Granitic Intrusions Research Articles

Two stages of gold mineralization in the Hebaoshan deposit: Evidence from the U-Pb dating and trace element geochemistry of rutile, monazite and apatite

The Hebaoshan gold deposit (41.5 t Au @ 3.5 g/t) is located in the southeastern region of the South China Block, central part of the Wuyishan metallogenic belt. The ore-hosting rocks in this area are predominantly Precambrian metasedimentary rocks and Caledonian granitic rocks. Two hydrothermal mineralization stages can be distinguished: a quartz-sericite-pyrite-native gold (stage I) and a chlorite-quartz-sericite-chalcopyrite-electrum (stage II), with hydrothermal monazite and rutile are firstly identified in separate stages. The complex geological history of the region has resulted in ongoing debates regarding the age of gold mineralization and the genesis of the major gold deposits in this area. In order to precisely constrain the mineralization age of the deposit and further establish a genetic model for the ore deposit, LA-ICP-MS U-Pb dating and trace element analysis on accessory minerals were conducted. Based on the textures mineral assemblages, and geochemical features of the accessory minerals, magmatic apatite, hydrothermal rutile, and both magmatic and hydrothermal monazite were identified. The U-Pb ages of magmatic apatite and monazite are determined to be 445.3 ± 15.80, 441.3 ± 15.10 Ma and 446.57 ± 1.03 Ma, respectively, suggesting that these ages represent the emplacement ages of the Caledonian intrusive rocks. The ages of hydrothermal monazite and hydrothermal rutile are determined to be 238.46 ± 2.01 Ma (single-mineral analysis), 238.46 ± 2.01 Ma (in-suit analysis) and 179.54 ± 7.28 Ma, respectively, suggesting that represent two mineralization events during the Late Triassic to early Jurassic in the Hebaoshan area. These data provide new constraints on the mineralization process in the Hebaoshan deposit and excludes the link between gold mineralization and the intrusion of the Caledonian granites. Regionally, It is speculated that the two mineralization events at Hebaoshan are respectively associated with intracontinental orogenic movements between the Yangtze Block and Cathaysia Block, the flat-slab subduction of the Paleo-Pacific Plate (stage I), and the subsequent extensional tectonics related to the collision between the Yangtze Block and Cathaysia Block (stage II).Our study indicates that the timing of multiple episodic mineralization can be constrained by analysis of accessory minerals, which provides a geological basis for better genetic model for the deposit and provide geological evidence for unraveling the relationships between magmatic activities and mineralization events in the region.

Geochronology, geochemistry, and geological evolution of the Troiseck-Floning and Rosskogel nappes (Eastern Alps): unraveling parallels between the Eastern Alps and Western Carpathians

The Troiseck-Floning and Rosskogel nappes are part of the Austroalpine Unit in the eastern part of the Eastern Alps. The nappes are in tectonic contact and comprise Permian to Mesozoic lower greenschist facies metamorphic metasediments, but only the Troiseck-Floning Nappe consists of a pre-Permian crystalline basement (Troiseck Complex) as well. LA-ICP-MS U–Pb zircon ages, Rb–Sr biotite ages and geochemical data unravel the geological evolution of these tectonic units from Neoproterozoic to Mesozoic times. Detrital U–Pb zircon analyses from siliciclastic metasediments of the Troiseck Complex indicate a late Ediacaran to early Cambrian deposition age of the volcanoclastic sequence. The age distribution correlates with a position along the northeastern Gondwana margin. A late Cambrian crystallization age (502.4 ± 6.8 Ma) of granitic intrusions together with evidence for Late Cambrian/Ordovician magmatism and metamorphism indicate a position at an active plate margin. Polyphase overprinting during the Variscan orogeny is recorded by Late Devonian/early Carboniferous pegmatite dikes (~ 353 Ma) that formed after an early Variscan event, while Pennsylvanian ages of overgrowth rims and inherited grains (~ 320 Ma) are evidence for late Variscan metamorphism. Rhyolitic to andesitic volcanic rocks from the Troiseck-Floning and Rosskogel nappes (271–264 Ma) concomitant with intrusions of porphyric granitoids now transformed to augen gneiss (271 Ma) yield evidence for Permian rift-related magmatism that is widely reported from the Eastern Alps and Western Carpathians. Rb–Sr biotite ages (75–74 Ma) indicate Late Cretaceous cooling below c. 300 °C. This relates to Late Cretaceous exhumation of the Troiseck-Floning Nappe following an Eo-Alpine metamorphic overprint at lower greenschist-facies metamorphic conditions. Based on the similar lithostratigraphy, analogous geological evolution and structure, the Troiseck-Floning Nappe represents the lateral extension of the Seckau Nappe. The new dataset also allows for correlations with other basement complexes that occur in the Western Carpathians.

Xenoliths of the bode dike system: evidence for early Devonian arc-type magmatism and late Carboniferous–Permian crust reworking beneath the eastern Harz Mountains (Germany)

Xenoliths recovered from the post-Variscan Bode dike system of the eastern Harz Mountains provide evidence for the existence of an Early Devonian magmatic arc system hidden beneath very low-grade metasedimentary rocks of the Rhenohercynian Zone, but also for Late Carboniferous–Early Permian crust reworking. This interpretation is based on petrographic observations and whole-rock geochemical analyses of granite xenoliths, in addition to results of zircon U–Pb dating and Hf isotope analyses. Zircon grains recovered from variably deformed granite xenoliths yield ages between 419 and 393 Ma, interpreted to reflect the timing of granite intrusion. Rare zircon xenocrysts of Archean (ca. 2.92–2.65 Ga) and Proterozoic age (ca. 1.5 to 0.56 Ga), all with subchondritic εHf420 Ma values (− 0.8 to − 5.5) indicate reworking of older crust. Compilation of age-Hf isotope data further suggests that the pre-Variscan granitoids beneath the Harz Mountains belong to the same magmatic arc system exposed widespread in the adjacent Mid-German Crystalline Zone, and interpreted to result from NW-ward subduction of the Rheic Ocean beneath Avalonia-Baltica. Zircon in xenoliths with granophyric texture yields ages at 400 Ma and 295–310 Ma, indicating re-melting of Devonian granitoid basement during post-Variscan rift-related magmatism, immediately prior to Bode dike intrusion.Graphical abstractLeft: Late Devonian intrusion of magmatic arc granites during NW-ward subduction of the Rheic ocean beneath Avalonia-Baltica. Right: Formation of the Bode dike system and Harz granites during Late Carboniferous-Permian extension.

1.88 Ga granitoids at Sorsakoski, Central Finland: A-type magmatism within the Raahe-Ladoga suture zone

Four quartz monzonite – granite intrusions forming the Sorsakoski granite lithodeme, are found within the Raahe-Ladoga suture zone in Central Finland. The prevailing potassium feldspar megacrystic quartz monzonites and granites form a bimodal association with diorites and gabbros. The granitoids are mainly calc-alkaline, ferroan, per- to metaluminous, and have high Zr and REE contents. Dominant mafic minerals are biotite and hornblende, clinopyroxene and orthopyroxene are locally present. The mafic units display effects of fractionation of clinopyroxene. In our interpretation, these intrusions were emplaced during regional late stages of deformation and post-crystallisation deformation partitioned into major shear zones leaving bulk of the intrusions relatively undeformed. Based on one new (1876 ± 6 Ma) and one pre-existing (1882 ± 5 Ma) U-Pb zircon age determination, the crystallisation age of the granitoids can be assumed at ca. 1880 Ma. Based on mineralogy, petrography, geochemistry, bimodal nature of magmatism and age, we correlate these intrusions to the A-type rocks of the previously described Saarijärvi suite. This shows that the syn-orogenic A-type magmatism extended eastwards beyond the Central Finland Granitoid Complex.

New insights on the formation of the polymetamorphic Felbertal tungsten deposit (Austria, Eastern Alps) revealed by CL, EPMA, and LA-ICP-MS investigation

AbstractThe Felbertal tungsten deposit is the only economic scheelite mine in Europe, yet its genesis is not fully understood. It has been argued recently that the formation of the deposit is most likely related to granitic intrusions of Variscan age, contrasting a previously suggested syn-depositional stratabound origin of Early Cambrian age. Solving this controversy remains challenging due to the polymetamorphic evolution of the deposit, which experienced both Variscan and Alpine metamorphism. In this contribution we present a comprehensive new data set of scheelite major, minor, and trace element concentrations from multiple scheelite generations of the Felbertal deposit along with microstructural observations. Our results show that Mo, Mo/Mn, REE, Y/Ho, Nb, and Nb/Ta in scheelite are variable within the different scheelite generations and are predominantly controlled by the host-rock lithologies on the local scale, whereas in general the data show a strong response to the shift of P, T, and pH upon changing magmatic-hydrothermal to metamorphic conditions. For the first time, we identify remnants of primary scheelite in the Western Ore Zone. The presented data support a magmatic-hydrothermal origin of the first scheelite mineralization during the Variscan orogeny with primary scheelite being characterized by wing-shaped REE patterns with a negative Eu-anomaly, high trace element concentrations, non-chondritic Y/Ho, and high Nb/Ta. Primary scheelite underwent metamorphic/hydrothermal alteration (recrystallization and dissolution-reprecipitation processes) during the Variscan and Alpine orogeny. This case study highlights that indicative mineralization-controlling geochemical ratios like Sr/Mn cannot be applied for polymetamorphic tungsten deposits like Felbertal.

Studies of radioactive minerals and geochemistry of uranium at the granitic rocks of Wadi Um Shillman Area, South Eastern Desert, Egypt

The northwestern part of Gabal Um Ara granitic pluton is represents a good example for uranium occurrence in the southeastern desert of Egypt. Among the different lithologies in the study area, the granitic rocks attract attention for more detailed geological, geochemical and radiometrical studies. Um Ara granitic masses cover an oval outline area of about 300 km2, which is characterised by moderate topography. The granitic rocks are classified as monzogranite and alkali feldspar granite. Both of them belong to the post-orogenic younger granite magmatic activity that intruded the Egyptian shield between 620 and 530 Ma. The intrusion of Um Ara monzogranite and alkali feldspar granite appears to have been controlled by deep-seated tectonic zones and block faulting. The studied area lies at southeast of Aswan City between 22ͦ 38′ 12˝–22ͦ 38′ 34˝ N and 33ͦ 47′ 27˝–33ͦ 48′ 14˝ E. Geochemically, the average concentration of the elements in North Um Ara granite shows that the relative abundance decreases gradually with decreasing incompatibility from Rb to Y. The common features are enrichment in more mobile elements Rb, Th and U. The monzogranite shows the lowest U and Th content, whereas the alkali-feldspar shows an enhanced contents of both elements, with average Th/U ratio = 3.0. the alkali-feldspar exhibits an expanded enrichment of Th relative to U. The U of the alkali-feldspar may be included within the structure of the refractory accessory minerals. The northern part of the Um Ara granitoids has subjected to different types of alterations. The radiometric survey of the northwestern part of Gabal Um area granitic pluton revealed the presence of several radioactive anomalies near the contact with the Dokhan volcanic and metavolcanic rocks in the north. Some visible uranium mineralisation of uranium minerals occur mainly along the NW, NE, E-W and N-S joints, of a highly sheared alkali feldspar-granite. Uranophane is visible secondary uranium mineral, characterised by bright yellow lemon colours and occurs mainly as filling fractures and joints associated with violet fluorite, iron and manganese oxides. The radioactive and accessory minerals studying and X-ray diffraction analysis that of the mineralised alkali feldspar-granite granite in the northwestern part of Gabal Um Ara granitic pluton revealed include the presence of fluorite, zircon, columbite, spessartine garnet whereas, the secondary uranium minerals are represented by uranophane, β-uranophane and kasolite. The hydrothermal origin was proposed as two possible alternatives for this uranium mineralisation.

Zircon U–Pb Dating and Lu–Hf Isotopic Composition of Some Granite Intrusions in Northern and Central Portugal: Constraints on the Emplacement Age and Nature of the Source Rocks

Zircon U–Pb Dating and Lu–Hf Isotopic Composition of Some Granite Intrusions in Northern and Central Portugal: Constraints on the Emplacement Age and Nature of the Source Rocks

Petrogenesis and tectonic setting of the Neoproterozoic Douling dioritic–granodioritic–granitic intrusion in the northern Yangtze Block, Central China

Voluminous Neoproterozoic intermediate to felsic rocks intruded the Neoarchean Douling Complex in the South Qinling Belt of Central China, which may provide new constraints on the controversial issue about the nature of the continental margin of the Yangtze Block during the Neoproterozoic. This study presents zircon U–Pb geochronology, whole‐rock geochemistry and Sr–Nd isotope of the Douling dioritic–granodioritic–granitic intrusion, aiming to clarify its petrogenesis and tectonic significance. The dioritic–granodioritic–granitic rocks yield similar zircon U–Pb ages ranging from 735 to 705 Ma. The enrichment of light rare earth elements (LREEs) and large‐ion lithophile elements (LILEs), and depletion of high‐ field‐strength elements (HFSEs) (e.g., Nb, Ta) are typical features of arc magmatic rocks. The whole‐rock Sr–Nd isotopic compositions show initial 87Sr/86Sr ratios ranging from 0.7034 to 0.7059, and εNd(t) values from −7.3 to −1.4. Elemental and isotopic data suggest that the Neoproterozoic dioritic–granodioritic–granitic rocks were co‐genetic and were generated by partial melting of lower crust materials combined with mantle‐derived melts. The granites were the derivative product of dioritic rocks by fractional crystallization of amphibolite, plagioclase, mica and zircon. Combined with literature data, we infer a subduction‐related setting for the northern margin of the Yangtze Block during the Middle Neoproterozoic, and a tectonic model of accretion along an Andean‐type active continental margin after the collision of the Douling micro‐block with the northern Yangtze Block is further proposed.

Geochemistry, Rb-Sr whole rock age and Sr-Nd isotopic constraints on the Variscan A1-type granite from Azegour area in the Marrakech High Atlas (Moroccan Meseta) and their geodynamic implications

In the northern part of the Marrakech High Atlas (MHA), along the southern Variscan segment of the Western Meseta, a Variscan granitic intrusion crops out, intruding metasediments and meta-volcanosedimentary rocks of Early Cambrian to Ordovician age. A new whole-rock Rb-Sr isochron age of 268 ± 9 Ma for the granite, combined with a previously published whole-rock Rb-Sr radiometric dating (271 ± 3 Ma), reveals a post-kinematic (tectonic) character with regard to the main Variscan deformational event, belonging within the tectonic context of the Moroccan Variscan orogenic belt. Geochemically, the Azegour intrusion is metaluminous to peraluminous and exhibits a calc-alkaline affinity with a ferruginous composition. The massif shows an extremely differentiated character (SiO2 = 77.53–78.14 per cent), K2O and high total alkali contents, FeOt/(FeOt + MgO) and Ga/Al ratios, which have typical characteristics of an A-type granite. In addition, the granite contains high concentrations of LREE (LaN/SmN= 7.9–13.67) relative to HREE (LaN/YbN= 4.81–11.61) and a well-defined Eu negative anomaly (Eu/Eu* = 0.44–0.75). The granitic samples exhibit a strong enrichment of the most incompatible elements (RbN/YbN = 69.84–159.98) and a strong depletion of Ba, Sr, Eu, Nb, P and Ti. These characteristics are similar to those of A1-type granites. The absence of mineralogy typical of an S-type granite, combined with its weakly peraluminous character [A/CNK (molar Al2O3/CaO+Na2O+K2O) = 1,013–1,045], suggest that there is little or no significant involvement of supracrustal sources in the petrogenesis of the intrusion studied. Despite the strongly differentiated character of Azegour granitic rocks samples, their multi-element patterns shows many similarities to those of I-type granitoids, which has led to postulate that the parental liquids of A1-type were derived from partial melting of mafic magmas. The representative samples studied show less depleted εNd(t = 270 Ma)values of –0.94 to –4.85 and lower positive to slightly negative εSr(t = 270 Ma) values of –1.45 to 9.32. The isotopic data suggest that the Azegour granite was emplaced 270 myr ago, apparently generated by partial melting of a mafic/intermediate magma source in the lower crust as a result of the underplating of the asthenosphere mantle-derived Oceanic Island Basalt-like magmas. Alternatively, their isotopic signatures also can be attributed to the interaction and/or hybridisation of basaltic liquids derived from the mantle with these lower crust materials. The generated parental magma probably occurred at deep structural levels and involved fractional crystallisation processes by the separation of a mineralogical association composed of plagioclase + potassium feldspar ± biotite ± amphibole ± sphene ± apatite. The whole-rock Rb-Sr age of 268 ± 9 Ma, whole-rock geochemistry and Sr-Nd isotopic compositions of εNd(t = 270 Ma) and εSr(t = 270 Ma), combined with fieldwork data, suggest that the Azegour granite was emplaced.

First identification of late Mesozoic intraplate magmatism in the Chinese north Tianshan: implications for the orogenic architecture and crustal evolution

The formation and dynamics of granitoids in an intra-continental setting are crucial for understanding the architecture and evolution of continental crust. Here, we report geochronological, geochemical and Sr–Nd–Hf isotopic data for newly discovered late Mesozoic granitic intrusions in the Tianshan belt, northwestern China. These granitoids are I-type granites derived from an igneous precursor and were emplaced at c . 145–132 Ma. They have positive ε Nd ( t ) values and young Nd model ages, together with relatively low Sr/Y ratios, indicating that they might have originated from partial melting of the juvenile lower crust. There is a prominent decoupling between zircon Hf and bulk-rock Nd isotopes, which may have resulted from the early crystallization of Ti-rich minerals. These granitic intrusions also display subduction-related geochemical characteristics, which are probably inherited from Paleozoic crustal sources that were metasomatized by subduction-related fluids. We conclude that these late Mesozoic granitoids were emplaced in an intra-continental setting, and were probably triggered by thermal relaxation owing to crustal shortening and thickening. These data further imply that the Tianshan changed into crustal reworking during the Mesozoic from its prominent crustal growth in the Paleozoic. Supplementary material: LA-ICP-MS zircon U–Pb dating results, whole-rock major and trace element compositions, whole-rock Sr–Nd isotopic data and zircon Lu–Hf isotopic data are available at https://doi.org/10.6084/m9.figshare.c.7167890 Thematic collection: This article is part of the Mesozoic and Cenozoic tectonics, landscape and climate change collection available at: https://www.lyellcollection.org/topic/collections/mesozoic-and-cenozoic-tectonics-landscape-and-climate-change

Application of geological and short wavelength infrared (SWIR) spectroscopy mapping in the Mailong gold deposit, East Kunlun: Implications for exploration targeting

Widespread regolith cover makes it difficult to identify the anomalous size of their mineralogical or geochemical footprint at the surface in gold exploration. Short wavelength infrared (SWIR) spectroscopy with effective identification of clays and other hydrous minerals shows potential application in gold exploration. The detailed geological and short wavelength infrared (SWIR) spectroscopy mapping was conducted in the newly-discovered orogenic-type Mailong gold deposit (13.06 t @ 6.29 g/t Au), East Kunlun, to determine alteration stage and mineral assemblages and discuss the potential values of SWIR spectral in gold exploration.In the Mailong area, magmatic rocks consist of granodiorite, biotite granodiorite, plagiogranite and mafic dikes, and the gold mineralization shows a close spatial and temporal relationship with mafic dikes. The earliest chloritization (chlorite-quartz) is widely distributed in granodiorite, biotite granodiorite and plagiogranite. The following potassic alteration (hydrothermal K-feldspar and quartz) is developed along high-angle fault/fracture, which cut through granodiorite, biotite granodiorite and plagiogranite. The subsequent sulfide alteration (chlorite-muscovite-sulfide-carbonate) overprints the former potassic and chloritization alteration, and shows spatial association with mafic dikes. Native gold occurs in fracture arsenopyrite or associated with minerals such as pyrite, and chalcopyrite during the early sulfide stage. Supergene alteration is characterized by limonite and malachite. At Mailong, the SWIR data indicate that the most abundant alteration minerals (chlorite, white micas and ankerite) mainly occurred in the northern area. White mica Al-OH absorption occurs at longer wavelengths (Pos2200 = 2202.5 ∼ 2203 nm) and higher Illite crystallinity (IC = 1.2 ∼ 3.1) probably reflecting a higher temperature and pH conduit at the bottom of ZK0001 and ZK0801. The sharp shift of IC values near the bottom reflects the control of fault. This area is also situated at the V-shaped intersections of the three granitic intrusions and structural transection, indicating more of a possible hydrothermal fluid channel than a mineralization center. Low-grade Au mineralization (Au = 0.1 ∼ 0.5 g/t) is mainly distributed within hydrothermal channels with higher Pos2200 (mainly 2022.5 ∼ 2203 nm) and IC values (mainly 1.2 ∼ 3.1), while high-grade Au endowment associated with mafic dikes has low Pos2200 (mainly 2201 ∼ 2202.5 nm) and IC values (mainly 0.43 ∼ 1.2). Meanwhile, an equation of distance = -15*IC + 31 (R2 = 0.47) can be summarized for low-grade orebodies vectoring. Integrating geological mapping and spectral data, target areas for high-grade ore bodies can be outlined using the criteria of white mica, shorter wavelength of Al-OH absorption position (Pos2200 = 2201 ∼ 2202.5 nm), lower IC values (IC = 0.43 ∼ 1.2), and chlorite Fe-OH absorption position Pos2250 (>2247 nm) along with occurrences of mafic dikes. This study demonstrates that utilizing the detailed SWIR identification in conjunction with accurate geological mapping has great potential for greenfield exploration of orogenic gold deposits.

Magmatic evolution and metallogenic diversity of the late Cretaceous granites in the Yidun terrane: Constraints from zircon and apatite geochemistry

Porphyry-hydrothermal type Cu-Mo(−W) deposits in the southern Yidun terrane (SYT) and hydrothermal-skarn type Sn-Pb-Zn-Ag deposits in the northern Yidun terrane (NYT) are closely related to late Cretaceous granitic intrusions in time and space. However, the genetic mechanisms and controlling factors responsible for the metallogenic diversity remain unclear. We investigated zircon and apatite compositions of the Sn-Pb-Zn-Ag-associated granites in northern Yidun terrane and the Mo-W-Cu and Mo-Cu-associated granites in southern Yidun terrane. The Cretaceous granites are distributed along a N–S-trending belt having ages ranging from 106 to 73 Ma, with a transition from predominant plagioclase crystallization to amphibole-dominated crystallization. Our data show that the granites from the NYT have lower zircon Eu/Eu* (0.06 ± 0.04), Ce4+/Ce3+, and ΔFMQ (FMQ is fayalite-magnetite-quartz) values compared to the granites in the SYT, indicating that the granites from the NYT are relatively reduced (ΔFMQ = -1.03 ± 1.02) in contrast to the oxidized granites in the SYT (ΔFMQ = 1.10 ± 1.05). Furthermore, apatite can record the volatile compositions of magma before fluid exsolution. Apatites in granites from the NYT with low XF/XCl ratios (≤120) are interpreted to have crystallized from volatile-undersaturated magma. These apatites are characterized by low Cl contents ranging from 0.04 to 0.12 wt% (0.07 ± 0.02 wt%; n = 21) and low SO3 contents of 0.01–0.06 wt%. In contrast, apatites in granite from the SYT with low XF/XCl ratios (≤80) have high Cl contents of 0.05 to 0.34 wt% (0.16 ± 0.07 wt%; n = 52) and SO3 contents of 0.01–0.46 wt%. The chemical compositions of zircon and apatite indicate that the Mo-W-Cu and Mo-Cu-associated granites in the SYT have higher fO2 and melt S contents before fluid exsolution than the Sn-Pb-Zn-Ag-associated granites in the NYT. Therefore, the contrasting magmatic oxidation states and S contents are critical in controlling the metallogenic diversity of the Cretaceous granites in the Yidun terrane. The Xingguolongba and Cuopu granites, first reported in this article, have U-Pb ages consistent with the Rongyicuo and Cuomolong granites. Furthermore, they exhibit similar geochemical properties, such as oxygen fugacity and volatiles, suggesting the possibility of forming Sn-Pb-Zn-Ag deposits.

Archean crustal growth and reworking in the Superior Province, Canada: Insights from whole-rock geochemistry and Nd isotopic data of the La Grande, Nemiscau and Opatica subprovinces

The southeastern Superior Province contains Meso- to Neoarchean (2952–2677 Ma) tonalite-trondhjemite-granodiorite (TTG) suites, volcanic (2773–2703 Ma) and sedimentary (<2724 Ma) supracrustal sequences, and granitoid intrusions (2708–2598 Ma). The region is a key crustal cross-section for understanding the growth, evolution, and stabilization of Archean cratons. Whole-rock geochemistry and Nd isotopic analyses have been performed on TTG suites, volcanic assemblages and granitoid plutons of the La Grande, Nemiscau and Opatica subprovinces. These analyses, combined with existing structural and U-Pb geochronological data, have been used to investigate the extend of the basement within the three subprovinces, their interaction, and the degree of crustal reworking in the southeastern Superior Province.Nd isotope data and zircon inheritance indicate that the TTG suites were generated from: (i) an old crustal domain with Nd model ages at 3.5–3.2 Ga that may represent the southern extension of the Langelier Complex, (ii) a ca. 3.0 Ga domain with isotopically juvenile signatures, and (iii) the reworking of < 3.0 Ga Nd model age TTG suites from the Opatica subprovince. The Nd juvenile signatures of the mafic to ultramafic volcanism at ca. 2773–2756 and ca. 2723–2703 Ma suggest continuous or multiple mantle plume events beneath the southeastern Superior Province, whereas interlayered felsic volcanic rocks were formed from anatectic melting at high pressure. Subsequent magmatism was related to sanukitoid suites (2704–2693 Ma) emplacement that record mantle-TTG melt interactions. Based on a common tectonometamorphic evolution of the three subprovinces from ca. 2756 Ma, previous studies argued that the Mesoarchean TTG suites exposed in the La Grande and Opatica subprovinces represent a single crustal block. The sedimentary belts of the area were deposited in sagduction-type basins formed at ca. 2724–2706 Ma and, within less than 15–20 myr, were buried and metamorphosed up to granulite facies at 2697–2685 Ma during dip-slip-dominated D2. The burial and the following exhumation of these rocks from ca. 2677 Ma may be attributed to the delamination of lower crustal residues, favoring interaction between mantle and TTG melts, and the formation of sanukitoids and anatectic S-type granites. Nd signatures of the 2646–2598 Ma I-type granitic intrusions indicate extensively reworking of TTGs due to crustal thickening during the D3-D4 events.Our study suggests that the Archean tectonic regime recorded in the southeastern Superior Province is the result of mantle plume tectonics. We conclude that the La Grande-Opatica boundary does not represent a major suture zone but rather but rather a fossil boundary within an older extensively reworked crustal block over which the metasedimentary rocks of the Nemiscau and La Grande subprovinces were deposited.

A new conceptual model of the Travale (Italy) enhanced geothermal system: Insights from electromagnetic geothermometry

The paper presents an electromagnetic geothermometer-based two-dimensional temperature model for the Travale (Italy) enhanced geothermal system derived from magnetotelluric and temperature data. Joint analysis of the temperature and electrical resistivity models made feasible a new self-consistent conceptual model of this site, which agrees with available geological data and previous geophysical results. It explains the nature of seismic reflection horizons detected in 1978 and unusual seismicity distribution in depth which could not be properly addressed earlier without temperature predicting beyond boreholes. It is concluded that the heat source feeding this system may be a granitic intrusion located at a depth below 4 km, which corresponds to the isotherm of 600 °C. A sharp temperature gradient above this intrusion forms a contact thermo-metamorphic halo in the depth range of 3–4 km. Assessment of the released fluid volume fraction from the electrical resistivity model indicates that the general amount of thermo-metamorphic and magmatic fluids in the rock-dominated Travale geothermal system is negligible. It is concluded that meteoric waters are the main source of fluids penetrating along normal faults up to 3 km. Despite some supercritical fluids of thermo-metamorphic origin could circulate in the system below this depth, their amount is hardly sufficient for economically justified exploration drilling. The results of the study indicate that building the temperature model of the geothermal area is crucially important for the exploration of enhanced geothermal systems.

Metallogeny and Mineral Exploration – Some Personal Reminiscences

The following personalised narrative aims to document the highlights of my involvement in some of the ground breaking developments in Economic Geology and their direct application to mineral exploration and discovery over the past half century. The story begins with my introduction to geology at secondary school and university, followed by doctoral research based on fieldwork in the Andes of South America. Then, as an employee of the Chilean Geological Survey, I got my introduction to porphyry copper deposits before returning to the UK to take up a post-doctoral research fellowship. This formative period concluded with my starting out as an independent geological consultant to the global exploration and mining industry. These early years happened to coincide with the plate tectonics revolution and its radical implications for metallogeny. I realised that porphyry copper and related deposits are integral parts of volcano-plutonic arcs generated during subduction of oceanic lithosphere, and volcanogenic massive sulphide deposits in ophiolite complexes must have formed at oceanic spreading centres. At approximately the same time, application of K-Ar dating to copper deposits led to definition of metallogenic belts and corresponding epochs in the Andes, and then established the timing of their economically important supergene oxidation and enrichment. Subsequently, using more modern and precise U-Pb zircon and Re-Os molybdenite methods, collaborative attempts were made to determine porphyry copper deposit lifespans and ages of various copper belts, deposits and prospects around the world, including the Zambian Copperbelt. The focus on porphyry copper deposits led first to an appreciation of the linkage between them and subaerial volcanism and the importance of potassic alteration as a major host of hypogene copper mineralisation, and then to geological characterisation of the increasing number of gold-rich examples. Appreciation of the importance of hydrothermal breccias in porphyry copper deposits, including recognition of mineralised diatremes, resulted in a classification scheme for breccias that may be extended to related deposit types. Extensive fieldwork showed that zones of advanced argillic alteration, termed lithocaps, constitute the shallow parts of porphyry copper systems. The role of tectonic uplift in both porphyry copper formation and subsequent supergene modification was also charted. The end result of this body of work was a porphyry copper model that can be used as a basic exploration guide. In response to a marked increase in the world gold price in the late 1970s, more effort was devoted to gold concentrations in magmatic arc terranes, commencing with epithermal gold deposits in the shallow lithocaps of porphyry copper systems. This led to an input to classification schemes for epithermal precious metal deposits and, eventually, to assignment of the three main epithermal types to specific tectono-magmatic settings. After years of speculation, porphyry gold deposits were recognised for the first time in northern Chile, followed by definition of a new gold deposit class in association with relatively reduced granitic intrusions. A magmatic-hydrothermal origin for Carlin-type gold deposits was steadfastly supported over many years, notwithstanding its unpopularity until relatively recently, culminating in a proposal for modern analogues. For decades, metallogenic provinces and corresponding epochs have been widely appreciated, but debate concerning their origin(s) persists. The nature of accompanying magmatism could well provide an adequate explanation for at least some provinces (e.g., tin, molybdenum and possibly silver), but precursor metal enrichment in the lowermost crust and/or subcontinental lithospheric mantle may well be required in the case of gold and copper provinces. The story concludes with brief commentary on mineral exploration, which has been my lifelong (pre)occupation. Requirements for success in mineral exploration are discussed, based primarily on familiarity with the circum-Pacific region, followed by analysis of the types of companies and individuals involved and the burgeoning challenges to the exploration process, which, if not remedied, will have dire consequences for future metal production and global plans for the energy transition. My involvement as a lone practitioner in both mineral exploration and metallogenic research probably says something about my independent character traits, but nonetheless has been largely unstructured and certainly unplanned. I have no hesitation in recommending a similar career path for any recent graduate who relishes adventure and is prepared to endure significant work-life imbalance.

Geology, U-Pb dating and 3D visualisation of late-orogenic Klenov Pluton (Pelhřimov Core Complex, Central European Variscides)

ABSTRACT The geological map of the Klenov Pluton (Moldanubian Batholith), and its 3D visualization, brings the new findings in the context of granite emplacement within late-Variscan settings. The Klenov Pluton has a peraluminous composition resulting from partial melting of metasedimentary sources and subsequent differentiation. The new ages 327.14 ± 0.21 Ma and 327.80 ± 0.37 Ma, reflect the narrow time-span of magma emplacement and cooling. The 327 Ma Klenov Pluton was emplaced syntectonically as a ‘sheet-like’ granite intrusion at depth ca. 10 kilometers during the later stages of the Pelhřimov Core Complex exhumation (at ca. 329 to 327 Ma) associated with ∼N–S oriented compression. Gravity modelling suggests that the Klenov Pluton has an asymmetric shape where its western flank is parallel to the ∼NW moderately dipping Pelhřimov Core Complex. The eastern margin of the Pluton is shallower and has been later modified by ∼SE-side-up normal faulting (Lodhéřov Fault Zone).

Major types, spatio-temporal distribution, and metallogenesis of magmatism-related polymetallic deposits in the Bangonghu–Nujiang metallogenic belt, Tibet

The Bangong–Nujiang metallogenic belt (BNMB) is one of the vital metallogenic belts in the Tibetan Plateau. At present, the metallogenic regularity on the scale of the whole metallogenic belt is still poorly understood. In this contribution, the geological, geochronological, geochemical, and isotopic data of 87 magmatism-related polymetallic deposits in the BNMB have been systematically collected to summarize the metallogenesis of polymetallic deposits in this belt. Our research shows that different segments of the BNMB have distinct metallogenic differences. The western, central, and eastern segments of the BNMB are characterized by the development of abundant Cu–Au, Fe–Cu–Cr–Ni, and W–Pb–Zn deposits, respectively. These various types of magmatism-related polymetallic deposits in the BNMB were formed between 188 Ma and 76 Ma, and the mineralization has two peak periods of 125–110 Ma and 90–75 Ma. The spatio-temporal variation of different types of magmatism-related polymetallic deposits in the BNMB is likely to be constrained by the lithospheric architecture and deep geodynamic processes. The elemental and Sr–Nd–Hf–S–Pb isotopic results indicate that various kinds of mineralization are closely related to relevant magmatism. The Cu–Au mineralization is related to dominantly mantle-derived, highly-oxidized, and less-evolved granitic intrusions; the Pb–Zn–W mineralization is genetically associated with dominantly ancient middle–upper crust-derived, relatively reduced, and highly-evolved granitic intrusions; the characteristics of the ore-causative intrusions related to Fe–Cu–Mo polymetallic mineralization are between those of the above two end members. In combination with previous studies, we propose a comprehensive model that includes four stages (>145 Ma, ∼145–125 Ma, ∼125–105 Ma, and ∼105–74 Ma) to illustrate the Jurassic–Cretaceous tectonic–magmatic–metallogenic evolution history in the whole BNMB.

Depositional cyclicity of lower Cambrian strata in the NW Himalayas: Regional sequence stratigraphy of the Indian passive margin

Lower Cambrian (538-512 Ma) strata have been deposited in the northern Hazara, Kashmir, Salt Range and Zanskar-Spiti basins, which were undergoing subsidence during this period. However, the southern part of the Hazara Basin remained uplifted (Muzaffarabad-Hazara paleo-high, MHP) and acted as a sediment source. Unlike the previous work, the present paper provides an integrated sequence stratigraphic framework of the Lower Cambrian in this region, based on outcrop data, petrography, and well, seismic and gravity data, thereby enabling a correlation among the basins. In the NW Himalayas (Pakistan), the Lower Cambrian strata outcrop in the Salt Range, northern Hazara and Kashmir basins were penetrated during drilling in the Salt Basin (Potwar, Punjab Platform and Bikaner-Naguar basins). Lower Cambrian stratal terminations and subaerial/composite unconformities formed towards the Sargodha paleo-high and the MHP. The Jehlum and Abbottabad groups are well preserved in outcrops of clastic and carbonate sequences. The top of the Khewra/Sangargali sandstone marks an erosional surface and separates two sequences – a progradational and a retrogradational/progradational sequence. The progradational sequence began with sandstone deposition (Khewra and Tanaki Boulder Bed/Sangar Gali formation), just after Khewrite volcanism (538 Ma), with fining upward cycles during a falling stage system tract. Sea level dropped further, as marked by an intraformational subaerial unconformity, and the fluvio-deltaic facies of a lowstand system tract was deposited; this was again capped by a subaerial unconformity. Once subsidence began, a transgressive systems tract developed in a marginal marine setting. Further transgression occurred and a widespread tidalflat was established. These subtidal facies marked the maximum flooding surface in Jutana and Abbottabad formations and a highstand system tract was developed. During the late stages of the highstand system tract the clastic Baghanwala and Hazira formations were deposited and subaerial unconformities were formed at the top and bottom of these formations. The Kashmir Basin remained uplifted during the late stages of the highstand systems tract and no deposition occurred until the Danian. The maximum flooding surfaces of the subtidal facies are correlatable on both shoulders of the MHP. The deposition ceased in the Middle Cambrian with the intrusion of the Mansehra type granites.

The Geochemical Characteristics of Trace Elements in the Magnetite and Fe Isotope Geochemistry of the Makeng Iron Deposit in Southwest Fujian and Their Significance in Ore Genesis

The Makeng iron deposit in southwest Fujian is a significant iron polymetallic deposit containing various types of iron ore, including garnet magnetite, diopside magnetite, and quartz magnetite. The metallogenetic type of the deposit has been a subject of debate, particularly in relation to the genesis of magnetite and the source of iron. In situ microanalysis of trace elements in magnetite from different ores shows relatively low levels of V, Ti, Cu, and Zn, with higher concentrations of Ca and Si, indicating the characteristics of a skarn type deposit. The δ57Fe values of the magnetite range from −0.091‰ to 0.317‰. Combining these data, whole-rock iron isotope analyses, including Juzhou and Dayang granites, diabase, and the Lower Carboniferous Lindi Formation sandstone, suggest that Fe in the magnetite primarily originates from granitic pluton, with potential contributions from diabase and the Lower Carboniferous Lindi Formation sandstone. Combined with field work, these results indicate that Makeng iron deposit is a skarn-type magnetite deposit associated with Yanshanian granitic intrusions. Therefore, the initial ore-forming fluid is postulated to be a high-temperature magmatic hydrothermal fluid with high oxygen fugacity. This fluid infiltrates spaces such as interlayer fracture zones between the Upper Carboniferous Jingshe Formation–Middle Permian Qixia Formation carbonate rocks and the Lower Carboniferous Lindi Formation sandstone, resulting in diverse magnetite ores due to metasomatism. The mineralization process of the Makeng iron deposit is basically the same, as it is composed of typical skarn deposits. Magnetite was mainly formed during calcic skarn formation stage, and this process persisted until the initial phase of the retrograde alteration of skarns. In contrast, sulfide minerals, including molybdenite, sphalerite, and galena, precipitated during the quartz–sulfide stage.

Petrogenesis of the Early Paleozoic Dioritic–Granitic Magmatism in the Eastern North Qilian Orogen, NW China: Implications for Tethyan Tectonic Evolution

Abstract The North Qilian Orogen witnessed the opening, subduction, and closure of the Proto-Tethys Qilian Ocean and the post-subduction of multiple exhumation events from Late Neoproterozoic to Early Paleozoic. The Early Paleozoic dioritic–granitic magmatic suites, prominently exposed in the eastern North Qilian Orogen, offer valuable insights into the evolution of the Proto-Tethys Ocean. However, their petrogenesis, magma source, and tectonic evolution remain controversial. Here, we investigate the Leigongshan, Zhigou, and Dalongcun intrusions and present geochronological, geochemical, and isotopic data, aiming to refine the comprehension of their timing and petrogenesis, which will contribute to understanding the tectonic evolution of the Proto-Tethys Ocean. Zircon U-Pb dating reveals mean ages of 471–427 Ma for these intrusions, consistent with compiled formation ages of dioritic–granitic intrusions in the eastern North Qilian Orogen, indicating close temporal links with the tectonic evolution of the Proto-Tethys Ocean during the Early Paleozoic. The studied magmatic rocks could be categorized into two major types: granitoids and diorites. The granitoids are majorly I-type granitoids that are generated through partial melting of the mafic lower crust and fractional crystallization at the middle-upper crust, with the involvement of mantle-derived materials. The diorites underwent limited crustal contamination and fractionation of hornblende, plagioclase, and some accessory minerals. They were derived mainly from the mixture of fertile mantle and reworked crustal components, with minor contributions from subduction-related slab fluids and sediment melts. In addition, all the studied Early Paleozoic dioritic–granitic intrusions (ca. 471–427 Ma) formed within subduction-related arc settings. Combined with the tectonic evolution of the Early Paleozoic Qilian orogenic system, we interpret these Cambrian to Silurian dioritic–granitic intrusions as tectonic responses to the subduction (ca. 520–460 Ma) and closure (~440 Ma) of the Proto-Tethys Ocean, whereas the Devonian Huangyanghe intrusion witnessed the final stage of extensional collapse of the Qilian orogenic system at ca. 400–360 Ma.