The direct synthesis of a binderless nanocrystalline cubic boron nitride (BNNC) from hexagonal boron nitride (hBN) has been developed by using a high-pressure / high-temperature process (HP/HT) with temperatures from 1400 °C - 2200 °C and pressures from 10 GPa - 20 GPa, the resulting BNNC compacts have a high hardness of more than 50 GPa as determined by Knoop-Indentation. A phase content of up to 97 % cBN could be determined by X-ray diffraction (XRD). The average crystallite size of the material is smaller than 100 nm and therefore significantly smaller than the crystallite size of conventional polycrystalline cubic boron nitride (PcBN) cutting materials. Compared to established PcBN cutting materials, the BNNC has an increased hardness and hot hardness and improved temperature stability. Utilization BNNC-based tools with defined cutting edge could provide an excellent alternative for the enhancement of the process limits for the machining of hardened steels and superalloys. This conference contribution will present the latest developments and challenges in the HP/HT direct synthesis of binderless nanocrystalline boron nitride (BNNC) as well as the investigation of its grinding characteristics for the application as cutting insert.
Read full abstract