Fresh, hardened properties and microstructural analysis on the effect of NaOH molarities of industrial by-products based self-compacting geopolymer concrete

Abstract

AbstractThe sodium hydroxide (NaOH) molarity in Self-compacting geopolymer concrete (SCGC) is essential for activating the precursor and aggregate to develop strength, workability, and microstructure. In this study, SCGC mixes prepared with 50% fly ash (FA) and 50% ground granulated blast furnace slag (GGBS) to investigate fresh and hardened properties with NaOH molarities (M) ranges from 8 to 16, the ratio of Na2SiO3 to NaOH kept constant at 2.5 and ratio of alkaline solution to the binder at 0.45 with 2% SP for the polymerization process. SCGC workability studies indicate the NaOH concentration increased, the slump flow decreased, and 14 M was the optimum molarity. The compressive, split tensile, and flexural strength results showed 39.4 MPa, 4.72 MPa, and 5.91 MPa at 28 days. The C–S–H gel enhanced the strength qualities studied from Fourier transform infrared spectroscopy. The scanning electron microscope showed microstructural densification of the entire system, which improved with the NaOH concentration, and the strength increased with the degree of polymerization and polycondensation. Hence, based on workability, the optimized NaOH concentration is 14 M with binder contents of FA (50%) and GGBS (50%). This study helps to improve the microstructure and strength properties with potential cost implications of SCGC.