are strongly variable because their solubilities and ability to be fractionated in the vapor phase depend on several parameters such as pressure, temperature, melt composition and redox state. Experimental and analytical studies show that CO2 is much less soluble in silicate melts compared to H2O (e.g., Javoy and Pineau 1991; Dixon et al. 1995). As much as 90% of the initial CO2 dissolved in basaltic melts may be already degassed at crustal depths, whereas H2O remains dissolved because of its higher solubility such that H2O contents of basaltic magmas at crustal depths may reach a few percents. Most subduction-related basaltic magmas are rich in H2O (up to 6–8 wt%; Sisson and Grove 1993; Roggensack et al. 1997; Newman et al. 2000; Pichavant et al. 2002; Grove et al. 2005) compared to mid-ocean ridge basalts (<1 wt%; Sobolev and Chaussidon 1996; Fischer and Marty 2005; Wallace 2005). During magma movement towards the surface, exsolution of major volatile constituents (CO2, H2O) causes gas bubble nucleation, growth, and possible coalescence that exert a strong control on the dynamics of magma ascent and eruption (Anderson 1975; Sparks 1978; Tait et al. 1989). Gas bubbles have the ability to move faster than magma (Sparks 1978), particularly in low viscosity basaltic magmas. Bubble accumulation, coalescence and foam collapse give rise to differential transfer of gas slugs and periodic gas bursting (Strombolian activity; Jaupart and Vergniolle 1988, 1989) or periodic lava fountains (Vergniolle and Jaupart 1990; Philips and Wood 2001) depending on magma physical properties and ascent rate. It is also thought that strombolian and lava …

Depths of Partial Crystallization of H2O-bearing MORB: Phase Equilibria Simulations of Basalts at the MAR near Ascension Island (7–11°S)

Phase equilibria simulations were performed on naturally quenched basaltic glasses to determine crystallization conditions prior to eruption of magmas at the Mid-Atlantic Ridge (MAR) east of Ascension Island (7–11°S). The results indicate that mid-ocean ridge basalt (MORB) magmas beneath different segments of the MAR have crystallized over a wide range of pressures (100–900 MPa). However, each segment seems to have a specific crystallization history. Nearly isobaric crystallization conditions (100–300 MPa) were obtained for the geochemically enriched MORB magmas of the central segments, whereas normal (N)-MORB magmas of the bounding segments are characterized by polybaric crystallization conditions (200–900 MPa). In addition, our results demonstrate close to anhydrous crystallization conditions of N-MORBs, whereas geochemically enriched MORBs were successfully modeled in the presence of 0·4–1 wt% H2O in the parental melts. These estimates are in agreement with direct (Fourier transform IR) measurements of H2O abundances in basaltic glasses and melt inclusions for selected samples. Water contents determined in the parental melts are in the range 0·04–0·09 and 0·30–0·55 wt% H2O for depleted and enriched MORBs, respectively. Our results are in general agreement (within ±200 MPa) with previous approaches used to evaluate pressure estimates in MORB. However, the determination of pre-eruptive conditions of MORBs, including temperature and water content in addition to pressure, requires the improvement of magma crystallization models to simulate liquid lines of descent in the presence of small amounts of water.

A spectral line survey of Orion KL in the bands 486-492 and 541-577 GHz with the Odin satellite

We investigate the physical and chemical conditions in a typical star forming region, including an unbiased search for new molecules in a spectral region previously unobserved. Due to its proximity, the Orion KL region offers a unique laboratory of molecular astrophysics in a chemically rich, massive star forming region. Several ground-based spectral line surveys have been made, but due to the absorption by water and oxygen, the terrestrial atmosphere is completely opaque at frequencies around 487 and 557 GHz. To cover these frequencies we used the Odin satellite to perform a spectral line survey in the frequency ranges 486-492 GHz and 541-577 GHz, filling the gaps between previous spectral scans. Odin's high main beam efficiency and observations performed outside the atmosphere make our intensity scale very well determined. We observed 280 spectral lines from 38 molecules including isotopologues, and, in addition, 64 unidentified lines. The beam-averaged emission is dominated by CO, H2O, SO2, SO, 13CO and CH3OH. Species with the largest number of lines are CH3OH, (CH33)2O, SO2, 13CH3OH, CH3CN and NO. Six water lines are detected including the ground state rotational transition o-H2O, its isotopologues o-H218O and o-H217O, the Hot Core tracing p-H2O transition 6(2,4)-7(1,7), and the 2(0, 2)-1(1,1) transition of HDO. Other lines of special interest are the 1_0-0_0 transition of NH3 and its isotopologue 15NH3. Isotopologue abundance ratios of D/H, 12C/13C, 32S/34S, 34S/33S, and 18O/17O are estimated. The temperatures, column densities and abundances in the various subregions are estimated, and we find very high gas-phase abundances of H2O, NH3, SO2, SO, NO, and CH3OH. A comparison with the ice inventory of ISO sheds new light on the origin of the abundant gas-phase molecules.

Regulation of H2O and CO in tropical tropopause layer by the Madden‐Julian oscillation

Impacts of the Madden‐Julian oscillation (MJO) on the water vapor (H2O) and carbon monoxide (CO) abundances in the tropical tropopause layer (TTL) are investigated using Aura Microwave Limb Sounder (MLS) data for November 2004 to May 2005. The effects of the eastward propagation of MJO on H2O and CO abundances in the TTL are evident. Deep convection transports H2O into the upper troposphere up to about the 355‐ to 365‐K level. Around the 365‐ to 375‐K level, a dry anomaly is collocated with a cold anomaly, which is above a warm anomaly located near the region of convection enhancement. Tropical mean H2O at 375 K is regulated by the MJO through convection enhancement and is coherent with the local MJO‐related temperature variation. The locations of dehydration follow the eastward propagation of convection enhancement, and its area extent depends on the phase of the MJO. Enhancement of deep convection associated with the MJO also injects CO from the lower troposphere to the TTL up to 375 K. However, tropical mean CO at 375 K responds instantaneously to the large injection event occurring over the African continent.

Discovery of Interstellar Heavy Water

We report the discovery of doubly deuterated water (D2O, heavy water) in the interstellar medium. Using the James Clerk Maxwell Telescope and the Caltech Submillimeter Observatory 10 m telescope, we detected the 110-101 transition of para-D2O at 316.7998 GHz in both absorption and emission toward the protostellar binary system IRAS 16293-2422. Assuming that the D2O exists primarily in the warm regions where water ices have been evaporated (i.e., in a environment), we determine a total column density of N(D2O) of 1.0 × 1013 cm-2 and a fractional abundance of D2O/H2 = 1.7 × 10-10. The derived column density ratios for IRAS 16293-2422 are D2O/HDO = 1.7 × 10-3 and D2O/H2O = 5 × 10-5 for the hot corino gas. Steady state models of water ice formation, either in the gas phase or on grains, predict D2O/HDO ratios that are about 4 times larger than that derived from our observations. For water formation on grain surfaces to be a viable explanation, a larger H2O abundance than that measured in IRAS 16293-2422 is required. Alternatively, the observed D2O/HDO ratio could be indicative of gas-phase water chemistry prior to a chemical steady state being attained, such as would have occurred during the formation of this source. Future observations with the Herschel Space Observatory satellite will be important for settling this issue.

Molecular line emission in HH54: a coherent view from near to far infrared

Aims. We present a detailed study of the infrared line emission (1–200 µm) in the Herbig-Haro object HH54. Our database comprises: high- (R ∼ 9000) and low- (R ∼ 600) resolution spectroscopic data in the near-infrared band (1–2.5 µm); mid-infrared spectrophotometric images (5–12 µm); and, far-IR (45–200 µm, R ∼ 200) spectra acquired with the ISO satellite. As a result, we provide the detection of and the absolute fluxes for more than 60 molecular features (mainly from H2 in the near- and mid-infrared and from H2O, CO and OH in the far-infrared) and 23 ionic lines. Methods. The H2 lines, coming from levels from v = 0t ov = 4 have been interpreted in the context of a state-of-the-art shock code, whose output parameters are adopted as input to a Large Velocity Gradient computation in order to interpret the FIR emission of CO, H2O and OH. Results. The H2 emission can be interpreted as originating in either steady-state J-type shocks or in quasi-steady J-type shocks with magnetic precursor. However, our multi-species analysis shows that only a model of a J-type shock with magnetic precursor (vshock = 18 km s −1 , nH = 10 4 cm −3 , B = 100 µG, age = 400 yr) can account for both the observed H2 emission and the CO and H2O lines. Such a model predicts a H2O abundance of ∼7 × 10 −5 , in agreement with estimations from other shock models of outflows associated with low mass protostars. We can exclude the possibility that the observed atomic lines arise in the same shock as the molecular lines, and give arguments in favour of the presence of a further high-velocity, fully dissociative shock component in the region. Finally, in view of the forthcoming spectroscopic facilities on board of the Herschel satellite, we provide predictions for H2O lines considered to be the most suitable for diagnostic purposes.

Composition and chemical structure of oceanic mantle plumes

The average compositions (including H2O, Cl, F, and S contents) and chemical structure of oceanic mantle plumes were estimated on the basis of the ratios of incompatible volatile components, potassium, and some other elements in the basaltic magmas of ocean islands (melt inclusions and quenched glasses). The following average concentrations were estimated for the plume mantle: 510 ppm K2O, 520 ppm H2O, 21 ppm Cl, 55 ppm F, and 83 ppm S; these values are significantly higher than those of the depleted mantle (except for S). The abundances of H2O, Cl, and S are lower than in the primitive mantle. The normalized H2O content in the plume mantle is similar to the concentrations of similarly incompatible La and Ce but lower than the concentrations of K2O, Cl, and Sr. This is at odds with the idea of wet mantle plumes. Three types of basaltic magmas corresponding to three types of plume sources (M1, M2, and M3) were distinguished. The concentrations of incompatible elements in these reservoirs were estimated using two models, assuming either an isochemical mantle or a moderately enriched composition of plume material. The latter model gave the following average concentrations of H2O, Cl, F, and S: 130, 33, 11, and 110 ppm for M1, 110, 12, 65, and 45 ppm for M2; 530, 29, 49, and 110 ppm for M3. The plume mantle is not homogeneous, and its heterogeneity is related to the existence of three main compositions, one of which (M1) is similar to the mantle of mid-ocean ridges, and two others (M2 and M3) are moderately enriched in K2O, TiO2, P2O5, F, and incompatible trace elements. The compositions of M2 and M3 are strongly different in H2O, Cl, and S contents. The M2 mantle reservoir is significantly poorer in these components and richer in incompatible trace elements than M3. The plume mantle was formed mainly by the mixing of three sources: ultradepleted mantle, moderately enriched relatively dry mantle, and moderately enriched H2O-rich mantle. In addition to the three main components of the plume mantle, there are probably minor components enriched in chlorine and depleted in fluorine. It is supposed that all these components are entrained into the plume mantle through the mantle recycling of components of the oceanic and continental crust. The established relationships are in agreement with the zonal model of a mantle plume, which includes a hot central part poor in H2O, Cl, and S; an outer part enriched in volatile and nonvolatile incompatible elements; and enclosing mantle material interacting with the plume.

SPICAM IR acousto‐optic spectrometer experiment on Mars Express

The SPICAM IR spectrometer on Mars Express mission (1.0–1.7 μm, spectral resolution 0.5–1.2 nm) is dedicated primarily to nadir measurements of H2O abundance. It is one of two channels of SPICAM UV‐IR instrument. In this spectrometer we applied for the first time in planetary research the technology of an acousto‐optic tunable filter (AOTF) that allowed unprecedented mass reduction for such an instrument: 0.75 kg. SPICAM IR is a point nadir‐looking spectrometer with sequential scanning of the spectrum by the AOTF. Sun occultations are performed with a help of dedicated solar port. We describe instrumentation, calibrations, and the modes of operations of the device and discuss its in‐flight performances. A brief overview of the scientific measurements includes water vapor measurements and the mapping of intensity of the O2(a1Δg) emission at 1.27 μm, described in detail in separate papers. Measurements in reflected solar light allow clear detection of H2O and CO2 ices on the surface or in the atmosphere of Mars. We discuss solar occultation measurements by SPICAM and present resulting vertical profiles of aerosol optical depth.

What Have We Learned from SWAS?

The Submillimeter Wave Astronomy Satellite (SWAS) has recently completed 5.5 years of successful operation. Among the legacies of the mission has been a greater understanding of the abundance and spatial distribution of H2O and O2 within molecular clouds. We summarize SWAS results and discuss how the measured low abundance of water vapor and non-detections of molecular oxygen are suggestive of a general lack of atomic oxygen in the dense centers of molecular clouds. We also present a new more comprehensive model for the oxygen chemistry in the interstellar medium.

Uptake of CO2, SO2, HNO3 and HCl on Calcite (CaCO3) at 300 K: Mechanism and the Role of Adsorbed Water

All experimental observations of the uptake of the four title compounds on calcite are consistent with the presence of a reactive bifunctional surface intermediate Ca(OH)(HCO3) that has been proposed in the literature. The uptake of CO2 and SO2 occurs on specific adsorption sites of crystalline CaCO3(s) rather than by dissolution in adsorbed water, H2O(ads). SO2 primarily interacts with the bicarbonate moiety whereas CO2, HNO3 and HCl all react first with the hydroxyl group of the surface intermediate. Subsequently, the latter two react with the bicarbonate group to presumably form Ca(NO3)2 and CaCl2.2H2O. The effective equilibrium constant of the interaction of CO2 with calcite in the presence of H2O(ads) is kappa = deltaCO2/(H2O(ads)[CO2]) = 1.62 x 10(3) bar(-1), where CO2 is the quantity of CO2 adsorbed on CaCO3. The reaction mechanism involves a weakly bound precursor species that is reversibly adsorbed and undergoes rate-controlling concurrent reactions with both functionalities of the surface intermediate. The initial uptake coefficients gamma0 on calcite powder depend on the abundance of H2O(ads) under the present experimental conditions and are on the order of 10(-4) for CO2 and 0.1 for SO2, HNO3 and HCl, with gamma(ss) being significantly smaller than gamma0 for HNO3 and HCl, thus indicating partial saturation of the uptake. At 33% relative humidity and 300 K there are 3.5 layers of H2O adsorbed on calcite that reduce to a fraction of a monolayer of weakly and strongly bound water upon pumping and/or heating.