Blast Furnace Slag Research Articles

Incorporating Limestone Powder and Ground Granulated Blast Furnace Slag in Ultra-high Performance Concrete to Enhance Sustainability

Abstract While ultra-high performance concrete (UHPC) offers numerous advantages, it also presents specific challenges, primarily due to its high cost and excessive cement content, which can pose sustainability concerns. To address this challenge, this study aims to develop cost-effective and sustainable UHPC mixtures by incorporating ground granulated blast furnace slag (GGBFS) and limestone powder (LP) as partial replacements for portland cement. Eight fiber-reinforced UHPC mixtures were investigated, with a water-to-cementitious materials (w/cm) ratio of 0.15. In four of the UHPC mixtures, 25% of the cement was replaced with GGBFS, and further, LP was added as a mineral filler, partially substituting up to 20% of the cement. In the remaining four mixtures, cement was replaced with only LP up to 20% (without GGBFS). The 28-day compressive strength of the UHPC mixture with 25% GGBFS and 20% LP was 149 MPa, 3.50% lower than the mixture without GGBFS. Its 28-day flexural strength decreased by 30%. Increasing LP replacement reduced drying and autogenous shrinkage, with a 29% shrinkage reduction at 20% LP replacement. Moreover, UHPC mixtures with GGBFS exhibited lower shrinkage compared to those without GGBFS for all LP replacements up to 20%. For evaluating the sustainability of UHPC mixtures, the cement composition index (CCI) and clinker to cement ratio (CCR) were determined. For 20% LP replacement with 25% GGBFS, CCI was 3.6 and the CCR was 0.5, 38% decrease from the global clinker to cement ratio. Overall, 20% LP replacement UHPC mixtures with and without GGBFS can produce UHPC class performance and reduce the environmental impact.

Characterization and Tribology Performance of Refractory Materials Coatings with Blast Furnace Slag (BFS) Fabricated by Thermal Spraying

Characterization and Tribology Performance of Refractory Materials Coatings with Blast Furnace Slag (BFS) Fabricated by Thermal Spraying

Assessing the Drying Sensitivity of Alkali-Activated Binders Through Mechanical Reliability: Effect of Particle Size and Packing

Despite the steady progress of research on the alkali activation of wastes or subproducts from established industrial processes, the brittleness of the hardened alkali-activated materials frequently results in questionable mechanical reliability, particularly in industrial applications beyond construction materials. This work used a 33 factorial Design of Experiments to examine the effect of three different particle size distributions on the compressive strength and mechanical reliability (Weibull modulus) of a sodium silicate-activated blast-furnace slag under the same processing conditions. As expected, curing temperature and time were strongly correlated, and the corresponding response surfaces showed that, for all studied particle sizes, compressive strengths above 60 MPa with mechanical reliability above 5.0 could be obtained by curing at ~60 °C for ~40 h. The particle size differences caused no significant changes in the extent of alkali activation, as seen in the infrared-spectroscopy results. However, the intersection of the response surfaces showed that a coarser and narrower particle size distribution extended the working area (time × temperature) and favored mechanical reliability. Thus, the precursor’s particle size distribution, which governs particle packing and viscosity during processing, also determines the permeability of the set binder, which affects water removal during drying and the dried binder’s mechanical performance.

Experimental and modelling analysis of waste material-based geopolymer concrete incorporated with crumb rubber particles

Rubberized geopolymer concrete (RuGPC) emerges as an eco-friendly alternative to conventional concrete, significantly reducing greenhouse gas emissions. This study investigates the use of steel slag (SS) in varying proportions (30 %, 35 %, and 40 %) as a replacement for ground granulated blast furnace slag (GGBS) in geopolymer concrete, with crumb rubber (CR) replacing crusher dust (CD) as fine aggregate due to its increasing demand. The research focuses on understanding the impact of aluminosilicate materials on the mechanical, thermal, and microstructural properties of geopolymer concrete cured at 60°C. Advanced characterization techniques, including Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDX), X-ray Diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR), were employed. SEM and EDX analyses revealed that the microstructural properties of GGBS and SS materials, mainly Na/Si, Si/Al, H₂O/Na₂O, and Na/Al ratios, significantly influence RuGPC performance through gel formation. FTIR analysis indicates a shift in the stretching vibrations of GGBS and SS to lower wavenumbers due to geopolymerization changes. XRD results show the formation of C-S-H gel at around 27–30° 2theta, attributed to increased GGBS and SS content. Despite efforts to incorporate CR into geopolymer matrices, challenges in mitigating strength degradation persist. To address this, a predictive model was developed to understand the key factors affecting RuGPC performance. Six machine learning techniques—M5P (pruned and unpruned), random forest, random tree, linear regression, and support vector machine with various kernels (PUK, RBF, PK, and NPK), and artificial neural network (ANN)—were employed to predict the physical and thermal behavior of RuGPC. The analysis identified ANN-based models as the most effective. Sensitivity analysis highlighted the grade of rubber and the CR replacement percentage by volume of CD as the most influential parameters determining RuGPC compressive strength, density, and thermal conductivity. Moreover, The economic analysis revealed that RuGPC mixtures were 1.2–11.61 % more cost-effective than OPC concrete. These findings underscore the importance of predictive model development in optimizing RuGPC properties for practical applications, offering valuable insights for decision-making processes.

Whole‐Life Embodied Carbon Reduction Strategies in UK Buildings: A Comprehensive Analysis

ABSTRACTThis paper presents a detailed analysis of embodied carbon (EC) in various case studies using life cycle assessment (LCA) methodology. Through comprehensive assessments, including modules A, B and C, the study evaluates EC across different stages of building life cycles. This study also considers the EC savings achievable through current end‐of‐life strategies in the UK context. As Module A accounts for the highest EC in the case studies, the majority of reduction strategies should focus on this stage. The most impactful strategy for reducing EC emissions involves incorporating Ground Granulated Blast Furnace Slag (GGBS) as a replacement for cement. This approach has the potential to achieve a substantial reduction in the EC of concrete within the buildings under investigation, ranging from 60% to 70%. The study reveals that specification strategy can lead to significant Whole Life Embodied Carbon (WLEC) reductions, with the residential building achieving a 30.59% reduction, the college building a 46.86% reduction, and the hotel building a reduction of 23.69%. Effective mitigation strategies, such as utilizing recycled and reclaimed materials, demonstrate promising results, showcasing significant reduction in WLEC emissions in the buildings.

An investigation on workability and strength on compression of GPC with addition of different aspect ratio glass fibers

The heating of limestone and other materials to high temperatures to produce Ordinary Portland cement (OPC), a key component in concrete releases of carbon dioxide CO2 which makes the construction industry a notable contributor to greenhouse gas emissions. The search for more sustainable alternatives has led to the exploration of alkali-activated materials as a replacement for OPC. Alkali-activated materials are a class of binders that can be used in concrete production without the need for traditional cement. These materials often include industrial by-products such as fly ash, GGBFS (sometimes also called GGBS) (Ground Granulated Blast Furnace Slag), and other waste materials. The development and adoption of alkali-activated materials represent a promising avenue for reducing the environmental impact of the construction industry. On-going research and collaboration are crucial to addressing technical challenges and promoting the widespread use of these alternative binders. The exploration and utilization of alternative materials such as GGBFS, fly ash, and geopolymer concrete play a crucial role in mitigating the environmental impact of the construction industry, particularly in terms of reducing CO2 emissions and utilizing industrial by-products effectively. A good concrete mix is obtained from combination of different size of aggregates. Addition of fibers plays a crucial role in enhancing the tensile strength of concrete. Similar synergy of addition of different aspect ratio of optimum dosages fibers as of different size of aggregates may improve strength and ductility of concrete. Short fibres can stop the propagation of micro-cracks with enhancement of toughness, and long fibres can stop the propagation of macro-cracks. From the aforementioned perspective, it is preferable to add the same volume of fibre with a different aspect ratio to improve the pre- and post-cracking performance of concrete. It also aids in boosting maximal strength.This study aims in preparing geopolymer concrete with graded glass fibres in order to investigate improvement the strength in compression and workability.

Self-Compacting Mixtures of Fair-Faced Concrete Based on GGBFS and a Multicomponent Chemical Admixture—Technological and Rheological Properties

The use of superplasticizers in a self-compacting concrete mix without the addition of a foaming agent in practice leads to a well-known problem associated with increased air entrainment and promotes the formation of harmful large bubbles, high-void content, and ununiform appearance. This paper presents research on the properties of cement paste consisting of Ordinary Portland Cement (OPC), powder based on ground granulated blast furnace slag (GBBS), and superplasticizer. The methodology of this study was the estimation of flow diameter and flow time, as well as the evaluation of the rheological characteristics. The influence of ground granulated blast furnace slag and polycarboxylate plasticizer on the flowability and viscosity of cement paste was studied. The effect of superplasticizer (SP) based on polycarboxylate esters (PCE) anti-foaming agent (AFA) based on a glycol ester and air-entraining admixture (AEA) based on an amphoteric surfactant on flowability, viscosity, rheological properties and the strength of the cement paste was evaluated. It was found that the increase of slag content in cement paste (25%) with the presence of superplasticizer (0.64%) significantly changes the flowability and viscosity. It was stated that the addition of 0.04% anti-foaming agents increases flowability (20%) and reduces viscosity (44%) of cement paste. It was stated that the addition of small dosages of glycol ester-based anti-foaming agent (0.02 and 0.04%) significantly changes the rheological properties, decreases the shear yield stress by 2.1–2.8 times, the plastic viscosity by 2.4–2.6 times and apparent viscosity 1.6–2.5 times, improves the compressive strength at the age of 1 and 7 days by 2.5 and 1.4 times, respectively. The addition of air-entraining admixture led to a decrease in the plastic viscosity by 1.2–1.4 times. It was stated that the presence of air-entraining admixture assists in increasing the apparent viscosity by 1.7–2.4 times. It was shown that the presence of complex admixtures of various origins, purposes, and mechanisms of action would assist in predicting the behavior of concrete mixtures under the conditions of the building site and reduce the consumption of polycarboxylate esters due to the enhancing plasticizing effect of anti-foaming agent and air-entraining admixture.

Effect of Different Supplementary Cementitious Materials on Concrete Workability

Supplementary cementitious materials (SCMs)are used for to increase the strength of concrete. The supplementary cementitious materials like fly ash and GGBS (ground-granulated blast-furnace slag) are using in this project. Supplementary cementing materials hardened concrete through pozzolanic activity. In this project the comparing of regular concrete block with Supplementary cementitious materials like fly ash and GGBS (ground-granulated blast-furnace slag). The quantity of fly ash and GGBS is 0%, 10%, 20% and 30%. To compare the block taking the test like workability and strength test. For workability the slump cone test is taken and for strength test the compression test is taken. Portland cement has a high carbon footprint. Using alternative Supplementary cementitious materials for block production might reduce the carbon footprint and price.

Optimizing sustainable concrete mixes with recycled aggregate and Portland slag cement for reducing environmental impact

Concrete is the world’s most extensively manufactured material, with the integration of recycled materials becoming crucial for sustainable construction. This study investigates the mechanical properties of concrete mixes containing Recycled Aggregates (RA) and Portland Slag Cement (PSC) to understand their suitability for sustainable construction applications. Utilizing normal-strength concrete with a compressive strength of 35 MPa and a 0.45 water-to-cement ratio, fifteen mix designs were tested, varying RA and PSC replacement levels from 0 to 100% and 0% to 50%, respectively. Comprehensive mechanical testing, including compressive and tensile strength assessments at 7 and 28 days, alongside modulus of elasticity and stress–strain curve evaluations, was conducted. The results reveal that full replacement of Natural Aggregate (NA) with RA decreased compressive strength by 10% and modulus of elasticity by 20%. However, a partial replacement of 25% of Ordinary Portland Cement (OPC) with PSC, in the presence of RA, moderated the reduction of compressive strength to 0.92% and increased the modulus of elasticity by 3.7%. The optimum mix, consisting of 75% OPC, 25% PSC, and 50% RA, significantly enhances concrete’s mechanical properties, recommending it for reinforced concrete applications due to its potential environmental and structural benefits.

Development of an eco-friendly geopolymer mortar using slag and fly ash with high bentonite content for thermal and environmental applications

The construction industry is exploring the use of low-cost waste materials to create eco-friendly geopolymer mortar binders. Our study aims to develop various environmentally friendly geopolymer mortar mixes for thermal and adsorption applications using natural materials like bentonite and industrial by-products such as ground-granulated blast furnace slag and fly ash. Ternary geopolymer mortar pastes are prepared using equimolar amounts of slag (GBFS) and fly ash (FA), with 6%, 8%, 10%, and 12% weight of bentonite (BC) from the total geopolymer weight to study the bentonite replacement effect. The prepared mortar are tested for their physico-chemical, mechanical, adsorption, and thermal stability properties (300 °C to 900 °C). The adsorption behavior of eco-friendly geopolymer mortar mixes against crystal violet dye in aqueous solutions is also identified. The study found that adding 6% bentonite to the slag/fly ash-based geopolymer mortar mix yielded the highest mechanical characteristics. Moreover, all the ternary geopolymer mortar mixes exhibited excellent thermal stability up to 900 °C. In adsorption study, the results indicated that the mortar mixes had excellent capacities and adhered well to the Freundlich isotherm model, suggesting potential applications in treating wastewater. Using bentonite in slag/fly ash geopolymer mortar offers a sustainable, cost-effective, and heat-resistant alternative to traditional cement binders.

Fresh, hardened properties and microstructural analysis on the effect of NaOH molarities of industrial by-products based self-compacting geopolymer concrete

AbstractThe sodium hydroxide (NaOH) molarity in Self-compacting geopolymer concrete (SCGC) is essential for activating the precursor and aggregate to develop strength, workability, and microstructure. In this study, SCGC mixes prepared with 50% fly ash (FA) and 50% ground granulated blast furnace slag (GGBS) to investigate fresh and hardened properties with NaOH molarities (M) ranges from 8 to 16, the ratio of Na2SiO3 to NaOH kept constant at 2.5 and ratio of alkaline solution to the binder at 0.45 with 2% SP for the polymerization process. SCGC workability studies indicate the NaOH concentration increased, the slump flow decreased, and 14 M was the optimum molarity. The compressive, split tensile, and flexural strength results showed 39.4 MPa, 4.72 MPa, and 5.91 MPa at 28 days. The C–S–H gel enhanced the strength qualities studied from Fourier transform infrared spectroscopy. The scanning electron microscope showed microstructural densification of the entire system, which improved with the NaOH concentration, and the strength increased with the degree of polymerization and polycondensation. Hence, based on workability, the optimized NaOH concentration is 14 M with binder contents of FA (50%) and GGBS (50%). This study helps to improve the microstructure and strength properties with potential cost implications of SCGC.

Experimental studies on strength and workability of mineral admixture modified cement-based fibre-reinforced self-compacting concrete

ABSTRACT Mineral admixtures such as fly ash (FA), ground granulated blast furnace slag (GGBS), metakaolin (MK), and silica fumes (SF) derived from industries are often referred to as secondary cementitious materials, as partial replacements for cement. Also, the use of fibres significantly enhances the flexural behaviour of concrete. Various kinds of literature highlight the performance of concrete with one or two types of admixtures. In this study, an attempt is made to explore the effect of the use of more than two admixtures viz. FA, GGBS and MK as a partial replacement to cement and fibrofor fibre (FF) on workability and strength properties of based Fibre-Reinforced Self-Compacting Concrete (FRSCC). The FF in Self-Compacting Concrete (SCC) is varied from 1.0 to 2.0 kg/cum. The SCC samples are tested for three curing durations. Based on the experimental investigations, the workability of all the mixes is found to be within the EFNARC limits. The variation in the compressive strength of SCC for various fibre dosages is within 10%, after 28 days of the curing period. It is noted that A-10 mix with fibre dosage of 1.0 Kg/cum yielded the highest compressive, split tensile, and flexural strengths after 56 days of curing, as compared to that of all other variations including conventional SCC mix.

Enhancement of Mechanical Properties of Geopolymer Ferrocement through Incorporation of a Novel Binder and through Optimization of Alkaline Activator Ratios

Geopolymer ferrocement is geopolymer mortar, reinforced with wire mesh. The ratios of binder composition and alkaline activator, with which the geopolymer has been prepared, have profound influence on the mechanical performance of geopolymer ferrocement. In this study the influence of a binder material Alccofine and variation in ratios of alkaline activators have been studied for their effect on mechanical properties of geopolymer ferrocement. Alccofine was replaced with varying proportions of Ground Granulated Blast-Furnace Slag (GGBS). The molarities of NaOH and NaOH/Na₂SiO₃ ratios were also variated to find their influence on strength and crack control of ferrocement, when combined with single, double, and triple-layers of ferro mesh configurations. Tests such as direct shear test, three-point bending, and four-point flexural tests were conducted to to measure shear strength, flexural strength and to estimate region of pure bending. It was observed that the mix with 20% Alccofine and 80% GGBS, an A/B ratio of 0.5, and a NaOH/Na₂SiO₃ ratio of 1.5 yielded a compressive strength of 50 MPa at 90 days of geopolymer ferrocement. Also the triple-layer mesh configuration exhibited the best results, achieving 10 N/mm² in shear strength and 12 N/mm² in flexural strength, compared with other configurations. These findings indicate that by incorporation of Alccofine, optimizing binder composition, activator ratios and reinforcement, the strength parameters of geopolymer ferrocement can be significantly improved.

Fluidized solidified soil using construction slurry improved by fly ash and slag: preparation, mechanical property, and microstructure

Abstract Fluidized solidified soil (FSS) is a cement-based engineering matergood working performance and mechanical properties. Based on fixed cement and desulphurisation gypsum (DG), fly ash (FA) and ground granulated blast furnace slag (GGBS) were added as admixtures to the construction slurry to prepare three types of FSS: namely cement-GGBS-DG FSS (CGD-FSS), cement-FA-GGBS-DG FSS (CFGD-FSS), and cement-FA-DG FSS (CFD-FSS). Considering 7 d, 14 d, and 28 d three curing times, compressive, flexural, scanning electron microscopy (SEM), and x-ray diffraction (XRD) analyses were conducted to explore the time-dependent mechanical properties and microscopic characterisation of FSS. The mechanical test showed that CFGD-FSS doped with FA and GGBS had better fluidity, compressive strength, and flexural strength than CGD-FSS doped with FA alone and CFD-FSS doped with GGBS. The CFGD-FSS specimen with a cement:FA:GGBS:DG ratio of 30: 10: 40: 20 in the curing agent had the best mechanical properties, i.e., the CFGD01 specimens. It has fluidity of 189 mm, compressive strength of 671 kPa, and flexural strength of 221 kPa with a 28d curing time, which can meet the working requirements of FSS for filling narrow engineering spaces. And compared with other specimens, it has the shortest setting time, which can effectively shorten the construction period. Microscopic analysis showed that a large number of hydration products, such as calcium silicate hydrate, calcium aluminate hydrate, and ettringite (Aft), were well-formed in the FSS, resulting in good mechanical properties, especially for the CFGD-01 specimens. Finally, two empirical models were established to describe the compressive strength–porosity and flexural strength–porosity relationships. Moreover, the investigated data agreed well with the modelling results.

Exploring effects of supplementary cementitious materials on setting time, strength, and microscale properties of mortar

The concept of sustainability has become a crucial concern for safeguarding the planet. The current research has focused on developing affordable and eco-friendly mortar by using industrial wastes. This study explores the use of fly ash (FA) and ground granulated blast furnace slag (GGBFS), byproducts of steelmaking and coal burning, in mortar production. It examines their impacts on the compressive strength and setting times, when utilizing varying proportions of the materials. The study also evaluates water requirements for the workability, thus demonstrating the sustainability of these waste products in construction. The cementitious materials were employed in finely ground form and were replaced with further tertiary mixes including both supplements at 10%, 30%, and 50% of each. The mixtures were allowed to cure for 7, 14, and 28 days by immersion in water. The results showed improvements in the compressive strength of mortar samples incorporating FA and GGBFS at various curing ages. However, the water requirement and workability of mortar samples were altered as a result of utilizing these supplementary cementitious materials (SCMs). These findings will serve as a standard for environmentally responsible mortar using GGBFS and/or FA as SCMs.

Cooperative stabilization of calcium carbonate powder, blast furnace slag, and white cement in composite concrete: Volume variation and hydration behavior

Volume stability was an important property of white concrete in long-term service. The purpose of this research is that volume stability of composite concrete was advanced by synergy of calcium carbonate powder and blast furnace slag, and its related hydration behavior was revealed. The results manifested that the early shrinkage, dry shrinkage, and creep of calcium carbonate powder-blast furnace slag-based white concrete (C20) were the lowest as content of calcium carbonate powder and blast furnace slag were 20 % and 10 %. Furthermore, early shrinkage, dry shrinkage, creep, and 120-days compressive strength of C20 were 52.49 %, 24.83 %, 22.47 %, and 82 MPa respectively, which superior to those of others white concrete. These results indicated that the long-term volume stability and strength of C20 was optimal. Information of hydration heat showed that accumulate hydration heat about C20 was minimum (226.91 J/g). This find proved that the effects of thermal expansion and cooling shrinkage on the volume of C20 were ameliorated efficiently. The results of microstructure, mineral phase, and pore structure demonstrated that dense degree of white concrete was boosted by flocculation gel product and rod ettringite. Therefore, the volume stability of white composite concrete could be enhanced by synergy of calcium carbonate powder, blast furnace slag, and white cement.

Functionalizing heavy metal contained incinerated sewage sludge ash in recycled glass-based alkali-activated materials for sewer environment

This study evaluates the performance of alkali-activated cement (AAC) mortars in an artificial sewage environment. The mortars, initially prepared with waste glass powder (GP) and ground granulated blast furnace slag (GGBS) in a 50:50 mass ratio, were modified by replacing 10 wt% of GGBS with incinerated sewage sludge ash (ISSA) with the goal of offering a biocidal effect. Comparisons were made with calcium aluminate cement (CAC), metakaolin (MK), and MK combined with zinc ferrite nanoparticles, each at a similar GGBS replacement level. The results showed that only incorporating CAC improved the strength development, achieving compressive and flexural strengths of 62.7 MPa and 7.4 MPa, respectively, at 28 days, while introducing ISSA or MK reduced the compressive strength to 47 MPa and flexural strength to 4.5 MPa. Although heavy metal ions from ISSA or zinc ferrite nanoparticles minimized biofilm thickness, they could not compensate for the reduced strength and increased alkalis leaching. Among all the tested mixtures, the 50GP40GGBS10CAC mixture exhibited superior biogenic acid resistance, possibly due to its Al-rich C-N-A-S-H gel phases (Ca/Si = 0.4, Na/Al = 0.8, Si/Al = 3.4) and refined pore structure (porosity = 3.4 %), making it the most microbial acid-resistant option for sewer rehabilitation.

Utilization of waste phosphogypsum in high-strength geopolymer concrete: Performance optimization and mechanistic exploration

Phosphogypsum (PG) is an industrial waste produced during the manufacture of phosphoric acid. In this study, dihydrate phosphogypsum (DPG), ground granulated blast furnace slag (GGBFS), fly ash (FA), Portland cement clinker (PCC), sulfate alumina cement clinker (SACC), water reducer, sand, and stone were combined to create a phosphogypsum-based geopolymer (PBG) concrete. Concrete mix design was carried out based on the principle of maximum packing density, and the effects of water reducer type, sand ratio, water-to-binder ratio, and DPG content on PBG concrete properties were investigated. Results indicated that compared to SiKa ViscoCrete 540P (SVC 540P) water reducer, Melflux PLUS 1087L (MP1087L) significantly enhanced the performance of PBG concrete. With a water-to-binder ratio of 0.34, a sand ratio of 32.2 %, and a PG:GGBFS:FA ratio of 5:4:1, the 28-day unconfined compressive strength (UCS) of the concrete exceeded 60 MPa. The concrete primarily consisted of phases such as dihydrate gypsum (CaSO4·2H2O), ettringite (Ca6(Al(OH)6)2(SO4)3(H2O)26), polymer (-Si-O-Al-), quartz (SiO2), albite (Na(AlSi3O8)) and Muscovite ((K,Na)Al2(Si,Al)4O10(OH)2). Using two mild alkalis as activators, PBG concrete can avoid the efflorescence often associated with geopolymer preparation and can cure at 20 °C. PBG concrete offers high strength, ease of preparation, and environmental benefits, providing a new avenue for the reuse of PG.

Synthesis of a novel one-part alkali-activated material from solid wastes salt sludge and soda residue

In this paper, salt sludge (SS), a solid waste from sodium hydroxide production, was activated at high temperature for the first time. It was combined with soda residue (SR), a solid waste from sodium carbonate production, as a solid activator to activate the solid aluminosilicate precursor, blast furnace slag (BFS). This process developed a novel one-part alkali-activated material, termed salt sludge and soda residue co-activated blast furnace slag cementitious material (SRB), which effectively utilizes solid wastes. The effects of ratios of calcined SS (CSS) to SR, fine aggregate types, and curing methods on the physical and mechanical properties of SRB were investigated. The composition of the hydration products was characterized using X-ray diffraction (XRD), thermogravimetric analysis (TGA), and fourier transform infrared spectroscopy (FTIR), while the hydration process during the setting stage was examined with 1H low-field nuclear magnetic resonance (1H LF NMR). The influence of mix ratio, fine aggregate type, and curing method on the microstructure of SRB was analyzed using scanning electron microscopy (SEM). The results showed that the synergistic activation of BFS by CSS and SR was significantly more effective than individual activation. At the optimal mix ratio (CSS:SR:BFS = 15:15:70), the 3/28 days compressive strength of SRB was 14.3/53.7 MPa. The primary hydration products were C-(A)-S-H gels, along with Friedel's salt, ettringite, and hydrotalcite crystals. Using manufactured sand (MS) as a fine aggregate reduced mortar fluidity compared to river sand (RS) but enhanced the interfacial transition zone (ITZ) with the hardened paste, resulting in a denser microstructure. Heat curing promoted hydration product generation, increasing early (3 days) strength by a factor of 2.5. However, the rapid accumulation and insufficient diffusion of hydration products adversely affected the later strength.

Enhancing sustainability in concrete construction: Utilizing copper slag for improved properties of geopolymer concrete

Geopolymer concrete (GPC), utilizing aluminosilicate precursor materials as binders, stands as an eco-friendly alternative to Portland cement concrete. These precursors commonly include natural resources like metakaolin, volcanic ash, and industrial solid waste such as fly ash (FA) and ground granulated blast furnace slag (GGBFS). However, despite not utilizing cement, GPC still faces environmental challenges due to the use of natural aggregates, leading to resource depletion. To mitigate this issue, researchers have explored replacing natural aggregates with waste materials, aiding both resource conservation and waste management. Copper slag (CS) is one such waste material with potential as fine aggregate in GPC. This study conducts a comprehensive evaluation of FA-GGBFS-based GPC incorporating CS as fine aggregate, revealing notable enhancements in transport, durability, and strength properties. The optimal replacement of 60 % natural sand with CS in GPC resulted in a 20–25 % increase in compressive strength, a 10–15 % improvement in slake durability, an 18–40 % reduction in water absorption, a 30–39 % decrease in permeable voids, and a 26–47 % reduction in depth of wear, all in comparison to the control specimen made with natural sand only. Thus, incorporating CS as a fine aggregate in GPC is recommended as an effective approach to enhance mechanical performance and durability, while contributing to sustainable construction practices.