The impact and significance of renewable energy in developing countries is increasing rapidly in latest years. There is much need of energy dependence to be based on off grid photovoltaic systems in developing countries like Pakistan which are suffering from severe power shortfalls annually and load shedding concern. In this paper, a concept assessment and estimation of standalone photovoltaic system is done for the site of Quetta, Pakistan in comparison to the location of the Copiapo-Chamonate. Copiapo-Chamonate site is situated in Atacama Desert which is often labelled as the best solar irradiation receiving location in the world with maximum solar insolation reaching to 9.28 kWh/m2/day. The systems for both locations is modelled and simulated in PVSYST for a constant load of 11.9 kWh/day with seasonal tilt adjustment. According to the simulation, results of the parameters including performance ratio, solar fraction, energy supplied to the load etc. show that Quetta meet its individual household demand quite efficiently.