Pyrolysis is a very promising thermochemical conversion technology because it can convert the plastic waste into energy, thus providing a strategy to solve the worldwide problem of plastic waste pollution. In this work, a 20 kg scale vacuum distillation tower was used to separate the plastic pyrolysis fuel into 74 fractions at different AET (atmospheric equivalent temperature). As AET increased, the viscosity and TAN of the separated samples increased. The samples from No.1 to No.25 showed similar properties to gasoline, including carbon range: C6 - C11, viscosity range: 0.55–0.72 cSt@ 40 ℃ and HHV: 42–45 MJ/kg. The samples from No.33 to No.48 exhibited kerosene-like properties such as carbon range: C10 - C20, viscosity range: 1.07–2.53 cSt@ 40 ℃ and HHV: 44–45 MJ/kg. The samples over No.60 contained heavy waxy content (> C20) with a high viscosity of 3.12–7.55 cSt@ 40 ℃. After separation, the O/C ratio decreased from 0.033 in plastic pyrolysis oil to 0.001 when the H/C ratio increased from 1.90 to 1.96. GC-MS analysis showed two major chemical groups of paraffins (20–40%) and olefins (16–41%) in all fractions. The evenly blended transparent fuel mixture and its FTIR analysis showed a good miscibility of separated samples and diesel. In addition, the light fractions (Nos.1 ~ 25) can be further upgraded to naphtha because of their similar chemical compositions. Finally, both characteristics of distillates and the AET conditions can be further used for the design of scale-up vacuum distillation setup for targeting desired products.