In order to investigate the law of basalt fibre to enhance the durability of concrete, this paper selects basalt fibre length as the main factor, supplemented by novel research methods such as neural networks, to study the rule of concrete resistance to multiple types of salt erosion. Tests have shown that large doses of mineral admixtures and basalt fibres can prolong the time that concrete is eroded by salt solutions; the age of maintenance has a small effect on the mechanical and durability of the concrete; the increase in length of basalt fibres enhances the mechanical properties of the concrete, but weakens the durability. This is exacerbated by the mixing of fibres, but the increase is not significant; the effect of length on concrete resistance to mass loss, corrosion resistance factor of compressive strength, and resistance to chloride ion attack is ranked as follows: 6 mm > 12 mm > 18 mm > 6 mm + 12 mm > 6 mm + 12 mm + 18 mm. The opposite is true for effective porosity; the highest compressive strength corrosion resistance coefficient was found in the length of 6 mm, with an average increase of 6.2% compared to 18 mm, and the mixed group was generally smaller than the single mixed group. The average increase in chloride content was 25.1% for length 18 mm compared to 6 mm; the triple-doped L6-12-18 group was the largest, with an average increase of 33.9% in effective porosity over the minimum 6 mm group. Based on the data from the above indoor trials, artificial neural network models and grey cluster analysis were used to predict and analyse the data, and the prediction and categorisation results were accurate and reliable, providing a reference for subsequent studies.