New insights on the formation of the polymetamorphic Felbertal tungsten deposit (Austria, Eastern Alps) revealed by CL, EPMA, and LA-ICP-MS investigation

Abstract

AbstractThe Felbertal tungsten deposit is the only economic scheelite mine in Europe, yet its genesis is not fully understood. It has been argued recently that the formation of the deposit is most likely related to granitic intrusions of Variscan age, contrasting a previously suggested syn-depositional stratabound origin of Early Cambrian age. Solving this controversy remains challenging due to the polymetamorphic evolution of the deposit, which experienced both Variscan and Alpine metamorphism. In this contribution we present a comprehensive new data set of scheelite major, minor, and trace element concentrations from multiple scheelite generations of the Felbertal deposit along with microstructural observations. Our results show that Mo, Mo/Mn, REE, Y/Ho, Nb, and Nb/Ta in scheelite are variable within the different scheelite generations and are predominantly controlled by the host-rock lithologies on the local scale, whereas in general the data show a strong response to the shift of P, T, and pH upon changing magmatic-hydrothermal to metamorphic conditions. For the first time, we identify remnants of primary scheelite in the Western Ore Zone. The presented data support a magmatic-hydrothermal origin of the first scheelite mineralization during the Variscan orogeny with primary scheelite being characterized by wing-shaped REE patterns with a negative Eu-anomaly, high trace element concentrations, non-chondritic Y/Ho, and high Nb/Ta. Primary scheelite underwent metamorphic/hydrothermal alteration (recrystallization and dissolution-reprecipitation processes) during the Variscan and Alpine orogeny. This case study highlights that indicative mineralization-controlling geochemical ratios like Sr/Mn cannot be applied for polymetamorphic tungsten deposits like Felbertal.